CN102146257A - Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof - Google Patents
Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof Download PDFInfo
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Abstract
The invention discloses a formaldehyde-resistance odor-removing total-effect environmental-friendly waterborne wood white paint and a preparation technology thereof. The wood white paint comprises the following components in percentage: 25 to 30 percent of formaldehyde removing emulsion, 10 to 15 percent of core-shell pure acrylic acid emulsion and polyurethane modified acrylic acid emulsion, 3 to 5 percent of bamboo carbon powder, 1 to 3 percent of nano TiO2 photocatalyst, 15 to 25 percent of calcium carbonate and pigment and filler, 0.1 to 0.3 percent of delustering powder, 0.1 to 0.2 percent of antifoaming agent, 0.5 to 1.5 percent of dispersing agent, 0.2 to 0.5 percent of anti-sedimentation agent and 18 to 38 percent of water and auxiliaries. The preparation technology comprises the following steps of: firstly adding the core-shell pure acrylic acid emulsion and the polyurethane modified acrylic acid emulsion into a dispersing cylinder and dispersing at an intermediate speed; then uniformly adding micron active bamboo carbon powder; after dispersing for 15 to 30 minutes at a high speed, adding the formaldehyde removing emulsion, scratch resistance wax additive, the water, the dispersing agent, the delustering agent, the antifoaming agent, the anti-sedimentation agent and other components; after dispersing for 40 minutes at an intermediate speed, sampling and detecting the fineness and the viscosity of a finished product; and carrying out filtering, canning and packaging on the finished product.
Description
Technical field
The present invention relates to a kind of aqueous wooden ware white paint; The present invention be more particularly directed to the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective, the invention still further relates to the technology of preparing of the environment-friendly water-based woodenware white paint of a kind of this anti-formaldehyde smell-clearing full-effective.
Background technology
The woodwork coating of domestic existing main flow mainly comprises following several, polyurethane woodware coating (PU), acid cure alkyd amino woodwork coating (Acidcuring), nitrocellulose woodenware coating (NC), UV solidified carpentry coating (UV), water-borne coatings (Waterborne) and several big classifications of polyester woodwork coating (PE).Wherein the polyurethane coating ratio is the highest, next is nitro, UV, alkyd, water-based and polyester lacquer successively.In furniture woodwork coating field, pyroxylin(e)finish is being replaced by water-borne coatings gradually.Water-based system will concentrate on the vinylformic acid single-component.In UV and the dual-component polyurethane.At furniture exporter face, China's policies and regulations do not stipulate clearly that wood furniture can not use solvent based coating at present, but the U.S., European Union and Japan have all put into effect the relevant laws and regulations that limit and ban use of the solvent-borne type woodwork coating.
The solvent-borne type woodwork coating in use owing to the release of organic substance, has brought Health hazard for wood furniture producer and user.
Summary of the invention
The objective of the invention is in order to overcome weak point of the prior art, provide a kind of prescription simple, can effectively anti-formaldehyde, the environment-friendly water-based woodenware white paint of full effect of clean flavor.
Another object of the present invention provides the technology of preparing of the environment-friendly water-based woodenware white paint of a kind of this anti-formaldehyde smell-clearing full-effective.
In order to achieve the above object, the present invention adopts following scheme:
The environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective is characterized in that percentage composition is composed of the following components by weight:
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described color stuffing comprises the filler of 10-15% pigment and 2-5%.
Wherein said pigment can be shades of colours such as Pigment white, Pigment blue, Pigment Yellow 73, Pigment green.Can be independent a kind of, also can be the mixture of multiple pigment.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described filler is for being SiO
2
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described defoamer is the water-based high effective antifoaming agent.The water-based high effective antifoaming agent that described water-based high effective antifoaming agent is model AC-900 is organic-silicon-modified compound defoamer.Belong to the commercially available prod.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described flatting silica is a diatomite.Described diatomaceous characteristic: have characteristics such as porosity is big, absorptivity is strong, chemical property is stable, wear-resisting, heat-resisting, can provide excellent surface property, increase-volume, thickening and raising sticking power for coating.Can isostatic control film coated surface gloss, increase the wear resistance and the mar-resistance of filming, dry, deodorizing and can also purify air sound insulation, waterproof and characteristics heat insulation, that permeability is good.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described anti-settling agent is a polyamide wax.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described auxiliary agent is a siccative, tensio-active agent, auxiliary rheological agents, film coalescence aid, the mixture more than 4 kinds in mould inhibitor or the active film coalescence aid.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described siccative is a dibutyl tin laurate, and its content is 0.03-0.08%; Described tensio-active agent is that its content of fluorocarbon surfactant is 0.02-0.5%; Described auxiliary rheological agents is that its content of tributyl phosphate is 0.6-0.9%; Described film coalescence aid is 0.8-1.5% for Yi Bingchunan content; Described mould inhibitor is that its content of 3-iodo-2 propargyl butyl carbamates is 0.1-0.3%; Described active film coalescence aid is a vinylformic acid double cyclopentenyl oxygen ethyl ester, and its content is 1-5%; Wherein said content is weight percentage.
The technology of preparing of the environment-friendly water-based woodenware white paint of the anti-formaldehyde smell-clearing full-effective of the present invention is characterized in that comprising following processing step:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, evenly sneak into micron order active bamboo powder afterwards, after high speed dispersion 15-30 minute, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, and sampling detects finish fineness and viscosity, filtered, tinning, packing.
Aforesaid technology of preparing is characterized in that the speed that described middling speed is decomposed is 600-800r/min; The speed of described high speed dispersion is 1000-1500r/min.
Aforesaid technology of preparing is characterized in that described finish fineness is 35-50 μ m, and described finished product viscosity is 30-60mm
2/ s.
Dispersion agent described in the present invention is Henkel KGaA 5040 dispersion agents, has good thermotolerance, mutual solubility, efficient height, and stable viscosity prevents the coating precipitation, coagulates wadding.Keep good, nontoxic, the no burn into of glossiness not have special odor.
Aldehydes removal emulsion described in the present invention is LG-DOW chemical industry 3030 emulsions.Have superpower aldehydes removal effect, can effectively decompose formaldehyde in the coating.
Bamboo charcoal powder described in the present invention is a specification: (1000～4000 order) is many as coating class Industrial products raw material.Because the specific surface area of bamboo charcoal increases by geometric progression after the super-fine processing, specific functions such as the absorption of bamboo charcoal, decomposition are also strengthened synchronously.
In the present invention's prescription:
1. preferred clean aldehyde emulsion of water-based and high-performance emulsion binder system
The selection PARA FORMALDEHYDE PRILLS(91,95) has adsorption and can carry out formulating of recipe with the emulsion of formaldehyde generation irreversible chemical reaction.The surface of formaldehyde reaction emulsion or inner residual a large amount of active groups (as amino, carboxyl, epoxy group(ing) etc., all can with formaldehyde generation irreversible chemical reaction).Formaldehyde reaction emulsion and ordinary emulsion all have the ability of certain elimination formaldehyde in indoor air.The mechanism that ordinary emulsion is eliminated formaldehyde is the adsorption of emulsion film PARA FORMALDEHYDE PRILLS(91,95), and this effect is a reversible; And reactive emulsion has the elimination formaldehyde ability more much better than than ordinary emulsion.
The water-borne wood coating system of present domestic formation is mainly based on the pure acrylic acid emulsion, the cold assembly emulsion of modified acrylic acid-polyurethane, binder systems for use such as urethane synthesis modification ACRYLIC EMULSION and polyurethane dispersions.Each binder systems for use has outstanding merits and demerits.Based on extensive collection to emulsion binder system market information and sample, the highly sophisticated products that compile advantage emulsion both domestic and external manufacturing enterprise, experimental design method and Recipe optimization by the advanced person, every performance of comprehensive assessment product, and is analyzed contrast and screened, therefrom optimize the binder systems for use and the sample of several optimums, for the further composite test of test mixing provides concrete advantage base-material sample.
2. mix composite high-performance emulsion binder system and reach maximum synergistic effect
Selection and collocation blend to present binder systems for use, form the base-material compound system, obtain synergistic effect, not only make the relative merits of different binder systems for use reach the effect that remedies mutually, on some performances, obtain simultaneously breaking through, reach a performance on the equal base-material technical foundation and break through.The polyurethane-modified acrylic acid binder systems for use that body series is selected for use will select for use the aliphatic polyurethane modified acroleic acid as a basic base-material, the composite pure acrylic acid emulsion system of going up, give full play to the advantage of the outstanding chemical resistance of the outstanding mechanical mechanics property of aliphatic polyurethane system, anti-yellowing property and vinylformic acid system, by the DOE experiment research of science, determine compound proportion, component concentration and the Recipe optimized the most.Its outstanding discovery is, not only allow two individual system reach the synergistic effect of a mutual supplement with each other's advantages, remedied weak tendency and shortcoming separately simultaneously, thereby when allowing the chemical-resistant of paint film and antiblocking effect satisfy the basic demand of industry standard, its mechanical property, anti-yellowing property etc. all rise to a higher aspect.
3. creatively introduce the clean aldehyde of the bamboo charcoal component of distinguishing the flavor of only, the optimization of C system reaches clean flavor effect
There is microvoid structure in bamboo charcoal, has greater porosity (macrovoid, mesopore and micropore) and high-specific surface area, and obnoxious flavoures such as PARA FORMALDEHYDE PRILLS(91,95), volatile solvent have good physical absorption effect, and the application in coating is more and more.Certainly, physisorption has certain limitation, mainly shows two aspects: the one, there is saturation ratio, and the 2nd, adsorptive power is relevant with temperature.Therefore, removing obnoxious flavoures such as formaldehyde in the room air and volatile solvent by physical adsorption, is practical, effective scheme to a certain extent.
The emulsion building-up process has been used various latex resist technologies, and simultaneously the difference of technology causes the difference of combined coefficient, and it is big even have irritating auxiliary agent and monomer often to have seen in some tastes, and the smell of base-material emulsion is comparatively stimulated; After being made into the coating finished product, the still secular release of taste makes the human consumer be difficult to accept.By with supplier's cooperative development, avoid in the base-material raw material, adding the composition that contains irritating smell, simultaneously by adjusting process with improve combined coefficient, by adopting additional process to reduce the residual quantity of the free monomer in the finished product, the smell of finished product reaches minimum the most at last.On the basis of this advantage emulsion,, make finished product have irritating smell because adding the auxiliary agent of a large amount of stimulation tastes in avoiding filling a prescription by adding the coating composition of preferred low smell, zero VOC (organic volatile component).In order to reach the minimum technical requirements of product odour, replacement has also been cancelled some conventional paint additives, and adopted the clean flavor technical formula platform of our company's uniqueness, jumped out traditional formula system framework, make the storage and the stability of formula for a product be subjected to great challenge, but also make the smell of product absolutely arrive clean flavor requirement.
4. add special auxiliary agent, improve the surperficial scratch resistance effect of water-miscible paint
The more solvent type coating of compactness of the dried paint film of water-borne wood coating low, cause the surperficial scratch resistance effect of paint film generally on the low side, usually stay together significantly scar at smooth coating surface easily in use, thereby destroyed the aesthetic feeling of coating surface because some shaggy hard objects streak fast.When this prescription makes paint film reach the physical and chemical performance an of the best on composite emulsion basis, add a kind of special scratch resistance auxiliary agent, thereby the resistance to marring of coating surface is improved greatly, the scratch resistance effect can match in excellence or beauty with solvent-borne type paint film effect, has improved the durable effect of water-borne wood coating greatly.
In sum, beneficial effect of the present invention:
1. the present invention adopts up-to-date coating technology of preparing and advanced water-base resin system, added the natural radioactivity bamboo charcoal factor, the formaldehyde that energy active adsorption and decomposition chamber inner decoration material discharge, purify various volatile injurant matter such as benzene class, ester class, ketone, can build the lasting pure and fresh living environment of air, can not produce irritating smell after construction process or construction, household's health redoubles one's care.This aqueous wooden ware white paint paint film is plentiful, strong covering power; Its priming paint has good filling properties and sanding property energy, and finish paint has excellent scratch resistance and anti-yellowing property.
2. product of the present invention adopts clean flavor paint technology, has reduced in the Lacquered Tin Plate Can and the amount of the pungency volatile matter of construction process, and the VOC of product reduces greatly simultaneously.The TVOC of white paint product is reduced to 150g/L, is significantly less than the 250g/L that HJ/T 201-2005 requires.The environmental-protecting performance of high-performance water-based woodwork coating has been given prominence in the raising of these performances more.
3. product of the present invention is by advantage latex composite compounding technology, remedied traditional defective that contains the alkali resistance difference of urethane composition, improved the chemical resistance of paint film, complete every chemicals-resistant test that requires by HG/T3828-2006 makes the use of this product have the advantage of weather resistance more.
4. to carry out technology by the base-material that screens various advantage technologies composite in the present invention, given play to synergy, improve the mechanical property of paint film greatly, the wear resistance loss of white paint product is not more than 0.022g (750g/500r), be lower than the standard of the 0.030g that sets among the HG/T 3828-2006, this standard is the standard of indoor solvent-borne type woodwork coating equally.
5. product satisfies industry standard: HG/T 3828-2006 " indoor water-borne wood coating " industry standard.Meet environmental protection standard " environmental labelling product technical requirements: water-borne coatings " HJ/T201-2005.
6. product of the present invention is volatile injurant matter in the decontamination chamber effectively.Has excellent scratch resistance performance.Paint film is plentiful.Has excellent anti-yellowing property.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 2
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 3
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 4
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 5
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Claims (10)
1. environment-friendly water-based woodenware white paint of anti-formaldehyde smell-clearing full-effective is characterized in that percentage composition is composed of the following components by weight:
2. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described color stuffing comprises the filler of 10-15% pigment and 2-5%.
3. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 2 is characterized in that described filler is for being SiO
2
The environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described defoamer is the water-based high effective antifoaming agent.
4. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described flatting silica is a diatomite.
5. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described anti-settling agent is a polyamide wax.
6. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described auxiliary agent is a siccative, tensio-active agent, auxiliary rheological agents, film coalescence aid, the mixture in mould inhibitor or the active film coalescence aid more than 4 kinds.
7. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described siccative is a dibutyl tin laurate, and its content is 0.03-0.08%; Described tensio-active agent is that its content of fluorocarbon surfactant is 0.02-0.5%; Described auxiliary rheological agents is that its content of tributyl phosphate is 0.6-0.9%; Described film coalescence aid is 0.8-1.5% for Yi Bingchunan content; Described mould inhibitor is that its content of 3-iodo-2 propargyl butyl carbamates is 0.1-0.3%; Described active film coalescence aid is a vinylformic acid double cyclopentenyl oxygen ethyl ester, and its content is 1-5%; Wherein said content is weight percentage.
8. the technology of preparing of the environment-friendly water-based woodenware white paint of any anti-formaldehyde smell-clearing full-effective of claim 1 to 7 is characterized in that comprising following processing step:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, evenly sneak into micron order active bamboo powder afterwards, after high speed dispersion 15-30 minute, add clean aldehyde emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, and sampling detects finish fineness and viscosity, filtered, tinning, packing.
9. technology of preparing according to claim 8 is characterized in that the speed that described middling speed is decomposed is 600-800r/min; The speed of described high speed dispersion is 1000-1500r/min.
10. technology of preparing according to claim 8 is characterized in that described finish fineness is 35-50 μ m, and described finished product viscosity is 30-60mm
2/ s.
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| CN 201110123392 CN102146257B (en) | 2011-05-13 | 2011-05-13 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
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|---|---|---|---|
| CN 201110123392 CN102146257B (en) | 2011-05-13 | 2011-05-13 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
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| CN104030604A (en) * | 2014-06-26 | 2014-09-10 | 中山蓝海洋水性涂料有限公司 | Environment-friendly weather-proof fouling-proof stone-like paint and preparation method thereof |
| CN105400258A (en) * | 2015-12-28 | 2016-03-16 | 淄博永辰环境影响评价有限公司 | Heat insulation and environmental protection woodenware paint |
| CN104817961B (en) * | 2014-05-16 | 2017-04-05 | 紫荆花涂料（上海）有限公司 | A kind of anti-formaldehyde aqueous wooden ware bottom surface unification varnish and its compound method |
| CN107201129A (en) * | 2016-05-20 | 2017-09-26 | 南京长江涂料有限公司 | A kind of room-temperature self crosslinking type PUA SiO2Hybridisation emulsion and preparation method thereof |
| CN107779081A (en) * | 2017-11-22 | 2018-03-09 | 广西超盛网络科技有限责任公司 | A kind of special-purpose aqueous coating of wood furniture |
| CN108219614A (en) * | 2018-01-05 | 2018-06-29 | 吕跃文 | Aqueous one-component negative oxygen ion woodware white paint and preparation method thereof |
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| CN104817961B (en) * | 2014-05-16 | 2017-04-05 | 紫荆花涂料（上海）有限公司 | A kind of anti-formaldehyde aqueous wooden ware bottom surface unification varnish and its compound method |
| CN104030604A (en) * | 2014-06-26 | 2014-09-10 | 中山蓝海洋水性涂料有限公司 | Environment-friendly weather-proof fouling-proof stone-like paint and preparation method thereof |
| CN104030604B (en) * | 2014-06-26 | 2016-03-30 | 中山蓝海洋水性涂料有限公司 | True mineral varnish of a kind of weather-proof anti-soil of environment-friendly type and preparation method thereof |
| CN105400258B (en) * | 2015-12-28 | 2018-03-23 | 河北晨阳工贸集团有限公司 | A kind of heat preservation environment protection woodcare paint |
| CN105400258A (en) * | 2015-12-28 | 2016-03-16 | 淄博永辰环境影响评价有限公司 | Heat insulation and environmental protection woodenware paint |
| CN107201129A (en) * | 2016-05-20 | 2017-09-26 | 南京长江涂料有限公司 | A kind of room-temperature self crosslinking type PUA SiO2Hybridisation emulsion and preparation method thereof |
| CN107201129B (en) * | 2016-05-20 | 2019-08-27 | 南京长江涂料有限公司 | A kind of room-temperature self crosslinking type PUA-SiO2Hybridisation emulsion and preparation method thereof |
| CN107779081A (en) * | 2017-11-22 | 2018-03-09 | 广西超盛网络科技有限责任公司 | A kind of special-purpose aqueous coating of wood furniture |
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| CN108219614A (en) * | 2018-01-05 | 2018-06-29 | 吕跃文 | Aqueous one-component negative oxygen ion woodware white paint and preparation method thereof |
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| CN111849329A (en) * | 2020-07-10 | 2020-10-30 | 东南大学 | In-situ-regulated water-based super-amphiphobic coating and preparation method thereof |
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