CN108219614A - Aqueous one-component negative oxygen ion woodware white paint and preparation method thereof - Google Patents
Aqueous one-component negative oxygen ion woodware white paint and preparation method thereof Download PDFInfo
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- CN108219614A CN108219614A CN201810012415.9A CN201810012415A CN108219614A CN 108219614 A CN108219614 A CN 108219614A CN 201810012415 A CN201810012415 A CN 201810012415A CN 108219614 A CN108219614 A CN 108219614A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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Abstract
The present invention relates to a kind of aqueous one-component negative oxygen ion woodware white paints and preparation method thereof.The aqueous one-component negative oxygen ion woodware white paint is made of by weight percentage following components:
Description
Technical field
The present invention relates to a kind of woodware white paint, concretely relate to a kind of aqueous one-component negative oxygen ion woodware white paint and
Preparation method.
Background technology
The height of negative oxygen ion concentration and people's health are closely bound up, and people need negative oxygen ion the moment, especially in dirt
Contaminate today of getting worse.Studied according to environmentalist, in air negative oxygen ion concentration it is per cubic centimeter below 20 when, people
It will feel burnout, feel dizzy;When the negative oxygen ion number in air per cubic centimeter is when between 1000~10000, people
It will feel even-tempered and good-humoured, tranquil stable;When the negative oxygen ion number in air per cubic centimeter is at 10000 or more, people is just
It can feel spirit and QI cleaning, comfortable satisfied;And when the negative oxygen ion number in air per cubic centimeter is up to 100,000 or more, just
Calmness can be played, Zhichuan, dispelling fatigue, adjust the preventing disease theraping effects such as nerve.
And existing woodware white paint cannot largely release negative oxygen ion, even if there have small part that can release to be negative
Oxonium ion, the amount of release also very at least, usually only have 0-50/cm3, it is impossible to meet the needs of people.
Invention content
For the deficiency of the prior art, the present invention provides a kind of aqueous one-component negative oxygen ion woodware white paint and its preparations
Method.
Wherein, the specific technical solution of aqueous one-component negative oxygen ion woodware white paint of the present invention is as follows:
A kind of aqueous one-component negative oxygen ion woodware white paint is made of by weight percentage following components:
Wherein, the sum of weight percent of the above components is 100%.
The aqueous one-component negative oxygen ion woodware white paint of the present invention is by using said components and by the weight of above-mentioned each component
Amount percentage is made, and can have its paint film nontoxic, pollution-free, the harmful substances such as containing benezene, formaldehyde, heavy metal, do not meet
USA and EU standard;It has no irritating odor in work progress or after construction, health environment-friendly;In addition, its paint film is with excellent
Chemical resistance, scoring resistance, non yellowing;It is also outstanding, resistance to dry rapid, strong adhesive force, hardness height, scratch resistance capability
Mill, it is ageing-resistant, can effectively fire-retardant and film it is plentiful the features such as;In addition aqueous one-component negative oxygen ion woodware white paint of the invention
Also have the advantages that easily to construct, not by construction time limit, non-ignitable, not quick-fried, easy storage and transport;And it also is able to sustained release
The negative oxygen ion of high concentration forms the small air negative oxgyen ion of higher concentration.
According to a preferred embodiment, aqueous one-component negative oxygen ion woodware white paint by 60wt% water soluble acrylic acid
Dispersion, the pure water of 6.3wt%, the levelling agent of 0.2wt%, the negative oxygen ion additive of 1wt%, 0.3wt% antifoaming agent,
The coalescents of 8wt%, the pH adjusting agent of 0.2wt%, the titanium dioxide of 20wt%, wax powder/mute powder of 2wt% and the increasing of 2wt%
Thick dose of composition.
According to a preferred embodiment, aqueous one-component negative oxygen ion woodware white paint by 55wt% water soluble acrylic acid
Dispersion, the pure water of 5wt%, the levelling agent of 0.3wt%, the negative oxygen ion additive of 2wt%, 0.2wt% antifoaming agent,
The coalescents of 6.2wt%, the pH adjusting agent of 0.3wt%, the titanium dioxide of 25wt%, wax powder/mute powder of 3wt% and 3wt%
Thickener forms.
According to a preferred embodiment, aqueous one-component negative oxygen ion woodware white paint by 65wt% water soluble acrylic acid
Dispersion, the pure water of 9.2wt%, the levelling agent of 0.2wt%, 1.5wt% negative oxygen ion additive, 0.5wt% defoaming
Agent, the coalescents of 5wt%, the pH adjusting agent of 0.1wt%, the titanium dioxide of 15wt%, 1wt% wax powder/mute powder and
The thickener composition of 2.5wt%.
According to a preferred embodiment, aqueous one-component negative oxygen ion woodware white paint by 64.5wt% aqueous acrylamide
Sour dispersion, the pure water of 10wt%, the levelling agent of 0.25wt%, the negative oxygen ion additive of 1.25wt%, 0.4wt% disappear
Infusion, the coalescents of 5wt%, the pH adjusting agent of 0.1wt%, the titanium dioxide of 15wt%, 1wt% wax powder/mute powder and
The thickener composition of 2.5wt%.
According to a preferred embodiment, aqueous one-component negative oxygen ion woodware white paint by 63wt% water soluble acrylic acid
Dispersion, the pure water of 5.45wt%, the levelling agent of 0.15wt%, the negative oxygen ion additive of 1.75wt%, 0.25wt% disappear
Infusion, the coalescents of 10wt%, the pH adjusting agent of 0.15wt%, the titanium dioxide of 15wt%, 1.5wt% wax powder/mute powder and
The thickener composition of 2.5wt%.
According to a preferred embodiment, the negative oxygen ion additive is H003 type negative oxygen ions additive, T22 types
Negative oxygen ion additive, TK113 type negative oxygen ions additive, NP01 type negative oxygen ion additives and 30000 type negative oxygen ions add
Add one or more of agent.
Wherein, the preparation method specific technical solution of aqueous one-component negative oxygen ion woodware white paint of the present invention is as follows:
A kind of preparation method of aqueous one-component negative oxygen ion woodware white paint, includes the following steps:
(1) low whipping speed is to sequentially add weight percent as described above in the stirring container of 200~300r/min
Pure water, levelling agent, antifoaming agent and negative oxygen ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Speed is mixed to continue to add in the aqueous of weight percent as described above into the stirring container under conditions of 200~300r/min
Acrylic acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continue to sequentially add into the stirring container under conditions of being 200~300r/min as
Coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder of the upper weight percent;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the increasing of weight percent as described above is added in
Thick dose of adjustment viscosity is finished product after stirring evenly.
The present invention aqueous one-component negative oxygen ion woodware white paint preparation method have step it is simple, it is easy to operate and system
The advantages that standby efficient.
Compared with prior art, aqueous one-component negative oxygen ion woodware white paint of the invention has the advantages that:
The aqueous one-component negative oxygen ion woodware white paint of the present invention is by using said components and by the weight of above-mentioned each component
Amount percentage is made, and can have its paint film nontoxic, pollution-free, the harmful substances such as containing benezene, formaldehyde, heavy metal, do not meet
USA and EU standard;It has no irritating odor in work progress or after construction, health environment-friendly;In addition, its paint film is with excellent
Chemical resistance, scoring resistance, non yellowing;It is also outstanding, resistance to dry rapid, strong adhesive force, hardness height, scratch resistance capability
Mill, it is ageing-resistant, can effectively fire-retardant and film it is plentiful the features such as;In addition aqueous one-component negative oxygen ion woodware white paint of the invention
Also have the advantages that easily to construct, not by construction time limit, non-ignitable, not quick-fried, easy storage and transport;And it also is able to sustained release
The negative oxygen ion of high concentration forms the small air negative oxgyen ion of higher concentration.
Specific embodiment
Aqueous one-component negative oxygen ion woodware white paint of the present invention and preparation method thereof is carried out with reference to embodiment detailed
Thin explanation.It is worth noting that, following embodiment is the preferred embodiment of the present invention, those skilled in the art should
Understand that embodiments of the present invention include working as and be not limited to following embodiment.
Embodiment 1
A kind of aqueous one-component negative oxygen ion woodware white paint is present embodiments provided, by following components by weight percentage
Composition:
Wherein, the sum of weight percent of the above components is 100%.
Preferably, in the present embodiment, H003 type negative oxygen ions additive may be used in negative oxygen ion additive, T22 types are born
Oxonium ion additive, TK113 type negative oxygen ions additive, NP01 type negative oxygen ion additives and the addition of 30000 type negative oxygen ions
One or more of agent.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) it is 5%~10% weight percent to be sequentially added in the stirring container that low whipping speed is 200~300r/min
Pure water, weight percent be 0.2%~0.3% levelling agent, weight percent be 0.2%~0.5% antifoaming agent and again
Measure the negative oxygen ion additive that percentage is 1%~2%;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue under conditions of speed is 200~300r/min into the stirring container add in weight percent be 55%~65%
Water soluble acrylic acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 5%~10% coalescents, weight percent be 0.1%~0.3% pH adjusting agent, weight percent
The wax powder that titanium dioxide and weight percent for 15%~25% are 1%~3%/mute powder;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the increasing that weight percent is 2%~3% is added in
Thick dose of adjustment viscosity is finished product after stirring evenly.
The aqueous one-component negative oxygen ion woodware white paint of the present embodiment using water soluble acrylic acid dispersion as main film forming substance,
Can have its paint film nontoxic, pollution-free, the harmful substances such as containing benezene, formaldehyde, heavy metal, do not meet USA and EU mark
It is accurate.In addition, its paint film has excellent chemical resistance, scoring resistance, non yellowing;Also have dry rapid, strong adhesive force,
Hardness is high, scratch resistance capability is outstanding, it is wear-resisting, ageing-resistant, can effectively fire-retardant and film it is plentiful the features such as;In addition, the present embodiment
Aqueous one-component negative oxygen ion woodware white paint also has easily construction, not by construction time limit, non-ignitable, not quick-fried, easy storage and transport
Advantage;It has no irritating odor in its work progress or after construction, health environment-friendly;And by using presently found nature
It is unique innately charge high-quality polarity inorganic material --- negative oxygen ion additive can be such that it also is able in normal temperature state
Under, the negative oxygen ion of sustained release high concentration forms the small air negative oxgyen ion of higher concentration.
Embodiment 2
The aqueous one-component negative oxygen ion woodware white paint of the present embodiment by 60wt% water soluble acrylic acid dispersion,
The pure water of 6.3wt%, the levelling agent of 0.2wt%, the negative oxygen ion additive of 1wt%, the antifoaming agent of 0.3wt%, 8wt%
Coalescents, the pH conditioning agents of 0.2wt%, the titanium dioxide of 20wt%, wax powder/mute powder of 2wt%, 2wt% thickener group
Into.
Preferably, in the present embodiment, the water soluble acrylic acid dispersion of imported from America may be used in water soluble acrylic acid dispersion;
Pure water can be self-control pure water;BYK-346 levelling agents may be used in levelling agent;He Teguo may be used in negative oxygen ion additive
The H003 type negative oxygen ion additives on border;BYK-023 antifoaming agent may be used in antifoaming agent;Dowanol may be used in coalescents
DPM coalescents;95 type pH adjusting agents of DOW of America DOW AP may be used in pH adjusting agent;Du Pont may be used in titanium dioxide
R706 titanium dioxides;30 thickeners of Viscalex LO of BASF may be used in thickener.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) sequentially added in the stirring container that low whipping speed is 200~300r/min weight percent be 6.3% it is pure
The antifoaming agent and weight percent that levelling agent that water, weight percent are 0.2%, weight percent are 0.3% be 1% it is negative
Oxonium ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue to add in that weight percent is 60% into the stirring container under conditions of speed is 200~300r/min aqueous third
Olefin(e) acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 8% coalescents, weight percent be 0.2% pH adjusting agent, weight percent be 20% titanium dioxide
With wax powder/mute powder that weight percent is 2%;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the thickener that weight percent is 2% is added in
Viscosity is adjusted, is finished product after stirring evenly.
The various test parameters of the aqueous one-component negative oxygen ion woodware white paint product of the present embodiment are as shown in table 1.
Embodiment 3
Compared with Example 2, used by the aqueous one-component negative oxygen ion woodware white paint difference of the present embodiment is
Negative oxygen ion additive is different.The present embodiment is using rock health science and technology limited public affairs of the weight percent for 1% Beijing day
The T22 type negative oxygen ion additives of department;Remaining component and weight percent are same as Example 2.
The preparation method of the aqueous one-component negative oxygen ion woodware white paint of the present embodiment is same as Example 2.
The various test parameters of the aqueous one-component negative oxygen ion woodware white paint product of the present embodiment are as shown in table 1.
Embodiment 4
Compared with Example 2, used by the aqueous one-component negative oxygen ion woodware white paint difference of the present embodiment is
Negative oxygen ion additive is different.The present embodiment is using Shanghai Shizhan Chemical Technology Co., Ltd. that weight percent is 1%
TK113 type negative oxygen ion additives;Remaining component and weight percent are same as Example 2.
The preparation method of the aqueous one-component negative oxygen ion woodware white paint of the present embodiment is same as Example 2.
The various test parameters of the aqueous one-component negative oxygen ion woodware white paint product of the present embodiment are as shown in table 1.
Embodiment 5
Compared with Example 2, used by the aqueous one-component negative oxygen ion woodware white paint difference of the present embodiment is
Negative oxygen ion additive is different.The present embodiment is using NP01 type negative oxygen ion of the weight percent for 1% Japanese import
Additive;Remaining component and weight percent are same as Example 2.
The preparation method of the aqueous one-component negative oxygen ion woodware white paint of the present embodiment is same as Example 2.
The various test parameters of the aqueous one-component negative oxygen ion woodware white paint product of the present embodiment are as shown in table 1.
Embodiment 6
Compared with Example 2, used by the aqueous one-component negative oxygen ion woodware white paint difference of the present embodiment is
Negative oxygen ion additive is different.The present embodiment adds using 30000 type negative oxygen ions of the Lingshou that weight percent is 1%
Add agent;Remaining component and weight percent are same as Example 2.
The preparation method of the aqueous one-component negative oxygen ion woodware white paint of the present embodiment is same as Example 2.
The various test parameters of the aqueous one-component negative oxygen ion woodware white paint product of the present embodiment are as shown in table 1.
Embodiment 7
Water soluble acrylic acid dispersion of the aqueous one-component negative oxygen ion woodware white paint of the present embodiment by 55wt%, 5wt%
Pure water, the levelling agent of 0.3wt%, the negative oxygen ion additive of 2wt%, the antifoaming agent of 0.2wt%, 6.2wt% film forming help
Agent, the pH adjusting agent of 0.3wt%, the titanium dioxide of 25wt%, wax powder/mute powder of 3wt% and 3wt% thickener composition.
Preferably, in the present embodiment, the water soluble acrylic acid dispersion of imported from America may be used in water soluble acrylic acid dispersion;
Pure water can be self-control pure water;BYK-346 levelling agents may be used in levelling agent;He Teguo may be used in negative oxygen ion additive
The H003 type negative oxygen ion additives on border;BYK-023 antifoaming agent may be used in antifoaming agent;Dowanol may be used in coalescents
DPM coalescents;95 type pH adjusting agents of DOW of America DOW AP may be used in pH adjusting agent;Du Pont may be used in titanium dioxide
R706 titanium dioxides;30 thickeners of Viscalex LO of BASF may be used in thickener.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) sequentially added in the stirring container that low whipping speed is 200~300r/min weight percent be 5% it is pure
The antifoaming agent and weight percent that levelling agent that water, weight percent are 0.3%, weight percent are 0.2% be 2% it is negative
Oxonium ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue to add in that weight percent is 55% into the stirring container under conditions of speed is 200~300r/min aqueous third
Olefin(e) acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 6.2% coalescents, weight percent be 0.3% pH adjusting agent, weight percent be 25% titanium white
Powder and wax powder/mute powder that weight percent is 3%;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the thickener that weight percent is 3% is added in
Viscosity is adjusted, is finished product after stirring evenly.
Embodiment 8
The aqueous one-component negative oxygen ion woodware white paint of the present embodiment by 65wt% water soluble acrylic acid dispersion,
The pure water of 9.2wt%, 0.2wt% levelling agents, 1.5wt% negative oxygen ions additive, the antifoaming agent of 0.5wt%, 5wt% into
Film auxiliary agent, the pH adjusting agent of 0.1wt%, the titanium dioxide of 15wt%, wax powder/mute powder of 1wt% and the thickener group of 2.5wt%
Into.
Preferably, in the present embodiment, the water soluble acrylic acid dispersion of imported from America may be used in water soluble acrylic acid dispersion;
Pure water can be self-control pure water;BYK-346 levelling agents may be used in levelling agent;Beijing day may be used in negative oxygen ion additive
Rock T22 type negative oxygen ion additives;BYK-023 antifoaming agent may be used in antifoaming agent;Coalescents may be used
Dowanol DPM coalescents;95 type pH adjusting agents of DOW of America DOW AP may be used in pH adjusting agent;Titanium dioxide can be adopted
With Du Pont's R706 titanium dioxides;30 thickeners of Viscalex LO of BASF may be used in thickener.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) sequentially added in the stirring container that low whipping speed is 200~300r/min weight percent be 9.2% it is pure
The antifoaming agent and weight percent that levelling agent that water, weight percent are 0.2%, weight percent are 0.5% are 1.5%
Negative oxygen ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue to add in that weight percent is 65% into the stirring container under conditions of speed is 200~300r/min aqueous third
Olefin(e) acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 5% coalescents, weight percent be 0.1% pH adjusting agent, weight percent be 15% titanium dioxide
With wax powder/mute powder that weight percent is 1%;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the thickening that weight percent is 2.5% is added in
Agent adjusts viscosity, is finished product after stirring evenly.
Embodiment 9
The aqueous one-component negative oxygen ion woodware white paint of the present embodiment by 64.5wt% water soluble acrylic acid dispersion,
The pure water of 10wt%, 0.25wt% levelling agents, 1.25wt% negative oxygen ions additive, the antifoaming agent of 0.4wt%, 5wt% into
Film auxiliary agent, the pH conditioning agents of 0.1wt%, the titanium dioxide of 15wt%, wax powder/mute powder of 1wt%, 2.5wt% thickener group
Into.
Preferably, in the present embodiment, the water soluble acrylic acid dispersion of imported from America may be used in water soluble acrylic acid dispersion;
Pure water can be self-control pure water;BYK-346 levelling agents may be used in levelling agent;Shanghai generation may be used in negative oxygen ion additive
The TK113 type negative oxygen ion additives of exhibition;BYK-023 antifoaming agent may be used in antifoaming agent;Coalescents may be used
Dowanol DPM coalescents;95 type pH adjusting agents of DOW of America DOW AP may be used in pH adjusting agent;Titanium dioxide can be adopted
With Du Pont's R706 titanium dioxides;30 thickeners of Viscalex LO of BASF may be used in thickener.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) sequentially added in the stirring container that low whipping speed is 200~300r/min weight percent be 10% it is pure
The antifoaming agent and weight percent that levelling agent that water, weight percent are 0.25%, weight percent are 0.4% are 1.25%
Negative oxygen ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue under conditions of speed is 200~300r/min into the stirring container add in weight percent be 64.5% it is aqueous
Acrylic acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 5% coalescents, weight percent be 0.1% pH adjusting agent, weight percent be 15% titanium dioxide
With wax powder/mute powder that weight percent is 1%;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the thickening that weight percent is 2.5% is added in
Agent adjusts viscosity, is finished product after stirring evenly.
Embodiment 10
The aqueous one-component negative oxygen ion woodware white paint of the present embodiment by 63wt% water soluble acrylic acid dispersion,
Pure water, 0.15wt% levelling agents, 1.75wt% negative oxygen ions additive, the antifoaming agent of 0.25wt%, the 10wt% of 5.45wt%
Coalescents, the pH adjusting agent of 0.15wt%, the titanium dioxide of 15wt%, wax powder/mute powder of 1.5wt% and the increasing of 2.5wt%
Thick dose of composition.
Preferably, in the present embodiment, the water soluble acrylic acid dispersion of imported from America may be used in water soluble acrylic acid dispersion;
Pure water can be self-control pure water;BYK-346 levelling agents may be used in levelling agent;Japan may be used in negative oxygen ion additive
NP01 type negative oxygen ion additives or 30000 type negative oxygen ion additives of Lingshou;Antifoaming agent may be used BYK-023 and disappear
Infusion;Dowanol DPM coalescents may be used in coalescents;95 types of DOW of America DOW AP may be used in pH adjusting agent
PH adjusting agent;Du Pont's R706 titanium dioxides may be used in titanium dioxide;The Viscalex LO 30 that BASF may be used in thickener are thickened
Agent.
The aqueous one-component negative oxygen ion woodware white paint preparation method of the present embodiment is as follows:
(1) it is 5.45% weight percent to be sequentially added in the stirring container that low whipping speed is 200~300r/min
The antifoaming agent and weight percent that levelling agent that pure water, weight percent are 0.15%, weight percent are 0.25% be
1.75% negative oxygen ion additive;
(2) it after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, is stirring
Mix continue to add in that weight percent is 63% into the stirring container under conditions of speed is 200~300r/min aqueous third
Olefin(e) acid dispersion;
(3) pure water, levelling agent, antifoaming agent, negative oxygen ion additive and the water soluble acrylic acid dispersion in the step (2) are treated
After body stirs evenly, low whipping speed continues to sequentially add weight into the stirring container under conditions of being 200~300r/min
Measure percentage be 10% coalescents, weight percent be 0.15% pH adjusting agent, weight percent be 15% titanium white
Powder and wax powder/mute powder that weight percent is 1.5%;
(4) mixing speed is adjusted to 600~800r/min, will be added under the mixing speed pure in stirring container
Water, levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and
Wax powder/mute powder stirs evenly;
(5) treat that the pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid disperse
After body, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, the thickening that weight percent is 2.5% is added in
Agent adjusts viscosity, is finished product after stirring evenly.
Table 1
By the data of table 1 it is found that the aqueous one-component negative oxygen ion woodware white paint of the present invention not only has existing woodenware
White paint (one-component) adhesive force is good, application property is good, the characteristic of scoring resistance and non yellowing sexual satisfaction standard etc., and free first
Aldehyde is than relatively low;And the negative oxygen ion content of aqueous one-component negative oxygen ion woodware white paint of the present invention is significantly greater than conventional
Woodware white paint (one-component).
In summary:
1. the present invention realizes the possibility of the negative oxygen ion of sustained release high concentration under normal temperature state;
2. the present invention is suitable for various woodenware external coatings and protection;
3. the present invention have it is nontoxic, pollution-free, the harmful substances such as containing benezene, formaldehyde, heavy metal, do not meet USA and EU
The advantages of standard, non-ignitable, not quick-fried, easy storage and transport;
4. have no irritating odor in work progress of the present invention or after construction, health environment-friendly, film is plentiful, easy construction, not by
It constructs the time limit;
5. solid content of the present invention is high, drying is rapid, strong adhesive force, hardness are high, scratch resistance capability is outstanding, wear-resisting, resistance to old
Change, it can be effectively fire-retardant;
6. the present invention can efficiently dispel the chemical types pollutants such as formaldehyde, ammonia, the benzene in air, and can be formed more highly concentrated
The small air negative oxgyen ion of degree.
It should be noted that this specification disclosed in all features disclosed all methods or in the process the step of,
Other than mutually exclusive feature and/or step, it can combine in any way.
In addition, above-mentioned specific embodiment is exemplary, those skilled in the art can opening in the disclosure of invention
It gives and finds out various solutions, and these solutions also belong to disclosure of the invention range and fall into the guarantor of the present invention
Within the scope of shield.It will be understood by those skilled in the art that description of the invention for it is illustrative be not to form to claim
Limitation.Protection scope of the present invention is limited by claim and its equivalent.
Claims (8)
1. aqueous one-component negative oxygen ion woodware white paint, which is characterized in that it is made of by weight percentage following components:
Wherein, the sum of weight percent of the above components is 100%.
2. aqueous one-component negative oxygen ion woodware white paint according to claim 1, which is characterized in that its water by 60wt%
Property acrylic acid dispersion, the pure water of 6.3wt%, the levelling agent of 0.2wt%, the negative oxygen ion additive of 1wt%, 0.3wt%
Antifoaming agent, the coalescents of 8wt%, the pH adjusting agent of 0.2wt%, the titanium dioxide of 20wt%, 2wt% wax powder/mute powder and
The thickener composition of 2wt%.
3. aqueous one-component negative oxygen ion woodware white paint according to claim 1, which is characterized in that its water by 55wt%
Property acrylic acid dispersion, the pure water of 5wt%, the levelling agent of 0.3wt%, the negative oxygen ion additive of 2wt%, 0.2wt% disappear
Infusion, the coalescents of 6.2wt%, the pH adjusting agent of 0.3wt%, the titanium dioxide of 25wt%, 3wt% wax powder/mute powder and
The thickener composition of 3wt%.
4. aqueous one-component negative oxygen ion woodware white paint according to claim 1, which is characterized in that its water by 65wt%
Property acrylic acid dispersion, the pure water of 9.2wt%, the levelling agent of 0.2wt%, 1.5wt% negative oxygen ion additive, 0.5wt%
Antifoaming agent, the coalescents of 5wt%, the pH adjusting agent of 0.1wt%, the titanium dioxide of 15wt%, 1wt% wax powder/mute powder and
The thickener composition of 2.5wt%.
5. aqueous one-component negative oxygen ion woodware white paint according to claim 1, which is characterized in that it is by 64.5wt%'s
Water soluble acrylic acid dispersion, the pure water of 10wt%, the levelling agent of 0.25wt%, 1.25wt% negative oxygen ion additive,
The antifoaming agent of 0.4wt%, the coalescents of 5wt%, the pH adjusting agent of 0.1wt%, the titanium dioxide of 15wt%, 1wt% wax powder/
The thickener of mute powder and 2.5wt% form.
6. aqueous one-component negative oxygen ion woodware white paint according to claim 1, which is characterized in that its water by 63wt%
Property acrylic acid dispersion, the pure water of 5.45wt%, the levelling agent of 0.15wt%, 1.75wt% negative oxygen ion additive,
The antifoaming agent of 0.25wt%, the coalescents of 10wt%, the pH adjusting agent of 0.15wt%, the titanium dioxide of 15wt%, 1.5wt%
The thickener of wax powder/mute powder and 2.5wt% form.
7. the aqueous one-component negative oxygen ion woodware white paint according to one of claim 1 to 6, which is characterized in that described negative
Oxonium ion additive for H003 type negative oxygen ions additive, T22 type negative oxygen ions additive, TK113 type negative oxygen ions additive,
One or more of NP01 type negative oxygen ion additives and 30000 type negative oxygen ion additives.
8. the preparation method of aqueous one-component negative oxygen ion woodware white paint, which is characterized in that it includes the following steps:
(1) low whipping speed is that the weight as described in one of claim 1 to 7 is sequentially added in the stirring container of 200~300r/min
Measure pure water, levelling agent, antifoaming agent and the negative oxygen ion additive of percentage;
(2) after pure water, levelling agent, antifoaming agent and the negative oxygen ion additive in the step (1) stir evenly, in stirring speed
It spends to continue to add in weight hundred as described in one of claim 1 to 7 into the stirring container under conditions of 200~300r/min
Divide the water soluble acrylic acid dispersion of ratio;
(3) treat that the pure water in the step (2), levelling agent, antifoaming agent, negative oxygen ion additive and water soluble acrylic acid dispersion are stirred
After mixing uniformly, low whipping speed continues to sequentially add such as right into the stirring container under conditions of being 200~300r/min
It is required that coalescents, pH adjusting agent, titanium dioxide and the wax powder of one of 1 to 7 weight percent/mute powder;
(4) mixing speed is adjusted to 600~800r/min, pure water, the stream that will be added in stirring container under the mixing speed
Flat agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, coalescents, pH adjusting agent, titanium dioxide and wax powder/mute
Powder stirs evenly;
(5) treat pure water in the step (4), levelling agent, antifoaming agent, negative oxygen ion additive, water soluble acrylic acid dispersion, into
After film auxiliary agent, pH adjusting agent, titanium dioxide and wax powder/mute powder stir evenly, weight hundred as described in one of claim 1 to 7 are added in
Divide the thickener adjustment viscosity of ratio, be finished product after stirring evenly.
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CN101575473A (en) * | 2009-06-30 | 2009-11-11 | 许元铭 | Full effect negative ion furniture paint |
CN102146257A (en) * | 2011-05-13 | 2011-08-10 | 中山蓝海洋水性涂料有限公司 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
CN102477239A (en) * | 2010-11-25 | 2012-05-30 | 殷春雷 | Aqueous wood paint |
CN103881502A (en) * | 2014-04-16 | 2014-06-25 | 雅士利涂料(苏州)有限公司 | Water-based transparent colored paint for wooden ware and preparation method of paint |
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2018
- 2018-01-05 CN CN201810012415.9A patent/CN108219614A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101575473A (en) * | 2009-06-30 | 2009-11-11 | 许元铭 | Full effect negative ion furniture paint |
CN102477239A (en) * | 2010-11-25 | 2012-05-30 | 殷春雷 | Aqueous wood paint |
CN102146257A (en) * | 2011-05-13 | 2011-08-10 | 中山蓝海洋水性涂料有限公司 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
CN103881502A (en) * | 2014-04-16 | 2014-06-25 | 雅士利涂料(苏州)有限公司 | Water-based transparent colored paint for wooden ware and preparation method of paint |
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