CN108102470A - Aqueous forest negative oxygen ion anti-fouling ship paint and preparation method thereof - Google Patents
Aqueous forest negative oxygen ion anti-fouling ship paint and preparation method thereof Download PDFInfo
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- CN108102470A CN108102470A CN201810012062.2A CN201810012062A CN108102470A CN 108102470 A CN108102470 A CN 108102470A CN 201810012062 A CN201810012062 A CN 201810012062A CN 108102470 A CN108102470 A CN 108102470A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D145/00—Coating compositions based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Coating compositions based on derivatives of such polymers
- C09D145/02—Coumarone-indene polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Life Sciences & Earth Sciences (AREA)
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Abstract
The present invention relates to the technical fields of environmental protection coating material, disclose a kind of aqueous forest negative oxygen ion anti-fouling ship paint, include the raw material of following parts by weight：Watersoluble chlorinated rubber is 5.0~10.0 parts, coumarone indene resin is 5.0~10.0 parts, deionized water is 15.0~25.0 parts, thixotropic agent is 0.5~1.0 part, negative oxygen ion additive is 1.0~2.0 parts, zinc oxide is 20.0~25.0 parts, cuprous oxide is 25.0~30 parts, tributyl tin fluoride is 5.0~10.0 parts, coalescents are 5.0~10.0 parts, pH adjusting agent is 0.1~0.3 part, thickener is 2.0~3.0 parts, with reach marine paint have the advantages that it is free of contamination, such coating is under normal temperature state, the negative oxygen ion of sustained release high concentration, form the small air negative oxgyen ion of higher concentration, make with fresh air, the purpose of invigorating.
Description
Technical field
The present invention relates to the technical fields of environmental protection coating material, and in particular, to a kind of aqueous forest negative oxygen ion marine antifouling
Coating and preparation method thereof.
Background technology
The height of negative oxygen ion concentration and people's health are closely bound up, and people need negative oxygen ion the moment, especially in dirt
In the environment of dye getting worse.Studied according to environmentalist, in air negative oxygen ion concentration it is per cubic centimeter below 20 when, people
It will feel burnout, feel dizzy；When the negative oxygen ion number in air per cubic centimeter is when between 1000~10000, people
It will feel even-tempered and good-humoured, tranquil stable；When the negative oxygen ion number in air per cubic centimeter is at 10000 or more, people is just
It can feel spirit and QI cleaning, comfortable satisfied；And when the negative oxygen ion number in air per cubic centimeter is up to 100,000 or more, with regard to energy
The preventing disease theraping effects such as calmness, Zhichuan, dispelling fatigue, adjusting nerve are played, therefore negative oxygen ion has with people’s lives quality
There is close relationship.
Aqueous forest negative oxygen ion anti-fouling ship paint refers to using painting of the organic metal as poison, chlorinated rubber for base-material
Material.Currently used marine paint film can discharge noxious material, cause environmental pollution, containing benezene, formaldehyde and heavy metal etc. harmful
Substance does not meet USA and EU standard；
And penetrating odor, unhealthy environmental protection can be generated in the construction process or after construction；And current ship paint film
Sterilizing ability with part cannot reach good assisting growth effect to algae, shell biology.
The content of the invention
To improve above-mentioned technical problem, the present invention provides a kind of aqueous forest negative oxygen ion anti-fouling ship paint and its systems
Preparation Method with reach marine paint have the advantages that it is free of contamination, such coating under normal temperature state, sustained release high concentration it is negative
Oxonium ion forms the small air negative oxgyen ion of higher concentration, makes with fresh air, and the purpose of invigorating improves existing
Marine paint film can discharge noxious material, cause environmental pollution, the problem of the harmful substances such as containing benezene, formaldehyde and heavy metal.
In order to realize above-mentioned technique effect, technical solution provided by the present invention is：A kind of aqueous forest negative oxygen ion ship
Oceangoing ship antifouling paint includes the raw material of following parts by weight：Watersoluble chlorinated rubber is 5.0~10.0 parts, coumarone indene resin is 5.0
~10.0 parts, deionized water be 15.0~25.0 parts, thixotropic agent is 0.5~1.0 part, negative oxygen ion additive is 1.0~2.0
Part, zinc oxide are 20.0~25.0 parts, cuprous oxide is 25.0~30 parts, tributyl tin fluoride is 5.0~10.0 parts, film forming helps
Agent is 5.0~10.0 parts, pH adjusting agent is 0.1~0.3 part, thickener is 2.0~3.0 parts.
Further, the parts by weight proportioning of coating components is：Watersoluble chlorinated rubber is 10.0 parts, coumarone indene resin is
10.0 parts, deionized water be 20.0 parts, thixotropic agent is 0.6 part, negative oxygen ion additive is 1.1 parts, zinc oxide is 20.0 parts, oxygen
Change it is cuprous be 25.0 parts, tributyl tin fluoride is 5.0 parts, coalescents are 6.0 parts, pH adjusting agent is 0.1 part, thickener is
2.2 part.
Further, the parts by weight proportioning of coating components is：Watersoluble chlorinated rubber is 5.0 parts, coumarone indene resin is
5.0 parts, deionized water be 15.0 parts, thixotropic agent is 0.9 part, negative oxygen ion additive is 1.9 parts, zinc oxide is 23.0 parts, oxygen
Change it is cuprous be 28 parts, tributyl tin fluoride is 8.0 parts, coalescents are 10.0 parts, pH adjusting agent is 0.3 part, thickener 2.9
Part.
Further, the parts by weight proportioning of coating components is：Watersoluble chlorinated rubber is 7 parts, coumarone indene resin is 7
Part, deionized water are 18 parts, thixotropic agent is 0.7 part, negative oxygen ion additive is 1.5 parts, zinc oxide is 22 parts, cuprous oxide is
27 parts, tributyl tin fluoride be 7 parts, coalescents are 7 parts, pH adjusting agent is 0.2 part, thickener is 2.6 parts.
Further, the parts by weight proportioning of coating components is：Watersoluble chlorinated rubber is 10.0 parts, coumarone indene resin is
5.0 parts, deionized water be 20.8 parts, thixotropic agent is 1.0 parts, negative oxygen ion additive is 1.0 parts, zinc oxide is 25.0 parts, oxygen
Change it is cuprous be 25.0 parts, tributyl tin fluoride is 5.0 parts, coalescents are 5.0 parts, pH adjusting agent is 0.2 part, thickener is
2.0 part.
The present invention also provides a kind of preparation methods of aqueous forest negative oxygen ion anti-fouling ship paint, and preparation process is such as
Under：
(1) under the mixing speed of 200~300r/min of stirring container, weight percent is sequentially added as 15.0~25.0
Part deionized water, 5.0~10.0 parts of watersoluble chlorinated rubber, 5.0~10.0 parts of coumarone indene resin, 0.5~1.0 part
Thixotropic agent stirs evenly；
(2) continue sequentially added under the stirring weight percent be 1.0~2.0 parts negative oxygen ion additive,
20.0~25.0 parts of zinc oxide, 25.0~30 parts of cuprous oxide, 5.0~10.0 parts of tributyl tin fluoride, stir evenly；
(3) rotating speed for adjusting stirring container is stirred uniformly to 600~800r/min；
(4) under the stirring of 200~300r/min of the stirring container, sequentially adding weight percent is, 5.0~
10.0 parts of coalescents, 0.1~0.3 part of pH adjusting agent；
(5) viscosity is adjusted with the thickener that weight percent is 2.0~3.0 parts, is finished product after stirring evenly.
Further, the adjustment viscosity in the step (5) refers to viscosity being adjusted to 120KU-130KU.
Compared with the prior art, the beneficial effects of the invention are as follows：
1. aqueous forest negative oxygen ion anti-fouling ship paint provided by the invention can be high in sustained release under normal temperature state
The negative oxygen ion of concentration, the negative oxygen ion (the lower 6000-8000/cm3 of static state) of sustained release high concentration, forms higher concentration
Small air negative oxgyen ion makes with fresh air, invigorating purpose；
2. the aqueous forest negative oxygen ion anti-fouling ship paint of the present invention could be applicable to aircraft, oil, in chemical industry
The various external coatings such as metal and protection, use scope is extensive, beneficial to the popularization of coating；
3. the present invention aqueous forest negative oxygen ion anti-fouling ship paint have it is nontoxic, pollution-free, not containing benezene, formaldehyde,
The harmful substances such as heavy metal meet USA and EU standard, non-ignitable, not quick-fried, easy storage and transport；
4. the coating of the present invention has no irritating odor in the construction process or after construction, health environment-friendly, film is plentiful, easily applies
Work, from construction the time limit；And paint film has broader sterilizing ability, has very strong effect to algae, shell biology；
5. of the invention non-toxic, the chemical types pollutants such as formaldehyde, ammonia, benzene in air can be efficiently dispelled, are formed more highly concentrated
The small air negative oxgyen ion of degree, makes with fresh air, makes us that people is relaxing, is a kind of product of great environmental consciousness.
Specific embodiment
The present invention is further described in detail with reference to specific embodiment, following word is intended to indicate that this hair
Protection domain that is bright, being not intended to limit the present invention.
The present invention can be implemented as follows, provide a kind of aqueous forest negative oxygen ion anti-fouling ship paint and its preparation
Method, embodiment 1 are as follows：
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 20.8 parts deionized water, 10.0
The watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, 1.0 parts of negative oxygen ion additive (He Te of part
International H003 types), 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, 5.0 parts of film forming
Auxiliary agent (DowanolDPM), 0.2 part of pH adjusting agent (DOW of America DOWAP95 types), 2.0 parts of thickener be (BASF's
ViscalexLO30)。
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint is as follows in the present embodiment 1：
(1) under the mixing speed of 200~300r/min of stirring container, sequentially add parts by weight be 20.8 parts go from
Sub- water, 10.0 parts of watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, stir evenly；
(2) continue to sequentially add negative oxygen ion additive (the He Te worlds that parts by weight are 1.0 parts under the stirring
H003 types), 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 600~800r/min；
(4) under the stirring of 200~300r/min of the stirring container, sequentially adding parts by weight is, 5.0 parts into
Film auxiliary agent, 0.2 part of pH adjusting agent；
(5) viscosity is adjusted to 120KU with the thickener that parts by weight are 2.0 parts, be finished product after stirring evenly.
Embodiment 2
Compared with Example 1, the brand of negative oxygen ion additive used by the difference of the present embodiment is.
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 20.8 parts deionized water, 10.0
The watersoluble chlorinated rubber of part, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, 1.0 parts negative oxygen ion additive (Beijing
The T22 types of it rock), 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, 5.0 parts into
Film auxiliary agent (DowanolDPM), 0.2 part of pH adjusting agent (DOW of America DOWAP95 types), 2.0 parts of thickener be (BASF's
ViscalexLO30)。
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint in the present embodiment 2 is as follows：
(1) under the mixing speed of 200~300r/min of stirring container, sequentially add parts by weight be 20.8 parts go from
Sub- water, 10.0 parts of watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, stir evenly；
(2) continue sequentially added under the stirring parts by weight be 1.0 parts negative oxygen ion additive (Beijing day
The T22 types of rock), 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 600~800r/min；
(4) under the stirring of 200~300r/min of the stirring container, sequentially adding parts by weight is, 5.0 parts into
Film auxiliary agent, 0.2 part of pH adjusting agent；
(5) viscosity is adjusted to 120KU with the thickener that parts by weight are 2.0 parts, be finished product after stirring evenly.
Embodiment 3
Compared with Example 1, the brand of negative oxygen ion additive used by the difference of the present embodiment is.
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 20.8 parts deionized water, 10.0
The watersoluble chlorinated rubber of part, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, 1.0 parts of negative oxygen ion additive (Shanghai
The TK113 types of generation exhibition), 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, 5.0 parts into
Film auxiliary agent (DowanolDPM), 0.2 part of pH adjusting agent (DOW of America DOWAP95 types), 2.0 parts of thickener be (BASF's
ViscalexLO30)。
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint in the present embodiment 3 is as follows：
(1) under the mixing speed of 200~300r/min of stirring container, sequentially add parts by weight be 20.8 parts go from
Sub- water, 10.0 parts of watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, stir evenly；
(2) continue to sequentially add under the stirring Shanghai generation exhibition that parts by weight are 1.0 parts TK113 types bear oxygen from
Sub- additive, 25.0 parts of zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 600~800r/min；
(4) under the stirring of 200~300r/min of the stirring container, sequentially adding parts by weight is, 5.0 parts into
Film auxiliary agent, 0.2 part of pH adjusting agent；
(5) viscosity is adjusted to 120KU with the thickener that parts by weight are 2.0 parts, be finished product after stirring evenly.
Embodiment 4
Compared with Example 1, negative oxygen ion additive is Japanese NP01 used by the difference of the present embodiment is
Type negative oxygen ion additive.
Embodiment 5
Compared with Example 1, negative oxygen ion additive is the 30000 of Lingshou used by the difference of the present embodiment is
Type negative oxygen ion additive
The various experimental test parameters of prepared finished product are as shown in table 1 in 1~embodiment of embodiment 5：
Table 1
By that can be drawn with the data of upper table 1, coating of the invention not only containing existing anti-fouling ship paint weatherability,
Wearability, water resistance and heat resistance etc. meet the characteristic of standard, and the content of negative oxygen ion of the present invention is significantly greater than routine
Anti-fouling ship paint.
Embodiment 6
The aqueous forest negative oxygen ion anti-fouling ship paint of the present invention by deionized water that parts by weight are 18 parts, 7 parts
Watersoluble chlorinated rubber, 7 parts of coumarone indene resin, 0.7 part of thixotropic agent, 1.5 parts of negative oxygen ion additive, 22 parts of oxidation
Zinc, 27 parts of cuprous oxide, 7 parts of tributyl tin fluoride, 7 parts of coalescents (DowanolDPM), 0.2 part of pH adjusting agent
(DOW of America DOWAP95 types), 2.6 parts of thickener (ViscalexLO30 of BASF).
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint in the present embodiment 6 is as follows：
(1) under the mixing speed of stirring container 250r/min, deionized water, 7 that parts by weight are 18 parts are sequentially added
The watersoluble chlorinated rubber, 7 parts of coumarone indene resin, 0.7 part of thixotropic agent of part, stir evenly；
(2) continue to sequentially add the negative oxygen ion additive, 22 parts of oxygen that parts by weight are 1.5 parts under the stirring
Change zinc, 27 parts of cuprous oxide, 7 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 700r/min；
(4) under the stirring of stirring container 250r/min, sequentially adding parts by weight is, 7 parts of coalescents,
0.2 part of pH adjusting agent；
(5) viscosity is adjusted to 125KU with the thickener that parts by weight are 2.6 parts, be finished product after stirring evenly.
Embodiment 7
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 20 parts deionized water, 10.0 parts
Watersoluble chlorinated rubber, 10.0 parts of coumarone indene resin, 0.6 part of thixotropic agent, 1.1 parts of negative oxygen ion additive, 20.0
Part zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, 6.0 parts of coalescents (DowanolDPM),
0.1 part of pH adjusting agent (DOW of America DOWAP95 types), 2.2 parts of thickener (ViscalexLO30 of BASF).
Embodiment 8
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 15.0 parts deionized water, 5.0
Part watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 0.9 part of thixotropic agent, 1.9 parts of negative oxygen ion additive, 23.0
Part zinc oxide, 28.0 parts of cuprous oxide, 8.0 parts of tributyl tin fluoride, 10.0 parts of coalescents (DowanolDPM),
0.3 part of pH adjusting agent (DOW of America DOWAP95 types), 2.9 parts of thickener (ViscalexLO30 of BASF).
Embodiment 9
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 15.0 parts deionized water, 5.0
Part watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 0.5 part of thixotropic agent, 1.0 parts of negative oxygen ion additive, 20.0
Part zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, 5.0 parts of coalescents (DowanolDPM),
0.1 part of pH adjusting agent (DOW of America DOWAP95 types), 2.0 parts of thickener (ViscalexLO30 of BASF)；
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint in the present embodiment 9 is as follows：
(1) under the mixing speed of stirring container 200r/min, sequentially add parts by weight be 15 parts deionized water,
5.0 parts of watersoluble chlorinated rubber, 5.0 parts of coumarone indene resin, 0.5 part of thixotropic agent, stir evenly；
(2) continuation sequentially adds the negative oxygen ion additive, 20.0 parts that parts by weight are 1.0 parts under the stirring
Zinc oxide, 25.0 parts of cuprous oxide, 5.0 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 600r/min；
(4) under the stirring of stirring container 200r/min, sequentially adding parts by weight is, 5.0 parts of film forming helps
Agent, 0.1 part of pH adjusting agent；
(5) viscosity is adjusted to 120KU with the thickener that parts by weight are 2.0 parts, be finished product after stirring evenly.
Embodiment 10
The present invention aqueous forest negative oxygen ion anti-fouling ship paint by parts by weight be 25.0 parts deionized water, 10.0
Part watersoluble chlorinated rubber, 10.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, 2.0 parts of negative oxygen ion additive,
25.0 parts of zinc oxide, 30.0 parts of cuprous oxide, 10.0 parts of tributyl tin fluoride, 10.0 parts of coalescents
(DowanolDPM), 0.3 part of pH adjusting agent (DOW of America DOWAP95 types), 3.0 parts of thickener (BASF's
ViscalexLO30)；
The preparation method of aqueous forest negative oxygen ion anti-fouling ship paint in the present embodiment 10 is as follows：
(1) under the mixing speed of stirring container 300r/min, sequentially add parts by weight be 25.0 parts deionized water,
10.0 parts of watersoluble chlorinated rubber, 10.0 parts of coumarone indene resin, 1.0 parts of thixotropic agent, stir evenly；
(2) continuation sequentially adds the negative oxygen ion additive, 25.0 parts that parts by weight are 2.0 parts under the stirring
Zinc oxide, 30.0 parts of cuprous oxide, 10.0 parts of tributyl tin fluoride, stir evenly；
(3) stirring container rotating speed is adjusted to stir evenly to 800r/min；
(4) under the stirring of stirring container 300r/min, sequentially adding parts by weight is, 10.0 parts of film forming helps
Agent, 0.3 part of pH adjusting agent；
(5) viscosity is adjusted to 130KU with the thickener that parts by weight are 3.0 parts, be finished product after stirring evenly
Any one skilled in the art in the technical scope disclosed by the present invention, can readily occur in variation or
It replaces, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the guarantor described in claim
It protects subject to scope.
Claims (7)
1. a kind of aqueous forest negative oxygen ion anti-fouling ship paint, which is characterized in that include the raw material of following parts by weight：It is aqueous
Chlorinated rubber is 5.0~10.0 parts, coumarone indene resin is 5.0~10.0 parts, deionized water is 15.0~25.0 parts, thixotropic agent
For 0.5~1.0 part, negative oxygen ion additive be 1.0~2.0 parts, zinc oxide is 20.0~25.0 parts, cuprous oxide be 25.0~
30 parts, tributyl tin fluoride be 5.0~10.0 parts, coalescents are 5.0~10.0 parts, pH adjusting agent is 0.1~0.3 part, are increased
Thick dose is 2.0~3.0 parts.
2. aqueous forest negative oxygen ion anti-fouling ship paint according to claim 1, which is characterized in that the weight of coating components
Amount number, which matches, is：Watersoluble chlorinated rubber is 10.0 parts, coumarone indene resin is 10.0 parts, deionized water is 20.0 parts, thixotroping
Agent is 0.6 part, negative oxygen ion additive is 1.1 parts, zinc oxide is 20.0 parts, cuprous oxide is 25.0 parts, tributyl tin fluoride
For 5.0 parts, coalescents be 6.0 parts, pH adjusting agent is 0.1 part, thickener is 2.2 parts.
3. aqueous forest negative oxygen ion anti-fouling ship paint according to claim 1, which is characterized in that the weight of coating components
Amount number, which matches, is：Watersoluble chlorinated rubber is 5.0 parts, coumarone indene resin is 5.0 parts, deionized water is 15.0 parts, thixotropic agent
For 0.9 part, negative oxygen ion additive be 1.9 parts, zinc oxide is 23.0 parts, cuprous oxide is 28.0 parts, tributyl tin fluoride is
8.0 parts, coalescents be 10.0 parts, pH adjusting agent is 0.3 part, thickener is 2.9 parts.
4. aqueous forest negative oxygen ion anti-fouling ship paint according to claim 1, which is characterized in that the weight of coating components
Amount number, which matches, is：Watersoluble chlorinated rubber is 7 parts, coumarone indene resin is 7 parts, deionized water is 18 parts, thixotropic agent 0.7
Part, negative oxygen ion additive are 1.5 parts, zinc oxide is 22 parts, cuprous oxide is 27 parts, tributyl tin fluoride is 7 parts, film forming helps
Agent is 7 parts, pH adjusting agent is 0.2 part, thickener is 2.6 parts.
5. aqueous forest negative oxygen ion anti-fouling ship paint according to claim 1, which is characterized in that the weight of coating components
Amount number, which matches, is：Watersoluble chlorinated rubber is 10.0 parts, coumarone indene resin is 5.0 parts, deionized water is 20.8 parts, thixotropic agent
For 1.0 parts, negative oxygen ion additive be 1.0 parts, zinc oxide is 25.0 parts, cuprous oxide is 25.0 parts, tributyl tin fluoride is
5.0 parts, coalescents be 5.0 parts, pH adjusting agent is 0.2 part, thickener is 2.0 parts.
6. a kind of preparation method of aqueous forest negative oxygen ion anti-fouling ship paint, which is characterized in that its preparation process is as follows：
(1) under the mixing speed of 200~300r/min of stirring container, it is 15.0~25.0 parts to sequentially add weight percent
Deionized water, 5.0~10.0 parts of watersoluble chlorinated rubber, 5.0~10.0 parts of coumarone indene resin, 0.5~1.0 part of thixotroping
Agent stirs evenly；
(2) continue to sequentially add the negative oxygen ion additive, 20.0 that weight percent is 1.0~2.0 parts under the stirring
~25.0 parts of zinc oxide, 25.0~30 parts of cuprous oxide, 5.0~10.0 parts of tributyl tin fluoride, stir evenly；
(3) rotating speed for adjusting stirring container is stirred uniformly to 600~800r/min；
(4) under the stirring of 200~300r/min of the stirring container, sequentially adding weight percent is, 5.0~10.0 parts
Coalescents, 0.1~0.3 part of pH adjusting agent；
(5) viscosity is adjusted with the thickener that weight percent is 2.0~3.0 parts, is finished product after stirring evenly.
7. aqueous forest negative oxygen ion anti-fouling ship paint according to claim 6, which is characterized in that the step (5)
In adjustment viscosity refer to viscosity being adjusted to 120KU-130KU.
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| CN201810012062.2A CN108102470A (en) | 2018-01-05 | 2018-01-05 | Aqueous forest negative oxygen ion anti-fouling ship paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112521783A (en) * | 2020-11-30 | 2021-03-19 | 北部湾海洋新材料研究院 | Antifouling and anticorrosive marine coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464920A (en) * | 2010-11-04 | 2012-05-23 | 南通五联品牌策划有限公司 | Mildew-resistant and antibacterial coating, and manufacture method thereof |
| CN103013307A (en) * | 2012-11-29 | 2013-04-03 | 益阳祥瑞科技有限公司 | Antifouling topping paint for boat |
| CN104893470A (en) * | 2015-06-05 | 2015-09-09 | 宁波健利康生物研究科技有限公司 | Environmental-friendly coating and preparation technology thereof |
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2018
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464920A (en) * | 2010-11-04 | 2012-05-23 | 南通五联品牌策划有限公司 | Mildew-resistant and antibacterial coating, and manufacture method thereof |
| CN103013307A (en) * | 2012-11-29 | 2013-04-03 | 益阳祥瑞科技有限公司 | Antifouling topping paint for boat |
| CN104893470A (en) * | 2015-06-05 | 2015-09-09 | 宁波健利康生物研究科技有限公司 | Environmental-friendly coating and preparation technology thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112521783A (en) * | 2020-11-30 | 2021-03-19 | 北部湾海洋新材料研究院 | Antifouling and anticorrosive marine coating |
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