CN108003738A - Water-based forest negative oxygen ion metallic finishe and preparation method thereof - Google Patents
Water-based forest negative oxygen ion metallic finishe and preparation method thereof Download PDFInfo
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- CN108003738A CN108003738A CN201810016825.0A CN201810016825A CN108003738A CN 108003738 A CN108003738 A CN 108003738A CN 201810016825 A CN201810016825 A CN 201810016825A CN 108003738 A CN108003738 A CN 108003738A
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- negative oxygen
- oxygen ion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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Abstract
The invention belongs to metallic finishe technical field.To solve the technical problem that existing metallic finishe is unable to sustained release negative oxygen ion, there is provided a kind of water-based forest negative oxygen ion metallic finishe and preparation method thereof, the metallic finishe includes the raw material of following parts by weight：55.0 parts~60.0 parts of water soluble acrylic acid dispersion；15.0 parts~20.0 parts of deionized water；0.2 part~0.3 part of levelling agent；1.0 parts~2.0 parts of negative oxygen ion additive；0.2 part~0.5 part of defoamer；5.0 parts~10.0 parts of coalescents；0.1 part~0.3 part of pH adjusting agent；Dodge 10.0 parts~15.0 parts of silver paste dispersion liquid；2.0 parts~3.0 parts of thickener；The step of preparation method includes preparing negative oxygen ion liquid, aqueous liquid dispersion, crude product and finished product.The present invention has the characteristics that sustained release negative oxygen ion, dispels coating peculiar smell.
Description
Technical field
The invention belongs to negative oxygen ion metallic finishe technical field, and in particular to a kind of water-based forest negative oxygen ion metallic finishe and
Its preparation method.
Background technology
The height of negative oxygen ion concentration and people's health are closely bound up, and people need negative oxygen ion the moment, especially in dirt
Contaminate today of getting worse.Studied according to environmentalist, in air negative oxygen ion concentration it is per cubic centimeter below 20 when, people is just
It can feel burnout, feel dizzy；When the negative oxygen ion number in air per cubic centimeter is when between 1000~10000, people is just
It can feel even-tempered and good-humoured, tranquil stable；When the negative oxygen ion number in air per cubic centimeter is more than 10000, people will
Feel spirit and QI cleaning, comfortable satisfied；And when the negative oxygen ion number in air per cubic centimeter is up to more than 100,000, it can just rise
To preventing disease theraping effects such as calmness, Zhichuan, dispelling fatigue, adjusting nerves.
However, existing metallic finishe is only used as coating, it is impossible to plays the role of sustained release negative oxygen ion.
The content of the invention
It is an object of the invention to solve above technical problem existing in the prior art, there is provided a kind of water-based forest bears oxygen
Ion metallic finishe and preparation method thereof.
The purpose of the present invention is what is be achieved through the following technical solutions：
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
Further, the water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
Further, the mixing speed of the stirring of the step A is 200~300r/min.
Further, the mixing speed of the stirring of the step B is 200~300r/min.
Further, the mixing speed of the stirring of the step C is 200~300r/min.
Further, the mixing speed of the new stirring of the step C is 600~800r/min.
It is of the invention to be relative to the beneficial effect of the prior art：
1st, the negative oxygen ion of the present invention sustainable release high concentration under normal temperature state.
2nd, the present invention is suitable for the various rigid plastic surface applications such as ABS, PE, PP, PVC foam section bar and protection.
3rd, the present invention has nontoxic, pollution-free, and the harmful substance such as containing benezene, formaldehyde, heavy metal, does not meet USA and EU
Standard, non-ignitable, not quick-fried, easy storage and transport.
4th, have no irritating odor in work progress of the present invention or after construction, health environment-friendly, film is plentiful, easy construction, from
Construct the time limit.
5th, solids content of the present invention is high, drying is rapid, strong adhesive force, hardness are high, scratch resistance capability is outstanding, wear-resisting, resistance to old
Change, can be effectively fire-retardant.
6th, the chemical type pollutant such as the formaldehyde of the invention that can efficiently dispel in air, ammonia, benzene, forms the small sky of higher concentration
Gas negative oxygen ion, makes with fresh air, is a kind of environment-friendly products.
Embodiment
Technical scheme is described in detail with reference to embodiments, it should be noted that be only below
The preferred embodiment of the present invention, for those of ordinary skill in the art, before the invention design is not departed from
Put, various modifications and improvements can be made, these should belong to protection scope of the present invention.
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
Further, the water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
Further, the mixing speed of the stirring of the step A is 200~300r/min.
Further, the mixing speed of the stirring of the step B is 200~300r/min.
Further, the mixing speed of the stirring of the step C is 200~300r/min.
Further, the mixing speed of the new stirring of the step C is 600~800r/min.
Embodiment 1
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
The mixing speed of the stirring of the step A is 200r/min.The mixing speed of the stirring of the step B
For 200r/min.The mixing speed of the stirring of the step C is 200r/min.The new stirring of the step C
Mixing speed is 600r/min.
Embodiment 2
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
The mixing speed of the stirring of the step A is 300r/min.The mixing speed of the stirring of the step B
For 300r/min.The mixing speed of the stirring of the step C is 300r/min.The new stirring of the step C
Mixing speed is 800r/min.
Embodiment 3
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
The mixing speed of the stirring of the step A is 250r/min.The mixing speed of the stirring of the step B
For 260r/min.The mixing speed of the stirring of the step C is 260r/min.The new stirring of the step C
Mixing speed is 650r/min.
Embodiment 4
A kind of water-based forest negative oxygen ion metallic finishe, includes the raw material of following parts by weight：
A kind of preparation method of water-based forest negative oxygen ion metallic finishe, including step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive are mixed, obtain negative oxygen
Ionic liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged,
After being mixed under new stirring, crude product is obtained；
D, thickener is uniformly mixed with crude product, obtains finished product.
The mixing speed of the stirring of the step A is 200r/min.The mixing speed of the stirring of the step B
For 300r/min.The mixing speed of the stirring of the step C is 300r/min.The new stirring of the step C
Mixing speed is 800r/min.
Embodiment 5
The water-based forest negative oxygen ion metallic finishe of the present embodiment by parts by weight are 58.0 parts high Tg DEG C of the U.S. it is water-based
Acrylic acid dispersion, 18.3 parts of deionized water, 0.2 part of BYK-346 levelling agents, the H003 types of the 1.0 Fen Hete worlds are born
Oxonium ion additive, 0.3 part of BYK-023 defoamers, 8 parts of Dowanol DPM coalescents, 0.2 part of Dow DOW
95 type pH adjusting agents of AP, 12 parts of sudden strain of a muscle silver paste dispersion liquid, 30 thickeners of Viscalex LO of 2.0 parts of BASF.
The preparation method of the water-based forest negative oxygen ion metallic finishe of the present embodiment is as follows：
(1) under the mixing speed of stirring container 200r/min, sequentially add parts by weight be 18.3 parts deionized water,
The H003 types negative oxygen ion addition of 0.2 part of BYK-346 levelling agents, 0.3 part of BYK-023 defoamers, the 1.0 Fen Hete worlds
Agent；
(2) continue to sequentially add high Tg DEG C water soluble acrylic acid of the parts by weight for 58.0 parts of the U.S. under the stirring
Dispersion, stirs evenly；
(3) under the stirring of stirring container 300r/min, the Dowanol that parts by weight are 8.0 parts is sequentially added
DPM coalescents, 0.2 part of 95 type pH adjusting agents of Dow DOW AP, 12.0 parts of sudden strain of a muscle silver paste dispersion liquid；
(4) stirring container rotating speed is adjusted to stir evenly to 600r/min；
(5) viscosity is adjusted with 30 thickeners of Viscalex LO for the BASF that parts by weight are 2.0 parts, after stirring evenly i.e.
For finished product.
It is as shown in table 1 as the various test parameters of the product prepared by above step.
Embodiment 6
Compared with Example 5, the brand of negative oxygen ion additive used by the difference of the present embodiment is.
The water-based forest negative oxygen ion metallic finishe of the present embodiment by parts by weight are 58.0 parts high Tg DEG C of the U.S. it is water-based
Acrylic acid dispersion, 18.3 parts of deionized water, 0.2 part of BYK-346 levelling agents, the T22 types of rock in 1.0 parts of Beijing day are born
Oxonium ion additive, 0.3 part of BYK-023 defoamers, 8 parts of Dowanol DPM coalescents, 0.2 part of Dow DOW
95 type pH adjusting agents of AP, 12 parts of sudden strain of a muscle silver paste dispersion liquid, 30 thickeners of Viscalex LO of 2.0 parts of BASF.
The preparation method of the water-based forest negative oxygen ion metallic finishe of the present embodiment is as follows：
(1) under the mixing speed of stirring container 200r/min, sequentially add parts by weight be 18.3 parts deionized water,
0.2 part of BYK-346 levelling agents, 0.3 part of BYK-023 defoamers, the T22 type negative oxygen ions of rock in 1.0 parts of Beijing day add
Add agent；
(2) continue to sequentially add high Tg DEG C water soluble acrylic acid of the parts by weight for 58.0 parts of the U.S. under the stirring
Dispersion, stirs evenly；
(3) under the stirring of stirring container 300r/min, the Dowanol that parts by weight are 8.0 parts is sequentially added
DPM coalescents, 0.2 part of 95 type pH adjusting agents of Dow DOW AP, 12.0 parts of sudden strain of a muscle silver paste dispersion liquid；
(4) stirring container rotating speed is adjusted to stir evenly to 600r/min；
(5) viscosity is adjusted with 30 thickeners of Viscalex LO for the BASF that parts by weight are 2.0 parts, after stirring evenly i.e.
For finished product.
It is as shown in table 1 as the various test parameters of the product prepared by above step.
Embodiment 7
Compared with Example 5, the brand of negative oxygen ion additive used by the difference of the present embodiment is.
The water-based forest negative oxygen ion metallic finishe of the present embodiment by parts by weight are 58.0 parts high Tg DEG C of the U.S. it is water-based
Acrylic acid dispersion, 18.3 parts of deionized water, 0.2 part of BYK-346 levelling agents, the TK113 types of 1.0 parts of Shanghai generation exhibition are born
Oxonium ion additive, 0.3 part of BYK-023 defoamers, 8 parts of Dowanol DPM coalescents, 0.2 part of Dow DOW
95 type pH adjusting agents of AP, 12 parts of sudden strain of a muscle silver paste dispersion liquid, 30 thickeners of Viscalex LO of 2.0 parts of BASF.
The preparation method of the water-based forest negative oxygen ion metallic finishe of the present embodiment is as follows：
(1) under the mixing speed of stirring container 200r/min, sequentially add parts by weight be 18.3 parts deionized water,
0.2 part of BYK-346 levelling agents, 0.3 part of BYK-023 defoamers, the TK113 type negative oxygen ions of 1.0 parts of Shanghai generation exhibition add
Add agent；
(2) continue to sequentially add high Tg DEG C water soluble acrylic acid of the parts by weight for 58.0 parts of the U.S. under the stirring
Dispersion, stirs evenly；
(3) under the stirring of stirring container 300r/min, the Dowanol that parts by weight are 8.0 parts is sequentially added
DPM coalescents, 0.2 part of 95 type pH adjusting agents of Dow DOW AP, 12.0 parts of sudden strain of a muscle silver paste dispersion liquid；
(4) stirring container rotating speed is adjusted to stir evenly to 600r/min；
(5) viscosity is adjusted with 30 thickeners of Viscalex LO for the BASF that parts by weight are 2.0 parts, after stirring evenly i.e.
For finished product.
It is as shown in table 1 as the various test parameters of the product prepared by above step.
Embodiment 8
Compared with Example 5, negative oxygen ion additive is Japanese NP01 used by the difference of the present embodiment is
Type negative oxygen ion additive.Remainder is same as Example 5.
Embodiment 9
Compared with Example 5, negative oxygen ion additive is the 30000 of Lingshou used by the difference of the present embodiment is
Type negative oxygen ion additive.Remainder is same as Example 5.
Test case
The test event of the water-based forest negative oxygen ion metallic finishe of embodiment 5-9 is as shown in table 1 below.
The performance parameter contrast table of the water-based forest negative oxygen ion metallic finishe of 1 embodiment 5-9 of table
It can be drawn by data above, metallic finishe of the invention is not only containing existing metallic finishe adhesive force is good, application property
The characteristic of good, scoring resistance and non yellowing sexual satisfaction standard etc., and free formaldehyde content is than relatively low.Negative oxygen ion of the present invention
Content is significantly greater than conventional metallic finishe.
Technical scheme can preferably be realized according to the record of this specification.
Claims (7)
1. a kind of water-based forest negative oxygen ion metallic finishe, it is characterised in that include the raw material of following parts by weight：
2. water-based forest negative oxygen ion metallic finishe according to claim 1, it is characterised in that including following parts by weight
Raw material：
A kind of 3. preparation method of the water-based forest negative oxygen ion metallic finishe described in claim 1 or 2, it is characterised in that including
Step：
A, under stirring, deionized water, levelling agent, defoamer and negative oxygen ion additive is mixed, obtain negative oxygen ion
Liquid；
B, under stirring, the negative oxygen ion liquid and water soluble acrylic acid dispersion is mixed, obtain aqueous liquid dispersion；
C, under stirring, by the aqueous liquid dispersion, coalescents, pH adjusting agent and the mixing of silver paste dispersion liquid is dodged, new
Stirring under mix after, obtain crude product；
D, thickener is uniformly mixed with crude product, obtains finished product.
4. the preparation method of water-based forest negative oxygen ion metallic finishe according to claim 3, it is characterised in that the step
The mixing speed of the stirring of A is 200~300r/min.
5. the preparation method of water-based forest negative oxygen ion metallic finishe according to claim 4, it is characterised in that the step
The mixing speed of the stirring of B is 200~300r/min.
6. the preparation method of water-based forest negative oxygen ion metallic finishe according to claim 5, it is characterised in that the step
The mixing speed of the stirring of C is 200~300r/min.
7. the preparation method of water-based forest negative oxygen ion metallic finishe according to claim 6, it is characterised in that the step
The mixing speed of the new stirring of C is 600~800r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810016825.0A CN108003738A (en) | 2018-01-05 | 2018-01-05 | Water-based forest negative oxygen ion metallic finishe and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810016825.0A CN108003738A (en) | 2018-01-05 | 2018-01-05 | Water-based forest negative oxygen ion metallic finishe and preparation method thereof |
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| CN108003738A true CN108003738A (en) | 2018-05-08 |
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| CN201810016825.0A Pending CN108003738A (en) | 2018-01-05 | 2018-01-05 | Water-based forest negative oxygen ion metallic finishe and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341902A (en) * | 2013-08-06 | 2015-02-11 | 青岛益群漆业集团有限公司 | Environment-friendly aluminum powder plastic paint |
| CN107236351A (en) * | 2017-06-26 | 2017-10-10 | 山东森凌环保科技有限公司 | A kind of releasable negative aeroion additive |
-
2018
- 2018-01-05 CN CN201810016825.0A patent/CN108003738A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341902A (en) * | 2013-08-06 | 2015-02-11 | 青岛益群漆业集团有限公司 | Environment-friendly aluminum powder plastic paint |
| CN107236351A (en) * | 2017-06-26 | 2017-10-10 | 山东森凌环保科技有限公司 | A kind of releasable negative aeroion additive |
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