CN101942274B - Anion environmental friendly paint and production method thereof - Google Patents
Anion environmental friendly paint and production method thereof Download PDFInfo
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- CN101942274B CN101942274B CN2010102913711A CN201010291371A CN101942274B CN 101942274 B CN101942274 B CN 101942274B CN 2010102913711 A CN2010102913711 A CN 2010102913711A CN 201010291371 A CN201010291371 A CN 201010291371A CN 101942274 B CN101942274 B CN 101942274B
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Abstract
The invention relates to anion environmental friendly paint and a production method thereof. The method comprises the following steps of: carrying out grinding of 1,200-1,400 turns/minute on a dispersed mixture of 3-16 percent by weight of water, 0.2-1 percent by weight of polyacrylate of sodium or ammonium and 0.1-3 percent by weight of titanium dioxide nano powder and then homogenizing; adding a dispersed mixture of 9-25 percent by weight of water, 0.2-1 percent by weight of polyacrylate of the sodium or the ammonium and 2-5 percent by weight of tourmaline powder into a sand mill to carry out grinding of 1,200-1,400 turns/minute and then homogenizing; and adding 58-80 percent by weight of prepared aqueous latex paint base stock to the two homogenized substances to disperse and mix to prepare the environmental friendly paint. By adopting the invention, the hue of the paint cannot be influenced by the tourmaline, and the capacities of decomposing harmful gas and generating anions are greatly improved under the condition of the same quantity of titanium dioxide or tourmaline.
Description
Technical field: the present invention relates to tourmaline powder is negative ion water-based coating and the working method that dominant shape becomes with Nano titanium dioxide, particularly can decompose multiple harmful organic substance environmental protection coating material and effectively guarantee water-borne coatings whiteness working method.
Background technology: existing be used for passive (hydroxyl) anion-generating material of indoor air purification and be applied in that water-borne coatings forms can produce negative ion and the water-borne coatings that decomposes harmful organic substance.This material is to be main raw material with the tourmalinite, adds multiple functional materials such as zeolite, aluminum oxide, nano titanium oxide, zeolite, white titanium pigment, medical stone, lime carbonate pearl slurry or the powder of multiple non-metallic material through adopting special super-fine processing technology to produce such as (shells) simultaneously.It has permanent release hydroxyl negative ion (H
3O
2 -), the high 4-18um of radiation is to functions such as the useful far infrared rays of human life, antibacterial bacteriostatic, the smelly taste removals that disappears, play produce the negative ion effect be tourmalinite in action.It can be widely used in various water-baseds and oil paint, the rubber-emulsion paint; Form various coating; Add in the filtering net, indoor decoration wallpaper, indoor decoration artificial compounded floor of various air conditioning machinerys;, obnoxious flavour poisonous to the formaldehyde of releases such as indoor various decorating and renovating materials, furniture, ammonia, benzene, VOC etc. has the effect of significantly dispeling, and the health to human body has tangible enhancement simultaneously.Yet can embody the water-borne coatings of these functions; Particularly the styrene-acrylonitrile copolymer alcohol ester emulsion of water-based, pure acrylic acid emulsion latex coating; The test of just carrying out in testing laboratory, the production technique of test are by routine all fillers to be added in the dispersion liquid to disperse, and are less than weight 2% tourmaline powder but test shows interpolation; The DeGrain of the negative ion that produces, the titanium oxide of adding can PARA FORMALDEHYDE PRILLS(91,95)s yet, ammonia, benzene, VOC etc. are poisonous, obnoxious flavour produces the removal effect of decomposing.What have attempts in order to increase the effect of generation negative ion; Just need to increase the content of tourmaline powder, but the weight content of tourmaline powder is increased to greater than after 2%, along with the increase of content; The effect that produces negative ion does not increase in proportion; And extremely low, the DeGrain of ratio that increases, also the increase along with content obviously increases the coating gray scale, has formed not basic whiteness coating; The versicolor coating color and luster that adds the filler formation of other colors also causes tangible deviation, has destroyed the basic form and aspect of coating.
Summary of the invention:
The present invention seeks to overcome in the prior art; The interpolation tourmaline powder has just formed the technical problem of grey (gray scale) in water emulsion coating; A kind of form and aspect that do not influence water emulsion coating are provided, obviously increase the working method of the environmental protection coating material that produces negative ion and resolving harmful gas effect and the environmental protection coating material that this method forms.
Anion environmental protection method for producing coating of the present invention; Polyacrylate, the 0.1-3% titanic oxide nano of weight 3-16% water, 0.2-1% sodium or ammonium are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200-1400 rev/min grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous; Polyacrylate, the 2-5% tourmaline powder of weight 9-25% water, 0.2-1% sodium or ammonium are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200-1400 rev/min grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous; Weight 58-80% has prepared the water emulsion coating base-material and has added in the dispersion machine, adds the material behind above-mentioned two kinds of homogeneous again, carries out dispersing and mixing, is prepared into environmental protection coating material.
The anion environmental protection coating of the working method production of the negative environmental protection coating material of the present invention is characterized in that: have the polyacrylate of weight 3-16% water, 0.2-1% sodium or ammonium, the titania nanoparticles that the 0.1-3% titanic oxide nano forms to grind the polyacrylate of homogeneous dispersion material and weight 9-25% water, 0.2-1% sodium or ammonium, the tourmaline powder particles dispersed homogeneous substance of 2-5% tourmaline powder formation and the weight 58-80% water emulsion coating base-material dispersing and mixing of preparation like this.
The coating that the present invention forms not only can make tourmalinite not influence the coating form and aspect, and under titanium oxide that adds same amount or tourmalinite condition, also improved greatly resolving harmful gas (as) ability or produce the ability of negative ion.
Embodiment:
The working method of embodiment 1, a kind of anion environmental protection coating of the present invention is with mixing in 5 kilograms in water, 0.5 kilogram of ammonium polyacrylate, 0.2 kilogram of skimmer, 1 kilogram of adding dispersion machine of titanic oxide nano; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200 ± 20 rev/mins grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.With mixing in 25 kilograms in water, 1 kilogram of polyacrylic ammonium salt, 0.3 kilogram of skimmer, 2 kilograms of adding dispersion machines of tourmaline powder; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1400 ± 20 rev/mins grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous; In preparing the 65 kilograms of adding dispersion machines of water emulsion coating that contain 15 kilograms of filler white titanium pigments, 15 kilograms in lime carbonate, add above-mentioned two kinds of homogeneous substances again, carry out blending dispersion, be prepared into environmental protection coating material.The coating whiteness that forms can reach 96.3%.The coating that forms so not only can make tourmalinite not influence the coating form and aspect, and the method below the contrast, under titanium oxide that adds same amount or tourmalinite condition, has also improved one times of resolving harmful gas ability, has improved 1.5 times of abilities that produce negative ion.
A kind of working method that contrasts coating is with mixing in 30 kilograms in water, 1.5 kilograms of ammonium polyacrylates, 0.5 kilogram of skimmer, 1 kilogram in nano titania (nano level) powder, 2 kilograms of tourmaline powders, 15 kilograms of white titanium pigments, 15 kilograms of adding dispersion machines of lime carbonate; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1300 ± 20 rev/mins grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.In preparing 35 kilograms of adding dispersion machines of water emulsion coating, add above-mentioned this homogeneous substance again, carry out blending dispersion, be prepared into environmental protection coating material.The coating that forms crosses in vain and can only reach 69.8%.
The working method of embodiment 2, a kind of anion environmental protection coating of the present invention; The tourmalinite breeze 3% and Nano titanium dioxide powder 3% that comprise weight percent, and dispersion agent ZX-I 1%, white titanium pigment 15%, lime carbonate 15%, styrene-acrylonitrile copolymer alcohol ester emulsion 25%, pure acrylic acid emulsion 18%, water 20%.The working method of this anion environmental protection coating adds mentioned component Nano titanium dioxide powder and half the water, the dispersion agent ZX-I of total amount in the dispersion machine and mixes; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1300 ± 20 rev/mins grinding 15 minutes, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.Above-mentioned tourmaline powder and half the water, the dispersion agent ZX-I of composition total amount are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1350 ± 20 rev/mins grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.In dispersion machine, prepare water emulsion coating with filler-calcium carbonate powder, titanium white titanium and styrene-acrylonitrile copolymer alcohol ester emulsion, pure acrylic acid emulsion.Prepared in the dispersion machine of water emulsion coating and added above-mentioned two kinds of homogeneous substances again, carried out blending dispersion, be prepared into environmental protection coating material.The coating that forms crosses in vain and can reach 98.1%.Method below the contrast has also improved nearly one times of resolving harmful gas ability under titanium oxide that adds same amount or tourmalinite condition, improved 1.4 times of abilities that produce negative ion.
A kind of working method that contrasts coating; The tourmalinite breeze 3% and Nano titanium dioxide powder 3% that comprise weight percent, and dispersion agent ZX-I 1%, white titanium pigment 15%, lime carbonate 15%, styrene-acrylonitrile copolymer alcohol ester emulsion 25%, pure acrylic acid emulsion 18%, water 20%.Water, dispersion agent ZX-I, Nano titanium dioxide powder, tourmaline powder, the filler-calcium carbonate powder of mentioned component are added in the dispersion machine and mix; Said mixture is carried out 1300 rev/mins high speed dispersion, the product after the dispersion adds band and presses clarifixator to carry out homogeneous formation homogeneous substance again.In dispersion machine, prepare water emulsion coating with styrene-acrylonitrile copolymer alcohol ester emulsion, pure acrylic acid emulsion.Prepared and added above-mentioned homogeneous substance in the water emulsion coating dispersion machine again, carried out blending dispersion, be prepared into environmental protection coating material.The coating that forms crosses in vain and can only reach 66.4%.
Embodiment 3, a kind of environment-friendly type aqueous latex coating of the present invention and environment-friendly type aqueous latex coating working method.Environment protection additive is made up of total amount per-cent following ingredients: 25% tourmaline powder, 8% white titanium pigment, 2% nano level titanium oxide powder, 3% Nano-class zinc oxide, 2% dispersion agent ROHM N, N-dihydroxy ethyl ethamine, 60% water.With water, the ROHM N of tourmaline powder and above-mentioned weight 3/4ths, N-dihydroxy ethyl ethamine adds in the dispersion machine and mixes; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1350 ± 10 rev/mins grinding 20 minutes, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.With water, the ROHM N of nano level titanium oxide powder and above-mentioned weight 1/4th, N-dihydroxy ethyl ethamine adds in the dispersion machine and mixes; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1350 ± 10 rev/mins grinding 20 minutes, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous.With the mixing of materials of above-mentioned two kinds of homogeneous and add white titanium pigment, Nano-class zinc oxide and mix to stir and process environment protection additive.Environment protection additive paint additive of the present invention is accounted for 20 percent of gross weight to be added in the water emulsion coating that accounts for gross weight 80 percent; Brushing is on room wall, top ceiling; Not only can beautify the room; Can also improve Air quality to interior space release anion equably, the wall after the coating can produce the negative oxygen ion concentration＞2000/cm that meets environmental requirement
3The coating whiteness can reach 99.1%.
A kind of correlated environment-friendly type aqueous latex coating and environment-friendly type aqueous latex coating working method.Constitute paint additive by total amount per-cent following ingredients: 25% tourmaline powder, 8% white titanium pigment, 2% nano level titanium oxide powder, 3% Nano-class zinc oxide, 2% dispersion agent ROHM N, N-dihydroxy ethyl ethamine, 1% skimmer, 60% water mix stirring and process.This paint additive is accounted for 20 percent of gross weight to be added in the water emulsion coating that accounts for gross weight 80 percent; Brushing is on room wall, top ceiling; Can be to interior space release anion equably; Improve Air quality, the wall after the coating can produce the negative oxygen ion concentration＞1000/cm that meets environmental requirement
3Coating crosses in vain and can only reach 60.4%.
Embodiment 4, the environment-friendly type aqueous latex coating of a kind of the present invention and environment-friendly type aqueous latex coating working method are made up of purifying air filler and 20 kilograms of styrene-acrylonitrile copolymer alcohol ester emulsions, 19 kilograms of water emulsion coatings that constitute of ACRYLIC EMULSION.The purifying air filler is to constitute by tourmaline powder, zeolite powder with by titanic oxide nano; The content of each composition (by weight) is: 3 kilograms of tourmaline powders; 20 kilograms of zeolite powders, 3 kilograms of titanic oxide nanos, 2 kilograms of dispersion agent ammonium polyacrylates, 1 kilogram of skimmer, 32 kilograms in water.Tourmaline powder and half the water, ammonium polyacrylate, the skimmer of above-mentioned weight are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1400 rev/mins grinding 20 minutes.Titanic oxide nano and half the water, ammonium polyacrylate, the skimmer of above-mentioned weight are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200-1400 rev/min grinding; Adding zeolite powder again proceeded to grind 15 minutes; Product behind the sand milling adds after band presses clarifixator to carry out homogeneous. and two kinds of slurries that above-mentioned grinding and homogeneous are crossed change Scattered Kettle over to, again styrene-acrylonitrile copolymer alcohol ester emulsion, pure acrylic acid emulsion are added in the Scattered Kettle dispersion 5 minutes.This environmental protection coating material has excellent hydrophobicity, brushing resistance and produces the performance of negative ion, reaches toxic gas and dust in sterilization, deodorizing, the absorbed air.Sterilization, deodorizing, absorption or decompose toxic gas in the air can force rate below the existing explained hereafter of same content composition go out the coating ability and improved 1.6 times, the air-anion concentration that therefore produces is high, even can reach 2500/cm
3More than.Coating crosses in vain and can reach 95.8%.
A kind of correlated environment-friendly type aqueous latex coating and environment-friendly type aqueous latex coating working method; The content of each composition (by weight) is: 3 kilograms of tourmaline powders; 20 kilograms of zeolite powders, 3 kilograms of nano TiO 2 powders, 2 kilograms of dispersion agent ammonium polyacrylates; 1 kilogram of skimmer also has 32 kilograms in water.Water, ammonium polyacrylate, skimmer, tourmaline powder, zeolite powder, nano TiO 2 powder are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1400 rev/mins grinding 20 minutes; Change the slurry of above-mentioned grinding over to Scattered Kettle, 20 kilograms of styrene-acrylonitrile copolymer alcohol ester emulsions, ACRYLIC EMULSION are added for 19 kilograms disperse to process in 5 minutes water emulsion coating in the Scattered Kettle.Therefore the air-anion concentration that produces is high, reaches 1200/cm
3Coating crosses in vain and can reach 60.9%.
Claims (2)
1. anion environmental protection method for producing coating; Polyacrylate, the 0.1-3% titanic oxide nano of weight 3-16% water, 0.2-1% sodium or ammonium are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200-1400 rev/min grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous; Polyacrylate, the 2-5% tourmaline powder of weight 9-25% water, 0.2-1% sodium or ammonium are added in the dispersion machine and mix; Again the mixture after the above-mentioned dispersion is added sand mill and carry out 1200-1400 rev/min grinding, the product behind the sand milling adds band and presses clarifixator to carry out homogeneous; Weight 58-80% has prepared the water emulsion coating base-material and has added in the dispersion machine, adds the material behind above-mentioned two kinds of homogeneous again, carries out dispersing and mixing, is prepared into environmental protection coating material.
2. the anion environmental protection coating that claim 1 anion environmental protection method for producing coating is produced is characterized in that; There are the polyacrylate of weight 3-16% water, 0.2-1% sodium or ammonium, the titania nanoparticles that the 0.1-3% titanic oxide nano forms to grind the polyacrylate of homogeneous dispersion material and weight 9-25% water, 0.2-1% sodium or ammonium, the tourmaline powder particles dispersed homogeneous substance of 2-5% tourmaline powder formation and the weight 58-80% water emulsion coating base-material dispersing and mixing of preparation.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010102913711A CN101942274B (en) | 2010-09-21 | 2010-09-21 | Anion environmental friendly paint and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010102913711A CN101942274B (en) | 2010-09-21 | 2010-09-21 | Anion environmental friendly paint and production method thereof |
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| CN101942274A CN101942274A (en) | 2011-01-12 |
| CN101942274B true CN101942274B (en) | 2012-11-07 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105669158A (en) * | 2016-01-23 | 2016-06-15 | 王秋芹 | Graphene far-infrared heating coating and preparation method thereof |
| CN105753425A (en) * | 2016-01-23 | 2016-07-13 | 王秋芹 | Graphene and aluminum oxide based far-infrared heating coating and method for preparing same |
| CN105645899A (en) * | 2016-01-23 | 2016-06-08 | 王秋芹 | Graphene oxide silicon based far infrared heating coating and preparation method thereof |
| CN105753426A (en) * | 2016-01-23 | 2016-07-13 | 王秋芹 | Graphene-zirconia-based far-infrared heat-emitting coating and preparation method thereof |
| CN110856820A (en) * | 2018-08-24 | 2020-03-03 | 义乌倍肯新材料科技有限公司 | Nano titanium dioxide dispersion emulsion and preparation process thereof |
| CN109395582A (en) * | 2018-12-24 | 2019-03-01 | 河南普绿环保科技有限公司 | A kind of preparation method of negative ion air purifying material |
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| CN1982379A (en) * | 2005-12-15 | 2007-06-20 | 朱文明 | Inner-wall coating composition |
| CN101089062A (en) * | 2006-06-15 | 2007-12-19 | 深圳市海川实业股份有限公司 | Paint and its prepn process |
| CN101139471A (en) * | 2006-09-08 | 2008-03-12 | 青岛喜盈门集团有限公司 | Environment-friendly coating material |
| CN101177586A (en) * | 2006-11-10 | 2008-05-14 | 深圳市海川实业股份有限公司 | Paint for automobile exhaust purification in tunnel and underground car park |
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- 2010-09-21 CN CN2010102913711A patent/CN101942274B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1441010A (en) * | 2003-03-28 | 2003-09-10 | 饶俊明 | Air purifying paint |
| CN1687268A (en) * | 2005-05-02 | 2005-10-26 | 复旦大学 | Controlled released stably coating material capable of purifying air and preparation method thereof |
| CN1982379A (en) * | 2005-12-15 | 2007-06-20 | 朱文明 | Inner-wall coating composition |
| CN101089062A (en) * | 2006-06-15 | 2007-12-19 | 深圳市海川实业股份有限公司 | Paint and its prepn process |
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| CN101942274A (en) | 2011-01-12 |
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