CN105778763B - A kind of preparation technology of anion decorative panel - Google Patents

A kind of preparation technology of anion decorative panel Download PDF

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Publication number
CN105778763B
CN105778763B CN201610352443.6A CN201610352443A CN105778763B CN 105778763 B CN105778763 B CN 105778763B CN 201610352443 A CN201610352443 A CN 201610352443A CN 105778763 B CN105778763 B CN 105778763B
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parts
anion
finish
decorative panel
preparation technology
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CN105778763A (en
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吴颜风
雷雪鹏
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Henan Gaorui building materials Co.,Ltd.
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HENAN XINRUIDA ENERGY-SAVING BUILDING MATERIALS TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush first on calcium silicates substrate, base coat is sprayed after seal coat drying, impressing pattern paint after base coat drying, finish is sprayed after the drying of pattern paint, overlay film is carried out after finish drying and suppresses the anion decorative panel obtained.The preparation technology of anion decorative panel of the present invention, the anion with extremely strong absorption and oxidation can be produced during use, bacterium and the virus in air can efficiently be killed, the indoor living environment using decorative panel of the present invention can be improved simultaneously, there is certain health-care effect to human body, it is bright in luster, covering power is good, scrubbing resistance and mould proof fungi-proofing, meet modern's requirement green to living environment, suitable for being promoted the use of in the relevant industries of Indoor decorative plate for building.

Description

A kind of preparation technology of anion decorative panel
Technical field
The invention belongs to environment-friendly building materials preparation field, specially a kind of preparation technology of anion decorative panel.
Background technology
In the various construction materials of interior decoration, containing various harmful volatile organic matters, these are poisonous Harmful organic matter includes halogenated hydrocarbon compound, arene compound, aldehydes, ketone and lipoid substance, after finishing Indoor environment and air cause very big pollution, human health are constituted potentially hazardous.
Traditional inner wall of building decorative board structure and function are relatively simple, easily produce the harmful substances such as formaldehyde, easily Injury is produced to human body, it is impossible to meet requirement of the modern to Green environment-friendlyhome home environment.
Atom or atomic group lose or obtained the charged particle formed after electronics ion, anion refer to one, band or The ion of multiple negative electrical charges, also known as " anion ".Negative ions in air are divided into large, medium and small three according to the size of mobility Kind ion.The anion of small particle has good bioactivity, is easy to pass through human body blood-brain barrier, it is played into human body Biological effect.Effect based on anion, it has the title of " air vitamin " again.Countless clinical researches find, anion can be with Improve neurasthenia, insomnia, unobstructed cardiovascular and cerebrovascular, reduce blood viscosity, improve body immunity, to improving insomnia, asthma, Alleviating the persistent ailments such as hypertension, diabetes has significant curative effect, and correlative study is edited in Chen Jingzao《Modern physicses acology》With And Tsing-Hua University's woods gold penetrating judgment awards chief editor's《Environment, health and negative oxygen ion》Deng having detailed explaination in works.
The content of the invention
In order to solve the problems, such as that traditional decoration harden structure is single and not environmentally, the purpose of the present invention is a kind of anion decoration The preparation technology of plate, by the basis of traditional decoration plate preparation technology environmentally friendly anion paint safe to use substitute it is traditional Finish so that caused anion has extremely strong absorption and oxidation to decorative panel when in use, can be efficient The bacterium in air and virus are killed, while the indoor living environment using decorative panel of the present invention can be improved, is had to human body There is certain health-care effect, meet modern's requirement green to living environment.
The present invention is for the taken technical scheme that solves the above problems:
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, seal coat first on calcium silicates substrate Spray base coat after drying, impressing pattern paint after base coat drying sprays finish after the drying of pattern paint, and finish dries It is obtained anion decorative panel that overlay film and compacting are carried out after dry, and according to weight ratio, the finish preparation process is by 60-80 Part emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05-0.13 part preservatives are dispersed with stirring uniformly, add the thickening of 1-4 parts Agent and 2-6 part anion liquid are stirred, and are eventually adding 0.08-0.7 parts defoamer and are carried out the scattered stirring of low speed, using containing hydrogen The alkaline solution of oxygen radical ion adjusts pH value to 8.5-10, stands the nylon net filter that 150 mesh are used after 10min, filtrate standing 2h, Produce finish;
Need to dispel the Mg in system while system ensures alkaline environment2+, add solvable with hydroxide ion Property salting liquid, on the one hand adjust the pH value of system, another aspect hydroxide ion and Mg2+Reaction is interacted, forms Mg (OH)2 Crystallization, filtered using nylon wire to remove larger crystallization, remaining less crystallization can strengthen the viscosity of finish And stability.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 3-5%;
The not easy-to-use pure water of industrial emulsion dilutes, and the ion containing debita spissitudo contributes to the dilution of industrial emulsion in water, but It is the Mg in water2+And Ca2+It can then impact, therefore the using effect of distilled water and running water is all bad, the present invention is from hard The soft water for 4 is spent, is the Mg because in soft water2+And Ca2+Relatively low concentration is not in that industrial emulsion dilutes uneven lump Situation.
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
According to weight ratio, the finish preparation process is that 70 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.1 part is anti- Rotten agent is dispersed with stirring uniformly, adds 3 parts of thickeners and 5 parts of anion liquid are stirred, and is eventually adding 0.5 part of defoamer and is carried out The scattered stirring of low speed, the uniformly rear nylon net filter with 150 mesh to be mixed, stands 2h after filtering, produces finish.
By 60-80 parts emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05- in described finish preparation process The high-speed stirred that rotating speed is 1200 revs/min is carried out at 40 DEG C after 0.13 part of preservative mixing, stirs 30min.
High-speed stirred can use high velocity dispersators, mixed liquor is produced strong in annular flow is rolled in agitator Vortex, mixed liquor surface particle drop to vortex bottom, turbulent area are formed at scattered plate edge 2.5-5mm, mix in the shape of a spiral Liquid and particle therein are closed by intensive shear and impact;Two lines above and below being formed outside stirring region, mixed liquor obtain fully Circulate and stir.It is in stable condition by the stirred mixed liquor distributed components of this agitating mode, it is not susceptible to after standing Layering.
The preparation process of the anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 Part former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second Edetate disodium and 0.3 part of dodecyl sodium sulfate stir, gained mixture carry out ultrasonic wave exhaust, produce bear from Sub- liquid.
Disodium ethylene diamine tetraacetate is added in the formula of anion liquid and used as complexing agent.With stronger network Conjunction ability, in smaller dosage even minimum dosage with regard to the complexing degree of needs can be reached, itself also have it is scattered, suspend and make With because easily occurring what is be layered containing the particle not soluble in water such as tourmaline powder and medical stone powder, when standing in anion liquid Situation, therefore addition disodium ethylene diamine tetraacetate can improve the stability of the suspended state of anion liquid.
Dodecyl sodium sulfate has stronger emulsification, in anion liquid as a kind of anion surfactant Middle use, emulsification and stable effect are played to anion liquid while anion release is not influenceed.
For the calcium silicates substrate by fixed thick sanding to 4cm, the round brush seal coat on sanding face, round brush thickness is often to put down 40 grams of side.
The drying course is to dry 30-50min in 50 DEG C of environment.
The coating thickness of the base coat is 50 grams every square metre;The printing thickness of the pattern paint is every square metre 35 Gram;The coating thickness of the finish is 20 grams every square metre.
Beneficial effects of the present invention:
The preparation technology of a kind of anion decorative panel of the present invention, by the basis of traditional decoration plate preparation technology On used the anion paint of safety and environmental protection to substitute traditional finish, industrial emulsion has used the solvent to be wherein in anion paint The sodium chloride solution of soft water is diluted, and has been dispelled calcium ion and magnesium ion in solvent, has been avoided both examples and anion Combination reaction occurs for some elements in liquid so as to influence the effect that finish produces anion, is added in addition in anion liquid A certain proportion of medical stone powder, medical stone is to no toxic biological and have certain bioactivity, and main component is except sial Beyond hydrochlorate and some macroelements, also containing various trace elements and rare earth element, its rare earth elements and tourmaline powder phase Interaction can significantly improve the anion growing amount of finish.
In summary, a kind of preparation technology of anion decorative panel of the present invention, obtained decorative panel are using During can produce the anion with extremely strong absorption and oxidation, can efficiently kill bacterium in air and Virus, while the indoor living environment using decorative panel of the present invention can be improved, there is certain health-care effect to human body, again Because successively coating four layers of paint in preparation process of the present invention, and methylisothiozoline is with the addition of in last finish Ketone so that anion decorative panel is bright in luster, and covering power is good, scrubbing resistance and mould proof fungi-proofing, and it is green to living environment to meet modern The requirement that colour circle is protected, suitable for being promoted the use of in the relevant industries of Indoor decorative plate for building.
Embodiment
With reference to specific examples below, the present invention is described in further detail, and protection scope of the present invention is not limited to In following examples.Implement process of the invention, condition, reagent, experimental method etc., in addition to the following content specially referred to, It is the universal knowledege and common knowledge of this area, content is not particularly limited in the present invention.
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, seal coat first on calcium silicates substrate Spray base coat after drying, impressing pattern paint after base coat drying sprays finish after the drying of pattern paint, and finish dries It is obtained anion decorative panel that overlay film and compacting are carried out after dry, and according to weight ratio, the finish preparation process is by 60-80 Part emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05-0.13 part preservatives are dispersed with stirring uniformly, add the thickening of 1-4 parts Agent and 2-6 part anion liquid are stirred, and are eventually adding 0.08-0.7 parts defoamer and are carried out the scattered stirring of low speed, using containing hydrogen The alkaline solution of oxygen radical ion adjusts pH value to 8.5-10, stands the nylon net filter that 150 mesh are used after 10min, filtrate standing 2h, Produce finish;
Need to dispel the Mg in system while system ensures alkaline environment2+, add solvable with hydroxide ion Property salting liquid, on the one hand adjust the pH value of system, another aspect hydroxide ion and Mg2+Reaction is interacted, forms Mg (OH)2 Crystallization, filtered using nylon wire to remove larger crystallization, remaining less crystallization can strengthen the viscosity of finish And stability.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 3-5%;
The not easy-to-use pure water of industrial emulsion dilutes, and the ion containing debita spissitudo contributes to the dilution of industrial emulsion in water, but It is the Mg in water2+And Ca2+It can then impact, therefore the using effect of distilled water and running water is all bad, the present invention is from hard The soft water for 4 is spent, is the Mg because in soft water2+And Ca2+Relatively low concentration is not in that industrial emulsion dilutes uneven lump Situation.
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
According to weight ratio, the finish preparation process is that 70 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.1 part is anti- Rotten agent is dispersed with stirring uniformly, adds 3 parts of thickeners and 5 parts of anion liquid are stirred, and is eventually adding 0.5 part of defoamer and is carried out The scattered stirring of low speed, the uniformly rear nylon net filter with 150 mesh to be mixed, stands 2h after filtering, produces finish.
By 60-80 parts emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05- in described finish preparation process The high-speed stirred that rotating speed is 1200 revs/min is carried out at 40 DEG C after 0.13 part of preservative mixing, stirs 30min.
High-speed stirred can use high velocity dispersators, mixed liquor is produced strong in annular flow is rolled in agitator Vortex, mixed liquor surface particle drop to vortex bottom, turbulent area are formed at scattered plate edge 2.5-5mm, mix in the shape of a spiral Liquid and particle therein are closed by intensive shear and impact;Two lines above and below being formed outside stirring region, mixed liquor obtain fully Circulate and stir.It is in stable condition by the stirred mixed liquor distributed components of this agitating mode, it is not susceptible to after standing Layering.
The preparation process of the anion liquid is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 Part former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second Edetate disodium and 0.3 part of dodecyl sodium sulfate stir, gained mixture carry out ultrasonic wave exhaust, produce bear from Sub- liquid.
Disodium ethylene diamine tetraacetate is added in the formula of anion liquid and used as complexing agent.With stronger network Conjunction ability, in smaller dosage even minimum dosage with regard to the complexing degree of needs can be reached, itself also have it is scattered, suspend and make With because easily occurring what is be layered containing the particle not soluble in water such as tourmaline powder and medical stone powder, when standing in anion liquid Situation, therefore addition disodium ethylene diamine tetraacetate can improve the stability of the suspended state of anion liquid.
Dodecyl sodium sulfate has stronger emulsification, in anion liquid as a kind of anion surfactant Middle use, emulsification and stable effect are played to anion liquid while anion release is not influenceed.
For the calcium silicates substrate by fixed thick sanding to 4cm, the round brush seal coat on sanding face, round brush thickness is often to put down 40 grams of side.
The drying course is to dry 30-50min in 50 DEG C of environment.
The coating thickness of the base coat is 50 grams every square metre;The printing thickness of the pattern paint is every square metre 35 Gram;The coating thickness of the finish is 20 grams every square metre.
Embodiment 1
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, calcium silicates first on calcium silicates substrate Substrate is 40 grams every square by fixed thick sanding to 4cm, round brush thickness, and seal coat sprays after drying 30min in 50 DEG C of environment Linging colored paint, the coating thickness of base coat is 50 grams every square metre, and base coat prints figure after 30min is dried in 50 DEG C of environment Case paint, the printing thickness of pattern paint is 35 grams every square metre, and cover is sprayed after 30min is dried in environment of the pattern paint at 50 DEG C Paint, the coating thickness of finish is 20 grams every square metre, and the anion dress that overlay film obtains with compacting is carried out after finish drying Plaque, according to weight ratio, the finish preparation process is by 60 parts of emulsions, 2 parts of mill bases, 10 parts of colouring agents and 0.05 part of anti-corrosion Agent is dispersed with stirring uniformly, adds 1 part of thickener and 2 parts of anion liquid are stirred, and is eventually adding 0.08 part of defoamer and is carried out The scattered stirring of low speed, pH value is adjusted to 8.5 using the alkaline solution containing hydroxide ion, stand after 10min with the Buddhist nun of 150 mesh Imperial net filtration, filtrate stand 2h, produce finish;By 60 parts of emulsions, 2 parts of mill bases, 10 parts of colouring agents in finish preparation process The high-speed stirred that rotating speed is 1200 revs/min is carried out after being mixed with 0.05 portion of preservative at 40 DEG C, stirs 30min.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 3%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;Preparation process is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part Former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second two Amine tetraacethyl disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasonic wave exhaust, produces anion Liquid.
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
Embodiment 2
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, calcium silicates first on calcium silicates substrate Substrate is 40 grams every square by fixed thick sanding to 4cm, round brush thickness, and seal coat sprays after drying 35min in 50 DEG C of environment Linging colored paint, the coating thickness of base coat is 50 grams every square metre, and base coat prints figure after 35min is dried in 50 DEG C of environment Case paint, the printing thickness of pattern paint is 35 grams every square metre, and cover is sprayed after 35min is dried in environment of the pattern paint at 50 DEG C Paint, the coating thickness of finish is 20 grams every square metre, and the anion dress that overlay film obtains with compacting is carried out after finish drying Plaque, according to weight ratio, the finish preparation process is by 65 parts of emulsions, 3 parts of mill bases, 12 parts of colouring agents and 0.08 part of anti-corrosion Agent is dispersed with stirring uniformly, adds 1.5 parts of thickeners and 3 parts of anion liquid are stirred, be eventually adding 0.15 part of defoamer and enter The scattered stirring of row low speed, pH value is adjusted to 9 using the alkaline solution containing hydroxide ion, stand after 10min with the Buddhist nun of 150 mesh Imperial net filtration, filtrate stand 2h, produce finish;By 65 parts of emulsions, 3 parts of mill bases, 12 parts of colouring agents in finish preparation process The high-speed stirred that rotating speed is 1200 revs/min is carried out after being mixed with 0.08 portion of preservative at 40 DEG C, stirs 30min.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 3.5%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;Preparation process is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part Former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second two Amine tetraacethyl disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasonic wave exhaust, produces anion Liquid.
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
Embodiment 3
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, calcium silicates first on calcium silicates substrate Substrate is 40 grams every square by fixed thick sanding to 4cm, round brush thickness, and seal coat sprays after drying 40min in 50 DEG C of environment Linging colored paint, the coating thickness of base coat is 50 grams every square metre, and base coat prints figure after 40min is dried in 50 DEG C of environment Case paint, the printing thickness of pattern paint is 35 grams every square metre, and cover is sprayed after 40min is dried in environment of the pattern paint at 50 DEG C Paint, the coating thickness of finish is 20 grams every square metre, and the anion dress that overlay film obtains with compacting is carried out after finish drying Plaque, according to weight ratio, the finish preparation process is by 70 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.1 part of anti-corrosion Agent is dispersed with stirring uniformly, adds 3 parts of thickeners and 5 parts of anion liquid are stirred, and it is low to be eventually adding 0.5 part of defoamer progress The scattered stirring of speed, the uniformly rear nylon net filter with 150 mesh to be mixed, stands 2h after filtering, produces finish.It is prepared by finish During will 70 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.1 portion of preservative mix after rotating speed is carried out at 40 DEG C is 1200 Rev/min high-speed stirred, stir 30min.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 4%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;Preparation process is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part Former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second two Amine tetraacethyl disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasonic wave exhaust, produces anion Liquid.
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
Embodiment 4
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, calcium silicates first on calcium silicates substrate Substrate is 40 grams every square by fixed thick sanding to 4cm, round brush thickness, and seal coat sprays after drying 45min in 50 DEG C of environment Linging colored paint, the coating thickness of base coat is 50 grams every square metre, and base coat prints figure after 45min is dried in 50 DEG C of environment Case paint, the printing thickness of pattern paint is 35 grams every square metre, and cover is sprayed after 45min is dried in environment of the pattern paint at 50 DEG C Paint, the coating thickness of finish is 20 grams every square metre, and the anion dress that overlay film obtains with compacting is carried out after finish drying Plaque, according to weight ratio, the finish preparation process is by 75 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.11 part of anti-corrosion Agent is dispersed with stirring uniformly, adds 3 parts of thickeners and 5 parts of anion liquid are stirred, and it is low to be eventually adding 0.6 part of defoamer progress The scattered stirring of speed, pH value is adjusted to 8.5-10 using the alkaline solution containing hydroxide ion, stand after 10min with 150 purposes Nylon net filter, filtrate stand 2h, produce finish;By 75 parts of emulsions, 5 parts of mill bases, 15 parts of colorings in finish preparation process The high-speed stirred that rotating speed is 1200 revs/min is carried out at 40 DEG C after agent and 0.11 part of preservative mixing, stirs 30min.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 3-5%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;Preparation process is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part Former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second two Amine tetraacethyl disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasonic wave exhaust, produces anion Liquid.
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
Embodiment 5
A kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush, calcium silicates first on calcium silicates substrate Substrate is 40 grams every square by fixed thick sanding to 4cm, round brush thickness, and seal coat sprays after drying 50min in 50 DEG C of environment Linging colored paint, the coating thickness of base coat is 50 grams every square metre, and base coat prints figure after 50min is dried in 50 DEG C of environment Case paint, the printing thickness of pattern paint is 35 grams every square metre, and cover is sprayed after 50min is dried in environment of the pattern paint at 50 DEG C Paint, the coating thickness of finish is 20 grams every square metre, and the anion dress that overlay film obtains with compacting is carried out after finish drying Plaque, according to weight ratio, the finish preparation process is by 80 parts of emulsions, 6 parts of mill bases, 16 parts of colouring agents and 0.13 part of anti-corrosion Agent is dispersed with stirring uniformly, adds 4 parts of thickeners and 6 parts of anion liquid are stirred, and it is low to be eventually adding 0.7 part of defoamer progress The scattered stirring of speed, pH value is adjusted to 10 using the alkaline solution containing hydroxide ion, stand after 10min with the nylon of 150 mesh Net filtration, filtrate stand 2h, produce finish;In finish preparation process by 80 parts of emulsions, 6 parts of mill bases, 16 parts of colouring agents and The high-speed stirred that rotating speed is 1200 revs/min is carried out at 40 DEG C after 0.13 part of preservative mixing, stirs 30min.
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10: 4:2:1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, the mass fraction of solute For 5%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polypropylene Acid amides forms, and the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part Former times purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and wheat meal The fineness of stone flour is 3000 mesh;Preparation process is by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part Former times purine natural gum carries out the stirring that rotating speed is 800 revs/min at room temperature, mixing time 10min, adds 0.05 part of second two Amine tetraacethyl disodium and 0.3 part of dodecyl sodium sulfate stir, and gained mixture carries out ultrasonic wave exhaust, produces anion Liquid.
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.

Claims (6)

1. a kind of preparation technology of anion decorative panel, the moistureproof seal coat of round brush first on calcium silicates substrate, seal coat warp Spray base coat after drying, impressing pattern paint after base coat drying, finish, finish drying are sprayed after the drying of pattern paint It is obtained anion decorative panel to carry out overlay film and compacting afterwards, it is characterised in that:According to weight ratio, the finish preparation process For 60-80 parts emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05-0.13 part preservatives are dispersed with stirring uniformly, add 1-4 parts thickener and 2-6 part anion liquid are stirred, and are eventually adding 0.08-0.7 parts defoamer and are carried out the scattered stirring of low speed, PH value is adjusted to 8.5-10 using the alkaline solution containing hydroxide ion, is stood after 10min with the nylon net filter of 150 mesh, Filtrate stands 2h, produces finish;
The emulsion is by industrial emulsion, sodium chloride solution, starch, polyvinyl alcohol and sodium carboxymethylcellulose according to 40:10:4:2: 1 ratio is sufficiently mixed obtained, and solvent wherein in sodium chloride solution is the soft water that hardness is 4, and the mass fraction of solute is 3- 5%;
According to weight ratio, the mill base is by 1 part of titanium dioxide, 23 parts of barium sulfate, 60 parts of distilled water and 0.08 part of polyacrylamide Composition, the fineness of wherein titanium dioxide and barium sulfate is 500 mesh;
According to weight ratio, the anion liquid is fast by 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water, 0.06 part of former times Purine natural gum, 0.05 part of disodium ethylene diamine tetraacetate, wherein 0.3 part of dodecyl sodium sulfate composition, tourmaline powder and medical stone powder Fineness be 3000 mesh;
The defoamer is organic silicon emulsion, and thickener is sodium carboxymethylcellulose, and preservative is methylisothiazolinone.
A kind of 2. preparation technology of anion decorative panel as claimed in claim 1, it is characterised in that:It is described according to weight ratio Finish preparation process adds for 70 parts of emulsions, 5 parts of mill bases, 15 parts of colouring agents and 0.1 portion of preservative are dispersed with stirring uniformly 3 parts of thickeners and 5 parts of anion liquid are stirred, and are eventually adding 0.5 part of defoamer and are carried out the scattered stirring of low speed, to be mixed uniform Afterwards with the nylon net filter of 150 mesh, 2h is stood after filtering, produces finish.
A kind of 3. preparation technology of anion decorative panel as claimed in claim 1, it is characterised in that:It is prepared by described finish During by 60-80 parts emulsion, 2-6 parts mill base, 10-16 parts colouring agent and 0.05-0.13 parts preservative mix after at 40 DEG C The high-speed stirred that rotating speed is 1200 revs/min is carried out, stirs 30min.
A kind of 4. preparation technology of anion decorative panel as claimed in claim 1, it is characterised in that:The system of the anion liquid Standby process is to carry out 20 parts of tourmaline powders, 10 parts of medical stone powders, 70 parts of distilled water and 0.06 part of former times purine natural gum at room temperature Rotating speed is 800 revs/min of stirring, mixing time 10min, adds 0.05 part of disodium ethylene diamine tetraacetate and 0.3 part ten Dialkyl sulfonates stir, and gained mixture carries out ultrasonic wave exhaust, produces anion liquid.
A kind of 5. preparation technology of anion decorative panel as claimed in claim 1, it is characterised in that:The calcium silicates substrate warp Fixed thick sanding is crossed to 4cm, the round brush seal coat on sanding face, round brush thickness is 40 grams every square.
A kind of 6. preparation technology of anion decorative panel as claimed in claim 1, it is characterised in that:The spraying of the base coat Thickness is 50 grams every square metre;The printing thickness of the pattern paint is 35 grams every square metre;The coating thickness of the finish is 20 grams every square metre.
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