CN102302927B - Air purification heath protection mud and production process thereof - Google Patents
Air purification heath protection mud and production process thereof Download PDFInfo
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Abstract
The invention provides air purification heath protection mud and a production process thereof. The health protection mud consists of a component I and a component II, wherein the component I comprises diatomite, zeolite powder, maifanitum powder, nano zinc oxide, negative ion powder, dispersible latex powder, methyl cellulose and an inorganic pigment; and the component II comprises water, an anti-freezing agent, a dispersing agent, an antifoaming agent, an emulsifying agent, a stabilizing agent, a macromolecule packaging agent, and cypress oil, clove oil or eucalyptus oil. The health protection mud has the effect of eliminating harmful substances such as formaldehyde, benzene and the like and improving indoor geomagnetic intensity, can produce negative ions, has the functions of deodorization, smell elimination, inflaming retardant, sound insulation and noise reduction, and can adjust indoor air humidity.
Description
Technical field
The present invention relates to a kind of air purification heath protection mud, especially a kind of health care mud and production technology thereof with air cleaning of in interior decoration, using.
Background technology
Along with the development of industry and science and technology, people's living standard progressively improves, but has also caused thus the problem of environmental pollution.The discharging of industrial area waste gas, the discharging of vehicle exhaust has all caused impact to the environment in cities and towns in the city.At present, energy-conserving and environment-protective have become the trend in epoch, and China has also formulated the standard of control air quality accordingly.
Material for air purification commonly used in the at present interior decoration is diatom ooze, diatom ooze is a kind of material, it is a kind of unicellular aquatic class biology that swims of living in before millions of years, that is to say the deposit of diatom, diatom after death, at the bottom of its meeting connate water, become diatom ooze through the accumulation in 1 years and geology transition.Diatom ooze is a kind of biogenic silicastone, and the remains of diatom form by ancient times, and its chemical composition is mainly SiO2, also has in addition a small amount of Al2O3, CaO, MgO etc., mainly is used as adsorbent, filter aid and decolorizer etc.Microscopically can be observed the special porous structure of natural diatomaceous earth, shows under the electron microscope that its particle surface has countless small holes, and porosity reaches more than 90%, and specific area reaches 65 ㎡/g.Many 5000 to 6000 times of its ultrafine micropore specific activity charcoal, this outstanding molecular sieve structure has determined the function that it is unique just, has extremely strong physical absorption performance and ion-exchange performance.The people all one's life about 30-70% time spend indoor, and indoorly contact maximum to be exactly metope, so in recent years, people utilize diatomaceous loose structure especially, to add again function additive and be applied to healthy household coating industry with the people.
But use at present separately diatom ooze still can not reach higher air standards, and its air cleaning and bacteria-eliminating efficacy are also undesirable.
Summary of the invention
The present patent application namely is for the defects that exists in interior decoration at present, provides a kind of take diatom ooze as basic material, add novel interior decoration raw material that macromolecular material, nano material and biomaterial obtain with and preparation method thereof.
One of purpose of the present patent application provides a kind of air purification heath protection mud:
Specifically, the described a kind of air purification heath protection mud of the present patent application is comprised of component one and component two, and wherein, component one comprises the various components of following weight portion:
Diatomite 30-60; Zeolite powder 10-30; Medical stone powder 20-30;
Nano zine oxide 1-10; Negative ion powder 0.3-3.0; Polymer dispersion powder 2.0-6.0;
Methylcellulose 0.3-1.0; Inorganic pigment 0.1-1.0;
Component two comprises the various components of following weight portion:
Water 60-80; Antifreezing agent 1.5-3.5; Dispersant 0.6-2.0;
Defoamer 0.6-1.5; Emulsifying agent 1.0-3.0 stabilizing agent 0.1-3.0;
Macromolecule coating agent 0.8-3.0; Cupressin, caryophyllus oil or lemon eucalyptus oil 10-30.
Another purpose of the present patent application provides the production technology of above-mentioned health care mud:
The production technology of described air purification heath protection mud, wherein, the production stage of component one is as described below:
1. according to the weight proportion in the said components one zeolite powder, negative ion powder, nano zine oxide, polymer dispersion powder, methylcellulose are added in the container and stir, rotating speed is 200 rev/mins, and the time of mixing is 5-10 minute;
2. the diatomite that adds proportioning in the component one, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
3. the medical stone powder and the inorganic pigment that add proportioning in the component one, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
4. to be mixedly pack after evenly;
The production stage of component two is as described below:
1. according to described proportioning water is added in the rustless steel container, start mixer and carry out mix and blend with 300 rev/mins rotating speed, then add successively dispersant, defoamer, the antifreezing agent of described proportioning, mix and blend 5-10 minute;
2. the macromolecule coating agent that then adds described proportioning, and rotating speed transferred to 1000 rev/mins, stir and add emulsifying agent after 10-15 minute, after carrying out mix and blend 5-10 minute with 300 rev/mins rotating speed again, add in the emulsify at a high speed cutter, disperseed 5-10 minute with 10000 rev/mins speed;
3. then gained liquid is placed rustless steel container again, start mixer and carry out mix and blend with 500 rev/mins rotating speed, the cupressin, caryophyllus oil or the lemon eucalyptus oil that slowly add described proportioning, and then rotating speed transferred to 1000 rev/mins, stir the stabilizing agent that adds again described proportioning after 5-10 minute, continue stirring and obtain component two after 5-10 minute, pack.
The present patent application also provides the using method of above-mentioned air purification heath protection mud, and its step is as follows: component two is put into an amount of water stirred, add component one after stirring again, wherein, the weight ratio of component one, component two and water is 10:1:10.
Methylcellulose claims again MC, for white or off-white color is fibrous or granulated powders, odorless.Almost insoluble in absolute ethyl alcohol, ether, acetone.In 80-90 ℃ hot water, disperse rapidly, swelling, rapidly dissolving after the cooling, the aqueous solution is quite stable at normal temperatures, can gel during high temperature, and this gel can change mutually with solution with the height of temperature.Have good wetability, dispersiveness, cementability, thickening property, emulsibility, water-retaining property and film forming, and to the impermeability of grease.Institute's film forming has good toughness, flexibility and transparency, because belonging to nonionic, can with other emulsifying agent compatibility, but easily saltout, solution is stable in the PH2-12 scope.Be widely used in construction, building materials, dispersion paint, wallpaper thickener, reagent and additive in polymerization, paint remover, leather, printing ink, papermaking philosophy are as thickener, bonding agent, water-loss reducer, film forming agent, excipient etc.As being used as adhesive, thickener and water-loss reducer at building materials, as film forming agent and thickener, use in addition also comparatively extensive at coatings industry in fields such as oil drilling and daily-use chemical industries.
Negative ion powder is the principle that human use's nature produces anion, and manually a kind of complex mineral of synthetic or proportioning generally all is tourmaline powder+lanthanide series or rare earth element.Negative ion powder has the effect that purifies air, eliminates human-body fatigue, promotes health.In addition, also have antibacterial, degermation, and have obvious deodorization functions.
Zeolite powder is natural levigate the forming of Zeolite Rock, and color is white.It contains aquatic animal to grow and grows required whole macroelements and most of trace element, these elements all exist with ionic condition, zeolite also has unique adsorptivity, catalytic, ion exchangeable, selective, the acid resistance of ion, heat endurance, many compositions property and very high biologically active and mithridatism etc.Cation in zeolite hole and the passage also has stronger selective ion exchange performance.Can with animal harmful heavy metal ion and cyanide are removed, useful metal ion be released.
Medical stone is a kind of to biological nontoxic, harmless and have certain bioactive complex mineral or medicinal rock, and the main chemical compositions of medical stone is inorganic alumino-silicate.Medical stone is a kind of natural medicine ore, contains 18 kinds of trace elements such as the necessary potassium of human body, sodium, calcium, magnesium, phosphorus macroelement and zinc, iron, selenium, copper, strontium, iodine, fluorine, metasilicic acid.Contain aluminum silicate (feldspar) in the medical stone, pigment and bacterium are had adsorption capacity, if with the medical stone pulverize, ion stripping and suction-operated strengthen.Medical stone energy adsorbed water middle reaches ion, medical stone is behind water, leachable to trace elements such as human body and organism useful macroelement K, Ca, Mg and Si, Fe, Zn, Cu, Mo, Se, Mn, Sr, Ni, V, Li, Co, Cr, I, Ge, Ti, medical stone can also the necessary amino acid of stripping human body in the aqueous solution.
Nano zine oxide (ZnO) particle diameter is a kind of novel high function fine inorganic product geared to the 21st century between 1-100 nm, shows many special character, such as non-migrating, fluorescence, piezoelectricity, absorption and scatters ultraviolet ability etc.
Polymer dispersion powder is water-soluble redispersible powder, is the copolymer of ethylene/vinyl acetate, vinyl acetate/versatic acid ethylene copolymer, acrylic acid copolymer etc., with polyvinyl alcohol as protecting colloid.Because polymer dispersion powder has high cementitiousness and unique performance, as: water-resistance, application property and thermal insulation etc., so their range of application is extremely widely.
Cupressin is the resin that Cupressaceae plant cypress trunk oozes out, and has and dispels the wind, detoxifcation, the effect of myogenic; " caryophyllus oil " is use plant by tropical medicinal, the spices that originate in Southeast Asia, for yellowish or colourless must clear and bright grease, the special aroma of cloves is arranged, the traditional Chinese medical science thinks to have warm stomach, fall contrary, as to wet kidney, detoxifcation effect; The lemon eucalyptus oil carries out fumigation, and lemon eucalyptus oil reaches 95.4% to natural bacteria killing rate in the room air; Shine with ultraviolet lamp under the same conditions, be 89.7% to natural bacteria killing rate in the room air, the lemon eucalyptus oil fumigation, under 10ml/m3 dosage to room air in the natural bacteria killing effect can reach the sterilization qualified requirement, more effective than ultraviolet lamp disinfection.
All the other antifreezing agents, dispersant, defoamer, emulsifying agent, stabilizing agent and macromolecule coating agent all are common chemical industry, all can be by commercially available acquisition.
Inorganic pigment comprises various metal oxides, chromate, carbonate, sulfate and sulfide etc., all belongs to the inorganic pigment category such as aluminium powder, copper powder, carbon black, zinc white and titanium white etc.
But its composition of antifreezing agent can be divided into strong electrolyte inorganic salts (chloride salt, villaumite resistance rust class, without chloride salt), water-soluble organic compounds class, organic compound and inorganic salts complex class, compound antifreezing agent.Divide freezing point reduction type and surfactant type two classes.That reduces freezing point has low-carbon (LC) alcohols, dihydroxylic alcohols and an amide-type etc.Surfactant type can make material form the hydrophobicity absorbing film on the surface, such as acid phosphate amine salt, alkylamine, fatty acid amide, organic acid esters, alkyl succinimide etc.As in concrete, for mixing concrete being hardened, and reach at the appointed time enough antifreeze intensity under subzero temperature.
Defoamer is called again anti-foaming agent, can produce many harmful foams in industrial process, needs to add defoamer.The kind of defoamer is a lot, organosiloxane, polyethers, silicon and ether grafting, contains amine, imines and amide-type, and it is faster to have an antifoaming speed, and it is longer to press down the bubble time, and Applicable media is wider, even the characteristics of harsh media environment such as high temperature, strong acid and highly basic.Common are silicone oil, polyethers, higher alcohol, mineral oil, plant wet goods.
Emulsifying agent is the stabilizing agent of emulsion, is a class surfactant.The effect of emulsifying agent is: when it is dispersed in dispersate surperficial, form film or electric double layer, can make decentralized photo with electric charge, so just can stop the droplet of decentralized photo to condense mutually, make the emulsion of formation more stable.Emulsifying agent commonly used has soap, Arabic gum, sodium alkyl benzene sulfonate etc.
The stability chemicals that can increase solution, colloid, solid, mixture all are stabilizing agent.Its reaction of can slowing down keeps chemical balance, reduces surface tension, prevents the effects such as light, thermal decomposition or oxidation Decomposition.
The described air purification heath protection mud of the present patent application has following advantage:
1, as a kind of interior decoration coating, be used for decorated wall surface and ceiling, and the quality that can purify the air of a room, and have bactericidal effect;
2, the effect that has harmful substances such as eliminating formaldehyde, benzene, and can produce anion, have deodorizing disappear the flavor function, and the air humidity in can conditioning chamber, anti-fire-retardant, sound insulation and noise reduction, and have the effect that increases indoor absolute force;
3, production technology is simple, is easy to promote.
The specific embodiment
Below in conjunction with concrete embodiment; the described air purification heath protection mud of the present patent application and manufacture craft thereof are described; purpose is better to understand the described technology contents of the present patent application for the public; rather than to the restriction of described technology contents; in fact; with the improvement of identical with the present patent application or approximate principle to described health care mud and manufacture craft thereof; comprise increase and decrease and replacement to respective components; and the change of regulating in the production technology; it is namely available all to be that persons skilled in the art need not performing creative labour, therefore all within the present patent application technical scheme required for protection.
Embodiment one
The described air purification heath protection mud of the present patent application is comprised of component one and component two, and wherein, component one comprises the various components of following weight portion:
Diatomite 30; Zeolite powder 30; Medical stone powder 20;
Nano zine oxide 1.0; Negative ion powder 3.0; Polymer dispersion powder 6.0;
Methylcellulose 0.3; Zinc white 0.1;
Component two comprises the various components of following weight portion:
Water 60; Antifreezing agent 1.5; Dispersant 2.0;
Defoamer 0.6; Emulsifying agent 1.0 stabilizing agents 3.0;
Macromolecule coating agent 0.8; Cupressin 10.
Embodiment two
The described air purification heath protection mud of the present patent application is comprised of component one and component two, and wherein, component one comprises the various components of following weight portion:
Diatomite 60; Zeolite powder 10; Medical stone powder 30;
Nano zine oxide 10; Negative ion powder 0.3; Polymer dispersion powder 2.0;
Methylcellulose 1.0; Copper powder 1.0;
Component two comprises the various components of following weight portion:
Water 80; Antifreezing agent 3.5; Dispersant 0.6;
Defoamer 1.5; Emulsifying agent 3.0 stabilizing agents 0.1;
Macromolecule coating agent 3.0; Caryophyllus oil 30.
Embodiment three
The described air purification heath protection mud of the present patent application is comprised of component one and component two, and wherein, component one comprises the various components of following weight portion:
Diatomite 40; Zeolite powder 20; Medical stone powder 25;
Nano zine oxide 5; Negative ion powder 2.0; Polymer dispersion powder 4.0;
Methylcellulose 0.7; Carbon black 0.7;
Component two comprises the various components of following weight portion:
Water 70; Antifreezing agent 2.0; Dispersant 1.2;
Defoamer 1.1; Emulsifying agent 2.0 stabilizing agents 2.0;
Macromolecule coating agent 2.0; Lemon eucalyptus oil 20.
Embodiment four
Be described with the production technology of embodiment three described components to this air purification heath protection mud, the production technology of all the other prescriptions is similar, repeats no more.
Wherein, the production stage of component one is as described below:
1, will stir in 20 parts of zeolite powders, 2 parts of negative ion powders, 5 parts of nano zine oxides, 4 parts of polymer dispersion powders, 0.7 part of adding container of methylcellulose according to above-mentioned weight proportion, rotating speed is 200 rev/mins, and the time of mixing is 5-10 minute;
2, add 40 parts in diatomite, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
3, add 0.7 part of 25 parts of medical stone powders and carbon black, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
4, to be mixedly pack after evenly;
The production stage of component two is as described below:
1, according to described proportioning 70 parts in water is added in the rustless steel container, start mixer and carry out mix and blend with 300 rev/mins rotating speed, then 2 parts of 1.2 parts of dispersants, the defoamers, 2 parts of the antifreezing agents that add successively described proportioning, mix and blend 5-10 minute;
2,2 parts of macromolecule coating agents that then add described proportioning, and rotating speed transferred to 1000 rev/mins, stir and add 2 parts of emulsifying agents after 10-15 minute, after carrying out mix and blend 5-10 minute with 300 rev/mins rotating speed again, add in the emulsify at a high speed cutter, disperseed 5-10 minute with 10000 rev/mins speed;
3, then gained liquid is placed rustless steel container again, start mixer and carry out mix and blend with 500 rev/mins rotating speed, 20 parts of the lemon eucalyptus oils of the described proportioning of slow adding, and then rotating speed transferred to 1000 rev/mins, stir 2 parts of stabilizing agents that add again described proportioning after 5-10 minute, continue stirring and obtain component two after 5-10 minute, pack.
Embodiment five
The air purification heath protection mud that obtains in the embodiment four illustrates its construction using method as example, its step is as follows: component two is put into an amount of water stirred, add component one after stirring, wherein, the weight ratio of component one, component two and water is 10:1:10 again.
Claims (4)
1. air purification heath protection mud, it is characterized in that: described health care mud is comprised of component one and component two, and wherein, component one is comprised of the component of following weight portion:
Diatomite 30-60; Zeolite powder 10-30; Medical stone powder 20-30;
Nano zine oxide 1-10; Negative ion powder 0.3-3.0; Polymer dispersion powder 2.0-6.0;
Methylcellulose 0.3-1.0; Inorganic pigment 0.1-1.0;
Component two is comprised of the component of following weight portion:
Water 60-80; Antifreezing agent 1.5-3.5; Dispersant 0.6-2.0;
Defoamer 0.6-1.5; Emulsifying agent 1.0-3.0 stabilizing agent 0.1-3.0;
Macromolecule coating agent 0.8-3.0; Cupressin, caryophyllus oil or lemon eucalyptus oil 10-30.
2. air purification heath protection mud according to claim 1, it is characterized in that: described health care mud is comprised of component one and component two, and wherein, component one comprises the various components of following weight portion:
Diatomite 40; Zeolite powder 20; Medical stone powder 25;
Nano zine oxide 5; Negative ion powder 2.0; Polymer dispersion powder 4.0;
Methylcellulose 0.7; Carbon black 0.7;
Component two comprises the various components of following weight portion:
Water 70; Antifreezing agent 2.0; Dispersant 1.2;
Defoamer 1.1; Emulsifying agent 2.0 stabilizing agents 2.0;
Macromolecule coating agent 2.0; Cupressin, caryophyllus oil or lemon eucalyptus oil 20.
3. the manufacture craft of air purification heath protection mud claimed in claim 1, it is characterized in that: wherein, the production stage of component one is as described below:
To stir in zeolite powder, negative ion powder, nano zine oxide, polymer dispersion powder, the methylcellulose adding container according to the weight proportion in the said components one, rotating speed is 200 rev/mins, and the time of mixing is 5-10 minute;
The diatomite that adds proportioning in the component one, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
The medical stone powder and the inorganic pigment that add proportioning in the component one, with 200 rev/mins rotating speed, mix and blend 5-10 minute;
To be mixedly pack after evenly;
The production stage of component two is as described below:
According to proportioning water is added in the rustless steel container, start mixer and carry out mix and blend with 300 rev/mins rotating speed, then add successively dispersant, defoamer, the antifreezing agent of proportioning, mix and blend 5-10 minute;
Then the macromolecule coating agent that adds proportioning, and rotating speed transferred to 1000 rev/mins, stir and add emulsifying agent after 10-15 minute, carry out mix and blend 5-10 minute with 300 rev/mins rotating speed again after, add in the emulsify at a high speed cutter, disperseed 5-10 minute with 10000 rev/mins speed;
Then gained liquid is placed rustless steel container again, start mixer and carry out mix and blend with 500 rev/mins rotating speed, the cupressin, caryophyllus oil or the lemon eucalyptus oil that slowly add proportioning, and then rotating speed transferred to 1000 rev/mins, stir the stabilizing agent that adds again proportioning after 5-10 minute, continue stirring and obtain component two after 5-10 minute, pack.
4. the using method of air purification heath protection mud claimed in claim 1, it is characterized in that: described using method comprises the steps: that component two is put into an amount of water to be stirred, add component one after stirring, wherein, the weight ratio of component one, component two and water is 10:1:10 again.
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Families Citing this family (13)
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| CN102519106B (en) * | 2012-01-13 | 2014-08-27 | 王钟贤 | Low-carbon health-care method for purifying indoor air |
| CN103253929A (en) * | 2012-02-21 | 2013-08-21 | 李心红 | Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof |
| CN103265310A (en) * | 2013-06-07 | 2013-08-28 | 许盛英 | Medical stone flame retardant foaming agent |
| CN104437026A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Formaldehyde absorbing scavenging agent and preparation method thereof |
| CN105153763A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | Environment-friendly and sterilization diatom ooze coating |
| CN105153764A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High-tenacity and shock-proof bactericidal diatom ooze coating |
| CN105838121A (en) * | 2016-06-07 | 2016-08-10 | 赵广全 | Waterborne thin-coating diatom mud |
| CN108033712A (en) * | 2017-12-19 | 2018-05-15 | 上海亮龙晋保新材料科技有限公司 | A kind of natural plant antimicrobial form diatom ooze and preparation method thereof |
| CN108855000B (en) * | 2018-06-25 | 2021-02-23 | 深圳市鑫诠景绿色环保科技有限公司 | Preparation method of nano adsorption material |
| CN109354960A (en) * | 2018-09-20 | 2019-02-19 | 界首永恩机电科技有限公司 | A method of promoting outdoor woodwork weatherability |
| CN113998966A (en) * | 2020-07-27 | 2022-02-01 | 傅吾录 | Efficient multifunctional environment-friendly zeolite wall material and preparation method thereof |
| CN112608075A (en) * | 2020-12-30 | 2021-04-06 | 吉林省姿利环保科技有限公司 | Wall coating and preparation method thereof |
| CN112794664A (en) * | 2021-01-13 | 2021-05-14 | 爱上佳环保新材料有限公司 | Long-acting dual-purification material added into diatom ooze and preparation method thereof |
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| CN1580142A (en) * | 2003-07-30 | 2005-02-16 | 谢建康 | Disease-proof negative ion putty powder composition |
| CN1982379B (en) * | 2005-12-15 | 2010-05-05 | 福建裕和皓月生物工程材料有限公司 | Inner-wall coating composition |
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