CN106243785A - A kind of diatom ooze anion dry powder paint and preparation method thereof - Google Patents
A kind of diatom ooze anion dry powder paint and preparation method thereof Download PDFInfo
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- CN106243785A CN106243785A CN201610605450.2A CN201610605450A CN106243785A CN 106243785 A CN106243785 A CN 106243785A CN 201610605450 A CN201610605450 A CN 201610605450A CN 106243785 A CN106243785 A CN 106243785A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses a kind of diatom ooze anion dry powder paint, belong to technical field of coatings.This coating includes the component of following mass percent: sierozem power 22.8% 28.9%, diatom ooze 12.2% 14.2%, anionic additive 5.5% 7.2%, antibacterial 3.1% 4.8%, anatase thpe white powder 0.8% 1.5%, Pulvis Talci 0.76% 0.92%, aluminium silicate 0.76% 0.92%, Kaolin 0.37% 0.52%, wollastonite 0.37% 0.52%, surfactant 0.18% 0.32%, redispersible latex powder 0.76% 0.92%, modified Sargassum rubber powder 0.0030% 0.0055%, surplus is dicalcium powder.The features such as this coating has the harmful gass such as efficient absorption formaldehyde, the most enduringly anion releasing, anti-mildew becomes and sterilizing ability is strong, good permeability, the humidity of adjustable room air, the intensity of coating and good toughness, water-wash resistance are good.
Description
Technical field
The present invention relates to technical field of coatings, particularly to a kind of diatom ooze anion dry powder paint and preparation method thereof.
Background technology
The quality of IAQ (indoor air quality) has important impact to the health of human body, along with development and the progress of society, more
Carry out the decorated finishing in indoor of the most buildings, typically add in indoor new furniture or on metope coating process to fit up room
In, but fit up the harmful gass such as the furniture in rear chamber or the volatile formaldehyde of coating, VOC, and the metope after application easily occurs
Mouldy or the phenomenon of breed bacteria, affects the health of human body.Additionally, in living environment, there is trade waste discharge, rubbish
The phenomenons such as burning, electromagnetic pollution, cause the anion in outdoor air and room air to fall sharply, and this will reduce the immunity of human body
Power, affects health.Along with the continuous progress of technology, functional coating can be used to carry out the harmful gas in absorption chamber, anti-
Only metope goes mouldy or breed bacteria, and increases the negative ion concentration of indoor, therefore it provides a kind of painting with above-mentioned functions
Material is the most necessary.
Prior art provides a kind of environmental protection diatom ooze coating, and this coating includes according to mass percent: kieselguhr 20%-
40%, filler 20%-30%, aggregate 20%-30%, photocatalyst catalyst 1%-2%, gellant 8%-13%, water-retaining agent
5%-10%.This diatom ooze coating can the harmful gas such as formaldehyde adsorption, and the humidity of room air can be regulated.
Inventor finds that prior art at least there is problems in that
The diatom ooze coating that prior art provides absorbs the ability of the harmful gas such as formaldehyde, VOC, it is impossible to anion releasing
Amount, anti-mildew becomes and sterilizing ability is poor, and the intensity of coating and poor toughness, water-wash resistance are poor.
Summary of the invention
Embodiment of the present invention technical problem to be solved is, it is provided that a kind of formaldehyde that do not contains itself, and can be high
Effect absorbs 300 kinds of harmful substances, the most enduringly anion releasings such as formaldehyde, VOC, and anti-mildew becomes and sterilizing ability is strong, coating
Intensity and good toughness, diatom ooze anion dry powder paint that water-wash resistance is good and preparation method thereof.Concrete technical scheme is as follows:
First aspect, embodiments provides a kind of diatom ooze anion dry powder paint, and described coating includes following
The component of mass percent: sierozem power 22.8%-28.9%, diatom ooze 12.2%-14.2%, anionic additive 5.5%-
7.2%, antibacterial 3.1%-4.8%, anatase thpe white powder 0.8%-1.5%, Pulvis Talci 0.76%-0.92%, aluminium silicate
0.76%-0.92%, Kaolin 0.37%-0.52%, wollastonite 0.37%-0.52%, surfactant 0.18%-
0.32%, redispersible latex powder 0.76%-0.92%, modified Sargassum rubber powder 0.0030%-0.0055%, surplus is triple superphosphate
Powder.
Specifically, as preferably, described coating includes the component of following mass percent: sierozem power 24.8%-25.9%,
Diatom ooze 12.4%-13.2%, anionic additive 6.1%-6.5%, antibacterial 4.1%-4.4%, anatase thpe white powder
1.2%-1.4%, Pulvis Talci 0.83%-0.86%, aluminium silicate 0.83%-0.86%, Kaolin 0.40%-0.45%, silicon ash
Stone 0.40%-0.45%, surfactant 0.20%-0.28%, redispersible latex powder 0.80%-0.88%, modified sea
Algin powder 0.0040%-0.0050%, surplus is dicalcium powder.
Specifically, as preferably, described anionic additive includes the component of following mass percent: aluminium oxide 32%-
42%, boron oxide 8%-14%, titanium dioxide 2%-5%, ferrum oxide 0.9%-1.6%, ferrous oxide 0.6%-1.1%, oxygen
Changing magnesium 0.2%-0.5%, lithium oxide 0.1%-0.3%, manganese monoxide 0.1%-0.3%, surplus is silicon dioxide.
Specifically, as preferably, described antibacterial is silver-based inorganic complex antimicrobials, zine series inorganic complex antimicrobials, copper
It is inorganic complex antimicrobials or titanium system inorganic complex antimicrobials.
Specifically, as preferably, described silver-based inorganic complex antimicrobials includes the component of following mass percent: aluminium oxide
28%-33%, silver nitrate 12%-18%, zeolite 7.5%-8.8%, ferrum oxide 0.9%-1.6%, ferrous oxide 0.4%-
1.1%, magnesium oxide 0.2%-0.4%, manganese monoxide 0.1%-0.3%, surplus is silicon dioxide.
Specifically, as preferably, described redispersible latex powder selected from ethylene-vinyl acetate copolymer rubber powder, ethylene-
At least one in acetate ethylene copolymer rubber powder, acrylic acid rubber powder, sbr powder.
Specifically, as preferably, described surfactant is selected from sodium carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl
At least one in methylcellulose, sodium polyacrylate.
Specifically, as preferably, the mesh number of described diatom ooze is 800-1200 mesh, and the mesh number of described sierozem power is 300-
500 mesh, the mesh number of described dicalcium powder is 300-500 mesh, and the mesh number of described anatase thpe white powder is 700-900 mesh, described silicic acid
The mesh number of aluminum is 700-900 mesh, and described kaolinic mesh number is 700-900 mesh, and the mesh number of described wollastonite is 700-900 mesh.
Second aspect, the embodiment of the present invention additionally provides the preparation method of above-mentioned coating, and described preparation method includes following
Step:
According to the mass percent of component each in coating, by dicalcium powder, sierozem power, diatom ooze, anionic additive, antibacterial
Agent, anatase thpe white powder, Pulvis Talci, aluminium silicate, Kaolin, wollastonite, surfactant, redispersible latex powder, modification
Sargassum rubber powder joins stirring 15-30min in blender, obtains described diatom ooze anion dry powder paint.
The technical scheme that the embodiment of the present invention provides has the benefit that
The diatom ooze anion dry powder paint that the embodiment of the present invention provides, has porous feature by adding in coating
Diatom ooze, the coating that enhancing the embodiment of the present invention provides absorbs 300 kinds of harmful substances such as formaldehyde, VOC, and diatom ooze compares silicon
Diatomaceous earth has the performances such as more excellent moisture expantion, moisture releasing reduction and water translocation, can preferably adjust the humidity of indoor.
By adding the coating anion releasing the most constantly that anionic additive can make the embodiment of the present invention provide,
Improve the immunity of human body, the harmful gas in air and particulate matter can be eliminated simultaneously, it is possible to play the effect purifying air.Logical
Cross interpolation antibacterial to avoid wall breed bacteria or kill the antibacterial grown.By adding anatase thpe white powder, cunning
Stone powder can play the effect of the skeleton generating coating, strengthens the tensile strength of the coating that the embodiment of the present invention provides, adds painting
The wash durability of layer, and add aluminium silicate, Kaolin can improve the dispersive property of each component of coating, it is ensured that each in coating
The homogeneity of component.By adding surfactant, redispersible latex powder and modified Sargassum rubber powder, surface can be reduced and open
Power, improves the mobility of coating, and the coating that the embodiment of the present invention can be made after application to provide forms the painting of high-flexibility
Layer.By the synergism of above-mentioned each component, the coating making the embodiment of the present invention provide has efficient absorption formaldehyde, VOC etc. 300
Plant harmful substance, the most enduringly anion releasing, anti-mildew becomes and sterilizing ability is strong, good permeability, adjustable room air
The feature such as humidity, the intensity of coating and good toughness, water-wash resistance are good.And the preparation method of the coating of embodiment of the present invention offer
Technique simple, time-consumingly few, be suitable for large-scale production and promote the use of.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention will be made into one below
Step ground describes in detail.
First aspect, embodiments provides a kind of diatom ooze anion dry powder paint, and this coating includes following matter
The component of amount percentage ratio: sierozem power 22.8%-28.9%, diatom ooze 12.2%-14.2%, anionic additive 5.5%-
7.2%, antibacterial 3.1%-4.8%, anatase thpe white powder 0.8%-1.5%, Pulvis Talci 0.76%-0.92%, aluminium silicate
0.76%-0.92%, Kaolin 0.37%-0.52%, wollastonite 0.37%-0.52%, surfactant 0.18%-
0.32%, redispersible latex powder 0.76%-0.92%, modified Sargassum rubber powder 0.0030%-0.0055%, surplus is triple superphosphate
Powder.
The diatom ooze anion dry powder paint that the embodiment of the present invention provides, has porous feature by adding in coating
Diatom ooze, the coating that enhancing the embodiment of the present invention provides absorbs 300 kinds of harmful substances such as formaldehyde, VOC, and diatom ooze compares silicon
Diatomaceous earth has the performances such as more excellent moisture expantion, moisture releasing reduction and water translocation, can preferably adjust the humidity of indoor.
By adding the coating anion releasing the most constantly that anionic additive can make the embodiment of the present invention provide,
Improve the immunity of human body, the harmful gas in air and particulate matter can be eliminated simultaneously, it is possible to play the effect purifying air.Logical
Cross interpolation antibacterial to avoid wall breed bacteria or kill the antibacterial grown.By adding anatase thpe white powder, cunning
Stone powder can play the effect of the skeleton generating coating, strengthens the tensile strength of the coating that the embodiment of the present invention provides, adds painting
The wash durability of layer, and add aluminium silicate, Kaolin can improve the dispersive property of each component of coating, it is ensured that each in coating
The homogeneity of component.By adding surfactant, redispersible latex powder and modified Sargassum rubber powder, surface can be reduced and open
Power, improves the mobility of coating, and the coating that the embodiment of the present invention can be made after application to provide forms the painting of high-flexibility
Layer.By the synergism of above-mentioned each component, the coating making the embodiment of the present invention provide has efficient absorption formaldehyde, VOC etc. 300
Plant harmful substance, the most enduringly anion releasing, anti-mildew becomes and sterilizing ability is strong, good permeability, adjustable room air
The feature such as humidity, the intensity of coating and good toughness, water-wash resistance are good.And the preparation method of the coating of embodiment of the present invention offer
Technique simple, time-consumingly few, be suitable for large-scale production and promote the use of.
Wherein, the mass percent of each component in the coating provide the embodiment of the present invention controls within the above range,
Each component preferably synergism can be made, and then the coating making the embodiment of the present invention provide has efficient absorption formaldehyde etc. and is harmful to
Gas, the most enduringly anion releasing, anti-mildew become and sterilizing ability is strong, good permeability, the humidity of adjustable room air, painting
The intensity of layer and the feature such as good toughness, water-wash resistance be good.Specifically, the matter of each component in the coating that the embodiment of the present invention provides
Amount percentage ratio can be multiple, for example, the mass percent of sierozem power can be 22.8%, 23.4%, 24.4%,
25.4%, 26.4%, 27.4%, 28.4% etc., the mass percent of diatom ooze can be 12.2%, 12.6%, 13.1%,
13.5%, 13.9%, 14.2% etc., the mass percent of anionic additive can be 5.5%, 5.8%, 6.2%, 6.4%,
6.8%, 7.2% etc., the mass percent of antibacterial can be 3.1%, 3.5%, 3.7%, 3.9%, 4.1%, 4.3%,
4.5%, 4.8% etc., the mass percent of anatase thpe white powder can be 0.8%, 1.0%, 1.1%, 1.2%, 1.3%,
1.4%, 1.5% etc., talcous mass percent can be 0.76%, 0.78%, 0.80%, 0.82%, 0.84%,
0.86%, 0.88%, 0.90%, 0.92% etc., the mass percent of aluminium silicate can be 0.76%, 0.78%, 0.80%,
0.82%, 0.84%, 0.86%, 0.88%, 0.90%, 0.92% etc., kaolinic mass percent can be 0.37%,
0.40%, 0.43%, 0.46%, 0.49%, 0.52% etc., the mass percent of wollastonite can be 0.37%, 0.40%,
0.43%, 0.46%, 0.49%, 0.52% etc., the mass percent of surfactant can be 0.18%, 0.20%,
0.22%, 0.24%, 0.26%, 0.28%, 0.30%, 0.32% etc., the mass percent of redispersible latex powder is permissible
It is 0.76%, 0.78%, 0.80%, 0.82%, 0.84%, 0.86%, 0.88%, 0.90%, 0.92% etc., modified alginate jelly
The mass percent of powder can be 0.0030%, 0.0034%, 0.0038%, 0.0042%, 0.0046%, 0.0050%,
0.0054% etc., the mass percent of dicalcium powder calculates equal to 100% according to the mass percent sum of above-mentioned each component,
The mass percent of such as dicalcium powder can be 45.3654%, 46.0556%, 46.4858%, 47.726%, 48.626%
Deng.
As preferably, in the coating that the embodiment of the present invention provides, the mass percent of each component is: sierozem power 24.8%-
25.9%, diatom ooze 12.4%-13.2%, anionic additive 6.1%-6.5%, antibacterial 4.1%-4.4%, anatase titanium dioxide titanium
White lead 1.2%-1.4%, Pulvis Talci 0.83%-0.86%, aluminium silicate 0.83%-0.86%, Kaolin 0.40%-0.45%,
Wollastonite 0.40%-0.45%, surfactant 0.20%-0.28%, redispersible latex powder 0.80%-0.88%, change
Property Sargassum rubber powder 0.0040%-0.0050%, surplus is dicalcium powder.The percent mass ratio being arranged such each component can make this
The coating that inventive embodiments provides preferably plays the excellent performance of each component.As preferably, the embodiment of the present invention provides
In coating, the mass percent of each component is: sierozem power 25.36%, diatom ooze 12.67%, anionic additive 6.34%, anti-
Microbial inoculum 4.23%, anatase thpe white powder 1.27%, Pulvis Talci 0.85%, aluminium silicate 0.85%, Kaolin 0.42%, wollastonite
0.42%, surfactant 0.25%, redispersible latex powder 0.85%, modified Sargassum rubber powder 0.0042%, dicalcium powder
46.4858%, the percent mass ratio being arranged such each component can make the synergism between each component strengthen, and then makes this
The various performances of the coating that inventive embodiments provides reach optimum state.
Specifically, the anion of the anionic additive release in the coating that the embodiment of the present invention provides can be with water effect shape
Becoming hydroxyl group anion, hydroxyl group anion can pass through the air in electrical neutralization, chemical reaction, physisorption clean room, and
And the minimum gas in air can be oxidized to negative oxygen ion by hydroxyl group anion, negative oxygen ion is useful to health, can improve
The immunity of human body.After adding anionic additive in the coating that the embodiment of the present invention provides, coating can be made at room air
Middle anion releasing the most enduringly, can play the effect improving body immunity and purifying the air of a room.Wherein, anion adds
Add the mixture that agent can be tourmaline powder and rare earth element powder lanthanum, indium, boron, cerium, terbium etc., it is also possible to for add boron, titanium its
His inorganic non-metallic composite negative ion additive.When anionic additive is the inorganic non-metal composite material adding boron, titanium,
This anionic additive includes the component of following mass percent: aluminium oxide 32%-42%, boron oxide 8%-14%, titanium dioxide
Titanium 2%-5%, ferrum oxide 0.9%-1.6%, ferrous oxide 0.6%-1.1%, magnesium oxide 0.2%-0.5%, lithium oxide
0.1%-0.3%, manganese monoxide 0.1%-0.3%, surplus is silicon dioxide.For example, the mass percent of aluminium oxide can
Think 32%, 34%, 36%, 38%, 40%, 42% etc., the mass percent of boron oxide can be 8%, 10%, 12%,
14% etc., the mass percent of titanium dioxide can be 2%, 3%, 4%, 5% etc., and the mass percent of ferrum oxide can be
0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5% etc., the mass percent of ferrous oxide can be 0.6%,
0.7%, 0.8%, 0.9%, 1.0%, 1.1% etc., the mass percent of magnesium oxide can be 0.2%, 0.3%, 0.4%,
0.5% etc., the mass percent of lithium oxide can be 0.1%, 0.2%, 0.3% etc., and the mass percent of manganese monoxide is permissible
Being 0.1%, 0.2%, 0.3% etc., the mass percent of silicon dioxide with the mass percent sum of above-mentioned each component is
100%, can be such as 43.4%, 43.6%, 46%, 50.3% etc..Use this inorganic non-metallic composite negative ion additive
Can play the effect of anion releasing, and low price, easily obtain.
As preferably, in above-mentioned inorganic non-metallic composite negative ion additive, the mass percent of each component is: titanium dioxide
Silicon 46%, aluminium oxide 37%, boron oxide 11%, titanium dioxide 3%, ferrum oxide 1.4%, ferrous oxide 0.8%, magnesium oxide
0.4%, lithium oxide 0.2%, manganese monoxide 0.2%, is arranged such the mass ratio of each component in this anionic additive permissible
Make the coating anion releasing the most constantly that the embodiment of the present invention provides.
Specifically, the antibacterial in the embodiment of the present invention can avoid wall to go mouldy or breed bacteria, but also can
To kill the antibacterial grown, it is possible to play the effect into the good gnotobasis of indoor creation.Wherein, antibacterial is silver system
Inorganic complex antimicrobials, zine series inorganic complex antimicrobials, copper system inorganic complex antimicrobials or titanium system inorganic complex antimicrobials, choosing
With inorganic complex antimicrobials will not volatile organic compounds matter, and preferable antibacterial effect can be played.As preferably, antibacterial is
Silver-based inorganic complex antimicrobials, the ability of the antibacterial or sterilization of silver-based inorganic complex antimicrobials is strong, selects silver-based inorganic compound anti-
The coating that microbial inoculum can make the embodiment of the present invention provide has the stronger antibacterial or ability of sterilization.
Wherein, silver-based inorganic complex antimicrobials includes the component of following mass percent: aluminium oxide 28%-33%, nitric acid
Silver 12%-18%, zeolite 7.5%-8.8%, ferrum oxide 0.9%-1.6%, ferrous oxide 0.4%-1.1%, magnesium oxide
0.2%-0.4%, manganese monoxide 0.1%-0.3%, surplus is silicon dioxide.Such as, the mass percent of aluminium oxide can be
28%, 29%, 30%, 31%, 32%, 33% etc., the mass percent of silver nitrate can be 12%, 13%, 14%, 15%,
16%, 17%, 18% etc., the mass percent of zeolite can be 7.5%, 7.7%, 7.9%, 8.1%, 8.3%, 8.5%,
8.7%, 8.8% etc., the mass percent of ferrum oxide can be 0.9%, 1.1%, 1.3%, 1.5%, 1.6% etc., oxidation Asia
The mass percent of ferrum can be 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1.0%, 1.1% etc., magnesium oxide
Mass percent can be 0.2%, 0.3%, 0.4% etc., the mass percent of manganese monoxide can be 0.1%, 0.2%,
0.3% etc., wherein, the mass percent of silicon dioxide is 100% with the mass percent sum of other components above-mentioned, such as two
The mass percent of silicon oxide can be 47.1%, 43%, 43.6%, 42.5% etc..Select as above component and mass ratio
Silver-based inorganic complex antimicrobials can play stronger antibacterial or sterilizing ability, and the content of silver is relatively low, therefore this silver-based inorganic is multiple
Close the cheap of antibacterial.As preferably, this silver-based inorganic complex antimicrobials includes the component of following mass percent: dioxy
SiClx 43%, aluminium oxide 31%, silver nitrate 15%, zeolite 8.2%, ferrum oxide 1.4%, ferrous oxide 0.8%, magnesium oxide
0.4%, manganese monoxide 0.2%, is arranged such the mass ratio of each component in silver-based inorganic complex antimicrobials, can make this silver system nothing
Machine complex antimicrobials reaches excellent antibacterial or bactericidal effect.
Specifically, the renewable dispersibility latex powder in the coating that the embodiment of the present invention provides has certain film property,
Can also make to be uniformly dispersed between each component in coating, and then make the coating eventually formed smooth, smooth, and have preferably
Pliability.Wherein, redispersible latex powder is selected from ethylene-vinyl acetate copolymer rubber powder, ethylene-vinyl acetate copolymer glue
At least one in powder, acrylic acid rubber powder, sbr powder, such as redispersible latex powder can be any in above-mentioned rubber powder
One, two kinds, three kinds or be the mixture of four kinds.When selecting the mixture of acrylate glue powder and sbr powder, rubber powder with
The mass ratio of sbr powder is 1:0.5-2, such as, can be 1:0.5,1:1,1:1.5,1:2 etc..Select above-mentioned any one or
Multiple redispersible latex powder can make the good film-forming property of the coating that the embodiment of the present invention provides, and the pliability of coating is good, and
And these several redispersible latex powders easily obtain.
Specifically, the surfactant in the coating that the embodiment of the present invention provides can reduce the table of various components in coating
Surface tension, can make each component in coating be uniformly dispersed simultaneously, further improves the mobility of coating, and live in surface during use
Property agent also with redispersable latex powder, modified Sargassum synergism, make the coating eventually formed have preferable pliability.Its
In, surfactant is in sodium carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate
At least one.Such as surfactant can be arbitrary a kind of in above-mentioned surfactant, two kinds, three kinds or whole four
Kind.When selecting the mixture of hydroxypropyl methyl cellulose and sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose and carboxymethyl
The mass ratio of sodium cellulosate is 1:0.5-2, such as, can be 1:0.5,1:1,1:1.5,1:2 etc., when selecting carboxymethyl cellulose
During the mixture of element sodium and sodium polyacrylate, sodium carboxymethyl cellulose is 1:0.5-2 with the mass ratio of sodium polyacrylate, such as
Can be 1:0.5,1:1,1:1.5,1:2 etc..The dispersion effect of above-mentioned several surfactant is good, cheap, easily obtains.
Specifically, the mesh number of diatom ooze is 800-1200 mesh, and the mesh number of sierozem power is 300-500 mesh, the mesh number of dicalcium powder
For 300-500 mesh, the mesh number of anatase thpe white powder is 700-900 mesh, and the mesh number of aluminium silicate is 700-900 mesh, kaolinic mesh
Number is 700-900 mesh, and the mesh number of wollastonite is 700-900 mesh.For example, the mesh number of diatom ooze can be 800,850,900,
950,1000,1050,1100,1150,1200 etc., the mesh number of sierozem power can be 300,350,400,450,500 etc., dicalcium powder
Mesh number can be 300,350,400,450,500 etc., the mesh number of anatase thpe white powder can be 700,750,800,850,900
Can be 700,750,800,850,900 etc. Deng, the mesh number of aluminium silicate, the mesh number of wollastonite can be 700,750,800,850,
900 etc..Visible, the mesh number of above-mentioned each component is relatively big, and the powder of the most above-mentioned each component is thinner, and this is easy to be formed smooth, high
Intensity, the coating of good toughness, and harmful gas or the suction of abnormal flavour such as the specific surface area of the diatom ooze of fine-powdered is big, PARA FORMALDEHYDE PRILLS(91,95)
Receipts ability is strong.
Second aspect, the embodiment of the present invention additionally provides the preparation method of above-mentioned coating, and its preparation method includes following step
Rapid: according to the mass percent of component each in coating, by dicalcium powder, sierozem power, diatom ooze, anionic additive, antibacterial, sharp
Titanium-type titanium dioxide, Pulvis Talci, aluminium silicate, Kaolin, wollastonite, surfactant, redispersible latex powder, modified alginate jelly
Powder joins stirring 15-30min in blender, obtains diatom ooze anion dry powder paint.Wherein, mixing time can be
15min, 17min, 19min, 21min, 23min, 25min, 27min, 30min etc..
The technique of the preparation method of the coating that the embodiment of the present invention provides is simple, time-consumingly few, is suitable for large-scale production and pushes away
Wide use.
Hereinafter will be further described through the present invention by specific embodiment.
In specific examples below, the unreceipted condition person of involved operation, all according to normal condition or manufacturer
The condition of suggestion is carried out.Raw materials used unreceipted production firm and specification person be can by city available from conventional products.
Embodiment 1
Present embodiments provide a kind of diatom ooze anion dry powder paint, by mixing the component of following mass percent:
Sierozem power 24.8%, diatom ooze 12.4%, anionic additive 6.2%, silver-based inorganic complex antimicrobials 4.1%, anatase titanium dioxide titanium
White lead 1.22%, Pulvis Talci 0.83%, aluminium silicate 0.83%, Kaolin 0.40%, wollastonite 0.40%, hydroxyethyl cellulose
0.26%, ethylene-vinyl acetate copolymer rubber powder 0.83%, modified Sargassum rubber powder 0.0040%, surplus are dicalcium powder, and by it
Joining stirring 18min in blender, i.e. can get the present embodiment desired diatom ooze anion dry powder paint, this diatom ooze is born
The average mesh number of ion dry powder paint is 510 mesh.
Wherein, anionic additive includes the component of following mass percent: aluminium oxide 35%, boron oxide 10%, dioxy
Change titanium 2%, ferrum oxide 1.2%, ferrous oxide 0.6%, magnesium oxide 0.3%, lithium oxide 0.3%, manganese monoxide 0.3%, surplus
For silicon dioxide.Silver-based inorganic complex antimicrobials includes the component of following mass percent: aluminium oxide 29%, silver nitrate 13%,
Zeolite 7.9%, ferrum oxide 1.5%, ferrous oxide 0.9%, magnesium oxide 0.3%, manganese monoxide 0.3%, surplus are silicon dioxide.
Embodiment 2
Present embodiments provide a kind of diatom ooze anion dry powder paint, by mixing the component of following mass percent:
Sierozem power 25.36%, diatom ooze 12.67%, anionic additive 6.34%, antibacterial 4.23%, anatase thpe white powder
1.27%, Pulvis Talci 0.85%, aluminium silicate 0.85%, Kaolin 0.42%, wollastonite 0.42%, sodium carboxymethyl cellulose
0.25%, ethylene-vinyl acetate copolymer rubber powder 0.85%, modified Sargassum rubber powder 0.0042%, surplus is dicalcium powder, and by it
Joining stirring 20min in blender, i.e. can get the present embodiment desired diatom ooze anion dry powder paint, this diatom ooze is born
The average mesh number of ion dry powder paint is 540 mesh.
Wherein, anionic additive is inorganic non-metallic composite negative ion additive, including the group of following mass percent
Point: aluminium oxide 37%, boron oxide 11%, titanium dioxide 3%, ferrum oxide 1.4%, ferrous oxide 0.8%, magnesium oxide 0.4%, oxygen
Change lithium 0.2%, manganese monoxide 0.2%, surplus are silicon dioxide.Silver-based inorganic complex antimicrobials includes following mass percent
Component: aluminium oxide 31%, silver nitrate 15%, zeolite 8.2%, ferrum oxide 1.4%, ferrous oxide 0.8%, magnesium oxide 0.4%,
Manganese oxide 0.2%, surplus are silicon dioxide.
Embodiment 3
Present embodiments provide a kind of diatom ooze anion dry powder paint, by mixing the component of following mass percent:
Sierozem power 25.5%, diatom ooze 12.74%, anionic additive 6.42%, antibacterial 4.28%, anatase thpe white powder
1.32%, Pulvis Talci 0.84%, aluminium silicate 0.86%, Kaolin 0.43%, wollastonite 0.43%, hydroxypropyl methyl cellulose with
The mixture 0.26% of sodium carboxymethyl cellulose, acrylic acid rubber powder and the mixture 0.86% of sbr powder, modified Sargassum rubber powder
0.0044%, surplus is dicalcium powder, and adds it to stir in blender 25min, i.e. can get the desired silicon of the present embodiment
Algae mud anion dry powder paint, the average mesh number of this diatom ooze anion dry powder paint is 480 mesh.
Wherein, anionic additive is inorganic non-metallic composite negative ion additive, including the group of following mass percent
Point: aluminium oxide 39%, boron oxide 10%, titanium dioxide 4%, ferrum oxide 1.5%, ferrous oxide 1.1%, magnesium oxide 0.4%, oxygen
Change lithium 0.3%, manganese monoxide 0.1%, surplus are silicon dioxide.Silver-based inorganic complex antimicrobials includes following mass percent
Component: aluminium oxide 32%, silver nitrate 14%, zeolite 7.9%, ferrum oxide 1.3%, ferrous oxide 0.6%, magnesium oxide 0.3%,
Manganese oxide 0.3%, surplus are silicon dioxide.Hydroxypropyl methyl cellulose is 1:1 with the mass ratio of sodium carboxymethyl cellulose, third
Olefin(e) acid rubber powder is 1:1 with the mass ratio of sbr powder.
Embodiment 4
Present embodiments provide a kind of diatom ooze anion dry powder paint, by mixing the component of following mass percent:
Sierozem power 25.9%, diatom ooze 12.8%, anionic additive 6.5%, antibacterial 4.32%, anatase thpe white powder 1.32%,
Pulvis Talci 0.86%, aluminium silicate 0.86%, Kaolin 0.45%, wollastonite 0.45%, sodium carboxymethyl cellulose and polyacrylic acid
The mixture 0.26% of sodium, sbr powder 0.86%, modified Sargassum rubber powder 0.0046%, surplus are dicalcium powder, and are added into
In blender, stir 28min, i.e. can get the present embodiment desired diatom ooze anion dry powder paint, this diatom ooze anion
The average mesh number of dry powder paint is 490 mesh.
Wherein, anionic additive is inorganic non-metallic composite negative ion additive, including the group of following mass percent
Point: aluminium oxide 40%, boron oxide 11%, titanium dioxide 3.0%, ferrum oxide 1.0%, ferrous oxide 0.8%, magnesium oxide 0.4%,
Lithium oxide 0.2%, manganese monoxide 0.2%, surplus are silicon dioxide.Silver-based inorganic complex antimicrobials includes following mass percent
Component: aluminium oxide 31%, silver nitrate 16%, zeolite 8.0%, ferrum oxide 1.1%, ferrous oxide 0.8%, magnesium oxide 0.3%,
Manganese monoxide 0.3%, surplus are silicon dioxide.Sodium carboxymethyl cellulose is 1:1 with the mass ratio of sodium polyacrylate.
Application Example 1
The diatom ooze anion dry powder paint that embodiment 1-4 is provided by this application embodiment by the following method absorbs formaldehyde
The performance of gas is tested: the diatom ooze anion dry powder paint sampling provided embodiment 1-4 respectively, and respectively accordingly
Diatom ooze anion dry powder paint sample in add with its mass ratio be the deionized water of 6:4, stir 20min, obtain corresponding
Water based paint, be respectively coated with 1m24 planks on, then 4 planks are individually placed to 4 containing same concentrations
Formaldehyde seal box in, and the empty plank of a uncoated coating is put into as blank there is same concentrations formaldehyde
In 5th seal box, after 96h, provide according to " GBT18204.26-2000 public place method for determining formaldehyde in air " standard
Method detect the concentration of formaldehyde in five different seal boxs respectively, the test result of the absorbance of concrete formaldehyde such as table 1 institute
Show:
Table 1
Can be drawn by table 1, the diatom ooze anion dry powder paint that embodiment of the present invention 1-4 provides can be efficiently absorbed
Formaldehyde, it is seen then that the diatom ooze anion dry powder paint that the embodiment of the present invention provides can be efficiently absorbed formaldehyde, VOC etc. 300 kinds
Harmful substance, has the ability purifying air of excellence.
Application Example 2
The anion amount of inducing of the diatom ooze anion dry powder paint that embodiment 1-4 is provided by this application embodiment is surveyed
Examination: this application embodiment uses the method for Application Example 1, obtains 4 and is applied the silicon that embodiment of the present invention 1-4 provides respectively
The plank sample of algae mud anion dry powder paint, and use the side that " HG/T4109-2009 anion function coating " standard provides
Method, carries out anion and induces measurement examination embodiment 1-4, and concrete test data are as shown in table 2:
Table 2
Can be drawn by table 2, the diatom ooze anion dry powder paint that embodiment of the present invention 1-4 provides can discharge substantial amounts of
Anion, it is seen then that the ability of the diatom ooze anion dry powder paint anion releasing that the embodiment of the present invention provides is strong, and then purify
The ability of air is strong, is of value to health.
Application Example 3
The sterilizing ability of the diatom ooze anion dry powder paint that embodiment 1-4 is provided by this application embodiment is tested:
The diatom ooze anion dry powder paint that embodiment 1-4 provides is respectively coated on 4 thickness is on the plank of 1mm, then will be coated with
Plank after covering is cut into 10 × 10mm pat, uses shaking method, respectively corresponding pat is put into 8 and be respectively provided with
Concentration is 2 × 105The escherichia coli of CFU/mmL and staphylococcus aureus rock in bottle, be 250 revs/min at shaking speed
Under conditions of, to rock 4 hours, then bacterial solution is tested, concrete test result is as shown in table 3 below:
Table 3
Can be drawn by table 3, the sterilizing rate of the diatom ooze anion dry powder paint that embodiment of the present invention 1-4 provides is high, can
Seeing, the antibacterial ability of the diatom ooze anion dry powder paint that the embodiment of the present invention provides is strong.
Application Example 4
The water-wash resistance of the diatom ooze anion dry powder paint that embodiment 1-4 is provided by this application embodiment is tested:
The diatom ooze anion dry powder paint that embodiment 1-4 provides is respectively coated on 4 1m2On plank, and the thickness of coating is
1mm, room temperature dries, and the most respectively it is carried out scrub washing test, and observes the pattern of coating, concrete test result such as table 4 below
Shown in:
Table 4
Can be drawn by table 4, the water-wash resistance of the diatom ooze anion dry powder paint that embodiment of the present invention 1-4 provides is good,
Visible, the water-wash resistance of the diatom ooze anion dry powder paint that the embodiment of the present invention provides is good, and service life is long.
From Application Example 1-4, the diatom ooze anion dry powder paint that the embodiment of the present invention provides has efficiently suction
Receive 300 kinds of harmful substances such as formaldehyde, VOC, the most enduringly anion releasing, anti-mildew becomes and sterilizing ability is strong, water-wash resistance is good
Etc. advantage, it is possible to be substantially improved indoor environment, the beneficially health of human body, can promote the use of.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the scope of the invention, all at this
Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in protection scope of the present invention
Within.
Claims (9)
1. a diatom ooze anion dry powder paint, it is characterised in that described coating includes the component of following mass percent: ash
Calcium powder 22.8%-28.9%, diatom ooze 12.2%-14.2%, anionic additive 5.5%-7.2%, antibacterial 3.1%-
4.8%, anatase thpe white powder 0.8%-1.5%, Pulvis Talci 0.76%-0.92%, aluminium silicate 0.76%-0.92%, Kaolin
0.37%-0.52%, wollastonite 0.37%-0.52%, surfactant 0.18%-0.32%, redispersible latex powder
0.76%-0.92%, modified Sargassum rubber powder 0.0030%-0.0055%, surplus are dicalcium powder.
Coating the most according to claim 1, it is characterised in that described coating includes the component of following mass percent: ash
Calcium powder 24.8%-25.9%, diatom ooze 12.4%-13.2%, anionic additive 6.1%-6.5%, antibacterial 4.1%-
4.4%, anatase thpe white powder 1.2%-1.4%, Pulvis Talci 0.83%-0.86%, aluminium silicate 0.83%-0.86%, Kaolin
0.40%-0.45%, wollastonite 0.40%-0.45%, surfactant 0.20%-0.28%, redispersible latex powder
0.80%-0.88%, modified Sargassum rubber powder 0.0040%-0.0050%, surplus are dicalcium powder.
Coating the most according to claim 1, it is characterised in that described anionic additive includes following mass percent
Component: aluminium oxide 32%-42%, boron oxide 8%-14%, titanium dioxide 2%-5%, ferrum oxide 0.9%-1.6%, oxidation Asia
Ferrum 0.6%-1.1%, magnesium oxide 0.2%-0.5%, lithium oxide 0.1%-0.3%, manganese monoxide 0.1%-0.3%, surplus are
Silicon dioxide.
Coating the most according to claim 1, it is characterised in that described antibacterial is silver-based inorganic complex antimicrobials, zinc system
Inorganic complex antimicrobials, copper system inorganic complex antimicrobials or titanium system inorganic complex antimicrobials.
Coating the most according to claim 4, it is characterised in that described silver-based inorganic complex antimicrobials includes following quality hundred
The component of proportion by subtraction: aluminium oxide 28%-33%, silver nitrate 12%-18%, zeolite 7.5%-8.8%, ferrum oxide 0.9%-1.6%,
Ferrous oxide 0.4%-1.1%, magnesium oxide 0.2%-0.4%, manganese monoxide 0.1%-0.3%, surplus are silicon dioxide.
Coating the most according to claim 1, it is characterised in that described redispersible latex powder is selected from ethyl vinyl acetate second
At least one in alkene copolymer rubber powder, ethylene-vinyl acetate copolymer rubber powder, acrylic acid rubber powder, sbr powder.
Coating the most according to claim 1, it is characterised in that described surfactant is selected from sodium carboxymethyl cellulose, hydroxyl
At least one in ethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate.
Coating the most according to claim 1, it is characterised in that the mesh number of described diatom ooze is 800-1200 mesh, described ash
The mesh number of calcium powder is 300-500 mesh, and the mesh number of described dicalcium powder is 300-500 mesh, and the mesh number of described anatase thpe white powder is
700-900 mesh, the mesh number of described aluminium silicate is 700-900 mesh, and described kaolinic mesh number is 700-900 mesh, described wollastonite
Mesh number be 700-900 mesh.
9. the preparation method of the coating described in any one of claim 1-8, it is characterised in that described preparation method includes following step
Rapid:
According to the mass percent of component each in coating, by dicalcium powder, sierozem power, diatom ooze, anionic additive, antibacterial,
Anatase thpe white powder, Pulvis Talci, aluminium silicate, Kaolin, wollastonite, surfactant, redispersible latex powder, modified Sargassum
Rubber powder joins stirring 15-30min in blender, obtains described diatom ooze anion dry powder paint.
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