CN108384413B - Environment-friendly coating with sterilization, mould prevention and air purification functions - Google Patents

Environment-friendly coating with sterilization, mould prevention and air purification functions Download PDF

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CN108384413B
CN108384413B CN201810152288.2A CN201810152288A CN108384413B CN 108384413 B CN108384413 B CN 108384413B CN 201810152288 A CN201810152288 A CN 201810152288A CN 108384413 B CN108384413 B CN 108384413B
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CN108384413A (en
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王美琴
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Jiangsu shunlicheng new building materials Co., Ltd
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Chongqing En Guang Technology Co Ltd
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
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    • C08K2003/2241Titanium dioxide
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    • C08L2205/00Polymer mixtures characterised by other features
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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Abstract

The invention provides an environment-friendly coating with functions of sterilization, mould prevention and air purification, which comprises the following raw materials in parts by weight: 55-60 parts of alkyd resin, 17-20 parts of polyacrylate emulsion, 10-12 parts of nano attapulgite, 12-15 parts of nano kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium silicate, 5-8 parts of polyamide resin, 0.5-0.8 part of mineral oil defoamer, 0.8-1.2 parts of nano titanium oxide, 8-10 parts of net gas sterilization powder, 0.5-0.8 part of organic bentonite, 0.1-0.2 part of polyacrylic acid ammonium salt dispersant, 0.1-0.2 part of carboxymethyl cellulose, 4-6 parts of coconut oil and 45-55 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.

Description

Environment-friendly coating with sterilization, mould prevention and air purification functions
Technical Field
The invention relates to the technical field of coatings, in particular to an environment-friendly coating with functions of sterilization, mould prevention and air purification.
Background
Currently, the pollution causing indoor air mainly originates from 5 aspects: firstly, human breath and smoke; formaldehyde, ammonia, benzene, toluene and the like in the decoration materials; thirdly, microorganisms, viruses and bacteria; fourthly, kitchen oil smoke; and fifthly, air conditioning syndrome. The pollutants enter the human body along with respiration, and are accumulated for a long time, so that the health of people is seriously harmed.
With the progress of the times, through long-term education and guidance of consumers, awareness of environment-friendly home decoration and healthy home furnishing of the consumers is increasingly strengthened, and the potential market demand for environment-friendly coatings is rapidly increased. In addition to high price, the existing environment-friendly coating often has some technical defects, such as poor adhesion, easy falling, poor weather resistance and stability, easy mildew or oxidation, poor water resistance, easy mildew phenomenon caused by air humidity, especially in the southern plum rain season, more humid air and more easy mildew phenomenon on the inner wall, which brings inconvenience to consumers. In addition, most of the existing coating products contain certain harmful substances such as formaldehyde, volatile organic compounds and the like, and can be normally used after long-time ventilation and air exchange are usually needed, and some hazardous substances such as formaldehyde and the like contained in the coating are easy to volatilize, have very poor environmental protection performance, and are easy to bring lasting harm to the bodies of people when being in the environment for a long time.
Therefore, the development of an environment-friendly coating with mildew-proof and sterilization effects, which is cheap, nontoxic and environment-friendly, is needed.
Disclosure of Invention
In view of the above, the invention provides a nontoxic and environment-friendly coating with functions of sterilization, mildew prevention and air purification, and the coating also has excellent adhesion capability, weather resistance, stability and good water resistance.
The invention provides an environment-friendly coating with functions of sterilization, mould prevention and air purification, which comprises the following raw materials in parts by weight: 55-60 parts of alkyd resin, 17-20 parts of polyacrylate emulsion, 10-12 parts of nano attapulgite, 12-15 parts of nano kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium silicate, 5-8 parts of polyamide resin, 0.5-0.8 part of mineral oil defoamer, 0.8-1.2 parts of nano titanium oxide, 8-10 parts of net gas sterilization powder, 0.5-0.8 part of organic bentonite, 0.1-0.2 part of polyacrylic acid ammonium salt dispersant, 0.1-0.2 part of carboxymethyl cellulose, 4-6 parts of coconut oil and 45-55 parts of deionized water;
the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1;
further, the raw materials of the coating comprise the following components in parts by weight: 57 parts of alkyd resin, 19 parts of polyacrylate emulsion, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium silicate, 6 parts of polyamide resin, 0.6 part of mineral oil defoamer, 1.0 part of nano-titanium oxide, 9 parts of gas-purifying bactericidal powder, 0.6 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil and 50 parts of deionized water;
further, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring at a stirring speed of 300r/min for at least 30min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring at a stirring speed of 1000r/min for 8h to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
The invention has the beneficial effects that:
the environment-friendly paint with the functions of sterilization, mildew prevention and air purification is prepared by mixing the nontoxic and harmless raw material components according to the specific dosage and the specific preparation method, wherein the raw material components organically form a whole, and can mutually cooperate to realize the complementary and synergistic effects so as to better exert the respective excellent performances.
Firstly, the wormwood, the cape jasmine, the eucalyptus citriodora leaves, the eucalyptus malus leaves and the lemon grass are prepared into the air purifying and sterilizing powder according to a specific proportion, and the powder is mixed with other raw materials, so that the coating not only has natural fragrant taste and air refreshing effect, but also can be synergistically enhanced with other components with sterilizing effect (such as nano attapulgite, nano titanium oxide, nano kaolinite, coconut oil and the like) of the coating, and the sterilizing effect of the coating is improved. Secondly, the adopted polyacrylate emulsion, alkyd resin and alkyd resin can realize good compatibility, raw materials such as nano attapulgite, nano kaolinite, diatomite, lithium silicate, nano titanium oxide, air purification sterilization powder, organic bentonite and the like can be well dispersed in the paint, so that the mutual synergistic effect among the raw material components can be better exerted, the bonding strength, the ageing resistance, the weather resistance, the chemical stability, the water resistance and the like of the paint are greatly improved, the phenomena of falling and mildew of the paint in the using process can be avoided, and the paint can be prevented from being oxidized due to sunshine or environmental change. In addition, the nano titanium oxide adopted in the invention can also be used as a photocatalyst to decompose and remove harmful organic substances such as formaldehyde, acetaldehyde and the like generated indoors under the irradiation of ultraviolet light, and can be used for realizing the synergistic effect with attapulgite, diatomite, lithium silicate, organic bentonite and kaolinite, realizing the physical adsorption and the chemical reaction to remove harmful substances such as formaldehyde, greenhouse gases and the like indoors, and playing a role in purifying air. After the organic bentonite is mixed with the carboxymethyl cellulose and the nano attapulgite, the three are jointly used as a composite thickening agent, so that the effects of optimizing the thickening effect and the film-forming property are achieved. The mineral oil defoaming agent is adopted, so that the defoaming capability is strong, other ingredients are easy to mix, and no side reaction is caused in the film forming process; by adopting the polyacrylic acid ammonium salt dispersing agent, not only can the raw material components be uniformly dispersed in the coating, but also the water resistance of the coating can be improved. The invention gives play to the excellent properties of the raw material components, realizes the complementation and synergistic interaction of the raw material components, and finally prepares the environment-friendly coating which has excellent bonding strength, aging resistance, weather resistance, chemical stability and water resistance, and has sterilization, mildew prevention and air purification effects.
Detailed Description
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 55-60 parts of alkyd resin, 17-20 parts of polyacrylate emulsion, 10-12 parts of nano attapulgite, 12-15 parts of nano kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium silicate, 5-8 parts of polyamide resin, 0.5-0.8 part of mineral oil defoamer, 0.8-1.2 parts of nano titanium oxide, 8-10 parts of net gas sterilization powder, 0.5-0.8 part of organic bentonite, 0.1-0.2 part of polyacrylic acid ammonium salt dispersant, 0.1-0.2 part of carboxymethyl cellulose, 4-6 parts of coconut oil and 45-55 parts of deionized water;
the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1;
preferably, the raw materials of the coating comprise the following components in parts by weight: 57 parts of alkyd resin, 19 parts of polyacrylate emulsion, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium silicate, 6 parts of polyamide resin, 0.6 part of mineral oil defoamer, 1.0 part of nano-titanium oxide, 9 parts of gas-purifying bactericidal powder, 0.6 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil and 50 parts of deionized water;
the environment-friendly paint with the functions of sterilization, mildew prevention and air purification is prepared by mixing the nontoxic and harmless raw material components according to the specific dosage and the specific preparation method, wherein the raw material components organically form a whole, and can mutually cooperate to realize the complementary and synergistic effects so as to better exert the respective excellent performances. Firstly, the wormwood, the cape jasmine, the eucalyptus citriodora leaves, the eucalyptus malus leaves and the lemon grass are prepared into the air purifying and sterilizing powder according to a specific proportion, and the powder is mixed with other raw materials, so that the coating not only has natural fragrant taste and air refreshing effect, but also can be synergistically enhanced with other components with sterilizing effect (such as nano attapulgite, nano titanium oxide, nano kaolinite, coconut oil and the like) of the coating, and the sterilizing effect of the coating is improved. Secondly, the adopted polyacrylate emulsion, alkyd resin and alkyd resin can realize good compatibility, raw materials such as nano attapulgite, nano kaolinite, diatomite, lithium silicate, nano titanium oxide, air purification sterilization powder, organic bentonite and the like can be well dispersed in the paint, so that the mutual synergistic effect among the raw material components can be better exerted, the bonding strength, the ageing resistance, the weather resistance, the chemical stability, the water resistance and the like of the paint are greatly improved, the phenomena of falling and mildew of the paint in the using process can be avoided, and the paint can be prevented from being oxidized due to sunshine or environmental change. In addition, the nano titanium oxide used in the present embodiment can also exert its function as a photocatalyst, and can decompose and remove harmful organic substances such as formaldehyde and acetaldehyde generated in a room under the irradiation of ultraviolet light, and can achieve the effect of removing harmful substances such as formaldehyde and greenhouse gases in the room by combining physical adsorption and chemical reaction through the synergistic effect with attapulgite, diatomite, lithium silicate, organobentonite and kaolinite, thereby achieving the effect of purifying air. After the organic bentonite is mixed with the carboxymethyl cellulose and the nano attapulgite, a composite thickening agent is formed, and the effects of optimizing the thickening effect and the film forming property are jointly realized. In the embodiment, the mineral oil defoaming agent is adopted, so that the defoaming capability is strong, other ingredients are easy to mix, and no side reaction is caused in the film forming process; by adopting the polyacrylic acid ammonium salt dispersing agent, not only can the raw material components be uniformly dispersed in the coating, but also the water resistance of the coating can be improved. The embodiment gives play to the excellent properties of the raw material components, realizes the complementation and synergistic interaction of the raw material components, and finally prepares the environment-friendly coating which has excellent bonding strength, aging resistance, weather resistance, chemical stability and water resistance, and has sterilization, mildew prevention and air purification effects.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring at a stirring speed of 300r/min for at least 30min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring at a stirring speed of 1000r/min for 8h to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification; the raw materials are better dispersed, better compatibility is realized, and better synergistic effect is achieved.
The following are specific examples:
example one
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 55 parts of alkyd resin, 20 parts of polyacrylate emulsion, 10 parts of nano attapulgite, 15 parts of nano kaolinite, 8 parts of diatomite, 6 parts of lithium silicate, 5 parts of polyamide resin, 0.8 part of mineral oil defoamer, 0.8 part of nano titanium oxide, 10 parts of gas-purifying bactericidal powder, 0.5 part of organic bentonite, 0.2 part of polyacrylic acid ammonium salt dispersant, 0.1 part of carboxymethyl cellulose, 6 parts of coconut oil and 45 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring for 30min at the stirring speed of 300r/min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring for 8h at the stirring speed of 1000r/min to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
Example two
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 60 parts of alkyd resin, 20 parts of polyacrylate emulsion, 12 parts of nano attapulgite, 15 parts of nano kaolinite, 10 parts of diatomite, 6 parts of lithium silicate, 8 parts of polyamide resin, 0.8 part of mineral oil defoamer, 1.2 parts of nano titanium oxide, 10 parts of gas-purifying bactericidal powder, 0.8 part of organic bentonite, 0.2 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 6 parts of coconut oil and 55 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring for 30min at the stirring speed of 300r/min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring for 8h at the stirring speed of 1000r/min to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
EXAMPLE III
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 60 parts of alkyd resin, 17 parts of polyacrylate emulsion, 12 parts of nano attapulgite, 12 parts of nano kaolinite, 10 parts of diatomite, 4 parts of lithium silicate, 8 parts of polyamide resin, 0.5 part of mineral oil defoamer, 1.2 parts of nano titanium oxide, 8 parts of gas-purifying bactericidal powder, 0.8 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 4 parts of coconut oil and 55 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring for 30min at the stirring speed of 300r/min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring for 8h at the stirring speed of 1000r/min to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
Example four
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 57 parts of alkyd resin, 19 parts of polyacrylate emulsion, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium silicate, 6 parts of polyamide resin, 0.6 part of mineral oil defoamer, 1.0 part of nano-titanium oxide, 9 parts of gas-purifying bactericidal powder, 0.6 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil and 50 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring for 30min at the stirring speed of 300r/min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring for 8h at the stirring speed of 1000r/min to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
EXAMPLE five
The embodiment provides an environment-friendly coating with functions of sterilization, mildew prevention and air purification, which comprises the following raw materials in parts by weight: 55 parts of alkyd resin, 17 parts of polyacrylate emulsion, 10 parts of nano attapulgite, 12 parts of nano kaolinite, 8 parts of diatomite, 4 parts of lithium silicate, 5 parts of polyamide resin, 0.5 part of mineral oil defoamer, 0.8 part of nano titanium oxide, 8 parts of gas-purifying bactericidal powder, 0.5 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.1 part of carboxymethyl cellulose, 4 parts of coconut oil and 45 parts of deionized water; the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
In this embodiment, the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring for 30min at the stirring speed of 300r/min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring for 8h at the stirring speed of 1000r/min to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
The raw material components in the above examples are all commercially available.
And (3) performance testing:
1. the environment-friendly coatings with the functions of sterilization, mildew prevention and air purification prepared in the first to fifth embodiments are respectively coated on a wall, the dosage of the coatings is controlled to be the same as the surface area of the wall coated with the five coatings, the phenomenon of the coatings in the using process is observed and recorded, and the results are shown in table 1:
Figure GDA0002195593500000081
Figure GDA0002195593500000091
TABLE 1
As shown in Table 1, the environment-friendly coatings prepared in the first to fifth examples have excellent adhesion performance, high bonding strength, excellent service performance and air freshening effect.
2. The water resistance, impact strength, adhesion level and drying time of the environment-friendly coatings of the first to fifth examples are tested by the existing testing method, and the results are shown in Table 2:
Figure GDA0002195593500000092
TABLE 2
As shown in Table 2, the environmental protection coatings prepared in the first to fifth examples have excellent adhesion and impact strength, good water resistance and quick curing.
3. And (3) sterilization test: the antibacterial rate of the products of the first embodiment and the fifth embodiment is tested according to the method in GB/T2591-2003, and the calculation formula of the antibacterial rate is as follows: q ═ X1-X2/X1 × 100%, where: x1 is the average number of recovered bacteria of the blank control sample, and X2 is the average number of recovered bacteria of the paint sample; coli and aspergillus niger were selected for testing, and the results are shown in table 3:
Figure GDA0002195593500000101
TABLE 3
As can be seen from table 3, the present application has excellent antifungal and bactericidal properties.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.

Claims (3)

1. An environment-friendly coating with sterilization, mould prevention and air purification functions is characterized in that: the coating comprises the following raw materials in parts by weight: 55-60 parts of alkyd resin, 17-20 parts of polyacrylate emulsion, 10-12 parts of nano attapulgite, 12-15 parts of nano kaolinite, 8-10 parts of diatomite, 4-6 parts of lithium silicate, 5-8 parts of polyamide resin, 0.5-0.8 part of mineral oil defoamer, 0.8-1.2 parts of nano titanium oxide, 8-10 parts of net gas sterilization powder, 0.5-0.8 part of organic bentonite, 0.1-0.2 part of polyacrylic acid ammonium salt dispersant, 0.1-0.2 part of carboxymethyl cellulose, 4-6 parts of coconut oil and 45-55 parts of deionized water;
the air purifying and sterilizing powder is prepared by crushing and mixing dry wormwood, cape jasmine, lemon eucalyptus leaves, apple eucalyptus leaves and lemon grass in a mass ratio of 3:1:1:2: 1.
2. The environment-friendly paint with functions of sterilization, mildew prevention and air purification as claimed in claim 1, which is characterized in that: the coating comprises the following raw materials in parts by weight: 57 parts of alkyd resin, 19 parts of polyacrylate emulsion, 11 parts of nano-attapulgite, 13 parts of nano-kaolinite, 9 parts of diatomite, 5 parts of lithium silicate, 6 parts of polyamide resin, 0.6 part of mineral oil defoamer, 1.0 part of nano-titanium oxide, 9 parts of gas-purifying bactericidal powder, 0.6 part of organic bentonite, 0.1 part of polyacrylic acid ammonium salt dispersant, 0.2 part of carboxymethyl cellulose, 5 parts of coconut oil and 50 parts of deionized water.
3. The environment-friendly paint with functions of sterilization, mildew prevention and air purification as claimed in claim 1, which is characterized in that:
the preparation method of the environment-friendly coating comprises the following steps:
a. firstly, grinding diatomite, lithium silicate and organic bentonite into fine powder, and then uniformly mixing the fine powder with nano attapulgite, nano kaolinite, nano titanium oxide and gas purification sterilization powder to prepare mixed powder;
b. mixing alkyd resin, polyacrylate emulsion and polyamide resin, stirring at a stirring speed of 300r/min for at least 30min, adding a polyacrylic acid ammonium salt dispersing agent, a mineral oil defoaming agent, carboxymethyl cellulose, coconut oil, deionized water and the mixed powder prepared in the step a, and stirring at a stirring speed of 1000r/min for 8h to obtain the environment-friendly paint with the functions of sterilization, mildew prevention and air purification.
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CN104513577A (en) * 2013-09-27 2015-04-15 天津单渡科技开发有限公司 Environmental-protection interior wall latex paint
CN107083141A (en) * 2017-06-17 2017-08-22 合肥市晨雷思建筑材料科技有限公司 A kind of indoor sterilization dust removing coating and preparation method
CN107325712A (en) * 2017-07-13 2017-11-07 安庆市星空化工涂料有限责任公司 A kind of fungicidal paint
CN107652895A (en) * 2017-10-23 2018-02-02 周瑛 Environment protection interior wall finish paint

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101186772A (en) * 2007-12-04 2008-05-28 华南农业大学 Helminthic emulsion paint and preparation method thereof
CN104513577A (en) * 2013-09-27 2015-04-15 天津单渡科技开发有限公司 Environmental-protection interior wall latex paint
CN107083141A (en) * 2017-06-17 2017-08-22 合肥市晨雷思建筑材料科技有限公司 A kind of indoor sterilization dust removing coating and preparation method
CN107325712A (en) * 2017-07-13 2017-11-07 安庆市星空化工涂料有限责任公司 A kind of fungicidal paint
CN107652895A (en) * 2017-10-23 2018-02-02 周瑛 Environment protection interior wall finish paint

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