CN101186772A - Helminthic emulsion paint and preparation method thereof - Google Patents
Helminthic emulsion paint and preparation method thereof Download PDFInfo
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- CN101186772A CN101186772A CNA2007100320531A CN200710032053A CN101186772A CN 101186772 A CN101186772 A CN 101186772A CN A2007100320531 A CNA2007100320531 A CN A2007100320531A CN 200710032053 A CN200710032053 A CN 200710032053A CN 101186772 A CN101186772 A CN 101186772A
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Abstract
The invention discloses emulsion paint for expelling flies and mosquitoes, and the components and weight percentage contents of the invention are that acrylate copolymer emulsion holds 20%-30%, polycarboxylate holds 0.5%-1.0%, aromatic hydrocarbyl polyether holds 0.2%-0.5%, titanium dioxide holds 10%-25%, fillers hold 25%-35%, defoaming agents hold 0.2%-0.5%, antiseptic holds 0.2%-0.5%, adsorbent holds 0.001%-0.5%, thickener holds 0.2%-0.5%, alcohol ester holds 1%-2%, pH regulator holds 0%-0.2%, essential oil holds 0.01%-0.5%, polyether flatting agents hold 0.1%-2%, and the rest is water. The invention simultaneously discloses a process for preparing the emulsion paint for expelling flies and mosquitoes, which employs a novel dispersing technique and utilizes the essential oil which is nontoxic, safe and environment-friendly as a raw material. The product has the advantages of water resistance, alkali proof, washability, scuff resistance, mould proof, algae resistance, safety, environment protection and nontoxicity, and further the product has the functions of permanently and effectively expelling flies and mosquitoes and purifying air.
Description
Technical field
The present invention relates to a kind of functional interior wall coating, relate in particular to Helminthic emulsion paint of a kind of nontoxic, safety and environmental protection and preparation method thereof.
Background technology
Improve constantly along with the enhancing of people's Environmental awareness and to health great attention and standard of living, people urgently pursue one had not both had the interference of insects such as fly mosquito, the environment of minimizing disease, and a residence that bright and colourful elegance is holy and pure is arranged again.Sanitary insect pest remains and adopts traditional spraying and stifling killing method at present, and this method time length is short, and human body and environment are all had certain influence.
In recent years; more deep to the research of insecticidal coating both at home and abroad; Development and Production goes out a series of insecticidal coating; " A Dilan " insecticidal emulsion paint as France; domestic " green king " insecticidal emulsion paint etc.; these products have desinsection concurrently and wall decoration is protected in one, and the desinsection lasting period can reach 3～5 years.But what add in these insecticidal emulsion paints is chemical pesticide, and human body is had certain influence.In emulsion paint, add the vegetal fly mosquito material production environment-friendly type coating that drives and temporarily do not see any report at home and abroad, still belong to technological gap.
Summary of the invention
The purpose of this invention is to provide a kind of nontoxic, safety and environmental protection mosquito repellent fly emulsion paint.
Another object of the present invention is to provide the preparation method of described mosquito repellent fly emulsion paint, method is simple, and cost is low, and step is clear, and required equipment is simple.
Technical scheme of the present invention provides a kind of Helminthic emulsion paint, and its component and content are:
Acrylate copolymer emulsion 20%～30%
Polycarboxylate 0.5%～1.0%
Aryl polyethers 0.2%～0.5%
Titanium dioxide 10%～25%
Filler 25%～35%
Defoamer 0.2%～0.5%
Sanitas 0.2%～0.5%
Sorbent material 0.001%～0.5%
Thickening material 0.2%～0.5%
Alcohol ester 1%～2%
PH regulator agent 0%～0.2%
Plants essential oil 0.01%～5%
Polyethers flow agent 0.1%～2%
Water surplus
All percentage ratios are weight percentage.
Described plants essential oil is following one or more mixtures:
Nim oil, neem oil, Salvia Sclare L.oil, perilla oil, rose oil, root tuber of aromatic turmeric sesame oil, jasmin oil, pamorusa oil, the hair oil of bay, Oleum Cinnamomi, Oleum Menthae Rotundifoliae, santal oil, sassafras wood oil, anistree leaf oil, anistree branch oil, spearmint oil, wild mint oil, Japanese mint oil, false spearmint oil, peppermint oil, Peppermint Oil, Litsea cubeba oil, pepper leaf oil, Fructus Zanthoxyli oil, star aniseed oil, Sweet fennel oil, star aniseed oil, pine and cypress oil, sandy ground pitch, cedar(wood)oil, sweet basil oil, the hair basil oil, tulsi oil, the Africa basil oil, wild thyme oil, the mother chrysanthemum caul-fat, oil of Flos Chrysanthemi, Dendranthema indicum oil, the amphibious crab elecampane oil, tagetes oil, ucuhuba oil, the fragrant shaddock oil of gold, Oils, Zingiber officinale, Armadal curcuma oil, eucalyptus oil, eucalyptus citriodora oil, gallery edge volatile oil extracted from eucalyptus' leaves or twigs, oleum anethi, Fructus Coriandri oil, oil of Rhizoma Acori Graminei, heroubill oil, Oleum Bulbus Allii, litsea cubeba oil, tori seed oil, Semen Armeniacae Amarum oil, oreodaphene, Oil﹠Ulan, white orchid oil, yellow blue oil, narcissus oil, oily with a smile, cananga oil, lotus oil, evening primrose oil, Citrus aurantium L. var. amara Engl. Oil, Syzygium aromaticum stem oil, caraway seed oil, tingia Calusena lansium oil, Calusena lansium oil, oil of Herba Pogostemonis, patchouli oil, Oleum lavandula angustifolia, lavandin oil, rosemary oil, Oleum Blumeae Balsamiferae, linaloe oil, sweet orange oil, citrus oil, oil of Folium Et Cacumen Murrayae, a thousand li sesame oil, sesame oil all over the sky, Mi Zilan oil, Oils, Apium graveolens, foenugreek oil, wild marjoram oil, lantana oil, Ledum palustre L. var. dilatatum Wahl.oil, bay-oil, gardenia flower oil, Herba Agerati Conyzoidis oil, Motherwort Herb oil, mango oil, rue oil, oleum graminis citrati, lemon oil, nepeta oil, Herba Nepetae catariae oil, Oil of chenopodium, the chrysanthemum sagebrush oil, the oriental wormwood sagebrush oil, the mugwort sagebrush oil, Oleum Folium Artemisiae Argyi, China pink oil, birch oil, lily of the valley oil, white strain wood oil, Radix Angelicae Sinensis oil, sweetsop oil, Artemisia scoparia oil; Toluamide between diethyl, dimethyl phthalate, dibutyl phthalate, anti-piperitol, trans-isoesdragol, camphor, borneol, estragole, mentha camphor, parsley camphor, the 4-terpinene, beta-myrcene, terpinene, limonene, α-Pai Xi, beta-pinene, α-santalol, β-santalol, styryl carbinol, alpha-terpineol, Linaool, right-Meng alkane-3, the 8-glycol, Geraniol, geraniol, phantol, menthol, geranial, citral, phenylacrolein, α-Eucarvone, the 8-acetoxycarvotanacetone, piperitone, yellow artemone, piperitone, Karvon, thymol, isothymol, Eugenol, methyl eugenol, methylisoeugenol, 1, the 8-eucalyptol, myristicin or piperine.
Described sorbent material is one or more a mixture of potter's clay, attapulgite, zeolite, vermiculite, calcite, diatomite, sandstone, float stone, precipitated silicate calcium, white carbon black, silica gel, silica sand, mud coal, brown coal, blast-furnace slag, phosphorus ore tailing, phosphatic rock, pyrophyllite, montmorillonite, wilkinite, precipitated chalk, river sand, extra large sand, expanded perlite, starch or beta-cyclodextrin.
Described water is tap water, distilled water or deionized water.
Described acrylic acid copolymer liquid is complete third, phenylpropyl alcohol, vinegar third or vinegar uncle.
Described filler is lime carbonate, talcum powder, kaolin, pure aluminium silicate or mica powder.
Described thickening material is Mierocrystalline cellulose, acrylic thickener or polyurethanes thickening material.
Described pH regulator agent is ammoniacal liquor or hydramine.
The invention provides the preparation method of described Helminthic emulsion paint, may further comprise the steps:
(1) sorbent material is mixed with plants essential oil, high speed dispersion makes the plants essential oil sustained release dosage;
(2) water, polycarboxylate, aryl polyethers, titanium dioxide, filler, defoamer are mixed, in the high speed dispersion to 50 micron; Add sanitas, alcohol ester and acrylate copolymer emulsion, middling speed is disperseed; The pH value is transferred to 6.5～7.5, add (1) plants essential oil sustained release dosage, middling speed is disperseed; Regulate viscosity to 95～105KU, filter and package.
Described high speed dispersion adopts 2000 rev/mins dispersion rate; Middling speed disperses to adopt 200 rev/mins dispersion rate.
The polycarboxylate that adopts among the present invention is polyacrylic acid sodium salt or ammonium polyacrylate salt etc.; The aryl polyethers is alkylphenol polyoxyethylene, polyether silicon, fatty alcohol-polyoxyethylene ether, aliphatic acid polyethenoxy ether, glycerin polyoxyethylene ether etc.; Defoamer is a mineral oils, silicone based etc.; Sanitas is pyrrolotriazine derivatives and ketones derivant etc.; Alcohol ester is propylene glycol ester, oleic acid octadecylene alcohol ester, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate etc.Select for use according to the emulsion paint conventional production process.
The invention has the beneficial effects as follows:
(1) the present invention adopts plants essential oil nontoxic, safety and environmental protection, reach the slowly-releasing effect by adsorbents adsorb, prolong and drive the fly mosquito time, thereby can reduce the VOC of emulsion paint, remove peculiar smell, reduce the toxicity of product, product not only has excellent water-alkali resistance performance, easily washes anti-wiping, the anti-algae of mildew-resistant, safety and environmental protection, characteristics such as nontoxic, also has the function that persistent high efficiency drives the fly mosquito and purifies air.
(2) the present invention adopts a kind of dispersion technology of novelty, makes to drive the release equably lastingly of fly mosquito activeconstituents, and the Helminthic emulsion paint of preparation has satisfactory stability, and method is easy, strong operability, and market application foreground and promotional value are very high.
Embodiment
Below in conjunction with specific embodiment technical solution of the present invention is described in further detail.In the present invention, simple the substituting of the material of identical application target do not given unnecessary details one by one in an embodiment.
One, Helminthic emulsion paint preparation experiment:
Embodiment 1:
According to following steps:
(1) sorbent material is mixed with plants essential oil, adopt electric blender to carry out high speed dispersion about 30 minutes, make the plants essential oil sustained release dosage with 2000 rev/mins speed;
(2) water, polycarboxylate, aryl polyethers, titanium dioxide, filler, defoamer are mixed, with 2000 rev/mins of high speed dispersion to particle diameter in 50 microns; Add sanitas, alcohol ester and acrylate copolymer emulsion, with 200 rev/mins of middling speed dispersing and mixing; The pH value is transferred to 6.5～7.5, add (1) plants essential oil sustained release dosage, with 200 rev/mins of middling speed dispersing and mixing; Regulate viscosity to 95～105KU, filter and package.
Specific operation process is:
Get sorbent material potter's clay powder 10Kg, Oleum Cinnamomi 100Kg, high speed dispersion to make the Oleum Cinnamomi sustained release dosage, is kept somewhere the back and is used.
Water intaking 258Kg, polycarboxylate 6Kg, aryl polyethers 3Kg, titanium dioxide 200Kg, lime carbonate 150Kg, talcum powder 40Kg, kaolin 60Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 10Kg, pure-acrylic emulsion 250Kg is with they blending dispersion, add the above-mentioned Oleum Cinnamomi sustained release dosage 11Kg for preparing, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 4Kg, the middling speed blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 2: step is with embodiment 1.
Get sorbent material white carbon black powder 10Kg, Oleum Menthae Rotundifoliae 150Kg, high speed dispersion to make the Oleum Menthae Rotundifoliae sustained release dosage, is kept somewhere the back and is used.
Water intaking 346Kg, polycarboxylate 5Kg, aryl polyethers 3Kg, titanium dioxide 180Kg, lime carbonate 130Kg, talcum powder 30Kg, kaolin 70Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, benzene-acrylic emulsion 200Kg is with they blending dispersion, add the above-mentioned Oleum Menthae Rotundifoliae sustained release dosage 16Kg for preparing, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 3:
Get sorbent material silica-gel powder 10Kg, Oleum Menthae Rotundifoliae 100Kg, Oleum Bulbus Allii 50Kg, high speed dispersion to make Oleum Menthae Rotundifoliae, Oleum Bulbus Allii mixing sustained release dosage, is kept somewhere the back and is used.
Water intaking 306Kg, polycarboxylate 4Kg, aryl polyethers 4Kg, titanium dioxide 200Kg, lime carbonate 150Kg, talcum powder 40Kg, kaolin 80Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, vinegar-acrylic emulsion 180Kg with they blending dispersion, adds the above-mentioned Oleum Menthae Rotundifoliae for preparing, Oleum Bulbus Allii mixing sustained release dosage 16Kg, the pH regulator agent is an amount of, adds Natvosol 2Kg, polyethers flow agent 4Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 4:
Get sorbent material diatomite in powder 20Kg, a thousand li sesame oil 100Kg, Oleum Menthae Rotundifoliae 50Kg, pamorusa oil stay 50Kg, high speed dispersion, and to make a thousand li sesame oil, Oleum Menthae Rotundifoliae, pamorusa oil mixing sustained release dosage are kept somewhere the back and are used.
Water intaking 319Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned a thousand li sesame oil for preparing, Oleum Menthae Rotundifoliae, pamorusa oil stays and mixes sustained release dosage 22Kg, and the pH regulator agent is an amount of, adds Natvosol 2Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 5:
Get sorbent material montmorillonite powder 10Kg, Oleum Cinnamomi 100Kg, oreodaphene 50Kg, high speed dispersion, to make Oleum Cinnamomi, oreodaphene mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 382Kg, polycarboxylate 6Kg, aryl polyethers 6Kg, titanium dioxide 200Kg, lime carbonate 150Kg, talcum powder 30Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, benzene-acrylic emulsion 150Kg with they blending dispersion, adds the above-mentioned Oleum Cinnamomi for preparing, oreodaphene mixing sustained release dosage 16Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 6:
Get sorbent material bentonite in powder 20Kg, rose oil 150Kg, high speed dispersion to make the rose oil sustained release dosage, is kept somewhere the back and is used.
Water intaking 332Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 50Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, benzene-acrylic emulsion 160Kg is with they blending dispersion, add the above-mentioned rose oil sustained release dosage 17Kg for preparing, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 7:
Get sorbent material starch powder 20Kg, Karvon 100Kg, phenylacrolein 100Kg, high speed dispersion, to make Karvon, phenylacrolein mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 348Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, pure-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned Karvon for preparing, phenylacrolein mixing sustained release dosage 11Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 8:
Get sorbent material beta-cyclodextrin powder 20Kg, evening primrose oil 100Kg, jasmin oil 100Kg, high speed dispersion, to make evening primrose oil, jasmin oil mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 348Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, pure-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned evening primrose oil for preparing, jasmin oil mixing sustained release dosage 11Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 9:
Get sorbent material potter's clay powder 20Kg, star aniseed oil 100Kg, sesame oil 100Kg all over the sky, high speed dispersion, to make star aniseed oil, sesame oil mixing sustained release dosage all over the sky is kept somewhere the back and is used.
Water intaking 358.89Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, benzene-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned star aniseed oil for preparing, sesame oil mixing sustained release dosage 0.11Kg all over the sky, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 10:
Get sorbent material precipitated chalk powder 20Kg, Peppermint Oil 200Kg, high speed dispersion to make the Peppermint Oil sustained release dosage, is kept somewhere the back and is used.
Water intaking 358.89Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, benzene-acrylic emulsion 160Kg is with they blending dispersion, add the above-mentioned Peppermint Oil sustained release dosage 0.11Kg for preparing, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 11:
Get sorbent material precipitated silicate calcium powder 20Kg, Oleum Bulbus Allii 100Kg, phenylacrolein 100Kg, high speed dispersion, to make Oleum Bulbus Allii, phenylacrolein mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 358.89Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, vinegar-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned Oleum Bulbus Allii for preparing, phenylacrolein mixing sustained release dosage 0.11Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 12:
Get sorbent material attapulgite powder 20Kg, root tuber of aromatic turmeric sesame oil 100Kg, Karvon 50Kg, oreodaphene 50Kg, high speed dispersion is to make root tuber of aromatic turmeric sesame oil, Karvon, oreodaphene mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 357.9Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, vinegar-acrylic emulsion 160Kg, with they blending dispersion, add the above-mentioned root tuber of aromatic turmeric sesame oil for preparing, Karvon, oreodaphene mixing sustained release dosage 1.1Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 13:
Get sorbent material pumice sand 20Kg, lemon oil 100Kg, Dendranthema indicum oil 100Kg, high speed dispersion, to make lemon oil, Dendranthema indicum oil mixes sustained release dosage, keeps somewhere the back and uses.
Water intaking 357.9Kg, polycarboxylate 6Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 40Kg, kaolin 30Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 9Kg, vinegar-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned lemon oil for preparing, Dendranthema indicum oil mixes sustained release dosage 1.1Kg, and the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 14:
Get sorbent material expanded perlite powder 20Kg, mother chrysanthemum caul-fat 100Kg, mentha camphor 50Kg, α-santalol 50Kg, high speed dispersion is to make the mother chrysanthemum caul-fat, mentha camphor, α-santalol mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 369.9Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 160Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 160Kg, with they blending dispersion, add the above-mentioned mother chrysanthemum caul-fat for preparing, mentha camphor, α-santalol mixing sustained release dosage 1.1Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 15:
Get sorbent material phosphorus ore tailing powder 20Kg, Oleum lavandula angustifolia 100Kg, Oleum Cinnamomi 50Kg, santal oil 50Kg, high speed dispersion is to make Oleum lavandula angustifolia, Oleum Cinnamomi, santal oil mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 346.5Kg, polycarboxylate 5Kg, aryl polyethers 4Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 160Kg, with they blending dispersion, add the above-mentioned Oleum lavandula angustifolia for preparing, Oleum Cinnamomi, santal oil mixing sustained release dosage 5.5Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 16:
Get sorbent material pyrophyllite in powder 20Kg, oil of Herba Pogostemonis 100Kg, oriental wormwood sagebrush oil 100Kg, high speed dispersion, to make oil of Herba Pogostemonis, oriental wormwood sagebrush oil mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 345.5Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned oil of Herba Pogostemonis for preparing, oriental wormwood sagebrush oil mixing sustained release dosage 5.5Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 17:
Get sorbent material white carbon black powder 20Kg, perilla oil 100Kg, beta-myrcene 100Kg, high speed dispersion, to make perilla oil, beta-myrcene mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 346.5Kg, polycarboxylate 5Kg, aryl polyethers 4Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 160Kg with they blending dispersion, adds the above-mentioned perilla oil for preparing, beta-myrcene mixing sustained release dosage 5.5Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 18:
Get sorbent material white carbon black powder 20Kg, ucuhuba oil 100Kg, rosemary oil 50Kg, piperitone 50Kg, high speed dispersion is to make ucuhuba oil, rosemary oil, piperitone mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 345.5Kg, polycarboxylate 5Kg, aryl polyethers 4Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned ucuhuba oil for preparing, rosemary oil, piperitone mixing sustained release dosage 16.5Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 19:
Get sorbent material bentonite in powder 20Kg, Radix Angelicae Sinensis oil 100Kg, Herba Nepetae catariae oil 50Kg, linaloe oil 50Kg, high speed dispersion is to make Radix Angelicae Sinensis oil, Herba Nepetae catariae oil, linaloe oil mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 345.5Kg, polycarboxylate 5Kg, aryl polyethers 4Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned Radix Angelicae Sinensis oil for preparing, Herba Nepetae catariae oil, linaloe oil mixing sustained release dosage 16.5Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 20:
Get sorbent material potter's clay powder 20Kg, oleum anethi 100Kg, wild thyme oil 50Kg, the oily 50Kg of the lily of the valley, high speed dispersion is to make oleum anethi, wild thyme oil, lily of the valley oil mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 345.5Kg, polycarboxylate 5Kg, aryl polyethers 4Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 40Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned oleum anethi for preparing, wild thyme oil, lily of the valley oil mixes sustained release dosage 16.5Kg, and the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 21:
Get sorbent material potter's clay powder 20Kg, Oleum Cinnamomi 100Kg, oil of Folium Et Cacumen Murrayae 100Kg, high speed dispersion, to make Oleum Cinnamomi, oil of Folium Et Cacumen Murrayae mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 318Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 180Kg, lime carbonate 200Kg, talcum powder 50Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg with they blending dispersion, adds the above-mentioned Oleum Cinnamomi for preparing, oil of Folium Et Cacumen Murrayae mixing sustained release dosage 33Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 22:
Get sorbent material bentonite in powder 20Kg, thymol 100Kg, isothymol 50Kg, Linaool 50Kg, high speed dispersion is to make thymol, isothymol, Linaool mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 298Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 200Kg, talcum powder 50Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned thymol for preparing, isothymol, Linaool mixing sustained release dosage 33Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 23:
Get sorbent material beta-cyclodextrin powder 20Kg, litsea cubeba oil 100Kg, anti-piperitol 50Kg, the oily 50Kg of pine and cypress, high speed dispersion is to make litsea cubeba oil, anti-piperitol, pine and cypress oil mixing sustained release dosage, usefulness after keeping somewhere.
Water intaking 296Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 50Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg, with they blending dispersion, add the above-mentioned litsea cubeba oil for preparing, anti-piperitol, pine and cypress oil mixes sustained release dosage 55Kg, and the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 24:
Get sorbent material beta-cyclodextrin powder 20Kg, Calusena lansium oil 100Kg, Oils, Apium graveolens 100Kg, high speed dispersion, to make Calusena lansium oil, anti-piperitol mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 316Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 180Kg, lime carbonate 180Kg, talcum powder 50Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg with they blending dispersion, adds the above-mentioned Calusena lansium oil for preparing, anti-piperitol mixing sustained release dosage 55Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 25:
Get sorbent material vermiculite power 20Kg, spearmint oil 100Kg, rue oil 100Kg, high speed dispersion, to make spearmint oil, rue oil mixing sustained release dosage is kept somewhere the back and is used.
Water intaking 296Kg, polycarboxylate 5Kg, aryl polyethers 5Kg, titanium dioxide 200Kg, lime carbonate 180Kg, talcum powder 50Kg, kaolin 40Kg, defoamer 3Kg, sanitas 2Kg, alcohol ester 8Kg, vinegar-acrylic emulsion 150Kg with they blending dispersion, adds the above-mentioned spearmint oil for preparing, rue oil mixing sustained release dosage 55Kg, the pH regulator agent is an amount of, adds Natvosol 3Kg, polyethers flow agent 3Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 26: step is with embodiment 1.
Get sorbent material white carbon black powder 10Kg, Oleum Menthae Rotundifoliae 100Kg, high speed dispersion to make the Oleum Menthae Rotundifoliae sustained release dosage, is kept somewhere the back and is used.
Water intaking 208.9Kg, polycarboxylate 5Kg, aryl polyethers 2Kg, titanium dioxide 100Kg, lime carbonate 200Kg, talcum powder 50Kg, kaolin 100Kg, defoamer 2Kg, sanitas 5Kg, alcohol ester 20Kg, benzene-acrylic emulsion 300Kg is with they blending dispersion, add the above-mentioned Oleum Menthae Rotundifoliae sustained release dosage 1.1Kg for preparing, the pH regulator agent is an amount of, adds acrylic thickener 5Kg, polyethers flow agent 1Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Embodiment 27: step is with embodiment 1.
Get sorbent material white carbon black powder 10Kg, Oleum Menthae Rotundifoliae 100Kg, high speed dispersion to make the Oleum Menthae Rotundifoliae sustained release dosage, is kept somewhere the back and is used.
Water intaking 286Kg, polycarboxylate 10Kg, aryl polyethers 5Kg, titanium dioxide 250Kg, lime carbonate 100Kg, talcum powder 20Kg, kaolin 40Kg, defoamer 5Kg, sanitas 5Kg, alcohol ester 9Kg, benzene-acrylic emulsion 193Kg is with they blending dispersion, add the above-mentioned Oleum Menthae Rotundifoliae sustained release dosage 55Kg for preparing, the pH regulator agent is an amount of, adds Natvosol 2Kg, polyethers flow agent 20Kg, blending dispersion filters and packages and promptly obtains 1000Kg Helminthic emulsion paint of the present invention.
Two, the repellent action of fly mosquito class is tested:
Embodiment 28
1. Helminthic emulsion paint is to the repellency test of housefly, mosquito
Test method:
Adult housefly after in the foster fly of two butt joints of 50 * 40 * 35cm, mosquito cage, inserting 150～200 emergence 7d or the mosquito adult behind the emergence 2d in the 7th, 90,180,360,720 day.Helminthic emulsion paint is coated on the cement plate of a 30 * 30cm, is placed in one and one supports in the fly mosquito cage, contrast (CK) places in another foster fly mosquito cage with the emulsion paint that does not add plants essential oil, observes also record contrast and the interior housefly of Helminthic emulsion paint cage, a mosquito number.Each is observed once at 9 o'clock in the morning that connects worm same day and at 3 o'clock in afternoon, and 15min established 3 and repeated each observing time.Be calculated as follows scattering ratio:
Test-results sees Table 1
Table 1 Helminthic emulsion paint is at the repellent effect of different time to housefly
| Helminthic emulsion paint | Average scattering ratio (%) | ||||
| 7d | 90d | 180d | 360d | 720d | |
| Example 1 example 2 examples 3 examples 4 examples 5 examples 6 examples 7 examples 8 examples 9 examples 10 examples 11 examples 12 examples 13 examples 14 examples 15 examples 16 examples 17 examples 18 examples 19 examples 20 examples 21 examples 22 examples 23 examples 24 examples 25 examples 26 examples 27 | 87.36 99.00 100.00 100.00 100.00 94.81 93.99 98.00 69.00 70.00 60.00 70.00 80.00 80.00 100.00 98.45 98.88 100.00 100.00 100.00 100.00 96.26 100.00 100.00 100.00 100.00 100.00 | 81.30 94.38 91.50 91.20 92.40 87.00 88.75 95.44 64.58 64.00 44.00 64.25 76.00 70.00 90.00 88.15 89.56 100.00 100.00 100.00 100.00 86.02 91.79 100.00 100.00 100.00 100.00 | 62.52 88.83 86.35 87.30 90.70 76.25 71.4 91.01 59.77 43.00 35.00 57.86 60.00 65.00 85.00 82.54 86.25 100.00 100.00 100.00 100.00 84.00 88.12 100.00 100.00 99.00 100.00 | 56.22 80.56 76.33 83.00 88.10 64.01 60.78 85.63 33.75 32.25 34.14 48.33 55.25 59.00 82.00 65.90 73.21 100.00 100.00 98.00 98.00 64.88 83.34 100.00 96.00 94.20 100.00 | 45.12 75.00 71.25 80.10 79.30 45.50 55.50 80.58 26.82 18.23 23.00 44.44 50.38 47.58 69.45 61.20 62.58 99.00 98.00 90.00 91.23 57.43 73.29 100.00 89.37 88.47 98.40 |
Annotate: average scattering ratio is the mean value of the scattering ratio of 3 tests on the same day 1).
2. Helminthic emulsion paint is to the repellency test of mosquito
Experimental technique is with the repellency test of Helminthic emulsion paint to housefly, mosquito, and experimental result sees Table 2.
Table 2 Helminthic emulsion paint is at the repellent effect of different time to mosquito
| Helminthic emulsion paint | Average scattering ratio (%) | ||||
| 7d | 90d | 180d | 360d | 720d | |
| Example 1 example 2 examples 3 examples 4 examples 5 examples 6 examples 7 examples 8 examples 9 examples 10 examples 11 examples 12 examples 13 examples 14 examples 15 examples 16 examples 17 examples 18 examples 19 examples 20 examples 21 examples 22 examples 23 examples 24 examples 25 examples 25 examples 25 | 84.45 100.00 100.00 100.00 100.00 94.68 96.30 100.00 90.00 80.00 70.00 100.00 100.00 100.00 100.00 99.58 100.00 100.00 100.00 100.00 96.92 97.00 100.00 100.00 100.00 100.00 100.00 | 79.50 98.14 92.36 100.00 100.00 82.03 96.27 96.65 75.33 77.00 66.00 93.33 90.00 100.00 100.00 89.74 98.01 100.00 100.00 100.00 89.34 88.44 94.10 100.00 97.26 95.53 100.00 | 66.54 96.57 88.44 100.00 100.00 80.19 92.00 94.11 59.59 70.00 56.00 86.73 81.00 100.00 100.00 88.50 90.02 100.00 100.00 100.00 84.86 77.00 89.12 100.00 89.98 86.28 99.00 | 62.21 89.98 87.01 100.00 100.00 75.24 85.33 84.25 54.33 63.00 53.00 78.33 71.56 100.00 100.00 80.71 83.21 100.00 100.00 100.00 83.21 68.69 83.34 100.00 87.21 83.41 96.21 | 60.83 85.68 74.14 100.00 100.00 59.36 76.38 89.55 47.00 50.00 38.98 74.28 61.11 99.22 99.35 72.20 83.33 100.00 100.00 100.00 80.00 54.48 75.29 100.00 86.98 80.78 94.42 |
Annotate: average scattering ratio is the mean value of the scattering ratio of 3 tests on the same day 1).
Claims (10)
1. Helminthic emulsion paint, its component and content are:
Acrylate copolymer emulsion 20%～30%
Polycarboxylate 0.5%～1.0%
Aryl polyethers 0.2%～0.5%
Titanium dioxide 10%～25%
Filler 25%～35%
Defoamer 0.2%～0.5%
Sanitas 0.2%～0.5%
Sorbent material 0.001%～0.5%
Thickening material 0.2%～0.5%
Alcohol ester 1%～2%
PH regulator agent 0%～0.2%
Plants essential oil 0.01%～5%
Polyethers flow agent 0.1%～2%
Water surplus
All percentage ratios are weight percentage.
2. Helminthic emulsion paint according to claim 1 is characterized in that described plants essential oil is following one or more mixtures:
Nim oil, neem oil, Salvia Sclare L.oil, perilla oil, rose oil, root tuber of aromatic turmeric sesame oil, jasmin oil, pamorusa oil, the hair oil of bay, Oleum Cinnamomi, Oleum Menthae Rotundifoliae, santal oil, sassafras wood oil, anistree leaf oil, anistree branch oil, spearmint oil, wild mint oil, Japanese mint oil, false spearmint oil, peppermint oil, Peppermint Oil, Litsea cubeba oil, pepper leaf oil, Fructus Zanthoxyli oil, star aniseed oil, Sweet fennel oil, star aniseed oil, pine and cypress oil, sandy ground pitch, cedar(wood)oil, sweet basil oil, the hair basil oil, tulsi oil, the Africa basil oil, wild thyme oil, the mother chrysanthemum caul-fat, oil of Flos Chrysanthemi, Dendranthema indicum oil, the amphibious crab elecampane oil, tagetes oil, ucuhuba oil, the fragrant shaddock oil of gold, Oils, Zingiber officinale, Armadal curcuma oil, eucalyptus oil, eucalyptus citriodora oil, gallery edge volatile oil extracted from eucalyptus' leaves or twigs, oleum anethi, Fructus Coriandri oil, oil of Rhizoma Acori Graminei, heroubill oil, Oleum Bulbus Allii, litsea cubeba oil, tori seed oil, Semen Armeniacae Amarum oil, oreodaphene, Oil﹠Ulan, white orchid oil, yellow blue oil, narcissus oil, oily with a smile, cananga oil, lotus oil, evening primrose oil, Citrus aurantium L. var. amara Engl. Oil, Syzygium aromaticum stem oil, caraway seed oil, tingia Calusena lansium oil, Calusena lansium oil, oil of Herba Pogostemonis, patchouli oil, Oleum lavandula angustifolia, lavandin oil, rosemary oil, Oleum Blumeae Balsamiferae, linaloe oil, sweet orange oil, citrus oil, oil of Folium Et Cacumen Murrayae, a thousand li sesame oil, sesame oil all over the sky, Mi Zilan oil, Oils, Apium graveolens, foenugreek oil, wild marjoram oil, lantana oil, Ledum palustre L. var. dilatatum Wahl.oil, bay-oil, gardenia flower oil, Herba Agerati Conyzoidis oil, Motherwort Herb oil, mango oil, rue oil, oleum graminis citrati, lemon oil, nepeta oil, Herba Nepetae catariae oil, Oil of chenopodium, the chrysanthemum sagebrush oil, the oriental wormwood sagebrush oil, the mugwort sagebrush oil, Oleum Folium Artemisiae Argyi, China pink oil, birch oil, lily of the valley oil, white strain wood oil, Radix Angelicae Sinensis oil, sweetsop oil, Artemisia scoparia oil; Toluamide between diethyl, dimethyl phthalate, dibutyl phthalate, anti-piperitol, trans-isoesdragol, camphor, borneol, estragole, mentha camphor, parsley camphor, the 4-terpinene, beta-myrcene, terpinene, limonene, α-Pai Xi, beta-pinene, α-santalol, β-santalol, styryl carbinol, alpha-terpineol, Linaool, right-Meng alkane-3, the 8-glycol, Geraniol, geraniol, phantol, menthol, geranial, citral, phenylacrolein, α-Eucarvone, the 8-acetoxycarvotanacetone, piperitone, yellow artemone, piperitone, Karvon, thymol, isothymol, Eugenol, methyl eugenol, methylisoeugenol, 1, the 8-eucalyptol, myristicin or piperine.
3. Helminthic emulsion paint according to claim 1 is characterized in that described sorbent material is one or more a mixture of potter's clay, attapulgite, zeolite, vermiculite, calcite, diatomite, sandstone, float stone, precipitated silicate calcium, white carbon black, silica gel, silica sand, mud coal, brown coal, blast-furnace slag, phosphorus ore tailing, phosphatic rock, pyrophyllite, montmorillonite, wilkinite, precipitated chalk, river sand, extra large sand, expanded perlite, starch or beta-cyclodextrin.
4. Helminthic emulsion paint according to claim 1 is characterized in that described water is tap water, distilled water or deionized water.
5. Helminthic emulsion paint according to claim 1 is characterized in that described acrylic acid copolymer liquid is complete third, phenylpropyl alcohol, vinegar third or vinegar uncle.
6. Helminthic emulsion paint according to claim 1 is characterized in that described filler is lime carbonate, talcum powder, kaolin, pure aluminium silicate or mica powder.
7. Helminthic emulsion paint according to claim 1 is characterized in that described thickening material is Mierocrystalline cellulose, acrylic acid or the like or polyurethanes.
8. Helminthic emulsion paint according to claim 1 is characterized in that described pH regulator agent is ammoniacal liquor or hydramine.
9. the preparation method of the described Helminthic emulsion paint of claim 1 is characterized in that may further comprise the steps:
(1) sorbent material is mixed with plants essential oil, high speed dispersion makes the plants essential oil sustained release dosage;
(2) water, polycarboxylate, aryl polyethers, titanium dioxide, filler, defoamer are mixed, high speed dispersion is to 50 microns of particle diameters; Add sanitas, alcohol ester and acrylate copolymer emulsion, middling speed is disperseed; The pH value is transferred to 6.5～7.5, add step (1) plants essential oil sustained release dosage, middling speed is disperseed; Regulate viscosity to 95～105KU, filter and package.
10. according to the preparation method of the described Helminthic emulsion paint of claim 9, it is characterized in that described high speed dispersion adopts 2000 rev/mins dispersion rate; Middling speed disperses to adopt 200 rev/mins dispersion rate.
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