CN107163848A - A kind of Natural environmentally-friepaint paint and preparation method thereof - Google Patents
A kind of Natural environmentally-friepaint paint and preparation method thereof Download PDFInfo
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- CN107163848A CN107163848A CN201710488258.4A CN201710488258A CN107163848A CN 107163848 A CN107163848 A CN 107163848A CN 201710488258 A CN201710488258 A CN 201710488258A CN 107163848 A CN107163848 A CN 107163848A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to building material technical field, and in particular to a kind of Natural environmentally-friepaint paint and preparation method thereof;Including following component raw material:Cellulose derivative, Folium Artemisiae Argyi extract, Rosmarinus officinalis extract, natural resin, tung oil and bamboo charcoal;Step is:1)Preparation of nano titanium oxide dispersion:Hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic anhydride, nano titanium oxide, water are added in mixer, 50min is stirred, temperature is at 80 100 DEG C;2)It is 10 μm standby plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant to be added fineness is ground in grinder;3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane resin, adjust pH, mix, rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then isocyanate curing agent is added;Using natural formula as raw material, without toxic component in preparation process, safety non-toxic.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of Natural environmentally-friepaint paint and preparation method thereof.
Background technology
When people lift this material of paint of coating, the sensation readily recognized that is exactly the dress being processed into industrial chemicals
Decorations property coating material, it has pungent peculiar smell, contains harmful substance composition.Since man invented paint of coating, in sheet not
Depart from the category of chemical industry, it also brings the invasion and attack of harmful substance while decoration functions are played.1st, benzene compound master
To be evaporated from paint, benzene,toluene,xylene is indispensable solvent in paint.2nd, the addition of various paints
Agent and diluent.Benzene largely exists in the organic solvent of various building and ornament materials, such as is commonly called as the dilute of Tianna solution in fitting up
Material, main component is all benzene,toluene,xylene.3rd, various adhesive.Particularly solvent-based adhesive still has in decoration industry
Certain market, and the solvent majority wherein used is toluene, wherein containing more than 30% benzene, but it is because price, dissolubility, viscous
The reasons such as connecing property, are also used by some enterprises.The sofa of some families purchase discharges substantial amounts of benzene, and main cause is in production
It is middle to have used containing the high adhesive of benzene.4th, waterproof material.Particularly some add the water-repellent paint that solvent or diluent is configured to former powder, operate
Detect within 15 hours afterwards, Indoor Air Benzene content, which exceedes country, allows 14.7 times of maximum concentration.5th, some are low-grade and personation
Coating, is also the major reason for causing Indoor Air Benzene content overproof.Harmful substance in paint and coating has to human body
Which harm, 1, Chronic Benzene Poisoning, mainly benzene has stimulation to skin, eyes and the upper respiratory tract.2nd, benzene is sucked for a long time
Alpastic anemia can be caused.3rd, women endangers sensitive compared with male to Benzene and Homologues, and toluene, dimethylbenzene are to reproductive function
Also there is certain influence.4th, benzene can cause the birth defects of fetus.With civilization and progress and scientific development, people are exploring all the time
Make great efforts in terms of research and development non-polluting coatings paint.
The content of the invention
Not enough present in background technology in order to overcome, the present invention proposes a kind of Natural environmentally-friepaint paint and preparation method thereof,
Using natural formula as raw material, and without toxic component, safety non-toxic in preparation process.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of Natural environmentally-friepaint paint, including following component raw material:Cellulose derivative, Folium Artemisiae Argyi extract, Rosmarinus officinalis extract, day
Right resin, tung oil and bamboo charcoal.
Further, including following composition by weight raw material:6-10 parts of cellulose derivative, 3-5 parts of Folium Artemisiae Argyi extract, rosemary
1-3 parts of 3-5 parts of extract, 20-30 parts of natural resin, 5-10 parts of tung oil and bamboo charcoal.
Further, including following composition by weight raw material:8 parts of cellulose derivative, 4 parts of Folium Artemisiae Argyi extract, rosemary are extracted
2 parts of 4 parts of thing, 25 parts of natural resin, 8 parts of tung oil and bamboo charcoal.
Further, 2-3 parts of zeolite is included.
Further, the aperture of the zeolite is 2-3mm.
A kind of preparation method of Natural environmentally-friepaint paint, including step in detail below:
1)Preparation of nano titanium oxide dispersion:By hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic acid
Acid anhydride, nano titanium oxide, water are added in mixer, stir 50min, temperature is at 80-100 DEG C;
2)Plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant are added in grinder and are ground to fineness
It is standby for 10 μm;
3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane tree
Fat, adjusts pH, mixes, and rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then isocyanates is added
Curing agent.
Further, in step 3)In, pH is 6-7.
Further, when in use, by the Paint dilution of preparation, the volume ratio of paint and water is 1-3-5.
Beneficial effects of the present invention:
1. inventive formulation uses natural component, and by the interaction between formula, enables to the paint peace prepared
Complete not public hazards, to health without negative effect;
2. adding folium artemisiae argyi and rosemary in formula, safety non-toxic can not only be realized, and with the effect of mosquito is prevented, no
Peculiar smell can be produced;
3. preparation technology of the present invention is simple, without noxious material, the control to preparation process parameters can realize preparation
Paint ingredients it is stable, adhesive force is strong.
Embodiment
In order that the purpose of the present invention, technical scheme and beneficial effect are clearer, the preferred embodiments of the present invention are entered
Row detailed description, to facilitate the technical staff to understand.
Embodiment 1
A kind of Natural environmentally-friepaint paint, including following composition by weight raw material:6-10 parts of cellulose derivative, 3-5 parts of Folium Artemisiae Argyi extract,
1-3 parts of 3-5 parts of Rosmarinus officinalis extract, 20-30 parts of natural resin, 5-10 parts of tung oil and bamboo charcoal.
A kind of preparation method of Natural environmentally-friepaint paint, including step in detail below:
1)Preparation of nano titanium oxide dispersion:By hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic acid
Acid anhydride, nano titanium oxide, water are added in mixer, stir 50min, temperature is at 80-100 DEG C;
2)Plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant are added in grinder and are ground to fineness
It is standby for 10 μm;
3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane tree
Fat, adjusts pH, pH is 6-7, mixes, and rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then add
Isocyanate curing agent.
When in use, by the Paint dilution of preparation, the volume ratio of paint and water is 1-3-5.
Embodiment 2
A kind of Natural environmentally-friepaint paint, including following composition by weight raw material:8 parts of cellulose derivative, 4 parts of Folium Artemisiae Argyi extract, fan change
2 parts of fragrant 4 parts of extract, 25 parts of natural resin, 8 parts of tung oil and bamboo charcoal.
A kind of preparation method of Natural environmentally-friepaint paint, including step in detail below:
1)Preparation of nano titanium oxide dispersion:By hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic acid
Acid anhydride, nano titanium oxide, water are added in mixer, stir 50min, temperature is at 80-100 DEG C;
2)Plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant are added in grinder and are ground to fineness
It is standby for 10 μm;
3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane tree
Fat, adjusts pH, pH is 6-7, mixes, and rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then add
Isocyanate curing agent.
When in use, by the Paint dilution of preparation, the volume ratio of paint and water is 1-3-5.
Embodiment 3
A kind of Natural environmentally-friepaint paint, including following composition by weight raw material:8 parts of cellulose derivative, 4 parts of Folium Artemisiae Argyi extract, fan change
2 parts of fragrant 4 parts of extract, 25 parts of natural resin, 8 parts of tung oil and bamboo charcoal.
Also include 2-3 parts of zeolite, the aperture of the zeolite is 2-3mm.
A kind of preparation method of Natural environmentally-friepaint paint, including step in detail below:
1)Preparation of nano titanium oxide dispersion:By hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic acid
Acid anhydride, nano titanium oxide, water are added in mixer, stir 50min, temperature is at 80-100 DEG C;
2)Plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant are added in grinder and are ground to fineness
It is standby for 10 μm;
3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane tree
Fat, adjusts pH, pH is 6-7, mixes, and rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then add
Isocyanate curing agent.
When in use, by the Paint dilution of preparation, the volume ratio of paint and water is 1-3-5.
Inventive formulation uses natural component, and by the interaction between formula, enables to the paint prepared
Safe not public hazards, to health without negative effect;Folium artemisiae argyi and rosemary are added in formula, safe nothing can not only be realized
Poison, and with the effect of mosquito is prevented, peculiar smell will not be produced;Preparation technology of the present invention is simple, without noxious material, to system
The control of standby process parameters, can realize that the paint ingredients of preparation is stable, adhesive force is strong.
Finally illustrate, preferred embodiment above is merely illustrative of the technical solution of the present invention and unrestricted, although logical
Cross above preferred embodiment the present invention is described in detail, it is to be understood by those skilled in the art that can be
Various changes are made to it in form and in details, without departing from claims of the present invention limited range.
Claims (8)
1. a kind of Natural environmentally-friepaint paint, it is characterised in that:Including following component raw material:Cellulose derivative, Folium Artemisiae Argyi extract, fan
Repeatedly fragrant extract, natural resin, tung oil and bamboo charcoal.
2. a kind of Natural environmentally-friepaint paint according to claim 1, it is characterised in that:Including following composition by weight raw material:It is fine
Plain 6-10 parts of the derivative of dimension, 3-5 parts of Folium Artemisiae Argyi extract, 3-5 parts of Rosmarinus officinalis extract, 20-30 parts of natural resin, 5-10 parts of tung oil
With 1-3 parts of bamboo charcoal.
3. a kind of Natural environmentally-friepaint paint according to claim 1, it is characterised in that:Including following composition by weight raw material:It is fine
2 parts of plain 8 parts of the derivative of dimension, 4 parts of Folium Artemisiae Argyi extract, 4 parts of Rosmarinus officinalis extract, 25 parts of natural resin, 8 parts of tung oil and bamboo charcoal.
4. a kind of Natural environmentally-friepaint paint according to claim 2, it is characterised in that:Also include 2-3 parts of zeolite.
5. a kind of Natural environmentally-friepaint paint according to claim 4, it is characterised in that:The aperture of the zeolite is 2-3mm.
6. a kind of preparation method of Natural environmentally-friepaint paint, it is characterised in that:Including step in detail below:
1)Preparation of nano titanium oxide dispersion:By hydroxy propyl methacrylate, sodium salicylate, sodium acetate, phthalic acid
Acid anhydride, nano titanium oxide, water are added in mixer, stir 50min, temperature is at 80-100 DEG C;
2)Plant oil pastes, sodium soap, nano-calcium carbonate calcium powder, antiwear assistant are added in grinder and are ground to fineness
It is standby for 10 μm;
3)By step(1)With(2)Material mixing, then add fatty acid modified high viscosity short oil alkyd resin, polyurethane tree
Fat, adjusts pH, mixes, and rotating speed control stirs 30min, 90 DEG C of keeping temperature in 800r/min;Then isocyanates is added
Curing agent.
7. a kind of preparation method of Natural environmentally-friepaint paint according to claim 6, it is characterised in that:In step 3)In, pH
For 6-7.
8. a kind of preparation method of Natural environmentally-friepaint paint according to claim 6, it is characterised in that:When in use, it will make
The volume ratio of standby Paint dilution, paint and water is 1-3-5.
Priority Applications (1)
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CN201710488258.4A CN107163848A (en) | 2017-06-23 | 2017-06-23 | A kind of Natural environmentally-friepaint paint and preparation method thereof |
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CN201710488258.4A CN107163848A (en) | 2017-06-23 | 2017-06-23 | A kind of Natural environmentally-friepaint paint and preparation method thereof |
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CN201710488258.4A Pending CN107163848A (en) | 2017-06-23 | 2017-06-23 | A kind of Natural environmentally-friepaint paint and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111560205A (en) * | 2020-07-08 | 2020-08-21 | 百草春天大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
CN112876979A (en) * | 2021-01-12 | 2021-06-01 | 罗叔干 | Antifouling wear-resistant conductive coating and preparation method thereof |
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CN104231757A (en) * | 2014-09-02 | 2014-12-24 | 三凯社(江苏)新材料有限公司 | Novel environment-friendly paint |
CN106280936A (en) * | 2016-09-22 | 2017-01-04 | 李艳荣 | A kind of building environment protection oil paint and preparation method thereof |
CN106433468A (en) * | 2016-08-19 | 2017-02-22 | 桂林福冈新材料有限公司 | Environment-friendly paint |
CN106634599A (en) * | 2016-12-06 | 2017-05-10 | 青岛巨能管道设备有限公司 | Environment-friendly paint and preparation method thereof |
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2017
- 2017-06-23 CN CN201710488258.4A patent/CN107163848A/en active Pending
Patent Citations (7)
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US20090081465A1 (en) * | 2007-09-25 | 2009-03-26 | Monsanto Technology Llc | Use of oils with high concentrations of polyunsaturated fatty acids in plastics and surface coatings |
CN101186772A (en) * | 2007-12-04 | 2008-05-28 | 华南农业大学 | Helminthic emulsion paint and preparation method thereof |
CN101724308A (en) * | 2008-11-03 | 2010-06-09 | 夏栋 | Paint additive |
CN104231757A (en) * | 2014-09-02 | 2014-12-24 | 三凯社(江苏)新材料有限公司 | Novel environment-friendly paint |
CN106433468A (en) * | 2016-08-19 | 2017-02-22 | 桂林福冈新材料有限公司 | Environment-friendly paint |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111560205A (en) * | 2020-07-08 | 2020-08-21 | 百草春天大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
CN111560205B (en) * | 2020-07-08 | 2021-11-09 | 百草边大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
CN112876979A (en) * | 2021-01-12 | 2021-06-01 | 罗叔干 | Antifouling wear-resistant conductive coating and preparation method thereof |
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