CN100448924C - Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof - Google Patents
Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof Download PDFInfo
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- CN100448924C CN100448924C CNB2005100119609A CN200510011960A CN100448924C CN 100448924 C CN100448924 C CN 100448924C CN B2005100119609 A CNB2005100119609 A CN B2005100119609A CN 200510011960 A CN200510011960 A CN 200510011960A CN 100448924 C CN100448924 C CN 100448924C
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Abstract
The present invention relates to a plastic fly-repellent bottle cap of a bottle for edible condiments and a manufacture method thereof. The plastic fly-repellent bottle cap is composed of active fly-repellent components, absorbing agents and thermoplastic resin. When used for bottles for packaging condiments, the plastic fly-repellent bottle cap can be effectively repel flies and avoid the situation that condiments are sucked and eaten by flies in the process of consumption, and even the condiments are polluted because of the egg laying of flies, and thus, the sanitation of condiments is ensured.
Description
Technical field
The present invention relates to a kind of repellent fly class plastic bottle closure of edible-flavouring product bottle, the manufacture method and the application in the edible flavouring packaged product of described repellent fly class plastic bottle closure.
Background technology
Soy sauce, edible products such as oyster sauce are China and the requisite seasonings of south east asia people daily life, they are rich in amino acid, multiple one-tenth flavor such as organic acid material, they can strengthen flavour of food products, improve a poor appetite, yet, these seasonings (comprise housefly to the fly class, black tail is deceived sarcophagid, the common fly type pests in rooms such as calliphorid) has very strong attracting action, fly type pests is often stayed the dirts such as harmful microorganism that carry on the condiment package bottle cap when sucking or on the seasonings of bottleneck, also even lay eggs, therefore pollute seasonings, thereby can endanger the healthy of people.The common method of preventing and treating is to adopt chemical agent directly to kill the fly class.Yet therefore these seasonings using method usually are directly to add in the food,, can not adopt chemical agent directly to prevent and treat these fly classes, on the other hand, though chemical agent is quick-acting, but long-lasting is poor, thereby, can not use chemical agent to solve the harm problem of these fly classes.Derive from active skull cap components-essential oil and monomer whose or the fatty oil of plant, it is pleasant to have smell delicate fragrance, safety non-toxic, to characteristics such as the human and environment pungency are little, and the fly class had good repellent activity and oviposition deterrence is kept away activity, if adopt slow release method, can guarantee that the human consumer is in the time of using seasonings, effectively repellent fly class makes it not rest on condiment package bottle cap or bottle mouth position, has therefore avoided foregoing fly class harm.
Summary of the invention
The technical problem to be solved in the present invention is a kind of plastic bottle closure and manufacture method thereof of driving the fly activeconstituents that contain, this plastic bottle closure is applied to the packing bottle of flavouring like sauce, fly class (comprising the common fly type pests in room such as housefly, sarcophagid, calliphorid) there is persistent repellent effect, can guarantee seasonings in human consumer's use the fly class not on bottle cap or bottle mouth position stop, suck the seasonings of leaving over, even lay eggs in bottle, pollute seasonings, harm people's health.
Therefore, the present invention relates to a kind of fly-repellent plastic-bottle cap of edible flavouring bottle, it is characterized in that described plastic bottle closure drives fly activeconstituents, 0.01%～49.99% sorbent material and 50%～99.98% thermoplastic resin in described plastic bottle closure weight by 0.01%～10% and forms.
Preferably, the described content that drives the fly activeconstituents is to count 0.4%～5% with described plastic bottle closure weight.
In addition, the invention still further relates to a kind of fly-repellent plastic-bottle cover manufacturing method of adorning the edible flavouring bottle, it is characterized in that this method comprises the steps:
(1) uses adsorbents adsorb to drive the fly activeconstituents, make a kind of slow release type solid state powder;
(2) described slow release type solid state powder and thermoplastic resin stir, and make a kind of uniform mixture;
(3) the employing injection moulding machine in 100 ℃～300 ℃ following injection mouldings of temperature, obtains containing the plastic bottle closure that drives the fly activeconstituents with above-mentioned uniform mixture;
Therefore, the plastic bottle closure of manufacturing contains and drives fly activeconstituents, sorbent material and thermoplastic resin, wherein driving the fly active component content is to count 0.01%～10% with described plastic bottle closure weight, and sorbent material content is 0.01%～49.99%, and thermoplastic resin content is 50%～99.98%.
On meaning of the present invention, the described fly activeconstituents that drives is a kind of safe biological active material.
The described fly activeconstituents that drives can be that one or more are selected from following plants essential oil, plants essential oil component or fatty oil: nim oil, neem oil, Salvia Sclare L.oil, perilla oil, rose oil, root tuber of aromatic turmeric sesame oil, jasmin oil, pamorusa oil, the hair oil of bay, Oleum Cinnamomi, Oleum Menthae Rotundifoliae, santal oil, sassafras wood oil, anistree leaf oil, anistree branch oil, spearmint oil, wild mint oil, Japanese mint oil, false spearmint oil, peppermint oil, Peppermint Oil, Litsea cubeba oil, pepper leaf oil, Fructus Zanthoxyli oil, star aniseed oil, Sweet fennel oil, star aniseed oil, pine and cypress oil, sandy ground pitch, cedar(wood)oil, sweet basil oil, the hair basil oil, tulsi oil, the Africa basil oil, wild thyme oil, the mother chrysanthemum caul-fat, oil of Flos Chrysanthemi, Dendranthema indicum oil, the amphibious crab elecampane oil, tagetes oil, ucuhuba oil, the fragrant shaddock oil of gold, Oils, Zingiber officinale, Armadal curcuma oil, eucalyptus oil, eucalyptus citriodora oil, gallery edge volatile oil extracted from eucalyptus' leaves or twigs, oleum anethi, Fructus Coriandri oil, oil of Rhizoma Acori Graminei, heroubill oil, Oleum Bulbus Allii, litsea cubeba oil, tori seed oil, Semen Armeniacae Amarum oil, oreodaphene, Oil﹠Ulan, white orchid oil, yellow blue oil, narcissus oil, oily with a smile, cananga oil, lotus oil, evening primrose oil, Citrus aurantium L. var. amara Engl. Oil, Syzygium aromaticum stem oil, caraway seed oil, tingia Calusena lansium oil, Calusena lansium oil, oil of Herba Pogostemonis, patchouli oil, Oleum lavandula angustifolia, lavandin oil, rosemary oil, Oleum Blumeae Balsamiferae, linaloe oil, sweet orange oil, citrus oil, oil of Folium Et Cacumen Murrayae, a thousand li sesame oil, sesame oil all over the sky, Mi Zilan oil, Oils, Apium graveolens, foenugreek oil, wild marjoram oil, lantana oil, Ledum palustre L. var. dilatatum Wahl.oil, bay-oil, gardenia flower oil, Herba Agerati Conyzoidis oil, Motherwort Herb oil, mango oil, rue oil, oleum graminis citrati, lemon oil, nepeta oil, Herba Nepetae catariae oil, Oil of chenopodium, the chrysanthemum sagebrush oil, the oriental wormwood sagebrush oil, the mugwort sagebrush oil, Oleum Folium Artemisiae Argyi, China pink oil, birch oil, lily of the valley oil, white strain wood oil, Radix Angelicae Sinensis oil, sweetsop oil, Artemisia scoparia oil; Toluamide between diethyl, dimethyl phthalate, dibutyl phthalate, anti-piperitol, trans-isoesdragol, camphor, borneol, estragole, mentha camphor, parsley camphor, 4-terpinene, beta-myrcene, terpinene, limonene, α-Pai Xi, beta-pinene, α-santalol, β-santalol, styryl carbinol, alpha-terpineol, Linaool, 3,8-
Alkane glycol, Geraniol, geraniol, phantol, menthol, suitable-
2-alkene-1-alcohol, geranial, citral, phenylacrolein, α-Eucarvone, 8-acetoxycarvotanacetone, piperitone, yellow artemone, piperitone, Karvon, thymol, isothymol, Eugenol, methyl eugenol, methylisoeugenol, 1,8-eucalyptol, myristicin or piperine.
On meaning of the present invention, described sorbent material is the inert substance with strong adsorptive power.Described sorbent material is one or more materials that are selected from potter's clay, attapulgite, kaolin, zeolite, vermiculite, talcum powder, calcite, diatomite, sandstone, float stone, precipitated silicate calcium, white carbon black, silica gel, silica sand, mud coal, brown coal, blast-furnace slag, phosphorus ore tailing, phosphatic rock, pyrophyllite, montmorillonite, wilkinite, precipitated chalk, river sand, extra large sand, expanded perlite, starch or beta-cyclodextrin.
The granularity of described sorbent material is 90% mistake, 200 mesh sieves.
Described thermoplastic resin is meant under the situation of high-temperature heating can be converted into fluid by solid, through cooling off the chain macromolecule compound of curable moulding again.
Described thermoplastic resin is one or more resins that are selected from polyethylene, polypropylene, polystyrene, ABS, polyvinyl chloride, nylon, polyvinyl alcohol, polycarbonate, PET, PBT, PCT, EVA, ethylene methyl acrylate, ethylene ethyl acrylate, ethylene butyl acrylate, vinylchlorid vinyl acetate between to for plastic interpolymer paste resin or acrylic resin.
On meaning of the present invention, term " slowly-releasing " be meant drive the fly activeconstituents have controlled from bottle cap slowly volatilization discharge, thereby keep the long period effectively drive fly concentration.
Fly-repellent plastic-bottle cap constructed in accordance application in the packing flavouring like sauce.According to spirit of the present invention, be used to drive various insects such as fly class if use the present invention to drive the resulting mixture of fly activeconstituents with adsorbents adsorb, also should be in protection scope of the present invention.
The present invention is directed to the cause harm characteristics of fly class to flavouring like sauce, making contains drives fly activeconstituents plastic bottle closure, be loaded on the bottleneck of condiment package bottle, effective repellent fly class, make its not on the bottle cap of condiment package bottle or bottle mouth position stop, suck the seasonings that remains on the bottle cap, even lay eggs in bottle, pollute seasonings.The present invention uses the natural fly activeconstituents that drives derive from plant, safety non-toxic, and smell delicate fragrance is pleasant, and is little to the human and environment pungency, has easy and simple to handlely, and the slowly-releasing lasting period is long, drives the effective advantage of fly.
The plastic bottle closure that the present invention makes has slowly-releasing and long advantage of lasting period, can keep the effective repellent to the fly class in a long time, thereby guarantees that flavouring like sauce is not encroached on by the fly class in the usage period the human consumer, guarantees health.
These materials or its composition have the good repellent or the deterrent effect of laying eggs to fly classes such as houseflies, and it is efficient to reach more than 70.0% or 100%.
Specific embodiments
Below in conjunction with embodiment technical solution of the present invention is described further
Embodiment 1: drive fly activeconstituents addition and be 0.01% plastic bottle closure
Drive fly activeconstituents, sorbent material, thermoplastic resin that present embodiment uses are respectively Oleum Cinnamomi, silica gel, polypropylene, and its mass ratio is respectively 0.01: 0.10: 99.89.
This plastic bottle closure manufacture method is as follows: (1) by mass ratio respectively accurately the weighing certain mass drive fly activeconstituents Oleum Cinnamomi, sorbent material silica gel and thermoplastic resin polypropylene; (2) will drive fly activeconstituents Oleum Cinnamomi and sorbent material silica gel mixes, make it absorption evenly, become the slow-release solid powder; (3),, can make to contain and drive fly activeconstituents plastic bottle closure through injection moulding machine injection moulding under 100 ℃～300 ℃ temperature with the slow-release solid powder and the uniform mixing of thermoplastic resin polypropylene that make.
Embodiment 2: drive fly activeconstituents addition and be 0.50% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive fly activeconstituents, sorbent material, the thermoplastic resin that use are respectively Oleum Cinnamomi, Oleum Menthae Rotundifoliae, diatomite, polyethylene, and its mass ratio is respectively=0.25: 0.25: 1.50: 98.00.
Embodiment 3: drive fly activeconstituents addition and be 0.40% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive fly activeconstituents, sorbent material, the thermoplastic resin that use are respectively Oleum Menthae Rotundifoliae, Oleum Bulbus Allii, diatomite, polyvinyl chloride, ethylene butyl acrylate, its mass ratio is respectively=and 0.25: 0.15: 1.60: 58: 40.
Embodiment 4: drive fly activeconstituents addition and be 10% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
A thousand li sesame oil, Oleum Menthae Rotundifoliae, pamorusa oil, diatomite, float stone, ABS, polycarbonate
＝4∶2∶4∶10∶5∶50∶25
Embodiment 5: drive fly activeconstituents addition and be 5% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oleum Cinnamomi, oreodaphene, white carbon black, polyethylene, EVA
＝3∶2∶10∶75∶10
Embodiment 6: drive fly activeconstituents addition and be 0.05% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Rose oil: talcum powder: polyethylene: ethylene ethyl acrylate
＝0.05∶2∶67.95∶30
Embodiment 7: drive fly activeconstituents addition and be 0.10% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Karvon: phenylacrolein: attapulgite: polyethylene: ethylene methyl acrylate
＝0.04∶0.06∶5∶54.90∶40
Embodiment 8: drive fly activeconstituents addition and be 0.80% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Evening primrose oil: jasmin oil: diatomite: polyethylene: acrylic resin
＝0.60∶0.20∶0.80∶58.40∶40
Embodiment 9: drive fly activeconstituents addition and be 0.60% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Star aniseed oil: sesame oil all over the sky: diatomite: silica gel: polyethylene: EVA: PET
＝0.30∶0.30∶0.50∶2.90∶32∶30∶34
Embodiment 10: drive fly activeconstituents addition and be 2.0% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Peppermint Oil: vermiculite: polyethylene: ethylene butyl acrylate
＝2.00∶28∶50∶20
Embodiment 11: drive fly activeconstituents addition and be 1.0% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oleum Bulbus Allii: phenylacrolein: silica gel: kaolin: polypropylene: polyvinyl alcohol: PCT
＝0.10∶0.90∶15∶25∶20∶20∶19
Embodiment 12: drive fly activeconstituents addition and be 0.45% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Root tuber of aromatic turmeric sesame oil: Karvon: oreodaphene: potter's clay: montmorillonite: PET: PCT
＝0.15∶0.15∶0.15∶10∶30∶39.55∶20
Embodiment 13: drive fly activeconstituents addition and be 1.20% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Lemon oil: Dendranthema indicum oil: sandstone: wilkinite: polycarbonate: polyethylene
＝0.90∶0.30∶1.20∶4.80∶22.80∶70
Embodiment 14: drive fly activeconstituents addition and be 2.50% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Mother chrysanthemum caul-fat: mentha camphor: α-santalol: precipitated silicate calcium: polyethylene
＝0.80∶0.70∶1.00∶15∶82.50
Embodiment 15: drive fly activeconstituents addition and be 4.0% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oleum lavandula angustifolia: Oleum Cinnamomi: santal oil: diatomite: polyethylene: polyvinyl alcohol
＝1.50∶2.00∶0.50∶10∶65∶21
Embodiment 16: drive fly activeconstituents addition and be 0.20% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oil of Herba Pogostemonis: oriental wormwood sagebrush oil: silica gel: polyethylene: PET
＝0.15∶0.05∶0.50∶39.30∶60
Embodiment 17: drive fly activeconstituents addition and be 0.30% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Perilla oil: beta-myrcene: diatomite: PET: PBT
＝0.10∶0.20∶5∶74.70∶20
Embodiment 18: drive fly activeconstituents addition and be 5.50% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Ucuhuba oil: rosemary oil: piperitone: vermiculite: blast-furnace slag: PET
＝1.50∶2.50∶1.50∶5.50∶4.50∶84.50
Embodiment 19: drive fly activeconstituents addition and be 6.00% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Radix Angelicae Sinensis oil: Herba Nepetae catariae oil: linaloe oil: mud coal: starch: polystyrene
＝0.50∶3.60∶1.90∶9∶5∶80
Embodiment 20: drive fly activeconstituents addition and be 8.00% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oleum anethi: wild thyme oil: lily of the valley oil: precipitated chalk: river sand: polypropylene: EVA
＝1.50∶3.50∶3.00∶6∶14∶52∶20
Embodiment 21: drive fly activeconstituents addition and be 0.25% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Oleum Cinnamomi: oil of Folium Et Cacumen Murrayae: beta-cyclodextrin: nylon: polyethylene
＝0.10∶0.15∶2.50∶27.25∶70
Embodiment 22: drive fly activeconstituents addition and be 0.15% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Thymol: isothymol: Linaool: precipitated silicate calcium: polyvinyl alcohol: polycarbonate
＝0.05∶0.05∶0.05∶5∶24.85∶70
Embodiment 23: drive fly activeconstituents addition and be 0.35% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Litsea cubeba oil: anti-piperitol: pine and cypress oil: diatomite: polyethylene: polypropylene
＝0.10∶0.15∶0.10∶15∶54.65∶30
Embodiment 24: drive fly activeconstituents addition and be 7.50% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Calusena lansium oil: Oils, Apium graveolens: diatomite: zeolite: polyethylene: EVA
＝6.50∶1.00∶10∶10∶50.50∶22
Embodiment 25: drive fly activeconstituents addition and be 0.70% plastic bottle closure
Present embodiment is according to the method manufacturing of embodiment 1, but drive the fly activeconstituents, sorbent material, thermoplastic resin that use are respectively:
Spearmint oil: rue oil: silica gel: polyethylene: vinylchlorid vinyl acetate between to for plastic interpolymer paste resin
＝0.50∶0.20∶3.50∶75.80∶20
Experimental example 1 fly-repellent plastic-bottle cap is to the repellent action test of fly class
1. fly-repellent plastic-bottle cap is to the repellency test of housefly
Test method
Adult housefly in the foster fly cage of 50 * 40 * 35cm behind 150～200 emergence 7d of access.With the fly-repellent plastic-bottle cap soy sauce bottleneck of packing into, draw inner cap, pour out soy sauce so that leave over a small amount of soy sauce in bottle cap, contrast (CK) is driven fly composition bottle cap with not adding.Place the diagonal angle of supporting the fly cage, observe and write down contrast and drive the tame tiny number and the laying of land on the fly bottle cap.1st, at 9 o'clock in 7,15,30,60 days the morning and afternoon 3 o'clock, each was observed once, and 15min established 3 and repeated each observing time.Be calculated as follows scattering ratio and oviposition deterrence is kept away rate:
Test-results sees Table 1
Table 1 fly-repellent plastic-bottle cap is at repellent and the oviposition deterrence avoiding effect of different time to housefly
Annotate: average scattering ratio is the mean value of the scattering ratio of 3 tests on the same day 1).
2) average scattering ratio or the oviposition deterrence rate of keeping away changes with the variation of population density.
The result of table 1 shows, the essential oil addition is 5.00% when above in the plastic bottle closure, and scattering ratio and the oviposition deterrence rate of keeping away to housefly in 60d all maintain 100%; The essential oil addition is 0.40% when above, in 60d to the average scattering ratio of housefly more than 70.25%, but can suppress laying eggs of housefly fully.
2. fly-repellent plastic-bottle cap is to the repellency test of the black sarcophagid of black tail
Test method is the same, and test-results sees Table 2.
Table 2 fly-repellent plastic-bottle cap is at repellent and the oviposition deterrence avoiding effect of different time to the black sarcophagid of black tail
Annotate: average scattering ratio is the mean value of the scattering ratio of 3 tests on the same day 1).
2) average scattering ratio or the oviposition deterrence rate of keeping away changes with the variation of population density.
Test (table 2) to the black sarcophagid of black tail shows, the essential oil addition can be deceived sarcophagid by successful repellent black tail 5.00% when above in the plastic bottle closure in 60d, suppresses it fully and lays eggs; The essential oil addition is 0.40% when above, in 60d to the average scattering ratio of the black sarcophagid of black tail more than 74.14%, but can suppress laying eggs of the black sarcophagid of black tail fully.
3. fly-repellent plastic-bottle cap is to the repellency test of calliphorid
Test method is the same, and test-results sees Table 3.
Table 3 fly-repellent plastic-bottle cap is at repellent and the oviposition deterrence avoiding effect of different time to calliphorid
Annotate: average scattering ratio is the mean value of the scattering ratio of 3 tests on the same day 1).
2) average scattering ratio or the oviposition deterrence rate of keeping away changes with the variation of population density.
As known from Table 3, in the plastic bottle closure essential oil addition 0.40% when above, in 60d to the average scattering ratio of calliphorid more than 77.34%, but can suppress laying eggs of calliphorid fully; The essential oil addition is 5.00% when above, can successful repellent calliphorid in 60d, and suppress it fully and lay eggs.
4. the application example of fly-repellent plastic-bottle cap
The fly-repellent plastic-bottle cap of making is applied to soy sauce, oyster sauce packing bottleneck, raise bottle cap and be placed in the room, establish and do not add the plastic bottle closure that drives the fly activeconstituents and be contrast (CK), place for some time after, observe infested situation in the soy cruet, result's following (table 4,5).
The infested effect of table 4 fly-repellent plastic-bottle cap control soy sauce
The infested effect of table 5 fly-repellent plastic-bottle cap control oyster sauce
From table 4,5 as can be seen, fly-repellent plastic-bottle cap is applied to soy sauce, the oyster sauce bottle places the room, under the situation of opening wide lid, the fly larvae digital display work of growth is less than and does not add the plastic bottle closure (CK) that drives the fly activeconstituents in the bottle, drive fly activeconstituents addition 0.4% when above, then all do not have larva and generate, show that fly-repellent plastic-bottle cap can use seasonings effective repellent fly class in the phase the human consumer, guarantee that seasonings is not caused harm by the fly class larva that lays eggs, grows in various test stages.Illustrate that the preferred addition that drives the fly activeconstituents in this patent is 0.4%～5%, suitable.
This patent has extremely strong operability and applicability.
Claims (6)
1, a kind of fly-repellent plastic-bottle cap of edible flavouring bottle is characterized in that described plastic bottle closure drives fly activeconstituents, 0.01%～49.99% sorbent material and 50%～99.98% thermoplastic resin in described plastic bottle closure weight by 0.01%～10% and forms; The described fly activeconstituents that drives is that one or more are selected from nim oil, neem oil, Salvia Sclare L.oil, perilla oil, rose oil, root tuber of aromatic turmeric sesame oil, jasmin oil, pamorusa oil, the hair oil of bay, Oleum Cinnamomi, Oleum Menthae Rotundifoliae, santal oil, sassafras wood oil, anistree leaf oil, anistree branch oil, spearmint oil, wild mint oil, Japanese mint oil, false spearmint oil, peppermint oil, Peppermint Oil, Litsea cubeba oil, pepper leaf oil, Fructus Zanthoxyli oil, star aniseed oil, Sweet fennel oil, star aniseed oil, pine and cypress oil, sandy ground pitch, cedar(wood)oil, sweet basil oil, the hair basil oil, tulsi oil, the Africa basil oil, wild thyme oil, the mother chrysanthemum caul-fat, oil of Flos Chrysanthemi, Dendranthema indicum oil, the amphibious crab elecampane oil, tagetes oil, ucuhuba oil, the fragrant shaddock oil of gold, Oils, Zingiber officinale, Armadal curcuma oil, eucalyptus oil, eucalyptus citriodora oil, gallery edge volatile oil extracted from eucalyptus' leaves or twigs, oleum anethi, Fructus Coriandri oil, oil of Rhizoma Acori Graminei, heroubill oil, Oleum Bulbus Allii, litsea cubeba oil, tori seed oil, Semen Armeniacae Amarum oil, Oil﹠Ulan, white orchid oil, yellow blue oil, narcissus oil, oily with a smile, cananga oil, lotus oil, evening primrose oil, Citrus aurantium L. var. amara Engl. Oil, Syzygium aromaticum stem oil, caraway seed oil, tingia Calusena lansium oil, Calusena lansium oil, oil of Herba Pogostemonis, patchouli oil, Oleum lavandula angustifolia, lavandin oil, rosemary oil, Oleum Blumeae Balsamiferae, linaloe oil, sweet orange oil, citrus oil, oil of Folium Et Cacumen Murrayae, a thousand li sesame oil, sesame oil all over the sky, Mi Zilan oil, Oils, Apium graveolens, foenugreek oil, wild marjoram oil, lantana oil, Ledum palustre L. var. dilatatum Wahl.oil, bay-oil, gardenia flower oil, Herba Agerati Conyzoidis oil, Motherwort Herb oil, mango oil, rue oil, oleum graminis citrati, lemon oil, nepeta oil, Herba Nepetae catariae oil, Oil of chenopodium, the chrysanthemum sagebrush oil, the oriental wormwood sagebrush oil, the mugwort sagebrush oil, Oleum Folium Artemisiae Argyi, China pink oil, birch oil, lily of the valley oil, white strain wood oil, Radix Angelicae Sinensis oil, sweetsop oil, Artemisia scoparia oil; Toluamide between diethyl, dimethyl phthalate, dibutyl phthalate, anti-piperitol, trans-isoesdragol, camphor, borneol, estragole, mentha camphor, parsley camphor, the 4-terpinene, beta-myrcene, terpinene, limonene, α-Pai Xi, beta-pinene, α-santalol, β-santalol, styryl carbinol, alpha-terpineol, Linaool, 3,8-alkane in Meng glycol, Geraniol, geraniol, phantol, suitable-Meng-2-alkene-1-alcohol, geranial, citral, phenylacrolein, α-Eucarvone, the 8-acetoxycarvotanacetone, piperitone, yellow artemone, piperitone, Karvon, thymol, isothymol, Eugenol, methyl eugenol, methylisoeugenol, 1, the 8-eucalyptol, myristicin or piperine; Described sorbent material is one or more materials that are selected from potter's clay, attapulgite, kaolin, zeolite, vermiculite, talcum powder, calcite, diatomite, sandstone, float stone, precipitated silicate calcium, white carbon black, silica gel, silica sand, mud coal, brown coal, blast-furnace slag, phosphorus ore tailing, phosphatic rock, pyrophyllite, montmorillonite, wilkinite, precipitated chalk, river sand, extra large sand, expanded perlite, starch or beta-cyclodextrin.
2, fly-repellent plastic-bottle cap according to claim 1 is characterized in that the described content that drives the fly activeconstituents is to count 0.4%～5% with described plastic bottle closure weight.
3. fly-repellent plastic-bottle cap according to claim 1 and 2 is characterized in that described thermoplastic resin is that one or more are selected from polyethylene, polypropylene, polystyrene, acrylonitrile butadient styrene, polyvinyl chloride, nylon, polyvinyl alcohol, polycarbonate, polyethylene terephthalate, polybutylene terephthalate, poly terephthalic acid cyclohexyl glycol ester, plastic of poly vinyl acetate, the polyethylene acrylic acid methyl esters, the polyethylene propylene acetoacetic ester, the polyethylene propylene acid butyl ester, the resin of vinylchlorid vinyl acetate between to for plastic interpolymer paste resin or polyacrylic resin.
4, a kind of fly-repellent plastic-bottle cap method for preparing the described edible flavouring bottle of claim 1 is characterized in that this method comprises the steps:
(1) uses adsorbents adsorb to drive the fly activeconstituents, make a kind of slow release type solid state powder;
(2) described slow release type solid state powder and thermoplastic resin stir, and make a kind of uniform mixture;
(3) the employing injection moulding machine in 100 ℃～300 ℃ following injection mouldings of temperature, obtains containing the plastic bottle closure that drives the fly activeconstituents with above-mentioned uniform mixture;
The plastic bottle closure of manufacturing contains and drives fly activeconstituents, sorbent material and thermoplastic resin, wherein in described plastic bottle closure weight, the described fly active component content that drives is 0.01%～10%, described sorbent material content is 0.01%～49.99%, and described thermoplastic resin content is 50%～99.98%; The described fly activeconstituents that drives is that one or more are selected from nim oil, neem oil, Salvia Sclare L.oil, perilla oil, rose oil, root tuber of aromatic turmeric sesame oil, jasmin oil, pamorusa oil, the hair oil of bay, Oleum Cinnamomi, Oleum Menthae Rotundifoliae, santal oil, sassafras wood oil, anistree leaf oil, anistree branch oil, spearmint oil, wild mint oil, Japanese mint oil, false spearmint oil, peppermint oil, Peppermint Oil, Litsea cubeba oil, pepper leaf oil, Fructus Zanthoxyli oil, star aniseed oil, Sweet fennel oil, star aniseed oil, pine and cypress oil, sandy ground pitch, cedar(wood)oil, sweet basil oil, the hair basil oil, tulsi oil, the Africa basil oil, wild thyme oil, the mother chrysanthemum caul-fat, oil of Flos Chrysanthemi, Dendranthema indicum oil, the amphibious crab elecampane oil, tagetes oil, ucuhuba oil, the fragrant shaddock oil of gold, Oils, Zingiber officinale, Armadal curcuma oil, eucalyptus oil, eucalyptus citriodora oil, gallery edge volatile oil extracted from eucalyptus' leaves or twigs, oleum anethi, Fructus Coriandri oil, oil of Rhizoma Acori Graminei, heroubill oil, Oleum Bulbus Allii, litsea cubeba oil, tori seed oil, Semen Armeniacae Amarum oil, Oil﹠Ulan, white orchid oil, yellow blue oil, narcissus oil, oily with a smile, cananga oil, lotus oil, evening primrose oil, Citrus aurantium L. var. amara Engl. Oil, Syzygium aromaticum stem oil, caraway seed oil, tingia Calusena lansium oil, Calusena lansium oil, oil of Herba Pogostemonis, patchouli oil, Oleum lavandula angustifolia, lavandin oil, rosemary oil, Oleum Blumeae Balsamiferae, linaloe oil, sweet orange oil, citrus oil, oil of Folium Et Cacumen Murrayae, a thousand li sesame oil, sesame oil all over the sky, Mi Zilan oil, Oils, Apium graveolens, foenugreek oil, wild marjoram oil, lantana oil, Ledum palustre L. var. dilatatum Wahl.oil, bay-oil, gardenia flower oil, Herba Agerati Conyzoidis oil, Motherwort Herb oil, mango oil, rue oil, oleum graminis citrati, lemon oil, nepeta oil, Herba Nepetae catariae oil, Oil of chenopodium, the chrysanthemum sagebrush oil, the oriental wormwood sagebrush oil, the mugwort sagebrush oil, Oleum Folium Artemisiae Argyi, China pink oil, birch oil, lily of the valley oil, white strain wood oil, Radix Angelicae Sinensis oil, sweetsop oil, Artemisia scoparia oil; Toluamide between diethyl, dimethyl phthalate, dibutyl phthalate, anti-piperitol, trans-isoesdragol, camphor, borneol, estragole, mentha camphor, parsley camphor, the 4-terpinene, beta-myrcene, terpinene, limonene, α-Pai Xi, beta-pinene, α-santalol, β-santalol, styryl carbinol, alpha-terpineol, Linaool, 3,8-alkane in Meng glycol, Geraniol, geraniol, phantol, suitable-Meng-2-alkene-1-alcohol, geranial, citral, phenylacrolein, α-Eucarvone, the 8-acetoxycarvotanacetone, piperitone, yellow artemone, piperitone, Karvon, thymol, isothymol, Eugenol, methyl eugenol, methylisoeugenol, 1, the 8-eucalyptol, myristicin or piperine; Described sorbent material is one or more materials that are selected from potter's clay, attapulgite, kaolin, zeolite, vermiculite, talcum powder, calcite, diatomite, sandstone, float stone, precipitated silicate calcium, white carbon black, silica gel, silica sand, mud coal, brown coal, blast-furnace slag, phosphorus ore tailing, phosphatic rock, pyrophyllite, montmorillonite, wilkinite, precipitated chalk, river sand, extra large sand, expanded perlite, starch or beta-cyclodextrin.
5, the manufacture method of fly-repellent plastic-bottle cap according to claim 4 is characterized in that described thermoplastic resin is that one or more are selected from polyethylene, polypropylene, polystyrene, acrylonitrile butadient styrene, polyvinyl chloride, nylon, polyvinyl alcohol, polycarbonate, polyethylene terephthalate, polybutylene terephthalate, poly terephthalic acid cyclohexyl glycol ester, plastic of poly vinyl acetate, the polyethylene acrylic acid methyl esters, the polyethylene propylene acetoacetic ester, the polyethylene propylene acid butyl ester, the resin of vinylchlorid vinyl acetate between to for plastic interpolymer paste resin or polyacrylic resin.
6, fly-repellent plastic-bottle cap according to claim 1 and 2 is driving fly and is avoiding the application that keeps away in the food product pack product that its fly lays eggs.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2005100119609A CN100448924C (en) | 2005-06-17 | 2005-06-17 | Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof |
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| CNB2005100119609A CN100448924C (en) | 2005-06-17 | 2005-06-17 | Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof |
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| CN100448924C true CN100448924C (en) | 2009-01-07 |
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