CN108659640A - Except the Chinese herbal medicine interior wall coating and preparation method thereof of formaldehyde - Google Patents
Except the Chinese herbal medicine interior wall coating and preparation method thereof of formaldehyde Download PDFInfo
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- CN108659640A CN108659640A CN201810233092.6A CN201810233092A CN108659640A CN 108659640 A CN108659640 A CN 108659640A CN 201810233092 A CN201810233092 A CN 201810233092A CN 108659640 A CN108659640 A CN 108659640A
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- extraction liquid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
There is provided a kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 5 10 mass parts；Wherein, extracting solution of the plant extraction liquid from lavender and wormwood.Interior wall coating of the present invention utilizes linalool, α absinthols, sesquiterpene alcohols and acetic acid lavender ester in plant extracts effectively to decompose the formaldehyde in air, make room air control in the range of being beneficial to health, it is pollution-free, zero release, the effect for making the living environment of people be optimal.
Description
Technical field
The present invention relates generally to paint fields, and particularly, are related to the Chinese herbal medicine interior wall coating except formaldehyde and its preparation side
Method.
Background technology
With the development of economy with the raising of living standards of the people, requirement of the people to air quality be also higher and higher.First
Aldehyde is to cause the main matter of room air pollution, and building and ornament materials are to cause the main source of formaldehyde pollution.
Research shows that:Formaldehyde has strong carcinogenic and tumor promotion.Lot of documents is recorded, shadow of the formaldehyde to health
Sound is mainly manifested in allotriosmia, stimulation, allergy, abnormal pulmonary function, dysfunction of liver and immunologic dysfunction etc..Work as sky
Concentration of formaldehyde reaches 0.06-0.07mg/m in gas3When, children will occur slightly to pant；When formaldehyde content in indoor air is
0.1mg/m3When, just there are peculiar smell and sense of discomfort；When formaldehyde content in indoor air reaches 0.5mg/m3When, eyes can be stimulated, are caused
It sheds tears；When formaldehyde content in indoor air reaches 0.6mg/m3, throat discomfort or pain can be caused.When concentration higher, it can cause
Nausea and vomiting, cough is uncomfortable in chest, asthma even pulmonary edema；When formaldehyde content in indoor air reaches 30mg/m3When, people can be caused immediately
It is dead.
Therefore, how to provide a kind of Chinese herbal medicine interior wall coating except formaldehyde is those skilled in the art's technology urgently to be resolved hurrily
Problem.
Invention content
The present invention provides a kind of Chinese herbal medicine interior wall coating except formaldehyde, adds plant extraction liquid in interior wall coating, utilizes plant
Linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender ester in object extract effectively decompose the formaldehyde in air, effectively
The formaldehyde in room air is removed, makes air quality control in the range of being beneficial to health, pollution-free, zero release makes
The effect that the living environment of people is optimal.
The present invention provides a kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes 5-10 mass parts
Plant extraction liquid；Wherein, the plant extraction liquid is the extracting solution of lavender and wormwood.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, the plant extraction liquid includes virtue
Camphor tree alcohol, α-absinthol, sesquiterpene alcohols and acetic acid lavender ester.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, the quality of the plant extraction liquid
A concentration of 80-90%, and α-arbor-vitae comprising the linalools of 20-30 mass parts, 50-70 mass parts in the plant extraction liquid
The acetic acid lavender ester of ketone, the sesquiterpene alcohols of 10-20 mass parts and 10-20 mass parts.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, which further includes 2-10
The plant fine powder of mass parts, the plant fine powder are almond fine powder.
In some embodiments, also include N- in the Chinese herbal medicine interior wall coating except formaldehyde, in the interior wall sealing wax
Phenyl-salicyl imines and n-Hydroxyphthalimide.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, the interior wall coating also 50-70 mass
The hydration resin lotion of part, the hydration resin lotion is vinyl acetate-acrylic ester copolymer that solid content is 50%-54%
Breast.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, which further includes 10-25
The filler of mass parts, the wetting agent of 0.1-0.5 mass parts, 0.2-0.4 mass parts dispersant, 0.2-0.6 mass parts defoaming
Agent, the natural botanical extraction liquid of 5-10 mass parts, the plant fine powder of 2-10 mass parts, the deionized water of 10-30 mass parts, 100-
The pH of the titanium dioxide of 250 mass parts, the thickener of 0.2-1 mass parts, the levelling agent of 0.3-0.8 mass parts, 0.1-0.3 mass parts
The coalescents of conditioning agent and 0.1-0.15 mass parts.
In some embodiments, in the Chinese herbal medicine interior wall coating except formaldehyde, the wetting agent is poly- for alkyl phenol
Ethylene oxide ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene block copolymer；The dispersant is Sodium Polyacrylate
Salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is polyurethanes levelling agent
In one kind；The filler is one or more combinations in calcined kaolin, diatomite and powdered whiting.
Another aspect of the present invention provides a kind of preparation method of the Chinese herbal medicine interior wall coating except formaldehyde comprising following step
Suddenly：Step 1: decladding almond, which is worn into powdery, is made almond fine powder；Step 2: sequentially add in a kettle plant extraction liquid,
Deionized water, pH adjusting agent, dispersant, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；Step
Rapid three, filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；Step 4: to reaction kettle
Middle addition hydration resin lotion and levelling agent stir 5-10min with 800-1200rpm rotating speeds, and thickener is added and is thickened to
Stormer viscosity meter 80-100KU (25 DEG C).
In some embodiments, in the preparation method except the Chinese herbal medicine interior wall coating of formaldehyde, in the step
Further include N- phenyl-salicyl imines and N- hydroxyl neighbour's benzene into the hydration resin lotion between rapid three and the step 4
Dicarboximide, 600-800rpm rotating speeds stir 20-30min.
Advantageous effect：
In Chinese herbal medicine interior wall coating of the present invention except formaldehyde, plant extraction liquid is added in interior wall coating, is utilized
Plant extraction liquid decomposes the formaldehyde in air, effectively removes the formaldehyde in room air, and can increase interior wall coating removes formaldehyde
Function, and the environmental requirement of interior wall coating can be met.
Specific implementation mode
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as the limit to the present invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that heretofore described term is only to describe special embodiment, being not intended to limit this hair
It is bright.In addition, for the numberical range in the present invention, it is thus understood that it is also specifically disclosed that every between the upper and lower bound of the range
A median.Median and any other statement value in any statement value or stated ranges or in the range in
Between each of between value smaller range be also included in the present invention.These small range of upper and lower bounds can include independently
Or it excludes in range.
Unless otherwise stated, all technical and scientific terms used herein has the routine in field of the present invention
The normally understood identical meanings of technical staff.Although the present invention only describes preferred method and material, the present invention's
Implement or can also be used and similar or equivalent any method and material described herein in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, to disclosure and description and the relevant method of the document and/or material.It is incorporated to any
When document conflicts, it is subject to the content of this specification.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
It is the term of opening, i.e., about "comprising" used herein, " comprising ", " having ", " containing " etc.
Mean including but not limited to.
Heretofore described " mass parts " or " % " unless otherwise instructed, by mass.
A kind of Chinese herbal medicine interior wall coating except formaldehyde of the present invention, wherein the interior wall coating includes 5-10 mass parts
Plant extraction liquid；Wherein, the plant extraction liquid is the extracting solution of lavender and wormwood.Preferably, the plant extraction liquid
It is the extracting solution of lavender, wormwood and cloves；It is highly preferred that the plant extraction liquid be lavender, wormwood, cloves, rheum officinale and
The extracting solution of galangal.
In some embodiments, the mass concentration of the plant extraction liquid is 80-90%, and in the plant extraction liquid
Include the sesquiterpene alcohols and 10-20 of α-absinthol of the linalool of 20-30 mass parts, 50-70 mass parts, 10-20 mass parts
The acetic acid lavender ester of mass parts.Preferably, the mass concentration of the plant extraction liquid is 80-85%, it is highly preferred that the plant
The mass concentration of object extracting solution is 80-82%, for example, the mass concentration of the plant extraction liquid is 80%, 81% or 82%.
Further include in certain embodiments, in the plant extraction liquid eugenols of 10-20 mass parts, 10-20 mass parts β-China pink
The gaultherolin of alkene, the methyl-n-amyl ketone of 5-10 mass parts and 5-10 mass parts.
In some embodiments, which further includes the plant fine powder of 2-10 mass parts, and the plant fine powder is
Almond fine powder.The plant essence point has intermiscibility well with the plant extraction liquid.
In some embodiments, also include N- phenyl-salicyl imines and N- hydroxyl neighbours benzene two in the interior wall sealing wax
Carboximide.In some embodiments, which includes the N- phenyl-salicyl imines and 5- of 5-15 mass parts
The n-Hydroxyphthalimide of 15 mass parts.Preferably, which includes N- phenyl-neighbour of 10-15 mass parts
The n-Hydroxyphthalimide of hydroxyphenyl imines and 10-15 mass parts.
Wherein, the N- phenyl-salicyl imines is salicylide to be extracted from plant as raw material, is repaiied by bromo
Decorations, are made 5- bromos and 3, and bis- bromo salicylides of 5- are condensed to yield N- phenyl-salicyl imines chemical combination with substituted aromatic amines
Object.N-Hydroxyphthalimide is the effective electron carrier of electrochemical oxidation, in n-Hydroxyphthalimide
O-H keys are easy homolysis and generate free radicals-N- oxygroup phthalimide free radicals.
In the interior wall sealing wax, which further includes the nanometer titanium dioxide of 100-250 mass parts.In use, in daylight
Under the action of so that Nanometer Titanium Dioxide is activated and generate the free radical with high catalytic activity, very strong photooxidation and also proper energy can be generated
Power, the photooxidation of nanometer titanium dioxide and reducing power can be catalyzed, photodissociation is attached to the formaldehyde of body surface, meanwhile, the N- benzene
The photooxidation of base-salicyl imines and imido grpup and free radical and nanometer titanium dioxide generation in n-Hydroxyphthalimide
Change under the collective effect with reducing power, absorb and decompose the formaldehyde in air, reduces the formaldehyde in air.In certain embodiment party
In formula, quality sum and the nano-titanium of the N- phenyl-salicyl imines and the n-Hydroxyphthalimide
White mass ratio is 0.1-0.5/1；Preferably, the N- phenyl-salicyl imines and the N- hydroxyls phthalyl
The quality sum of imines and the mass ratio of the Nanometer Titanium Dioxide are 0.1-0.3/1；For example, the N- phenyl-salicyl is sub-
The mass ratio of the quality sum of amine and the n-Hydroxyphthalimide and the Nanometer Titanium Dioxide be 0.1/1,0.2/1 or
0.3/1.In some embodiments, the N- phenyl-salicyl imines and the n-Hydroxyphthalimide and institute
It states that Nanometer Titanium Dioxide is mixed according to the above mentioned proportion, can preferably play the ability of the decomposing formaldehyde of nanometer titanium dioxide alone, meanwhile,
It promotes nanometer titanium dioxide and N- phenyl-coordinates decomposition first between salicyl imines and the n-Hydroxyphthalimide
The ability of aldehyde maximizes the ability of interior wall sealing wax degradation formaldehyde in indoor air.
In some embodiments, the hydration resin lotion of the interior wall coating also 50-70 mass parts, the hydration resin breast
Liquid is vinyl acetate-acrylic ester copolymer breast that solid content is 50%-54%.The vinyl acetate-acrylic ester copolymer breast is
New photoinitiator chemical production.
In some embodiments, the interior wall coating further include the filler of 10-25 mass parts, 0.1-0.5 mass parts profit
Humectant, the dispersant of 0.2-0.4 mass parts, the antifoaming agent of 0.2-0.6 mass parts, 5-10 mass parts natural botanical extraction liquid,
The plant fine powder of 2-10 mass parts, the deionized water of 10-30 mass parts, the nanometer titanium dioxide of 100-250 mass parts, 0.2-1 matter
Measure the thickener of part, the levelling agent of 0.3-0.8 mass parts, the pH adjusting agent of 0.1-0.3 mass parts and 0.1-0.15 mass parts
Coalescents.
Wherein, the wetting agent is alkyl phenol polyoxyethylene ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene
Block copolymer；The dispersant is Sodium Polyacrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile
Titanium dioxide；The levelling agent is one kind in polyurethanes levelling agent；The filler is calcined kaolin, diatomite and heavy carbon
One or more combinations in sour calcium；
Another aspect of the present invention also provides a kind of preparation method of the Chinese herbal medicine interior wall coating except formaldehyde comprising following step
Suddenly：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially add plant extraction liquid, deionized water, pH adjusting agent in a kettle, dispersant, antifoaming agent and
Wetting agent stirs 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
In some embodiments, further include to the hydration resin lotion between the step 3 and the step 4
Middle N- phenyl-salicyl imines and n-Hydroxyphthalimide, 600-800rpm rotating speeds stir 20-30min.
Surface drying time of the present invention is by referring to national standard《GB/T 6753.2-1986 coating surface drying experiments
Ballotini method》To test.
Contrast ratio of the present invention is by referring to national standard《GB/T23981-2009 whites and light colour paint contrast ratio
It measures》To test.
Alkali resistance of the present invention passes through national standard《GB/T 1763-1979 paint film chemical reagent resistance measuring methods》
To test.
The formaldehyde of the present invention that removes is by the way that coating is formed a film by being coated in indoor wall with the method for roller coating or spraying
Afterwards, its Formaldehyde decomposition rate is tested.
VOC content of the present invention is by reference to national standard《GB/T 23986-2009 paint and varnish volatility has
The measurement gas chromatography of machine compound (VOC) content》To test.
Embodiment
Embodiment 1
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 5 mass parts；Its
In, extracting solution of the plant extraction liquid from lavender and wormwood.
In said program, the plant extraction liquid includes linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender
Ester.
In said program, the mass concentration of the plant extraction liquid is 80%, and includes 20 matter in the plant extraction liquid
Measure the acetic acid lavender ester of the linalool of part, α-absinthol of 50 mass parts, the sesquiterpene alcohols of 10 mass parts and 10 mass parts.
In said program, which further includes the plant fine powder of 2 mass parts, and the plant fine powder is almond fine powder.
In said program, hydration resin lotion, the filler of 10 mass parts, 0.1 mass of the interior wall coating also 50 mass parts
The wetting agent of part, the dispersant of 0.2 mass parts, the antifoaming agent of 0.2 mass parts, the natural botanical extraction liquid of 5 mass parts, 2 mass
The plant fine powder, the deionized water of 10 mass parts, the titanium dioxide of 100 mass parts, the thickener of 0.2 mass parts, 0.3 mass parts of part
Levelling agent, 0.1 mass parts pH adjusting agent and 0.1 mass parts coalescents, wherein the hydration resin lotion be contain admittedly
Amount is newborn for 50% vinyl acetate-acrylic ester copolymer；The wetting agent is alkyl phenol polyoxyethylene ether；The dispersant is poly-
Sodium acrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is polyurethane
One kind in class levelling agent；The filler is calcined kaolin.
Preparation method：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, disperse
Agent, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
Embodiment 2
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 0 mass parts；Its
In, extracting solution of the plant extraction liquid from lavender and wormwood.
In said program, the plant extraction liquid includes linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender
Ester.
In said program, the mass concentration of the plant extraction liquid is 90%, and includes 30 matter in the plant extraction liquid
Measure the acetic acid lavender ester of the linalool of part, α-absinthol of 70 mass parts, the sesquiterpene alcohols of 20 mass parts and 20 mass parts.
In said program, which further includes the plant fine powder of 10 mass parts, and the plant fine powder is almond fine powder.
In said program, hydration resin lotion, the filler of 25 mass parts, 0.5 mass of the interior wall coating also 70 mass parts
The wetting agent of part, the dispersant of 0.4 mass parts, the antifoaming agent of 0.6 mass parts, the natural botanical extraction liquid of 10 mass parts, 10 matter
Measure the plant fine powder, the deionized water of 30 mass parts, the titanium dioxide of 250 mass parts, the thickener of 1 mass parts, 0.8 mass parts of part
Levelling agent, 0.3 mass parts pH adjusting agent and 0.15 mass parts coalescents, wherein the hydration resin lotion is solid
The vinyl acetate that content is 54%-acrylic ester copolymer breast；The wetting agent is polyoxyethylene aliphatic alcohol ether；The dispersant is
Sodium Polyacrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is poly- ammonia
One kind in esters levelling agent；The filler is diatomite.
Preparation method：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, disperse
Agent, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
Embodiment 3
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 7 mass parts；Its
In, extracting solution of the plant extraction liquid from lavender and wormwood.
In said program, the plant extraction liquid includes linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender
Ester.
In said program, the mass concentration of the plant extraction liquid is 85%, and includes 25 matter in the plant extraction liquid
Measure the linalool of part, α-absinthol of 60 mass parts, the sesquiterpene alcohols of 15 mass parts and the acetic acid lavender of 10-20 mass parts
Ester.
In said program, which further includes the plant fine powder of 7 mass parts, and the plant fine powder is almond fine powder.
In said program, hydration resin lotion, the filler of 20 mass parts, 0.3 mass of the interior wall coating also 60 mass parts
The wetting agent of part, the dispersant of 0.3 mass parts, the antifoaming agent of 0.4 mass parts, the natural botanical extraction liquid of 7 mass parts, 8 mass
The plant fine powder, the deionized water of 20 mass parts, the titanium dioxide of 200 mass parts, the thickener of 0.8 mass parts, 0.5 mass parts of part
Levelling agent, 0.2 mass parts pH adjusting agent and 0.1-0.15 mass parts coalescents, wherein the hydration resin lotion
Vinyl acetate-acrylic ester copolymer the breast for being 52% for solid content；The wetting agent is alkyl phenol polyoxyethylene ether, polyoxyethylene
The mixture of fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer；The dispersant is Sodium Polyacrylate salt；It is described
Antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is one kind in polyurethanes levelling agent；
The filler is a mixture of calcined kaolin, diatomite and powdered whiting.
Preparation method：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, disperse
Agent, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
Embodiment 4
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 8 mass parts, 15
N- phenyl-salicyl the imines and 15 mass parts n-Hydroxyphthalimide of mass parts；Wherein, the plant extraction liquid
From the extracting solution of lavender and wormwood.
In said program, the plant extraction liquid includes linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender
Ester.
In said program, the mass concentration of the plant extraction liquid is 83%, and includes 22 matter in the plant extraction liquid
Measure the acetic acid lavender ester of the linalool of part, α-absinthol of 58 mass parts, the sesquiterpene alcohols of 18 mass parts and 17 mass parts.
In said program, which further includes the plant fine powder of 6 mass parts, and the plant fine powder is almond fine powder.
In said program, hydration resin lotion, the filler of 18 mass parts, 0.4 mass of the interior wall coating also 62 mass parts
The wetting agent of part, the dispersant of 0.2 mass parts, the antifoaming agent of 0.5 mass parts, the natural botanical extraction liquid of 8 mass parts, 6 mass
The plant fine powder, the deionized water of 22 mass parts, the titanium dioxide of 180 mass parts, the thickener of 0.6 mass parts, 0.6 mass parts of part
Levelling agent, 0.2 mass parts pH adjusting agent and 0.13 mass parts coalescents, wherein the hydration resin lotion is solid
The vinyl acetate that content is 53%-acrylic ester copolymer breast；The wetting agent is polyoxyethylene polyoxypropylene block copolymer；Institute
It is Sodium Polyacrylate salt to state dispersant；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The stream
Flat agent is one kind in polyurethanes levelling agent；The filler is the mixture of diatomite and powdered whiting, the diatomite
It is mixed according to mass ratio 1/1 with the powdered whiting；
Preparation method：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, disperse
Agent, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: N- phenyl-salicyl imines and n-Hydroxyphthalimide into the hydration resin lotion,
600-800rpm rotating speeds stir 20-30min；
Step 5: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
Embodiment 5
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 6 mass parts, 11
N- phenyl-salicyl the imines and 11 mass parts n-Hydroxyphthalimide of mass parts；Wherein, the plant extraction liquid
From the extracting solution of lavender and wormwood.
In said program, the plant extraction liquid includes linalool, α-absinthol, sesquiterpene alcohols and acetic acid lavender
Ester.
In said program, the mass concentration of the plant extraction liquid is 88%, and includes 21 matter in the plant extraction liquid
Measure the acetic acid lavender ester of the linalool of part, α-absinthol of 59 mass parts, the sesquiterpene alcohols of 18 mass parts and 18 mass parts.
In said program, which further includes the plant fine powder of 9 mass parts, and the plant fine powder is almond fine powder.
In said program, hydration resin lotion, the filler of 19 mass parts, 0.3 mass of the interior wall coating also 58 mass parts
The wetting agent of part, the dispersant of 0.4 mass parts, the antifoaming agent of 0.3 mass parts, the natural botanical extraction liquid of 9 mass parts, 9 mass
The plant fine powder, the deionized water of 29 mass parts, the titanium dioxide of 220 mass parts, the thickener of 0.9 mass parts, 0.6 mass parts of part
Levelling agent, 0.3 mass parts pH adjusting agent and 0.15 mass parts coalescents, wherein the hydration resin lotion is solid
The vinyl acetate that content is 51%-acrylic ester copolymer breast；The wetting agent is alkyl phenol polyoxyethylene ether；The dispersant is
Sodium Polyacrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is poly- ammonia
One kind in esters levelling agent；The filler is the mixture of calcined kaolin and diatomaceous case mass ratio 1/1.
In said program, the quality of the N- phenyl-salicyl imines and the n-Hydroxyphthalimide it
Ratio with the quality with the nanometer titanium dioxide is 1/10.
Preparation method：
Step 1: decladding almond is worn into almond fine powder；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, disperse
Agent, antifoaming agent and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: N- phenyl-salicyl imines and n-Hydroxyphthalimide into the hydration resin lotion,
600-800rpm rotating speeds stir 20-30min；
Step 5: hydration resin lotion and levelling agent are added into reaction kettle, 5- is stirred with 800-1200rpm rotating speeds
10min is added thickener and carries out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
Comparative example 1
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes that 1-3 mass parts remove formaldehyde agent.
In said program, the hydration resin lotion of the interior wall coating also 50-70 mass parts, the filler of 10-25 mass parts,
The wetting agent of 0.1-0.5 mass parts, the dispersant of 0.2-0.4 mass parts, the antifoaming agent of 0.2-0.6 mass parts, 5-10 mass parts
Natural botanical extraction liquid, the plant fine powder of 2-10 mass parts, the deionized water of 10-30 mass parts, 100-250 mass parts titanium
White powder, the thickener of 0.2-1 mass parts, the levelling agent of 0.3-0.8 mass parts, the pH adjusting agent of 0.1-0.3 mass parts and 0.1-
The coalescents of 0.15 mass parts, wherein the hydration resin lotion is vinyl acetate-propylene that solid content is 50%-54%
Acid esters copolymerization breast；The wetting agent is that alkyl phenol polyoxyethylene ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene are embedding
Section copolymer；The dispersant is Sodium Polyacrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium
White powder；The levelling agent is one kind in polyurethanes levelling agent；The filler is calcined kaolin, diatomite, heavy carbonic acid
One or more combinations in calcium；
Comparative example 2
A kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes N- phenyl-neighbour's hydroxyl of 5-10 mass parts
Phenyl imine and 5-10 mass parts n-Hydroxyphthalimide；
In said program, the hydration resin lotion of the interior wall coating also 40-50 mass parts, the filler of 10-25 mass parts,
The wetting agent of 0.1-0.5 mass parts, the dispersant of 0.2-0.4 mass parts, the antifoaming agent of 0.2-0.6 mass parts, 5-10 mass parts
Natural botanical extraction liquid, the plant fine powder of 2-10 mass parts, the deionized water of 10-30 mass parts, 0.2-1 mass parts thickening
Agent, the levelling agent of 0.3-0.8 mass parts, the pH adjusting agent of 0.1-0.3 mass parts and 0.1-0.15 mass parts coalescents,
In, the hydration resin lotion is vinyl acetate-acrylic ester copolymer breast that solid content is 50%-54%；The wetting agent is
Alkyl phenol polyoxyethylene ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene block copolymer；The dispersant is poly-
Sodium acrylate salt；The antifoaming agent is mineral oils；The titanium dioxide is rutile titanium white powder；The levelling agent is polyurethane
One kind in class levelling agent；The filler is one or more combinations in calcined kaolin, diatomite, powdered whiting.
Table 1
Be prepared in above-described embodiment 1-5 and comparative example 1-2 except formaldehyde Chinese herbal medicine interior wall coating characterization test
The results are shown in Table 1, it can be seen that using the Chinese herbal medicine interior wall coating of the present invention except formaldehyde, VOC and heavy metal etc.
In the range of being not detected, while washability, adjustable wet are significantly better than that national standard, can not only reach persistently beautiful decoration
Effect, additionally it is possible to effectively adjust indoor air humidity, be allowed to control in the range of being beneficial to health, people preferably occupy
Firmly.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
Claims (10)
1. a kind of Chinese herbal medicine interior wall coating except formaldehyde, wherein the interior wall coating includes the plant extraction liquid of 5-10 mass parts；
Wherein, the plant extraction liquid is the extracting solution of lavender and wormwood.
2. the Chinese herbal medicine interior wall coating according to claim 1 except formaldehyde, wherein the plant extraction liquid includes fragrant camphor tree
Alcohol, α-absinthol, sesquiterpene alcohols and acetic acid lavender ester.
3. the Chinese herbal medicine interior wall coating according to claim 2 except formaldehyde, wherein the mass concentration of the plant extraction liquid
For 80-90%, and α-absinthol, the 10- of the linalool comprising 20-30 mass parts in the plant extraction liquid, 50-70 mass parts
The sesquiterpene alcohols of 20 mass parts and the acetic acid lavender ester of 10-20 mass parts.
4. the Chinese herbal medicine interior wall coating according to claim 1 except formaldehyde, wherein the interior wall sealing wax further includes 2-10 mass
The plant fine powder of part, the plant fine powder are almond fine powder.
5. the Chinese herbal medicine interior wall coating according to claim 4 except formaldehyde, wherein also include N- benzene in the interior wall sealing wax
Base-salicyl imines and n-Hydroxyphthalimide.
6. the Chinese herbal medicine interior wall coating according to claim 3 except formaldehyde, wherein the interior wall coating also 50-70 mass parts
Hydration resin lotion, the hydration resin lotion be solid content be 50%-54% vinyl acetate-acrylic ester copolymer breast.
7. the Chinese herbal medicine interior wall coating according to claim 1 except formaldehyde, wherein the interior wall coating further includes 10-25 matter
Measure the filler of part, the wetting agent of 0.1-0.5 mass parts, the dispersant of 0.2-0.4 mass parts, 0.2-0.6 mass parts antifoaming agent,
Natural botanical extraction liquid, the plant fine powder of 2-10 mass parts, the deionized water of 10-30 mass parts, the 100-250 of 5-10 mass parts
The pH tune of the titanium dioxide of mass parts, the thickener of 0.2-1 mass parts, the levelling agent of 0.3-0.8 mass parts, 0.1-0.3 mass parts
Save agent, 0.1-0.15 mass parts coalescents.
8. the Chinese herbal medicine interior wall coating according to claim 7 except formaldehyde, wherein
The wetting agent is alkyl phenol polyoxyethylene ether, polyoxyethylene aliphatic alcohol ether or polyoxyethylene polyoxypropylene block copolymerization
Object；
The dispersant is Sodium Polyacrylate salt；
The antifoaming agent is mineral oils；
The titanium dioxide is rutile titanium white powder；
The levelling agent is one kind in polyurethanes levelling agent；
The filler is one or more combinations in calcined kaolin, diatomite and powdered whiting.
9. a kind of preparation method of Chinese herbal medicine interior wall coating according to claim 1 to 8 any one of them except formaldehyde comprising
Following steps：
Step 1: it is spare that decladding almond is worn into powdery；
Step 2: sequentially adding almond fine powder, plant extraction liquid, deionized water, pH adjusting agent in a kettle, dispersant disappears
Infusion and wetting agent stir 2-5min to uniform with the rotating speed of 500-800rpm；
Step 3: filler is added in reaction kettle, 20-30min is stirred to uniform with the rotating speed of 800-1200rpm；
Step 4: hydration resin lotion and levelling agent are added into reaction kettle, 5-10min is stirred with 800-1200rpm rotating speeds, is added
Enter thickener to carry out being thickened to stormer viscosity meter 80-100KU (25 DEG C).
10. according to described in claim 9 except the preparation method of the Chinese herbal medicine interior wall coating of formaldehyde, in the step 3 and described
Further include N- phenyl-salicyl imines and N- hydroxyls phthalyl Asia into the hydration resin lotion between step 4
Amine, 600-800rpm rotating speeds stir 20-30min.
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| CN201810233092.6A CN108659640A (en) | 2018-03-21 | 2018-03-21 | Except the Chinese herbal medicine interior wall coating and preparation method thereof of formaldehyde |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571564A (en) * | 2020-12-07 | 2021-03-30 | 徐州绿之蓝环保科技有限公司 | Formaldehyde scavenging agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730583A (en) * | 2005-08-17 | 2006-02-08 | 马金山 | Lavender flavor type environment protective latex paint and its preparation method |
| CN103709842A (en) * | 2012-09-29 | 2014-04-09 | 上海绿色建材研究中心有限公司 | Herbal essence health paint and preparation method thereof |
| CN104177950A (en) * | 2014-08-20 | 2014-12-03 | 中山艺展装饰工程有限公司 | Negative ion antibacterial latex paint containing folium artemisiae argyi extract |
| CN105295581A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Indoor multifunctional waterborne coating and preparation method thereof |
-
2018
- 2018-03-21 CN CN201810233092.6A patent/CN108659640A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730583A (en) * | 2005-08-17 | 2006-02-08 | 马金山 | Lavender flavor type environment protective latex paint and its preparation method |
| CN103709842A (en) * | 2012-09-29 | 2014-04-09 | 上海绿色建材研究中心有限公司 | Herbal essence health paint and preparation method thereof |
| CN104177950A (en) * | 2014-08-20 | 2014-12-03 | 中山艺展装饰工程有限公司 | Negative ion antibacterial latex paint containing folium artemisiae argyi extract |
| CN105295581A (en) * | 2015-12-03 | 2016-02-03 | 海城市家庭空间装饰材料厂 | Indoor multifunctional waterborne coating and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张明: "C-N链为桥基的邻羟基二苯基桥连化合物合成及抑菌活性研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 李静等: "N-羟基邻苯二甲酰亚胺的研究进展", 《广州化工》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571564A (en) * | 2020-12-07 | 2021-03-30 | 徐州绿之蓝环保科技有限公司 | Formaldehyde scavenging agent and preparation method thereof |
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