CN109206958A - A kind of gloss oil and preparation method thereof for discharging anion - Google Patents
A kind of gloss oil and preparation method thereof for discharging anion Download PDFInfo
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- CN109206958A CN109206958A CN201810978698.2A CN201810978698A CN109206958A CN 109206958 A CN109206958 A CN 109206958A CN 201810978698 A CN201810978698 A CN 201810978698A CN 109206958 A CN109206958 A CN 109206958A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
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Abstract
The invention discloses a kind of gloss oil and preparation method thereof for discharging anion, a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, and 35-45 parts of negative ion powder, 95-105 parts of LED light oil；The preparation method includes the following steps: S1: preparing negative ion powder and LED light oil；S2: it will be kept the temperature after the LED light oil heating water bath produced in step S1；S3: it will be stirred in the LED light oil in the negative ion powder produced in S1 addition S2, negative ion powder and LED light oil is set to carry out being sufficiently mixed the gloss oil that can be prepared by having negative ion powder, the gloss oil is coated in body surface and can be radiated to air so that air, which is ionized, releases negative oxygen ion, indoor formaldehyde is purged, so that indoor air is purified, the content of formaldehyde in air is reduced, simultaneously, negative oxygen ion can also be provided for interior, the environment of health is built for people.
Description
Technical field
The present invention relates to a kind of gloss oil, and in particular to a kind of gloss oil and preparation method thereof for discharging anion.
Background technique
Gloss oil is a kind of synthetic resin, now typically refers to surface clear varnish, has base-material and auxiliary agent etc. to be made into, and is not added any
Pigment, it is glossy shinny after film forming, it is commonly called as being varnish；Earliest gloss oil refers to tung oil, and there are no synthetic resin that kind, only native
Paint the thing of raw lacquer etc.It is much local in rural area, directly tung oil brushing in the wooden barrel newly done, on tub etc thing, rise
To waterproof, protection, decoration function.Tung oil purposes at that time is quite wide, and lacquer worker is used in furniture, building, the fine arts after tung oil is processed
Etc. in many industries.
Wherein, LED light oil is that LED curing light source is used to carry out cured gloss oil.
In life, gloss oil has glossiness good, colour-fast, non-discolouring, and dry quick feature is usually used in package,
Decorative painting, furniture surface, wallpaper surface, the spray treatment of surface of wall, although gloss oil can effectively fill article
Decorations, but having a single function for gloss oil, are not able to satisfy the demand of people；Meanwhile with the development of society, people to itself health
Increasingly value, maximum hazardous substance will belong to formaldehyde indoors, and when formaldehyde reaches a certain concentration indoors, people just has discomfort
Sense；It can cause to be envious greater than the concentration of formaldehyde of 0.08m3, eye is itched, throat discomfort or pain, hoarseness, sneeze, uncomfortable in chest, gas
Asthma, dermatitis etc..
Newly-decorated room content of formaldehyde is higher, is the main inducing of numerous diseases；The irritant smell of formaldehyde, low concentration
It can smell, the olfactory threshold of people's PARA FORMALDEHYDE PRILLS(91,95) is usually 0.06-0.07mg/m3.But there is biggish individual difference, someone is reachable
2.66mg/m³.For a long time, low concentration Formaldehyde Exposed can cause headache, dizzy, out of strength, sensory disturbance, immunity to reduce, and can go out
Existing drowsiness, failure of memory or neurasthenia, mental depression；Slow poisoning be also to the harm of respiratory system it is huge, for a long time
Formaldehyde Exposed can cause respiratory dysfunction and hepatogenotoxicity lesion, show as hepatocellular injury, liver radiation energy exception etc..
Summary of the invention
The purpose of the present invention is to provide a kind of for discharging the gloss oil of anion, which is used for the table coated in object
Face forms one layer of light oil reservoir in body surface, which, which can firmly be adsorbed on body surface and carry out radiation to air, makes
Air is ionized and releases negative oxygen ion, indoor formaldehyde can be purged, indoor air is had
The purification of effect reduces the content of formaldehyde in air, additionally it is possible to which providing negative oxygen ion for interior is that people's construction one is green and healthy
Environment；It is another object of the present invention in order to provide the gloss oil preparation method for discharging anion.
In order to solve the above technical problems, the technical scheme adopted by the invention is that:
It is a kind of for discharging the gloss oil of anion, it is characterised in that: the gloss oil mainly by negative ion powder and LED light oil mixing after
Composition, 35-45 parts of negative ion powder, 95-105 parts of LED light oil.
40 parts of the negative ion powder, described 100 parts of LED light oil.
The negative ion powder is mainly made of following components in parts by weight: 10-25 parts of tourmaline, astroies 5-10
Part, 6-15 parts of opal, 20-25 parts of Strange ice stone, 30-35 parts of calcium carbonate, six 25-30 parts of ring stones, 15-20 parts of far-infrared powder, two
10-12 parts of aluminium oxide, 4-4.5 parts of laruyl alcohol, 10-15 parts of Yiwang stone, 20-23 parts of di-iron trioxide, 5-10 parts of terbium peroxide,
1-3 parts of basic zirconium phosphate, 5-10 parts of potassium feldspar, 0.5-5 parts of quaternary ammonium salt, 0.2-1.2 parts of zinc powder, 0.2-1.4 parts of copper powder, bamboo charcoal powder 10-
15 parts；The LED light oil is made of in parts by weight following components: 40-45 parts of heat resistance epoxy novolac based polyurethanes, acrylic acid
20-25 parts of resin, 15-25 parts of isobornyl methacrylate, 35-40 parts of hexylene glycol acrylate, trimethylolpropane tris third
15-30 parts of olefin(e) acid ester, 10-30 parts of tripropylene glycol diacrylate, 3-11 parts of photoinitiator, 0.8-4 parts of surfactant, water
0.6-4.2 parts of levelling agent of property.
The negative ion powder is mainly made of following components in parts by weight: 15-20 parts of tourmaline, 6-9 parts of astroies,
9-12 parts of opal, 21-24 parts of Strange ice stone, 32-34 parts of calcium carbonate, six 27-29 parts of ring stones, 17-19 parts of far-infrared powder, titanium dioxide
11.5-12 parts of aluminium, 4.1-4.4 parts of laruyl alcohol, 12.5-14.5 parts of Yiwang stone, 21.5-22.5 parts of di-iron trioxide, seven oxidations four
6.5-9 parts of terbium, 1.5-2.8 parts of basic zirconium phosphate, 6.5-9.5 parts of potassium feldspar, 0.6-4 parts of quaternary ammonium salt, 0.35-1.15 parts of zinc powder, copper powder
0.35-1.35 parts, 11.5-14.5 parts of bamboo charcoal powder；The LED light oil is made of in parts by weight following components: heat resistance phenolic aldehyde
42-44 parts of epoxy based polyurethanes, 21-24 parts of acrylic resin, 16-24 parts of isobornyl methacrylate, hexylene glycol acrylic acid
37-39 parts of ester, 16-28 parts of trimethylolpropane trimethacrylate, 15-25 parts of tripropylene glycol diacrylate, photoinitiator 4-
10 parts, 1-3 parts of surfactant, 0.8-3.5 parts of aqueous levelling agent.
It is a kind of for discharging the gloss oil preparation method of anion, characterized by the following steps:
S1: negative ion powder and LED light oil are prepared；
S2: heat preservation 10-30min is carried out after the LED light grease produced in step S1 bath is heated to 35-45 °；
S3: the negative ion powder produced in S1 is added in the LED light oil in S2, stirs 45-70min, temperature is 35- when stirring
45 °, negative ion powder and LED light oil is made to carry out being sufficiently mixed the gloss oil that can be prepared by having negative ion powder；Wherein stirred described in S3
Mix the time are as follows: 60min.
The detailed process of negative ion powder is prepared in S1 are as follows:
S11: negative ion powder each component material is crushed respectively and is ground 3-6h, the powder body material of each component is obtained after sieving；S11
It is middle to be sieved using 300-600 mesh screen.
S12: the powder body material of each component is weighed according to proportion, and grinds 0.5- after the powder body material of each component is mixed
1h obtains negative ion powder after being sieved again；It is sieved in S12 using 800-1000 mesh screen.
Whipping process described in S3 specifically: mix preparation is obtained after negative ion powder is added in LED light oil, it will
The mix preparation stirs 10-20min clockwise, then speed of agitator 100-200r/min stirs mix preparation counterclockwise
10-20min, speed of agitator 600-900r/min；Counterclockwise after stirring, the upper partially liq of mix preparation is carried out suitable
Hour hands stirring, lower partially liq are stirred counterclockwise, mixing time 5-20min, speed of agitator 200-300r/min.
Compared with prior art, the invention has the following advantages:
1. the present invention by being added negative ion powder in LED light oil in parts by weight, wherein 35-45 parts of negative ion powder, LED light
It is 95-105 parts oily, i.e., negative ion powder is added in LED light oil, negative ion powder can carry out the radiation ionization that makes to have leisure to air and release
Negative oxygen ion is released, after negative ion powder is added, the viscosity of LED light oil will not be reduced, it, should when gloss oil is coated in the surface of object
Gloss oil forms one layer of light oil reservoir for having negative ion powder on the surface of object, which can be firmly attached to the table of object
Face will not fall off；Body surface can not only be isolated with air for the light oil reservoir, additionally it is possible to be protected to body surface
Shield, meanwhile, the negative ion powder in gloss oil is dissolved into external radiation, so that the air ionization in room forms negative oxygen ion, effectively
The negative oxygen ion concentration increased in room；And the formaldehyde in room is subjected to purification removing, so that indoor formaldehyde is dense
Degree reduces；Simultaneously as the light oil reservoir with negative ion powder is covered on the surface of object, can be avoided interior of articles has
Noxious material comes out, meanwhile, the radiation of negative ion powder is passed through in the inside of object, can effectively eliminate the toxic of interior of articles
Substance；35-45 parts of negative ion powder, 95-105 parts of LED light oil, by the gloss oil of the rear formation of this proportion mixing, negative ion powder is not
The viscosity and adhesion of gloss oil can be destroyed, gloss oil effectively can avoid negative ion powder from falling out after being coated in body surface,
And it is convenient for carrying out following process in the light oil reservoir formed after gloss oil solidification, such as carries out the subsequent work of flocking in the light oil reservoir
Sequence；If the amount that negative ion powder adds is excessive, it will the viscosity for destroying gloss oil, the gloss oil that will be formed after when the surface of gloss oil coating of objects
Layer is easy to fall off, and light oil reservoir service life is not grown, and after a period of use, the negative ion powder on surface can be shedded into largely to room
It is interior, certain injury will be caused after being sucked by human body to human body；Meanwhile if the amount that adds of negative ion powder is very few, although will not shadow
Ring gloss oil viscosity, still, it will influence generate negative oxygen ion quantity so that the quantity of negative oxygen ion be much not achieved it is pre-
The dosage of the quantity of phase, only strict control negative ion powder and LED light oil could make in the case where not destroying gloss oil viscosity
The negative oxygen ion quantity that must be generated is most.
2. negative ion powder of the present invention includes following components: tourmaline, astroies, opal, Strange ice stone, carbonic acid
Calcium, six ring stones, far-infrared powder, aluminium dioxide, laruyl alcohol, Yiwang stone, di-iron trioxide, terbium peroxide, basic zirconium phosphate, potassium are long
Stone, quaternary ammonium salt, zinc powder, copper powder, bamboo charcoal powder；Enable to air ionization a large amount of out by the negative ion powder that said components are formed
Negative oxygen ion, negative oxygen ion are able to suppress the volatilization of the formaldehyde with positive charge, achieve the purpose that remove formaldehyde in air；When people is logical
When crossing breathing the air containing anion being sent into alveolar, nervous system can be stimulated to generate good physiological effect, through blood circulation
It sends the charge of institute's band in the histocyte of whole body, the conversion capability of oxygen can be improved, adjust blood pH, activation is thin
Born of the same parents increase cell permeability, increase oxygen absorbed, improve lung function.In addition, negative aeroion can also purify blood, reduce blood pressure
And cholesterol, improve cerebral cortex and myocardial function, increase myocardial nutrition, improves cell metabolization rate, enhance human immunity；
The LED light oil includes following components: heat resistance epoxy novolac based polyurethanes, acrylic resin, isobornyl methacrylate,
Hexylene glycol acrylate, trimethylolpropane trimethacrylate, tripropylene glycol diacrylate, photoinitiator, surfactant
And aqueous levelling agent；Being formed by LED light oil by said components has preferable viscosity and adhesion, can be with negative ion powder
It is adequately mixed, negative ion powder and LED light oil form close one, and LED light oil can carry out negative ion powder firmly
Absorption, negative ion powder will not be scattering into interior.
3. gloss oil made of the method described in through the invention, negative ion powder can carry out adequately molten with LED light oil
It closes, negative ion powder is adequately and uniformly dispersed in LED light oil, finally formed gloss oil has good adhesion
And viscosity, it can firmly be clinged on the surface of object after gloss oil to be coated in the surface of object, the light formed after gloss oil is dry
Oil reservoir is not easily to fall off；The negative ion powder being added in LED light oil, the light formed after will not being mixed to negative ion powder with LED light oil
The viscosity of oil has an impact, while can also make the negative oxygen ion quantity generated in air most in the case where guaranteeing viscosity
It is more.
Specific embodiment
The present invention will be further described with reference to the examples below, and described embodiment is only present invention a part
Embodiment is not whole embodiment.Based on the embodiments of the present invention, those skilled in the art are not making
Other embodiments used obtained, belong to protection scope of the present invention under the premise of creative work.
Embodiment 1
It is a kind of for discharging the gloss oil of anion, it is characterised in that: the gloss oil mainly by negative ion powder and LED light oil mixing after
Composition, 35-45 parts of negative ion powder, 95-105 parts of LED light oil.
Wherein, in the present embodiment, 35 parts of the negative ion powder, described 95 parts of LED light oil；The negative ion powder mainly by
Following components form in parts by weight: 10 parts of tourmaline, 5 parts of astroies, and 6 parts of opal, 20 parts of Strange ice stone, calcium carbonate 30
Part, six 25 parts of ring stones, 15 parts of far-infrared powder, 10 parts of aluminium dioxide, 4 parts of laruyl alcohol, 10 parts of Yiwang stone, 20 parts of di-iron trioxide,
5 parts of terbium peroxide, 1 part of basic zirconium phosphate, 5 parts of potassium feldspar, 0.5 part of quaternary ammonium salt, 0.2 part of zinc powder, 0.2 part of copper powder, 10 parts of bamboo charcoal powder；
The LED light oil is made of in parts by weight following components: 40 parts of heat resistance epoxy novolac based polyurethanes, acrylic resin 20
Part, 15 parts of isobornyl methacrylate, 35 parts of hexylene glycol acrylate, 15 parts of trimethylolpropane trimethacrylate, 3 third
10 parts of omega-diol diacrylate, 2.5 parts of photoinitiator, 0.8 part of surfactant, 0.6 part of aqueous levelling agent；
Wherein the photoinitiator is the mixture (ratio of the two are as follows: 2:5) of alpha-alcohol ketone and monoacyl phosphine, surfactant
Selected from 104 surfactant of U.S. gas chemical industry Surfynol, aqueous levelling agent is selected from Dongguan three and paints chemical industry Lencolo
3002。
Embodiment 2
It is a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, anion
Powder is specially 40 parts, and LED light oil is specially 100 parts；Wherein, the negative ion powder is mainly by following components array by weight
At: 15 parts of tourmaline, 7 parts of astroies, 12 parts of opal, 22 parts of Strange ice stone, 32 parts of calcium carbonate, six 27 parts of ring stones, far infrared
17 parts of powder, 10.5 parts of aluminium dioxide, 4.3 parts of laruyl alcohol, 12 parts of Yiwang stone, 22.5 parts of di-iron trioxide, terbium peroxide 7.5
Part, 1.5 parts of basic zirconium phosphate, 7 parts of potassium feldspar, 3 parts of quaternary ammonium salt, 0.8 part of zinc powder, 0.8 part of copper powder, 12 parts of bamboo charcoal powder；The LED light oil
It is made of in parts by weight following components: 42.5 parts of heat resistance epoxy novolac based polyurethanes, 22.5 parts of acrylic resin, methyl-prop
20.5 parts of olefin(e) acid isobornyl thiocyanoacetate, 37.5 parts of hexylene glycol acrylate, 16.5 parts of trimethylolpropane trimethacrylate, 3 the third two
20 parts of alcohol diacrylate, 8 parts of photoinitiator, 3.5 parts of surfactant, 2.5 parts of aqueous levelling agent；
Wherein, photoinitiator, surfactant and aqueous levelling agent with it is used in embodiment 1 identical.
Embodiment 3
It is a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, anion
Powder is specially 45 parts, and LED light oil is specially 105 parts, wherein the negative ion powder is mainly by following components array by weight
At: 25 parts of tourmaline, 10 parts of astroies, 15 parts of opal, 25 parts of Strange ice stone, 35 parts of calcium carbonate, six 30 parts of ring stones, far infrared
20 parts of powder, 12 parts of aluminium dioxide, 4.5 parts of laruyl alcohol, 15 parts of Yiwang stone, 23 parts of di-iron trioxide, 10 parts of terbium peroxide, phosphoric acid
3 parts of zirconium, 10 parts of potassium feldspar, 5 parts of quaternary ammonium salt, 1.2 parts of zinc powder, 1.4 parts of copper powder, 15 parts of bamboo charcoal powder；The LED light oil is by following groups
Divide and forms in parts by weight: 45 parts of heat resistance epoxy novolac based polyurethanes, 25 parts of acrylic resin, isobornyl methacrylate
25 parts, 40 parts of hexylene glycol acrylate, 30 parts of trimethylolpropane trimethacrylate, 30 parts of tripropylene glycol diacrylate, light
11 parts of initiator, 4 parts of surfactant, 4.2 parts of aqueous levelling agent；
Wherein, photoinitiator, surfactant and aqueous levelling agent with it is used in embodiment 1 identical.
Embodiment 4
It is a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, anion
Powder is specially 35 parts, and LED light oil is specially 95 parts, wherein the negative ion powder is mainly made of following components in parts by weight:
15 parts of tourmaline, 6 parts of astroies, 9 parts of opal, 21 parts of Strange ice stone, 32 parts of calcium carbonate, six ring stones 27,17 parts of far-infrared powder,
11.5 parts of aluminium dioxide, 4.1 parts of laruyl alcohol, 12.5 parts of Yiwang stone, 21.5 parts of di-iron trioxide, 6.5 parts of terbium peroxide, phosphoric acid
1.5 parts of zirconium, 6.5 parts of potassium feldspar, 0.6 part of quaternary ammonium salt, 0.35 part of zinc powder, 0.35 part of copper powder, 11.5 parts of bamboo charcoal powder；The LED light
Oil is made of in parts by weight following components: 42 parts of heat resistance epoxy novolac based polyurethanes, and 21 parts of acrylic resin, metering system
16 parts of sour isobornyl thiocyanoacetate, 37 parts of hexylene glycol acrylate, 16 parts of trimethylolpropane trimethacrylate, two propylene of tripropylene glycol
15 parts of acid esters, 4 parts of photoinitiator, 1 part of surfactant, 0.8 part of aqueous levelling agent；Wherein, photoinitiator, surfactant and
Aqueous levelling agent with it is used in embodiment 1 identical.
Embodiment 5
It is a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, anion
Powder is specially 40 parts, and LED light oil is specially 100 parts, wherein the negative ion powder is mainly by following components array by weight
At: 18.5 parts of tourmaline, 7.5 parts of astroies, 10.5 parts of opal, 22.5 parts of Strange ice stone, 33 parts of calcium carbonate, six ring stones 28
Part, 18 parts of far-infrared powder, 11.8 parts of aluminium dioxide, 4.3 parts of laruyl alcohol, 13 parts of Yiwang stone, 22 parts of di-iron trioxide, seven oxidations four
7.5 parts of terbium, 2.5 parts of basic zirconium phosphate, 7.5 parts of potassium feldspar, 3.5 parts of quaternary ammonium salt, 0.85 part of zinc powder, 0.95 part of copper powder, 12 parts of bamboo charcoal powder；
The LED light oil is made of in parts by weight following components: 43.5 parts of heat resistance epoxy novolac based polyurethanes, acrylic resin
22.5 parts, 20.5 parts of isobornyl methacrylate, 37.5 parts of hexylene glycol acrylate, trimethylolpropane trimethacrylate
26.5 parts, 20.5 parts of tripropylene glycol diacrylate, 8.5 parts of photoinitiator, 2.8 parts of surfactant, aqueous levelling agent 2.8
Part.
Embodiment 6
It is a kind of for discharging the gloss oil of anion, the gloss oil after negative ion powder and the mixing of LED light oil mainly by forming, anion
Powder is specially 45 parts, and LED light oil is specially 105 parts, wherein the negative ion powder is mainly by following components array by weight
At: 20 parts of tourmaline, 9 parts of astroies, 12 parts of opal, 24 parts of Strange ice stone, 34 parts of calcium carbonate, six 29 parts of ring stones, far infrared
19 parts of powder, 12 parts of aluminium dioxide, 4.4 parts of laruyl alcohol, 14.5 parts of Yiwang stone, 22.5 parts of di-iron trioxide, 9 parts of terbium peroxide,
2.8 parts of basic zirconium phosphate, 9.5 parts of potassium feldspar, 4 parts of quaternary ammonium salt, 1.15 parts of zinc powder, 1.35 parts of copper powder, 14.5 parts of bamboo charcoal powder；The LED
Gloss oil is made of in parts by weight following components: 44 parts of heat resistance epoxy novolac based polyurethanes, and 24 parts of acrylic resin, methyl-prop
24 parts of olefin(e) acid isobornyl thiocyanoacetate, 39 parts of hexylene glycol acrylate, 28 parts of trimethylolpropane trimethacrylate, two propylene of tripropylene glycol
25 parts of acid esters, 10 parts of photoinitiator, 3 parts of surfactant, 3.5 parts of aqueous levelling agent.
Embodiment 7
It is a kind of for discharging the gloss oil preparation method of anion, characterized by the following steps:
S1: negative ion powder and LED light oil are prepared；
In the present embodiment, the weight fraction ratio of the negative ion powder and LED light oil specifically: 40:100 is weighed obtained negative
40 parts of ion powder, 100 parts of LED light oil；
Wherein；
It weighs: 10 parts of tourmaline, 5 parts of astroies, 6 parts of opal, 20 parts of Strange ice stone, 30 parts of calcium carbonate, six 25 parts of ring stones, far
15 parts of infrared powder, 10 parts of aluminium dioxide, 4 parts of laruyl alcohol, 10 parts of Yiwang stone, 20 parts of di-iron trioxide, 5 parts of terbium peroxide, phosphorus
1 part of sour zirconium, 5 parts of potassium feldspar, 0.5 part of quaternary ammonium salt, 0.2 part of zinc powder, 0.2 part of copper powder, 10 parts of bamboo charcoal powder for producing negative ion powder；
It weighs: 40 parts of heat resistance epoxy novolac based polyurethanes, 20 parts of acrylic resin, 15 parts of isobornyl methacrylate, oneself
35 parts of butanediol acrylate, 15 parts of trimethylolpropane trimethacrylate, 10 parts of tripropylene glycol diacrylate, photoinitiator 2
Part, 0.8 part of surfactant, 0.6 part of aqueous levelling agent for producing LED light oil；
The negative ion powder in remaining any embodiment can also be used, LED light oil formula is produced.
S2: heat preservation 10min is carried out after the LED light grease produced in step S1 bath is heated to 35 °；
The LED light oil produced in S1 is heated so that the molecule in LED light oil has biggish interior energy, quickening molecular motion speed
Degree, even if molecule becomes active；Carrying out isothermal holding is to be convenient for subsequent addition to guarantee that molecule is constantly in active state
Negative ion powder is fused.
S3: the negative ion powder produced in S1 being added in the LED light oil in S2,45min is stirred, and temperature is 35 ° when stirring,
Negative ion powder and LED light oil is set to carry out being sufficiently mixed the gloss oil that can be prepared by having negative ion powder.
Negative ion powder is added in LED light oil and is stirred, it is sufficiently molten to guarantee that negative ion powder can be carried out with LED light oil
Close, stirring when guarantee temperature be 35 °, further ensure between the two it is abundant fuse.
Light oil reservoir is formed in use, only needing gloss oil obtained in S3 being coated in body surface；Specific coating procedure are as follows:
By gloss oil brush on the surface of object, one layer of light oil reservoir is formed after gloss oil solidification, scratch brushing oil is repeated in the light oil reservoir, is formed
New light oil reservoir；And specific gloss oil layer number should be determined according to the actual needs.
It advanced optimizes, wherein the detailed process of negative ion powder is prepared in S1 are as follows:
S11: negative ion powder each component material is crushed respectively and is ground 3h, the powder body material of each component is obtained after sieving；Herein
The sieving of 300 mesh screens is selected in sieving.
S12: weighing the powder body material of each component according to proportion, and grind 0.5h after the powder body material of each component is mixed,
Negative ion powder is obtained after being sieved again；The sieving of 800 mesh screens is selected in sieving herein.
Whipping process described in S3 specifically: mix preparation is obtained after negative ion powder is added in LED light oil, it will
The mix preparation stirs 10min clockwise, then mix preparation is stirred 10min counterclockwise, stirred by speed of agitator 100r/min
Mixing revolving speed is 600r/min；Counterclockwise after stirring, the upper partially liq of mix preparation is stirred clockwise, lower part
Liquid is stirred counterclockwise, mixing time 5min, speed of agitator 200r/min；Negative ion powder is added to LED light
After oil, since the negative ion powder being just added is powdery, if the revolving speed of stirring is too fast, when just starting stirring, it may result in
Negative ion powder, which flies out, causes the pollution of air, meanwhile, outbound negative ion powder also results in the waste of raw material, it will occurs
The inaccurate situation of proportion；Rotate forward when, when enabling to just be put into negative ion powder using 100-200 r/min, negative ion powder with
LED light oil is slowly fused；It after mixing slowly, is quickly being stirred, is enabling to negative ion powder and LED light oil into one
Step is quickly fused, and it is not in the problem of negative ion powder flies out that quickly stirring can accelerate fused speed at this time at this time；Quickly
After stirring, the upper partially liq of mix preparation is stirred clockwise, lower partially liq is stirred counterclockwise, and will
Revolving speed is turned down, and revolving speed is 200r/min, so that the mixing system on blender top stirs clockwise, and blender lower part is mixed
Close system stirring counterclockwise so that the mix preparation in blender is further sufficiently stirred, clockwise with stirring simultaneously counterclockwise when,
So that colliding between molecule, negative ion powder can preferably can be merged with LED light oil.
It should be noted that the upper partially liq of mix preparation is stirred clockwise, lower partially liq carries out the inverse time
Two agitating devices are respectively set in needle stirring in stirring container, one is located at bottom, and one is located at top, and mixing is made
After agent is placed in stirring container, two agitating devices be respectively positioned on the liquid level of mix preparation hereinafter, one of agitating device just
Turn, the reversion of another agitating device, i.e., the mixing directions of two agitating devices can make on the contrary, agitating mode in this way
Negative ion powder is fused more abundant with LED light oil.
Embodiment 8
The present embodiment is substantially the same manner as Example 7, the difference is that: in the present embodiment,
In S2: carrying out heat preservation 15min after the LED light grease produced in step S1 bath is heated to 40 °；
In S3: the negative ion powder produced in S1 being added in the LED light oil in S2, stirs 50 min or 60min, temperature when stirring
Degree is 40 °, and negative ion powder and LED light oil is made to carry out being sufficiently mixed the gloss oil that can be prepared by having negative ion powder；By negative ion powder
It is added in LED light oil and is stirred, it is sufficiently fused to guarantee that negative ion powder can be carried out with LED light oil, guarantees temperature in stirring
Degree be 40 °, further ensure between the two it is abundant fuse.
In S11: crushing and grind 4h respectively for negative ion powder each component material, the powder material of each component is obtained after sieving
Material；The sieving of 500 mesh screens is selected in sieving herein.
In S12: weighing the powder body material of each component according to proportion, and ground after the powder body material of each component is mixed
0.8h obtains negative ion powder after being sieved again；The sieving of 900 mesh screens is selected in sieving herein.
Whipping process described in S3 specifically: mix preparation is obtained after negative ion powder is added in LED light oil, it will
The mix preparation stirs 15min clockwise, then mix preparation is stirred 15min counterclockwise, stirred by speed of agitator 150r/min
Mixing revolving speed is 700r/min；Counterclockwise after stirring, the upper partially liq of mix preparation is stirred clockwise, lower part
Liquid is stirred counterclockwise, mixing time 10min, speed of agitator 250r/min.
Embodiment 9
The present embodiment is substantially the same manner as Example 7, the difference is that:
S2: heat preservation 30min is carried out after the LED light grease produced in step S1 bath is heated to 45 °；
S3: the negative ion powder produced in S1 is added in the LED light oil in S2,70min is stirred, temperature is 45 ° when stirring, makes to bear
Ion powder and LED light oil, which be sufficiently mixed, can be prepared by the gloss oil with negative ion powder；
Negative ion powder is added in LED light oil and is stirred, it is sufficiently fused to guarantee that negative ion powder can be carried out with LED light oil,
Stirring when guarantee temperature be 45 °, further ensure between the two it is abundant fuse.
S11: negative ion powder each component material is crushed respectively and is ground 6h, the powder body material of each component is obtained after sieving；
The sieving of 600 mesh screens is selected in sieving herein.
S12: weighing the powder body material of each component according to proportion, and grind 1h after the powder body material of each component is mixed, then
Negative ion powder is obtained after secondary sieving；The sieving of 1000 mesh screens is selected in sieving herein.
Whipping process described in S3 specifically: mix preparation is obtained after negative ion powder is added in LED light oil, it will
The mix preparation stirs 20min clockwise, then mix preparation is stirred 20min counterclockwise, stirred by speed of agitator 200r/min
Mixing revolving speed is 900r/min；Counterclockwise after stirring, the upper partially liq of mix preparation is stirred clockwise, lower part
Liquid is stirred counterclockwise, mixing time 20min, speed of agitator 300r/min.
It should be noted that gloss oil of the present invention is used to coat on a surface of an, body surface described here
Including packing box, furniture surface, backplate surface, decoration painting, wallpaper surface, surface of wall, door body surface, vase surface, glass
Surface etc., after being coated in body surface, the negative oxygen ion formed in air not only has the function of that pure air, degerming de-taste,
There are also promote health, promote longevity.
The gloss oil produced in embodiment 1-6 is made a flocking decorating respectively to draw, flocking decorating described herein draws packet
Ground paper layer is included, gloss oil is coated on ground paper layer, forms one layer of light oil reservoir after the solidification of first layer gloss oil, in the light oil reservoir again
Secondary coating gloss oil, forms new light oil reservoir, that is, has two layers of light oil reservoir；Then it is planted in light oil reservoir by photoelectricity laminating machine
Suede, so that flocking vertically on base stock, forms space pattern；Using anion measuring instrument respectively to using institute in embodiment 1-6
The flocking decorating picture for the gloss oil production produced is detected.
When not placing flocking decorating in the room and drawing, the indoor negative ion concentration that detects at this time are as follows: 375/cm3；
Then the flocking decorating picture of the gloss oil produced in embodiment 1-6 production is individually placed in room, then to negative in room
Ion concentration is detected, and wherein anion measuring instrument is drawn apart from flocking decorating and detected at 30cm, and testing result is as follows:
(1) it is coated on base stock using the gloss oil produced in embodiment 1, and forms light oil reservoir on base stock, in the light oil reservoir
It is detected after carrying out flocking, the negative ion concentration detected are as follows: 1769/cm3.
(2) it is coated on base stock using the gloss oil produced in embodiment 2, and forms light oil reservoir on base stock, in the gloss oil
It is detected after carrying out flocking on layer, the negative ion concentration detected are as follows: 1812/cm3.
(3) it is coated on base stock using the gloss oil produced in embodiment 3, and forms light oil reservoir on base stock, in the gloss oil
It is detected after carrying out flocking on layer, the negative ion concentration detected are as follows: 1925/cm3.
(4) it is coated on base stock using the gloss oil produced in embodiment 4, and forms light oil reservoir on base stock, in the gloss oil
It is detected after carrying out flocking on layer, the negative ion concentration detected are as follows: 1795/cm3.
(5) it is coated on base stock using the gloss oil produced in embodiment 5, and forms light oil reservoir on base stock, in the gloss oil
It is detected after carrying out flocking on layer, the negative ion concentration detected are as follows: 1806/cm3.
(6) it is coated on base stock using the gloss oil produced in embodiment 6, and forms light oil reservoir on base stock, in the gloss oil
It is detected after carrying out flocking on layer, the negative ion concentration detected are as follows: 1835/cm3.
The negative ion concentration drawn at 30cm apart from flocking decorating is significantly larger than indoor negative ion concentration, and the light oil reservoir
It can firmly be sticked on base stock.
Claims (10)
1. a kind of for discharging the gloss oil of anion, it is characterised in that: the gloss oil is mainly mixed by negative ion powder and LED light oil
After form, 35-45 parts of negative ion powder, 95-105 parts of LED light oil.
2. according to claim 1 a kind of for discharging the gloss oil of anion, it is characterised in that: the negative ion powder 40
Part, described 100 parts of LED light oil.
3. according to claim 1 a kind of for discharging the gloss oil of anion, it is characterised in that: the negative ion powder is main
It is made of in parts by weight following components: 10-25 parts of tourmaline, 5-10 parts of astroies, 6-15 parts of opal, Strange ice stone 20-
25 parts, 30-35 parts of calcium carbonate, six 25-30 parts of ring stones, 15-20 parts of far-infrared powder, 10-12 parts of aluminium dioxide, laruyl alcohol 4-4.5
Part, 10-15 parts of Yiwang stone, 20-23 parts of di-iron trioxide, 5-10 parts of terbium peroxide, 1-3 parts of basic zirconium phosphate, 5-10 parts of potassium feldspar,
0.5-5 parts of quaternary ammonium salt, 0.2-1.2 parts of zinc powder, 0.2-1.4 parts of copper powder, 10-15 parts of bamboo charcoal powder；The LED light oil is by following components
It forms in parts by weight: 40-45 parts of heat resistance epoxy novolac based polyurethanes, 20-25 parts of acrylic resin, the different ice of methacrylic acid
15-25 parts of piece ester, 35-40 parts of hexylene glycol acrylate, 15-30 parts of trimethylolpropane trimethacrylate, tripropylene glycol dipropyl
10-30 parts of olefin(e) acid ester, 3-11 parts of photoinitiator, 0.8-4 parts of surfactant, 0.6-4.2 parts of aqueous levelling agent.
4. according to claim 3 a kind of for discharging the gloss oil of anion, it is characterised in that: the negative ion powder is main
It is made of in parts by weight following components: 15-20 parts of tourmaline, 6-9 parts of astroies, 9-12 parts of opal, Strange ice stone 21-24
Part, 32-34 parts of calcium carbonate, six 27-29 parts of ring stones, 17-19 parts of far-infrared powder, 11.5-12 parts of aluminium dioxide, laruyl alcohol 4.1-
4.4 parts, 12.5-14.5 parts of Yiwang stone, 21.5-22.5 parts of di-iron trioxide, 6.5-9 parts of terbium peroxide, basic zirconium phosphate 1.5-2.8
Part, 6.5-9.5 parts of potassium feldspar, 0.6-4 parts of quaternary ammonium salt, 0.35-1.15 parts of zinc powder, 0.35-1.35 parts of copper powder, bamboo charcoal powder 11.5-
14.5 parts；The LED light oil is made of in parts by weight following components: 42-44 parts of heat resistance epoxy novolac based polyurethanes, propylene
21-24 parts of acid resin, 16-24 parts of isobornyl methacrylate, 37-39 parts of hexylene glycol acrylate, trimethylolpropane tris
It is 16-28 parts of acrylate, 15-25 parts of tripropylene glycol diacrylate, 4-10 parts of photoinitiator, 1-3 parts of surfactant, aqueous
0.8-3.5 parts of levelling agent.
5. a kind of for discharging the gloss oil preparation method of anion, characterized by the following steps:
S1: negative ion powder and LED light oil are prepared；
S2: heat preservation 10-30min is carried out after the LED light grease produced in step S1 bath is heated to 35-45 °；
S3: the negative ion powder produced in S1 is added in the LED light oil in S2, stirs 45-70min, temperature is 35- when stirring
45 °, negative ion powder and LED light oil is made to carry out being sufficiently mixed the gloss oil that can be prepared by having negative ion powder.
6. according to claim 5 a kind of for discharging the gloss oil preparation method of anion, it is characterised in that: described in S3
Mixing time are as follows: 60min.
7. according to claim 5 a kind of for discharging the gloss oil preparation method of anion, it is characterised in that: the institute in S3
The whipping process stated specifically: mix preparation is obtained after negative ion powder is added in LED light oil, the mix preparation is clockwise
10-20min is stirred, then mix preparation is stirred 10-20min, speed of agitator by speed of agitator 100-200r/min counterclockwise
For 600-900r/min；Counterclockwise after stirring, the upper partially liq of mix preparation is stirred clockwise, lower part liquid separation
Body is stirred counterclockwise, mixing time 5-20min, speed of agitator 200-300r/min.
8. according to claim 5 a kind of for discharging the gloss oil preparation method of anion, it is characterised in that: prepared in S1
The detailed process of negative ion powder are as follows:
S11: negative ion powder each component material is crushed respectively and is ground 3-6h, the powder body material of each component is obtained after sieving；
S12: weighing the powder body material of each component according to proportion, and grind 0.5-1h after the powder body material of each component is mixed, then
Negative ion powder is obtained after secondary sieving.
9. according to claim 8 a kind of for discharging the gloss oil preparation method of anion, it is characterised in that: make in S11
It is sieved with 300-600 mesh screen.
10. according to claim 8 a kind of for discharging the gloss oil preparation method of anion, it is characterised in that: make in S12
It is sieved with 800-1000 mesh screen.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810978698.2A CN109206958B (en) | 2018-08-27 | 2018-08-27 | Gloss oil for releasing negative ions |
| CN202011172943.4A CN112266642B (en) | 2018-08-27 | 2018-08-27 | Preparation method of gloss oil for releasing negative ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810978698.2A CN109206958B (en) | 2018-08-27 | 2018-08-27 | Gloss oil for releasing negative ions |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202011172943.4A Division CN112266642B (en) | 2018-08-27 | 2018-08-27 | Preparation method of gloss oil for releasing negative ions |
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| CN109206958B CN109206958B (en) | 2020-11-13 |
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| CN202011172943.4A Active CN112266642B (en) | 2018-08-27 | 2018-08-27 | Preparation method of gloss oil for releasing negative ions |
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| CN202011172943.4A Active CN112266642B (en) | 2018-08-27 | 2018-08-27 | Preparation method of gloss oil for releasing negative ions |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111621187A (en) * | 2019-12-16 | 2020-09-04 | 中国地质大学（武汉） | Semiconductor composite material capable of releasing negative oxygen ions and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN112266642A (en) | 2021-01-26 |
| CN112266642B (en) | 2022-04-22 |
| CN109206958B (en) | 2020-11-13 |
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