CN112266642B - Preparation method of gloss oil for releasing negative ions - Google Patents
Preparation method of gloss oil for releasing negative ions Download PDFInfo
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- CN112266642B CN112266642B CN202011172943.4A CN202011172943A CN112266642B CN 112266642 B CN112266642 B CN 112266642B CN 202011172943 A CN202011172943 A CN 202011172943A CN 112266642 B CN112266642 B CN 112266642B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a preparation method of gloss oil for releasing anions, which mainly comprises the following steps of mixing anion powder and LED gloss oil, wherein 35-45 parts of anion powder and 95-105 parts of LED gloss oil are used as the gloss oil; the preparation method comprises the following steps of S1: preparing anion powder and LED gloss oil; s2: heating the LED gloss oil prepared in the step S1 in a water bath, and then preserving heat; s3: the negative ion powder prepared in the S1 is added into the LED gloss oil in the S2 and stirred, so that the negative ion powder and the LED gloss oil are fully mixed to prepare the gloss oil with the negative ion powder, the gloss oil is coated on the surface of an object and can radiate the air to ionize the air to release negative oxygen ions, indoor formaldehyde is removed, the indoor air is purified, the content of the formaldehyde in the air is reduced, meanwhile, the negative oxygen ions can be provided indoors, and a healthy environment is created for people.
Description
The application is a divisional application, and the application number of the parent application is as follows: CN201810978698.2, publication no: CN 109206958A.
Technical Field
The invention relates to gloss oil, in particular to a preparation method of gloss oil for releasing negative ions.
Background
Gloss oil is a synthetic resin, which is usually a transparent varnish on the surface, is made of base materials, auxiliary agents and the like, is not added with any pigment, and is shiny after film forming, and is commonly called as varnish; the earliest gloss oil was tung oil, which had no synthetic resin at that time, only to the extent of paint, raw lacquer, and the like. In many places in rural areas, tung oil is directly coated on newly made wooden barrels, wooden basins and the like, so that waterproof, protective and decorative effects are achieved. The application of the tung oil is quite wide at that time, and the painter processes the tung oil and uses the processed tung oil in a plurality of industries such as furniture, buildings, art and the like.
The LED gloss oil is the gloss oil solidified by using an LED solidification light source.
In life, the gloss oil has the characteristics of good glossiness, fastness, no color change and quick drying, is commonly used for spraying treatment of packaging products, oil painting decoration, furniture surfaces, wallpaper surfaces and wall surfaces, and although the gloss oil can effectively decorate objects, the gloss oil has a single function and cannot meet the requirements of people; meanwhile, with the development of society, people pay more and more attention to their health, the largest indoor hazardous substance belongs to formaldehyde, and when the formaldehyde reaches a certain concentration indoors, people feel uncomfortable; formaldehyde concentrations higher than 0.08m may cause redness, itching of the eyes, discomfort or pain in the throat, hoarseness, sneezing, chest distress, asthma, dermatitis, etc.
The newly decorated room has higher formaldehyde content and is the main cause of a plurality of diseases; formaldehyde has an irritating odor and can be smelled at a low concentration, and human olfaction threshold for formaldehyde is usually 0.06-0.07mg/m in thin-wall cultivation. However, the individual difference is large, and the yield can reach 2.66mg/m for some people. Long-term and low-concentration formaldehyde contact can cause headache, dizziness, hypodynamia, sensory disturbance and immunity reduction, and can cause sleepiness, hypomnesis or neurasthenia and mental depression; the harm of chronic poisoning to the respiratory system is also huge, and the long-term exposure to formaldehyde can cause respiratory dysfunction and hepatotoxic lesion, which are manifested as hepatocyte injury, liver radiation energy abnormality and the like.
Disclosure of Invention
The invention aims to provide gloss oil for releasing negative ions, which is used for coating the surface of an object to form a gloss oil layer on the surface of the object, wherein the gloss oil layer can be firmly adsorbed on the surface of the object and radiates air to ionize the air to release negative oxygen ions, so that indoor formaldehyde can be removed, the indoor air can be effectively purified, the content of the formaldehyde in the air is reduced, and a green and healthy environment can be created for people by providing the negative oxygen ions indoors;
the invention also aims to provide a preparation method of the gloss oil for releasing negative ions.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
the gloss oil for releasing negative ions is characterized by mainly comprising 35-45 parts of negative ion powder and 95-105 parts of LED gloss oil which are mixed.
40 parts of negative ion powder and 100 parts of LED gloss oil.
The anion powder mainly comprises the following components in parts by weight: 10-25 parts of tourmaline, 5-10 parts of corallitic fossil, 6-15 parts of opal, 20-25 parts of mirabilite, 30-35 parts of calcium carbonate, 25-30 parts of hexacyclic stone, 15-20 parts of far infrared powder, 10-12 parts of alumina, 4-4.5 parts of lauryl alcohol, 10-15 parts of medical king stone, 20-23 parts of ferric oxide, 5-10 parts of terbium heptaoxide, 1-3 parts of zirconium phosphate, 5-10 parts of potassium feldspar, 0.5-5 parts of quaternary ammonium salt, 0.2-1.2 parts of zinc powder, 0.2-1.4 parts of copper powder and 10-15 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 40-45 parts of heat-resistant novolac epoxy polyurethane, 20-25 parts of acrylic resin, 15-25 parts of isobornyl methacrylate, 35-40 parts of hexanediol acrylate, 15-30 parts of trimethylolpropane triacrylate, 10-30 parts of tripropylene glycol diacrylate, 3-11 parts of a photoinitiator, 0.8-4 parts of a surfactant and 0.6-4.2 parts of a water-based leveling agent.
The anion powder mainly comprises the following components in parts by weight: 15-20 parts of tourmaline, 6-9 parts of corallitic fossil, 9-12 parts of opal, 21-24 parts of mirabilite, 32-34 parts of calcium carbonate, 27-29 parts of hexacyclic stone, 17-19 parts of far infrared powder, 11.5-12 parts of alumina, 4.1-4.4 parts of lauryl alcohol, 12.5-14.5 parts of King's stone, 21.5-22.5 parts of ferric oxide, 6.5-9 parts of terbium heptaoxide, 1.5-2.8 parts of zirconium phosphate, 6.5-9.5 parts of potash feldspar, 0.6-4 parts of quaternary ammonium salt, 0.35-1.15 parts of zinc powder, 0.35-1.35 parts of copper powder and 11.5-14.5 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 42-44 parts of heat-resistant novolac epoxy polyurethane, 21-24 parts of acrylic resin, 16-24 parts of isobornyl methacrylate, 37-39 parts of hexanediol acrylate, 16-28 parts of trimethylolpropane triacrylate, 15-25 parts of tripropylene glycol diacrylate, 4-10 parts of a photoinitiator, 1-3 parts of a surfactant and 0.8-3.5 parts of a water-based leveling agent.
A preparation method of gloss oil for releasing negative ions is characterized by comprising the following steps: the method comprises the following steps:
s1: preparing anion powder and LED gloss oil;
s2: heating the LED gloss oil prepared in the step S1 to 35-45 ℃ in a water bath, and then carrying out heat preservation for 10-30 min;
s3: adding the anion powder prepared in the step S1 into the LED gloss oil in the step S2, stirring for 45-70min at the temperature of 35-45 ℃ to fully mix the anion powder and the LED gloss oil to obtain the gloss oil with the anion powder; wherein the stirring time in S3 is: and (5) 60 min.
The specific process for preparing the anion powder in the S1 comprises the following steps:
s11: respectively crushing and grinding each component material of the negative ion powder for 3-6h, and sieving to obtain powder materials of each component; s11, the mixture is sieved by a 300-600-mesh sieve.
S12: weighing the powder materials of each component according to the proportion, mixing the powder materials of each component, grinding for 0.5-1h, and sieving again to obtain negative ion powder; s12 is sieved by using a 800-1000-mesh sieve.
The stirring process described in S3 specifically includes: adding anion powder into the LED gloss oil to obtain a mixed preparation, stirring the mixed preparation clockwise for 10-20min at the stirring speed of 100-900 r/min, and then stirring the mixed preparation anticlockwise for 10-20min at the stirring speed of 600-900 r/min; and after the anticlockwise stirring is finished, stirring the upper part liquid of the mixed preparation clockwise, and stirring the lower part liquid anticlockwise, wherein the stirring time is 5-20min, and the stirring speed is 200-300 r/min.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, the negative ion powder is added into the LED gloss oil according to the parts by weight, wherein 35-45 parts of the negative ion powder and 95-105 parts of the LED gloss oil are adopted, namely the negative ion powder is dissolved into the LED gloss oil, the negative ion powder can radiate air to enable air ions to release negative oxygen ions, after the negative ion powder is added, the viscosity of the LED gloss oil cannot be reduced, when the gloss oil is coated on the surface of an object, the gloss oil forms a gloss oil layer with the negative ion powder on the surface of the object, and the gloss oil layer can be tightly attached to the surface of the object and cannot fall off; the gloss oil layer can not only isolate the surface of an object from air, but also protect the surface of the object, and meanwhile, the negative ion powder fused into the gloss oil is radiated to the outside, so that the air in a room is ionized to form negative oxygen ions, and the concentration of the negative oxygen ions in the room is effectively increased; and the formaldehyde in the room is purified and removed, so that the concentration of the formaldehyde in the room is reduced; meanwhile, the gloss oil layer with the anion powder covers the surface of the object, so that toxic substances in the object can be prevented from being emitted, and meanwhile, the toxic substances in the object can be effectively eliminated through the radiation of the anion powder in the object; 35-45 parts of anion powder and 95-105 parts of LED gloss oil, wherein the gloss oil formed by mixing the anion powder and the LED gloss oil according to the proportion does not damage the viscosity and the adhesiveness of the gloss oil, can effectively prevent the anion powder from scattering after the gloss oil is coated on the surface of an object, and is convenient for subsequent processing on a gloss oil layer formed after the gloss oil is solidified, such as subsequent procedures of flocking and the like on the gloss oil layer; if the amount of the negative ion powder is too much, the viscosity of the gloss oil can be damaged, a gloss oil layer formed after the gloss oil is coated on the surface of an object is easy to fall off, the service life of the gloss oil layer is not long, after the gloss oil layer is used for a period of time, a large amount of negative ion powder on the surface can fall off and enter a room, and the negative ion powder can cause certain damage to a human body after being inhaled by the human body; meanwhile, if the addition amount of the negative ion powder is too small, although the viscosity of the gloss oil is not influenced, the amount of the generated negative oxygen ions is influenced, so that the amount of the negative oxygen ions is far from the expected amount, and the amount of the generated negative oxygen ions can be maximized under the condition of not damaging the viscosity of the gloss oil only by strictly controlling the use amounts of the negative ion powder and the LED gloss oil.
2. The anion powder comprises the following components: tourmaline, corallitic fossil, opal, mirabilite, calcium carbonate, hexacyclic stone, far infrared powder, alumina, lauryl alcohol, medical king stone, ferric oxide, terbium tetraoxide, zirconium phosphate, potassium feldspar, quaternary ammonium salt, zinc powder, copper powder and bamboo charcoal powder; the negative ion powder formed by the components can ionize air to generate a large amount of negative oxygen ions, and the negative oxygen ions can inhibit formaldehyde with positive charges from volatilizing, so that the aim of removing formaldehyde in the air is fulfilled; when people breathe and send air containing negative ions into alveoli, the negative ions can stimulate the nervous system to generate good physiological effect, and charges carried by the negative ions are sent to tissue cells of the whole body through blood circulation, so that the oxygen conversion capability can be improved, the pH value of blood can be adjusted, cells can be activated, the cell permeability can be increased, the oxygen absorption amount can be increased, and the lung function can be improved. In addition, the air negative ions can purify blood, reduce blood pressure and cholesterol, improve cerebral cortex and myocardial functions, increase myocardial nutrition, improve cell metabolism speed and enhance human immunity; the LED gloss oil comprises the following components: heat-resistant novolac epoxy polyurethane, acrylic resin, isobornyl methacrylate, hexanediol acrylate, trimethylolpropane triacrylate, tripropylene glycol diacrylate, a photoinitiator, a surfactant and an aqueous leveling agent; the LED gloss oil formed by the components has good viscosity and adhesiveness, can be fully mixed with the anion powder, the anion powder and the LED gloss oil form a tight whole, the LED gloss oil can firmly adsorb the anion powder, and the anion powder cannot scatter indoors.
3. According to the gloss oil prepared by the method, the negative ion powder can be fully blended with the LED gloss oil, so that the negative ion powder can be fully and uniformly dispersed in the LED gloss oil, the finally formed gloss oil has good adhesiveness and viscosity, the gloss oil can be firmly adhered to the surface of an object after being coated on the surface of the object, and a gloss oil layer formed after the gloss oil is dried is not easy to fall off; the negative ion powder added into the LED gloss oil can not influence the viscosity of the gloss oil formed after the negative ion powder and the LED gloss oil are mixed, and meanwhile, the quantity of negative oxygen ions generated in the air can be maximum under the condition of ensuring the viscosity.
Detailed Description
The present invention will be further described with reference to the following examples, which are intended to illustrate only some, but not all, of the embodiments of the present invention. Based on the embodiments of the present invention, other embodiments used by those skilled in the art without any creative effort belong to the protection scope of the present invention.
Example 1
The gloss oil for releasing negative ions is characterized by mainly comprising 35-45 parts of negative ion powder and 95-105 parts of LED gloss oil which are mixed.
In the embodiment, 35 parts of the negative ion powder and 95 parts of the LED gloss oil are used; the anion powder mainly comprises the following components in parts by weight: 10 parts of tourmaline, 5 parts of corallitic fossil, 6 parts of opal, 20 parts of mirabilite, 30 parts of calcium carbonate, 25 parts of hexacyclic stone, 15 parts of far infrared powder, 10 parts of alumina, 4 parts of lauryl alcohol, 10 parts of medical king stone, 20 parts of ferric oxide, 5 parts of terbium heptaoxide, 1 part of zirconium phosphate, 5 parts of potassium feldspar, 0.5 part of quaternary ammonium salt, 0.2 part of zinc powder, 0.2 part of copper powder and 10 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 40 parts of heat-resistant novolac epoxy polyurethane, 20 parts of acrylic resin, 15 parts of isobornyl methacrylate, 35 parts of hexanediol acrylate, 15 parts of trimethylolpropane triacrylate, 10 parts of tripropylene glycol diacrylate, 2.5 parts of a photoinitiator, 0.8 part of a surfactant and 0.6 part of a water-based leveling agent;
wherein the photoinitiator is a mixture of alpha-hydroxy ketone and monoacylphosphine (the proportion of the alpha-hydroxy ketone and the monoacylphosphine is 2: 5), the surfactant is selected from American gas chemical industry Surfynol 104 surfactant, and the water-based leveling agent is selected from Dongguan triple paint chemical industry Lencolo 3002.
Example 2
The gloss oil for releasing negative ions is mainly formed by mixing 40 parts of negative ion powder and 100 parts of LED gloss oil; the anion powder mainly comprises the following components in parts by weight: 15 parts of tourmaline, 7 parts of corallitic fossil, 12 parts of opal, 22 parts of mirabilite, 32 parts of calcium carbonate, 27 parts of hexacyclic stone, 17 parts of far infrared powder, 10.5 parts of alumina, 4.3 parts of lauryl alcohol, 12 parts of medical king stone, 22.5 parts of ferric oxide, 7.5 parts of terbium heptaoxide, 1.5 parts of zirconium phosphate, 7 parts of potassium feldspar, 3 parts of quaternary ammonium salt, 0.8 part of zinc powder, 0.8 part of copper powder and 12 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 42.5 parts of heat-resistant novolac epoxy polyurethane, 22.5 parts of acrylic resin, 20.5 parts of isobornyl methacrylate, 37.5 parts of hexanediol acrylate, 16.5 parts of trimethylolpropane triacrylate, 20 parts of tripropylene glycol diacrylate, 8 parts of a photoinitiator, 3.5 parts of a surfactant and 2.5 parts of a water-based leveling agent;
among them, the photoinitiator, the surfactant and the aqueous leveling agent were the same as those used in example 1.
Example 3
The gloss oil for releasing negative ions is mainly formed by mixing negative ion powder and LED gloss oil, wherein the negative ion powder is 45 parts, and the LED gloss oil is 105 parts, wherein the negative ion powder is mainly formed by the following components in parts by weight: 25 parts of tourmaline, 10 parts of corallitic fossil, 15 parts of opal, 25 parts of mirabilite, 35 parts of calcium carbonate, 30 parts of hexacyclic stone, 20 parts of far infrared powder, 12 parts of aluminum oxide, 4.5 parts of lauryl alcohol, 15 parts of medical king stone, 23 parts of ferric oxide, 10 parts of terbium tetraoxide, 3 parts of zirconium phosphate, 10 parts of potassium feldspar, 5 parts of quaternary ammonium salt, 1.2 parts of zinc powder, 1.4 parts of copper powder and 15 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 45 parts of heat-resistant novolac epoxy polyurethane, 25 parts of acrylic resin, 25 parts of isobornyl methacrylate, 40 parts of hexanediol acrylate, 30 parts of trimethylolpropane triacrylate, 30 parts of tripropylene glycol diacrylate, 11 parts of a photoinitiator, 4 parts of a surfactant and 4.2 parts of a water-based leveling agent;
among them, the photoinitiator, the surfactant and the aqueous leveling agent were the same as those used in example 1.
Example 4
The gloss oil for releasing negative ions is mainly formed by mixing negative ion powder and LED gloss oil, wherein the negative ion powder is 35 parts, and the LED gloss oil is 95 parts, wherein the negative ion powder is mainly formed by the following components in parts by weight: 15 parts of tourmaline, 6 parts of corallitic fossil, 9 parts of opal, 21 parts of mirabilite, 32 parts of calcium carbonate, 27 parts of hexacyclic stone, 17 parts of far infrared powder, 11.5 parts of alumina, 4.1 parts of lauryl alcohol, 12.5 parts of Kingsite, 21.5 parts of ferric oxide, 6.5 parts of terbium heptaoxide, 1.5 parts of zirconium phosphate, 6.5 parts of potassium feldspar, 0.6 part of quaternary ammonium salt, 0.35 part of zinc powder, 0.35 part of copper powder and 11.5 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 42 parts of heat-resistant novolac epoxy polyurethane, 21 parts of acrylic resin, 16 parts of isobornyl methacrylate, 37 parts of hexanediol acrylate, 16 parts of trimethylolpropane triacrylate, 15 parts of tripropylene glycol diacrylate, 4 parts of a photoinitiator, 1 part of a surfactant and 0.8 part of a water-based leveling agent; among them, the photoinitiator, the surfactant and the aqueous leveling agent were the same as those used in example 1.
Example 5
The gloss oil for releasing negative ions is mainly formed by mixing negative ion powder and LED gloss oil, wherein the negative ion powder is 40 parts, and the LED gloss oil is 100 parts, wherein the negative ion powder is mainly formed by the following components in parts by weight: 18.5 parts of tourmaline, 7.5 parts of corallitic fossil, 10.5 parts of opal, 22.5 parts of mirabilite, 33 parts of calcium carbonate, 28 parts of hexacyclic stone, 18 parts of far infrared powder, 11.8 parts of alumina, 4.3 parts of lauryl alcohol, 13 parts of Kingshi, 22 parts of ferric oxide, 7.5 parts of terbium heptaoxide, 2.5 parts of zirconium phosphate, 7.5 parts of potassium feldspar, 3.5 parts of quaternary ammonium salt, 0.85 part of zinc powder, 0.95 part of copper powder and 12 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 43.5 parts of heat-resistant novolac epoxy polyurethane, 22.5 parts of acrylic resin, 20.5 parts of isobornyl methacrylate, 37.5 parts of hexanediol acrylate, 26.5 parts of trimethylolpropane triacrylate, 20.5 parts of tripropylene glycol diacrylate, 8.5 parts of a photoinitiator, 2.8 parts of a surfactant and 2.8 parts of a water-based leveling agent.
Example 6
The gloss oil for releasing negative ions is mainly formed by mixing negative ion powder and LED gloss oil, wherein the negative ion powder is 45 parts, and the LED gloss oil is 105 parts, wherein the negative ion powder is mainly formed by the following components in parts by weight: 20 parts of tourmaline, 9 parts of corallitic fossil, 12 parts of opal, 24 parts of mirabilite, 34 parts of calcium carbonate, 29 parts of hexacyclic stone, 19 parts of far infrared powder, 12 parts of alumina, 4.4 parts of lauryl alcohol, 14.5 parts of Kingsite, 22.5 parts of ferric oxide, 9 parts of terbium heptaoxide, 2.8 parts of zirconium phosphate, 9.5 parts of potassium feldspar, 4 parts of quaternary ammonium salt, 1.15 parts of zinc powder, 1.35 parts of copper powder and 14.5 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 44 parts of heat-resistant novolac epoxy polyurethane, 24 parts of acrylic resin, 24 parts of isobornyl methacrylate, 39 parts of hexanediol acrylate, 28 parts of trimethylolpropane triacrylate, 25 parts of tripropylene glycol diacrylate, 10 parts of a photoinitiator, 3 parts of a surfactant and 3.5 parts of a water-based leveling agent.
Example 7
A preparation method of gloss oil for releasing negative ions is characterized by comprising the following steps: the method comprises the following steps:
s1: preparing anion powder and LED gloss oil;
in this embodiment, the negative ion powder and the LED gloss oil are specifically in the following weight parts: 40:100, namely weighing 40 parts of prepared anion powder and 100 parts of LED gloss oil;
wherein;
weighing: 10 parts of tourmaline, 5 parts of corallitic fossil, 6 parts of opal, 20 parts of mirabilite, 30 parts of calcium carbonate, 25 parts of hexacyclic stone, 15 parts of far infrared powder, 10 parts of alumina, 4 parts of lauryl alcohol, 10 parts of medical king stone, 20 parts of ferric oxide, 5 parts of terbium heptaoxide, 1 part of zirconium phosphate, 5 parts of potassium feldspar, 0.5 part of quaternary ammonium salt, 0.2 part of zinc powder, 0.2 part of copper powder and 10 parts of bamboo charcoal powder for preparing anion powder;
weighing: 40 parts of heat-resistant novolac epoxy polyurethane, 20 parts of acrylic resin, 15 parts of isobornyl methacrylate, 35 parts of hexanediol acrylate, 15 parts of trimethylolpropane triacrylate, 10 parts of tripropylene glycol diacrylate, 2 parts of a photoinitiator, 0.8 part of a surfactant and 0.6 part of a water-based leveling agent, wherein the water-based leveling agent is used for preparing LED gloss oil;
or prepared by adopting the formula of the negative ion powder and the LED gloss oil in any other embodiment.
S2: heating the LED gloss oil prepared in the step S1 to 35 ℃ in a water bath, and then carrying out heat preservation for 10 min;
heating the LED gloss oil prepared in S1 to enable molecules in the LED gloss oil to have larger internal energy, and accelerating the molecular movement speed, namely enabling the molecules to become active; the heat preservation treatment is carried out to ensure that molecules are always in an active state, so that anion powder is conveniently added for mixing in the subsequent process.
S3: and adding the negative ion powder prepared in the step S1 into the LED gloss oil prepared in the step S2, stirring for 45min at the temperature of 35 ℃ so that the negative ion powder and the LED gloss oil are fully mixed to obtain the gloss oil with the negative ion powder.
The anion powder is added into the LED gloss oil for stirring, so that the anion powder can be fully blended with the LED gloss oil, the temperature is guaranteed to be 35 ℃ during stirring, and the full blending between the anion powder and the LED gloss oil is further guaranteed.
When in use, the gloss oil prepared in the S3 is only required to be coated on the surface of an object to form a gloss oil layer; the specific coating process is as follows: brushing gloss oil on the surface of an object, forming a gloss oil layer after the gloss oil is solidified, and repeatedly brushing the gloss oil on the gloss oil layer to form a new gloss oil layer; the specific number of gloss oil layers is determined according to actual needs.
Further optimization, wherein the specific process for preparing the anion powder in the step S1 is as follows:
s11: respectively crushing and grinding each component material of the negative ion powder for 3 hours, and sieving to obtain powder materials of each component; the screen is selected from a 300-mesh screen.
S12: weighing the powder materials of each component according to the proportion, mixing the powder materials of each component, grinding for 0.5h, and sieving again to obtain negative ion powder; the screen is selected from 800 mesh screen.
The stirring process described in S3 specifically includes: adding the anion powder into the LED gloss oil to obtain a mixed preparation, clockwise stirring the mixed preparation for 10min at the stirring speed of 100r/min, and anticlockwise stirring the mixed preparation for 10min at the stirring speed of 600 r/min; after the anticlockwise stirring is finished, stirring the upper part liquid of the mixed preparation clockwise, and stirring the lower part liquid anticlockwise for 5min at the stirring speed of 200 r/min; after the anion powder is added into the LED gloss oil, because the anion powder which is just added is powdery, if the stirring rotating speed is too high, the anion powder can fly out to cause air pollution when the stirring is just started, and meanwhile, the flying anion powder also causes the waste of raw materials, so that the situation of inaccurate proportioning can occur; during forward rotation, 100-200r/min is adopted, so that when negative ion powder is just put in, the negative ion powder and the LED gloss oil are slowly mixed; after the stirring at a low speed, the rapid stirring is carried out, so that the anion powder and the LED gloss oil can be further rapidly mixed, the rapid stirring can accelerate the mixing speed, and the problem of the flying-out of the anion powder can be avoided; after rapid mixing, the upper portion liquid that will mix the preparation carries out clockwise stirring, lower part liquid carries out anticlockwise stirring, and turn down the rotational speed, and the rotational speed is 200r/min, make the clockwise stirring of mixing system on agitator upper portion like this, the anticlockwise stirring of mixing system of agitator lower part, make the further intensive mixing of mixed preparation in the agitator, when clockwise and anticlockwise stirring simultaneously, make collision between the molecule, anion powder can be better fuse with LED gloss oil.
It should be noted that, the upper part liquid of the mixed preparation is stirred clockwise, and the lower part liquid is stirred counterclockwise, that is, two stirring devices are respectively arranged in the stirring container, one is located at the bottom and the other is located at the upper part, after the mixed preparation is placed in the stirring container, the two stirring devices are both located below the liquid level of the mixed preparation, wherein one stirring device rotates clockwise, the other stirring device rotates reversely, that is, the stirring directions of the two stirring devices are opposite, and by such stirring mode, the mixing of the negative ion powder and the LED gloss oil can be more sufficient.
Example 8
This example is substantially the same as example 7 except that: in the present embodiment, the first and second electrodes are,
in S2: heating the LED gloss oil prepared in the step S1 to 40 ℃ in a water bath, and then carrying out heat preservation for 15 min;
in S3: adding the anion powder prepared in the step S1 into the LED gloss oil prepared in the step S2, stirring for 50 min or 60min at 40 ℃, and fully mixing the anion powder and the LED gloss oil to obtain the gloss oil with the anion powder; the anion powder is added into the LED gloss oil for stirring, so that the anion powder can be fully mixed with the LED gloss oil, the temperature is guaranteed to be 40 ℃ during stirring, and the full mixing between the anion powder and the LED gloss oil is further guaranteed.
In S11: respectively crushing and grinding each component material of the negative ion powder for 4 hours, and sieving to obtain powder materials of each component; the screen is selected from a 500-mesh screen.
In S12: weighing the powder materials of each component according to the proportion, mixing the powder materials of each component, grinding for 0.8h, and sieving again to obtain negative ion powder; the screen is screened by a 900-mesh screen.
The stirring process described in S3 specifically includes: adding the anion powder into the LED gloss oil to obtain a mixed preparation, stirring the mixed preparation clockwise for 15min at a stirring speed of 150r/min, and then stirring the mixed preparation anticlockwise for 15min at a stirring speed of 700 r/min; and after the anticlockwise stirring is finished, stirring the upper part liquid of the mixed preparation clockwise, and stirring the lower part liquid anticlockwise, wherein the stirring time is 10min, and the stirring speed is 250 r/min.
Example 9
This example is substantially the same as example 7 except that:
s2: heating the LED gloss oil prepared in the step S1 to 45 ℃ in a water bath, and then carrying out heat preservation for 30 min;
s3: adding the anion powder prepared in the step S1 into the LED gloss oil in the step S2, stirring for 70min at the temperature of 45 ℃ to fully mix the anion powder and the LED gloss oil to obtain the gloss oil with the anion powder;
the anion powder is added into the LED gloss oil for stirring, so that the anion powder can be fully blended with the LED gloss oil, the temperature is ensured to be 45 ℃ during stirring, and the full blending between the anion powder and the LED gloss oil is further ensured.
S11: respectively crushing and grinding each component material of the negative ion powder for 6 hours, and sieving to obtain powder materials of each component; the screen is selected from a 600-mesh screen.
S12: weighing the powder materials of each component according to the proportion, mixing the powder materials of each component, grinding for 1h, and sieving again to obtain negative ion powder; the screen is selected from a 1000-mesh screen.
The stirring process described in S3 specifically includes: adding the anion powder into the LED gloss oil to obtain a mixed preparation, stirring the mixed preparation clockwise for 20min at a stirring speed of 200r/min, and then stirring the mixed preparation anticlockwise for 20min at a stirring speed of 900 r/min; and after the anticlockwise stirring is finished, stirring the upper part liquid of the mixed preparation clockwise, and stirring the lower part liquid anticlockwise, wherein the stirring time is 20min, and the stirring speed is 300 r/min.
The gloss oil is used for coating the surface of an object, wherein the surface of the object comprises a packaging box, a furniture surface, a bottom plate surface, a decorative picture, a wallpaper surface, a wall surface, a door body surface, a vase surface, a glass surface and the like, and negative oxygen ions formed in the air after the gloss oil is coated on the surface of the object have the effects of cleaning the air, removing bacteria and odor, promoting body health and prolonging life.
Respectively manufacturing a flocked decorative picture by using the gloss oil prepared in the examples 1-6, wherein the flocked decorative picture comprises a base paper layer, coating the gloss oil on the base paper layer, forming a gloss oil layer after the first layer of gloss oil is solidified, and coating the gloss oil layer again to form a new gloss oil layer, namely, two gloss oil layers; flocking is carried out on the gloss oil layer through a photoelectric film laminating machine, so that the flocking is vertical to the base paper, and a three-dimensional pattern is formed; the flocked decorative paintings made with the gloss oil prepared in examples 1-6 were each inspected with an anion meter.
When the flocking decorative picture is not placed in the room, the detected indoor negative ion concentration is as follows: carrying out 375/cm high harvest; then the flocking decorative painting made by the gloss oil prepared in the embodiment 1-6 is respectively placed in a room, and then the concentration of negative ions in the room is detected, wherein the negative ion measuring instrument detects the flocking decorative painting at a position 30cm away from the flocking decorative painting, and the detection result is as follows:
(1) the gloss oil prepared in the example 1 is coated on the base paper, a gloss oil layer is formed on the base paper, flocking is carried out on the gloss oil layer, and then the gloss oil layer is detected, wherein the detected anion concentration is as follows: 1769 and/cm.
(2) The gloss oil prepared in the embodiment 2 is coated on the base paper, a gloss oil layer is formed on the base paper, the gloss oil layer is flocked and then is detected, and the detected anion concentration is as follows: 1812/cm.
(3) The gloss oil prepared in example 3 was coated on a base paper, and a gloss oil layer was formed on the base paper, and the gloss oil layer was flocked and then detected, and the detected negative ion concentration was: 1925 and/cm.
(4) The gloss oil prepared in example 4 was coated on a base paper, and a gloss oil layer was formed on the base paper, and the gloss oil layer was flocked and then detected, and the detected negative ion concentration was: 1795/cm.
(5) The gloss oil prepared in example 5 was coated on a base paper, and a gloss oil layer was formed on the base paper, and the gloss oil layer was flocked and then detected, and the detected negative ion concentration was: and 1806 and/cm.
(6) The gloss oil prepared in example 6 was coated on a base paper, and a gloss oil layer was formed on the base paper, and the gloss oil layer was flocked and then detected, and the detected negative ion concentration was: 1835/cm.
The anion concentration of the position 30cm away from the flocking decorative picture is far higher than that of the indoor anion concentration, and the gloss oil layer can be firmly stuck on the base paper.
Claims (5)
1. A preparation method of gloss oil for releasing negative ions is characterized by comprising the following steps:
s1: preparing anion powder and LED gloss oil;
40 parts of negative ion powder and 100 parts of LED gloss oil;
the anion powder comprises the following components in parts by weight: 10-25 parts of tourmaline, 5-10 parts of corallitic fossil, 6-15 parts of opal, 20-25 parts of mirabilite, 30-35 parts of calcium carbonate, 25-30 parts of hexacyclic stone, 15-20 parts of far infrared powder, 10-12 parts of alumina, 4-4.5 parts of lauryl alcohol, 10-15 parts of medical king stone, 20-23 parts of ferric oxide, 5-10 parts of terbium heptaoxide, 1-3 parts of zirconium phosphate, 5-10 parts of potassium feldspar, 0.5-5 parts of quaternary ammonium salt, 0.2-1.2 parts of zinc powder, 0.2-1.4 parts of copper powder and 10-15 parts of bamboo charcoal powder;
the LED gloss oil comprises the following components in parts by weight: 40-45 parts of heat-resistant novolac epoxy polyurethane, 20-25 parts of acrylic resin, 15-25 parts of isobornyl methacrylate, 35-40 parts of hexanediol acrylate, 15-30 parts of trimethylolpropane triacrylate, 10-30 parts of tripropylene glycol diacrylate, 3-11 parts of a photoinitiator, 0.8-4 parts of a surfactant and 0.6-4.2 parts of a water-based leveling agent;
wherein the photoinitiator is a mixture of alpha-hydroxy ketone and monoacylphosphine, and the proportion of the alpha-hydroxy ketone to the monoacylphosphine is as follows: 2: 5;
the specific process is as follows:
s11: respectively crushing and grinding each component material of the negative ion powder for 3-6h, and sieving to obtain powder materials of each component;
s12: weighing the powder materials of each component according to the proportion, mixing the powder materials of each component, grinding for 0.5-1h, and sieving again to obtain negative ion powder;
s2: heating the LED gloss oil prepared in the S1 to 35-45 ℃ in a water bath, and then carrying out heat preservation for 10-30 min;
s3: adding the anion powder prepared in the step S1 into the LED gloss oil in the step S2, stirring for 45-70min at the temperature of 35-45 ℃ to fully mix the anion powder and the LED gloss oil to obtain the gloss oil with the anion powder;
wherein the stirring process in S3 specifically includes:
adding anion powder into the LED gloss oil to obtain a mixed preparation, stirring the mixed preparation clockwise for 10-20min at the stirring speed of 100-900 r/min, and then stirring the mixed preparation anticlockwise for 10-20min at the stirring speed of 600-900 r/min; and after the anticlockwise stirring is finished, stirring the upper part liquid of the mixed preparation clockwise, and stirring the lower part liquid anticlockwise, wherein the stirring time is 5-20min, and the stirring speed is 200-300 r/min.
2. The method for preparing gloss oil for releasing negative ions according to claim 1, wherein the method comprises the following steps: s11, the mixture is sieved by a 300-600-mesh sieve.
3. The method for preparing gloss oil for releasing negative ions according to claim 1, wherein the method comprises the following steps: s12 is sieved by using a 800-1000-mesh sieve.
4. The method for preparing gloss oil for releasing negative ions according to claim 1, wherein the method comprises the following steps: the stirring time in S3 is: and (5) 60 min.
5. The method for preparing gloss oil for releasing negative ions according to claim 1, wherein the method comprises the following steps: the anion powder comprises the following components in parts by weight: 18.5 parts of tourmaline, 7.5 parts of corallitic fossil, 10.5 parts of opal, 22.5 parts of mirabilite, 33 parts of calcium carbonate, 28 parts of hexacyclic stone, 18 parts of far infrared powder, 11.8 parts of alumina, 4.3 parts of lauryl alcohol, 13 parts of Kingshi, 22 parts of ferric oxide, 7.5 parts of terbium heptaoxide, 2.5 parts of zirconium phosphate, 7.5 parts of potassium feldspar, 3.5 parts of quaternary ammonium salt, 0.85 part of zinc powder, 0.95 part of copper powder and 12 parts of bamboo charcoal powder; the LED gloss oil comprises the following components in parts by weight: 43.5 parts of heat-resistant novolac epoxy polyurethane, 22.5 parts of acrylic resin, 20.5 parts of isobornyl methacrylate, 37.5 parts of hexanediol acrylate, 26.5 parts of trimethylolpropane triacrylate, 20.5 parts of tripropylene glycol diacrylate, 8.5 parts of a photoinitiator, 2.8 parts of a surfactant and 2.8 parts of a water-based leveling agent.
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