CN102504692A - UV (Ultraviolet) gloss oil with negative ion effect and preparation method thereof - Google Patents

UV (Ultraviolet) gloss oil with negative ion effect and preparation method thereof Download PDF

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Publication number
CN102504692A
CN102504692A CN2011103433307A CN201110343330A CN102504692A CN 102504692 A CN102504692 A CN 102504692A CN 2011103433307 A CN2011103433307 A CN 2011103433307A CN 201110343330 A CN201110343330 A CN 201110343330A CN 102504692 A CN102504692 A CN 102504692A
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phase component
percent
gloss oil
negative ion
grouped
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CN102504692B (en
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王绪珍
姚鼎山
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Jiangsu Yuneng Environmental Protection Technology Co ltd
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Abstract

The invention provides UV (Ultraviolet) gloss oil with a negative ion effect. The UV gloss oil is prepared by mixing a phase A component with a phase B component in the ratio of 1:1, wherein the phase A component consists of the following components in percentage by weight: 25-30 percent of UV adhesive light-cured resin UV1202, 24-26 percent of waterborne polyurethane acrylic acid, 10-22 percent of 1.6-hexanediol diacrylic ester, 10-11 percent of benzoin dimethyl ether, 9-11 percent of phenoxy propandiol and 9-11 percent of dipropylene glycol methyl ether; and the phase B component consists of the following components in percentage by weight: 14-50 percent of nano-TiO2, 14-28 percent of tourmaline, 5-18 percent of ferrous oxide, 5-18 percent of ferric oxide, 5-18 percent of copper oxide, 1-2 percent of sodium hexametahposphate and 10-20 percent of deionized water. The defects of the conventional UV gloss oil are overcome, and produced negative ions have the biological effects of activating cells, purifying blood, eliminating human body fatigue, stabilizing vegetative nervous systems, enhancing the disease resistance of human bodies, resisting electromagnetic radiation, relieving pain and the like. Environmental protection is facilitated, and the health level of people can be raised. The method is easy and practicable, is suitable for industrial production, and has high application value.

Description

A kind of UV gloss oil and preparation method thereof with negative ion effect
Technical field
The present invention relates to Chemicals, be specifically related to a kind of UV gloss oil and preparation method thereof with negative ion effect.
Background technology
Ultraviolet-curing paint (is called for short UV coating; The UV gloss oil) coating of processing than traditional organic cpds has environmental pollution and lacks, save energy, and advantage such as security is good, therefore, the UV gloss oil has become substitute, extensively uses as coating.As be used for aspects such as electronic product, metal products and machinofacture.Along with rapid economy development, every profession and trade also improves for the demand of UV gloss oil day by day, and therefore, its consumption is increasing sharply, the output surge of UV gloss oil, and market is very big.Though this coating is significantly improved than original traditional material,, also there are some shortcomings, for example, behind the glazing that is used for printed matter, the residual pungency intensive smell of meeting can not disappear for a long time.Also, contain chemical substance in the solidifying agent, also have residual toxic and harmful etc. after the use as when paint solidification.This also can influence operator's health not only bad for environmental protection, thereby, have much room for improvement.Tourmaline is a kind of ore, because of it has the effect that discharges negative ion, has been widely used in many products.The negative ion that Tourmaline discharged passes through neutralization, redox reaction, and luminous energy is converted into chemical energy, bacterium for degrading, virus, dust. and objectionable impuritiess such as waste gas formaldehyde and ammonia reach the purpose that purifies air.Negative ion is bigger to the effect of health, has the cytoactiveization of making, purifies the blood, stablizes vegetative nervous system, biological effects such as enhances human body resistance against diseases, opposing electromagnetic radiation, analgesia.A large amount of clinical datas confirm: negative ion has nourishing function to human body, as improving the human body cell oxygen carrying capacity, improves body immunity, and anti-ageing, antifatigue is to hypertension. mellitus. and asthma. neurasthenia. diseases such as insomnia all have mitigation.The research Tourmaline is the novel UV gloss oil of main raw material, makes it have environmental protection and energy saving, the effect of favourable HUMAN HEALTH.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned weak point, and research and design contains the coating that Tourmaline etc. has the effect of negative ion.
The invention provides a kind of UV gloss oil, form with 1: 1 mixed by A phase component and B phase component with negative ion effect.
Said A phase component is grouped into by the one-tenth of following weight percent proportioning:
Figure BDA0000105222210000021
Light-cured resin according to the invention is UV glue light-cured resin UV1202 and watersoluble polyurethane acrylic acid.
The two CALCIUM ACRYLATEs (HDDA) of said 1.6-pinakon are bifunctional class reactive thinner.
Said st-yrax dme is a photosensitizers.
Said Ucar 35 phenylate and dipropylene glycol methyl ether are film coalescence aid.
B phase component according to the invention is grouped into by the one-tenth of following weight percent proportioning:
Nano-TiO according to the invention 2For photocatalyst, by providing in the ShangHai HuaMing GaoNa tombar thite New Materials Co., Ltd.
Iron protoxide (FeO), red oxide of iron (Fe 2O 3), cupric oxide (CuO) is transition metal oxide.
Sodium hexametaphosphate 99 is a dispersion agent.
Another object of the present invention has provided a kind of preparation method with UV gloss oil of negative ion effect.This method comprises the following steps:
(1) A phase component preparation:
(1) UV glue light-cured resin UV1202 and watersoluble polyurethane acrylic acid thorough mixing are stirred;
(2) step (1) mixture adds the two CALCIUM ACRYLATEs (HDDA) of 1.6-pinakon, fully after the dissolving, adds st-yrax dme and Ucar 35 phenylate more successively, the dipropylene glycol methyl ether thorough mixing stirs;
(3) step (1) mixture filters with pressure filter, obtains the A phase component, and is for use;
(2) B phase component preparation:
(1) the Tourmaline preheating is 300 ℃, continues 4h, after the cooling, with nano TiO 2, iron protoxide (FeO), red oxide of iron (Fe2O3), cupric oxide (CuO), Sodium hexametaphosphate 99 and deionized water uniform mixing;
(2) step (1) mixture is put into ball mill and use wet grinding 6-8h, obtain the B phase component, for use;
(3) the A phase component that makes and 1: 1 thorough mixing of B phase component are stirred promptly get UV gloss oil with negative ion effect.
Product of the present invention has overcome the deficiency of existing UV gloss oil, biological effects such as the negative ion of generation has the cytoactiveization of making, purifies the blood, eliminates human-body fatigue, stablizes vegetative nervous system, enhances human body resistance against diseases, opposing electromagnetic radiation, analgesia.Help environmental protection and can improve people's health level.The inventive method is simple and easy to do, is suitable for suitability for industrialized production, and bigger using value is arranged.
Embodiment
Present embodiment material therefor specification and supplier are following:
Figure BDA0000105222210000041
Figure BDA0000105222210000051
Figure BDA0000105222210000061
Embodiment 1
A phase component (100 gram)
Prescription:
Figure BDA0000105222210000062
2, technology:
(1) UV glue light-cured resin UV1202, the watersoluble polyurethane acrylic acid thorough mixing stirs
(2) add (1) in the two CALCIUM ACRYLATEs (HDDA) of 1.6-pinakon, fully add the st-yrax dme more successively after the dissolving, the Ucar 35 phenylate, dipropylene glycol methyl ether, thorough mixing stirs
(3) filter, for use;
B phase component (100 gram)
1. fill a prescription:
Figure BDA0000105222210000071
2, technology:
(1) the Tourmaline preheating is 300 ℃, continues 4h, cooling back and nano-TiO 2, red stone (FeO), red oxide of iron (Fe 2O 3), cupric oxide (CuO), Sodium hexametaphosphate 99 and deionized water uniform mixing;
(2) ball mill is put in (1) and obtain the B phase component with wet grinding 6-8h;
1: 1 thorough mixing of A phase component and B phase component stirred promptly get UV gloss oil 200 grams of the present invention.
Embodiment 2
A phase component (100 gram)
Figure BDA0000105222210000072
B phase component (100 gram)
Prescription:
Figure BDA0000105222210000082
The preparation method is with embodiment 1.
Embodiment 3
A phase component (100 gram)
Prescription:
B phase component (100 gram)
Prescription:
Figure BDA0000105222210000092
The preparation method is with embodiment 1.
The product negative ion incidence test result of the foregoing description 1-3 is following:
(model: 6A232), stationary method is measured with " negative aeroion tester " that consecutive victories Electronics Co., Ltd. in camphor tree state produces.
It is (individual/cm3) 24h formaldehyde elimination factor (%) to detect distance (m) negative ion
Embodiment 1 0.5 1,200 90
Embodiment 2 0.5 1,000 86
Embodiment 3 0.5 1,050 88
Conclusion
The above results shows that the present invention solves traditional UV gloss oil and do not solve difficult point as yet fully, and having brought into play is the advantage of the novel UV gloss oil of main raw material with the Tourmaline: 1, and purify air: the negative ion that Tourmaline discharged is through neutralization; Redox reaction; Luminous energy is converted into chemical energy, bacterium for degrading, virus; Dust. objectionable impuritiess such as waste gas formaldehyde and ammonia reach the purpose that purifies air; 2. favourable HUMAN HEALTH: the negative ion that Tourmaline discharged has nourishing function to human body; As improve the human body cell oxygen carrying capacity, and improve body immunity, anti-ageing; Antifatigue is to hypertension. mellitus. and asthma. neurasthenia. diseases such as insomnia all have mitigation.The present invention can be widely used in the packages printing fields such as metope, wallpaper, plastics and food, medicine, daily necessities, can bring into play the function of environmental protection and energy saving and the health level that improves people.

Claims (4)

1. the UV gloss oil with negative ion effect is characterized in that, said UV gloss oil is made up of with 1: 1 mixed A phase component and B phase component; Said A phase component is grouped into by the one-tenth of following weight percent proportioning:
Figure FDA0000105222200000011
Said B phase component is grouped into by the one-tenth of following weight percent proportioning:
2. the UV gloss oil with negative ion effect is characterized in that, said UV gloss oil is made up of with 1: 1 mixed A phase component and B phase component; Said A phase component is grouped into by the one-tenth of following weight: 100 grams
Said B phase component is grouped into by the one-tenth of following weight: 100 grams
Figure FDA0000105222200000022
3. the UV gloss oil with negative ion effect is characterized in that, said UV gloss oil is made up of with 1: 1 mixed A phase component and B phase component; Said A phase component is grouped into by the one-tenth of following weight: 100 grams
Figure FDA0000105222200000031
Said B phase component is grouped into by the one-tenth of following weight: 100 grams
Figure FDA0000105222200000032
4. one kind like each said preparation method with UV gloss oil of negative ion effect among the claim 1-3, it is characterized in that this method comprises the following steps:
(1) A phase component preparation:
(1) UV glue light-cured resin UV1202 and watersoluble polyurethane acrylic acid thorough mixing are stirred;
(2) step (1) mixture adds the two CALCIUM ACRYLATEs of 1.6-pinakon, fully after the dissolving, adds st-yrax dme and Ucar 35 phenylate more successively, the dipropylene glycol methyl ether thorough mixing stirs;
(3) step (1) mixture filters with pressure filter, obtains the A phase component, and is for use;
(2) B phase component preparation:
(1) the Tourmaline preheating is 300 ℃, continues 4h, after the cooling, with nano-TiO 2, iron protoxide, red oxide of iron, cupric oxide, Sodium hexametaphosphate 99 and deionized water uniform mixing;
(2) step (1) mixture is put into ball mill and use wet grinding 6-8h, obtain the B phase component, for use;
(3) the A phase component that makes and 1: 1 thorough mixing of B phase component are stirred promptly get UV gloss oil with negative ion effect.
CN 201110343330 2011-11-03 2011-11-03 UV (Ultraviolet) gloss oil with negative ion effect and preparation method thereof Active CN102504692B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433443A (en) * 2015-08-10 2017-02-22 湖南邦弗特新材料技术有限公司 Aldehyde removing, antibacterial and negative ion integrated ultraviolet light curable coating material and preparation process thereof
CN109401556A (en) * 2018-08-17 2019-03-01 浙江摩登新型材料有限公司 A kind of anion protecting wall and preparation method thereof with the function that purifies the air of a room
CN112266642A (en) * 2018-08-27 2021-01-26 成都韩尚艺术贴花有限公司 Preparation method of gloss oil for releasing negative ions

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101108949A (en) * 2007-05-31 2008-01-23 佘学彬 Active ecological paint and method of manufacturing the same
CN101423676A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing non-toxic visible ultraviolet heat insulating UV coating material
CN101575903A (en) * 2009-03-25 2009-11-11 广东盈然木业有限公司 Active ecological wood floor and manufacturing method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN101775254A (en) * 2010-01-27 2010-07-14 吴江友鑫高分子材料科技有限公司 Anti-light reflection ultraviolet light curing coating for plastic surfaces
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101108949A (en) * 2007-05-31 2008-01-23 佘学彬 Active ecological paint and method of manufacturing the same
CN101423676A (en) * 2008-12-18 2009-05-06 江南大学 Method for preparing non-toxic visible ultraviolet heat insulating UV coating material
CN101575903A (en) * 2009-03-25 2009-11-11 广东盈然木业有限公司 Active ecological wood floor and manufacturing method thereof
CN101638554A (en) * 2009-05-06 2010-02-03 佛山市顺德区希贵光固化材料有限公司 Ultraviolet curing coating
CN101775254A (en) * 2010-01-27 2010-07-14 吴江友鑫高分子材料科技有限公司 Anti-light reflection ultraviolet light curing coating for plastic surfaces
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433443A (en) * 2015-08-10 2017-02-22 湖南邦弗特新材料技术有限公司 Aldehyde removing, antibacterial and negative ion integrated ultraviolet light curable coating material and preparation process thereof
CN109401556A (en) * 2018-08-17 2019-03-01 浙江摩登新型材料有限公司 A kind of anion protecting wall and preparation method thereof with the function that purifies the air of a room
CN112266642A (en) * 2018-08-27 2021-01-26 成都韩尚艺术贴花有限公司 Preparation method of gloss oil for releasing negative ions
CN112266642B (en) * 2018-08-27 2022-04-22 成都韩尚艺术贴花有限公司 Preparation method of gloss oil for releasing negative ions

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Effective date of registration: 20240111

Address after: 214000 Hongxing Road 8-2-202, Liangxi District, Wuxi City, Jiangsu Province

Patentee after: Jiangsu Yuneng Environmental Protection Technology Co.,Ltd.

Address before: Room 101, Building 4, Jinlian Huayuan, Chezhan Avenue, Wenzhou City, Zhejiang Province, 325000

Patentee before: Wang Xuzhen

Patentee before: Yao Dingshan