CN107954498A - A kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof - Google Patents

A kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof Download PDF

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Publication number
CN107954498A
CN107954498A CN201711181201.6A CN201711181201A CN107954498A CN 107954498 A CN107954498 A CN 107954498A CN 201711181201 A CN201711181201 A CN 201711181201A CN 107954498 A CN107954498 A CN 107954498A
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CN
China
Prior art keywords
parts
drinking water
clean reagent
removal rate
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711181201.6A
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Chinese (zh)
Inventor
温九江
袁松平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Xiaocao Information Industry Co Ltd
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Guangxi Xiaocao Information Industry Co Ltd
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Application filed by Guangxi Xiaocao Information Industry Co Ltd filed Critical Guangxi Xiaocao Information Industry Co Ltd
Priority to CN201711181201.6A priority Critical patent/CN107954498A/en
Publication of CN107954498A publication Critical patent/CN107954498A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • C02F2101/22Chromium or chromium compounds, e.g. chromates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/34Organic compounds containing oxygen
    • C02F2101/345Phenols

Abstract

The present invention relates to a kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof.The clean reagent in drinking water of the high phenol removal rate, including following parts by weight of component:15 30 parts of sodium metasilicate, 10 30 parts of sodium peroxydisulfate, 3 10 parts, 15 40 parts of iron oxide, 10 30 parts of calcium carbonate, 57 parts of calcium stearate, 5 15 parts of zeolite powder, 5 15 parts of activated carbon.Drinking water emergency caused by technical scheme can be used for deep treatment for drinking water or sudden water pollution event pre-processes, environmentally friendly, pollution-free, and purified drinking water does not contain harmful aluminium element.Clean reagent in drinking water carrying is easy to use, can solve the problems, such as to be difficult to purification because Rural water supply disperses, water supply is small.The clean reagent in drinking water use cost is cheap, is produced without discarded object, and the standard of drinking water can be directly reached by the purified water of the clean reagent in drinking water, meanwhile, the method for preparing the clean reagent in drinking water is simple and convenient, easily operated.

Description

A kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof
Technical field
The invention belongs to new energy and environmental protection and energy saving technical field, more particularly to a kind of drinking water of high phenol removal rate are net Agent and preparation method thereof.
Background technology
With the fast development of economic society, industry, agricultural and water pollution problem caused by resident living are increasingly Seriously, the pollution of drinking water and the short supply of purifying drinking water are also more and more troubling.Drinking water by it is harmful it is inorganic from Son and heavy metal pollution, heavy metal poisoning can cause lung cancer, kidney wing, Guang cancer and cutaneum carcinoma and other skin diseases, and phenol Poisoning can cause phenol tooth disease or phenol bone disease.Therefore drink water purifying becomes one of topic most popular at present.It has recently found that Aluminium element has human body certain harm, and traditional water purification agent generally all aluminium containing salt class compound, after being complexed to water, Although eliminating most of harmful material still can remain a small amount of aluminium element in water, to human body, there is potential Harm.
The content of the invention
In view of the problems of prior art, it is an object of the invention to provide it is a kind of being capable of effective purifying drinking water Cleanser.
The technical solution that the present invention solves above-mentioned technical problem is as follows:A kind of clean reagent in drinking water of high phenol removal rate, Including following parts by weight of component:15-25 parts of sodium metasilicate, 20-40 parts of sodium peroxydisulfate, 5-15 parts, 20-50 parts of iron oxide, calcium carbonate 10-30 parts, 5-7 parts of calcium stearate, 5-15 parts of zeolite powder, 5-15 parts of activated carbon, 15-30 parts of polyvinyl alcohol, acrylamide 10- 30 parts
Based on the above technical solutions, the present invention can also be improved as follows.
Further, the clean reagent in drinking water of the high phenol removal rate includes following parts by weight of component:15 parts of sodium metasilicate, 20 parts of sodium peroxydisulfates, 20 parts of iron oxide, 10 parts of calcium carbonate, 5 parts of calcium stearates, 5 parts of zeolite powders, 5 parts of activated carbon, 15 parts of polyethylene Alcohol, 10 parts of acrylamides.
Further, the clean reagent in drinking water of the high phenol removal rate includes following parts by weight of component:25 parts of sodium metasilicate, 40 parts of sodium peroxydisulfates, 50 parts of iron oxide, 30 parts of calcium carbonate, 7 parts of calcium stearates, 15 parts of zeolite powders, 15 parts of activated carbon, 30 parts of poly- second Enol, 30 parts of acrylamides..
Further, the clean reagent in drinking water of the high phenol removal rate includes following parts by weight of component:20 parts of sodium metasilicate, 30 parts of sodium peroxydisulfates, 30 parts of iron oxide, 30 parts of calcium carbonate, 6 parts of calcium stearates, 8 parts of zeolite powders, 10 parts of activated carbon, 20 parts of poly- second Enol, 20 parts of acrylamides.
Present invention also offers a kind of preparation method of the clean reagent in drinking water of high phenol removal rate, comprise the following steps: Following components is weighed by weight ratio:Sodium metasilicate, sodium peroxydisulfate, iron oxide, calcium carbonate, calcium stearate, zeolite powder, activity Said components are dried processing, crush and be uniformly mixed by carbon at 110-140 DEG C.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
The present invention provides a kind of clean reagent in drinking water of high phenol removal rate, including following parts by weight of component:Sodium metasilicate 15-25 parts, 20-40 parts of sodium peroxydisulfate, 5-15 parts, 20-50 parts of iron oxide, 10-30 parts of calcium carbonate, 5-7 parts of calcium stearate, zeolite 5-15 parts of powder, 5-15 parts of activated carbon, 15-30 parts of polyvinyl alcohol, acrylamide are 10-30 parts.
Technical scheme is by reasonably matching and the combination of each component is with the effect that significantly purifies water Fruit and it is easily manufactured, purification is quick;Clean reagent in drinking water using the present invention, can be effectively from water except dechromising and benzene Phenol ion, and the flow velocity of water will not be reduced;Clean reagent in drinking water using the present invention, not only clean-up effect it is reliable, it is cheap, It is easy to use, environmental-friendly, and can effectively increase de- phenol and take off chromium effect, have for the drinking water containing chromium and phenol Good removal effect.The shortcomings that conventional water purification agent is not easy to be uniformly mixed is overcome, and using effect is excellent, natural nothing Poison, tasteless, excellent in physical and chemical performance, available for drinking water emergency caused by deep treatment for drinking water or sudden water pollution event Pretreatment, it is environmentally friendly, it is pollution-free, and purified drinking water does not contain harmful aluminium element.The drinking water Cleanser carrying is easy to use, can solve the problems, such as to be difficult to purification because Rural water supply disperses, water supply is small.The drink water purifying Agent use cost is cheap, is produced without discarded object, and drinking water can be directly reached by the purified water of the clean reagent in drinking water Standard, meanwhile, the method for preparing the clean reagent in drinking water is simple and convenient, easily operated.
Activated carbon has the advantages that porous, specific surface area is big, and adsorption capacity is strong again, can not only adsorb impurities in water, again Adsorbable a certain amount of heavy metal ion;The two large storage capacity in nature, price is low, and production cost is low, and flow is short, operation letter Just, it is adapted to industrialized production.Chromium and phenol in drinking water are significantly reduced using cleanser of the present invention, Cr in source water can be made The removal rate of (chromium) 77.76%~95.83%, phenol removal rate up to 87.77%~97.73%;Along with it can be mended The trace element in source water is filled, makes source water obtain effectively purifying while greatly increasing the quality of drinking water source.
It is introduced below by specific embodiment.
Embodiment 1
Following components is weighed by weight:15 parts of sodium metasilicate, 20 parts of sodium peroxydisulfates, 5 parts, 20 parts of iron oxide, 10 parts of carbonic acid Calcium, 5 parts of calcium stearates, 5 parts of zeolite powders, 5 parts of activated carbon, 15 parts of polyvinyl alcohol, 10 parts of acrylamides, by said components in 110- Processing is dried at 140 DEG C, crushes and is uniformly mixed, the clean reagent in drinking water of the high phenol removal rate is made.
Embodiment 2
Following components is weighed by weight:25 parts of sodium metasilicate, 40 parts of sodium peroxydisulfates, 15 parts, 50 parts of iron oxide, 30 parts of carbonic acid Calcium, 7 parts of calcium stearates, 15 parts of zeolite powders, 15 parts of activated carbon, 30 parts of polyvinyl alcohol, 30 parts of acrylamides, said components are existed Processing is dried at 110-140 DEG C, crushes and is uniformly mixed, the clean reagent in drinking water of the high phenol removal rate is made.
Embodiment 3
Following components is weighed by weight:20 parts of sodium metasilicate, 30 parts of sodium peroxydisulfates, 10 parts, 30 parts of iron oxide, 30 parts of carbonic acid Calcium, 6 parts of calcium stearates, 8 parts of zeolite powders, 10 parts of activated carbon, 20 parts of polyvinyl alcohol, 20 parts of acrylamides, said components are existed Processing is dried at 110-140 DEG C, crushes and is uniformly mixed, the clean reagent in drinking water of the high phenol removal rate is made.
Measure of merit
The clean reagent in drinking water 1g of embodiment 1-3 and commercially available clean reagent in drinking water 1g (comparative example) are added to respectively In the pending drinking water of 100ml, stir and evenly mix, be precipitated to clarification, take supernatant liquor to be detected.Testing result is shown in Table 1.
Test result is as shown in table 1.
Table 1
Chromium removal rate (%) Phenol removal rate (%)
Embodiment 1 90 86
Embodiment 2 92 87
Embodiment 3 94 93
Comparative example 1 68 72
Data in table 1 can be seen that the huge sum of moneys such as the chromium that technical scheme can be preferably gone in water removal Belong to ion, can be effectively from water except the flow velocity for dechromising and reducing water;Not only clean-up effect it is reliable, it is cheap, make It with convenient, environmental-friendly, and can effectively increase de- chromium effect, while can effectively remove in water removal the phenol contained, Have good clean-up effect for the drinking water containing chromium and phenol, along with its can be in make-up water source water micro member Element, makes source water obtain effectively purifying while greatly increasing the quality of drinking water source.
Embodiment described above only expresses the several embodiments of the present invention, its description is more specific and detailed, but simultaneously Cannot therefore it be construed as limiting the scope of the patent.It should be pointed out that come for those of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be subject to appended right will.

Claims (5)

1. a kind of clean reagent in drinking water of high phenol removal rate, it is characterised in that including following parts by weight of component:Sodium metasilicate 15- 25 parts, 20-40 parts of sodium peroxydisulfate, 20-50 parts of iron oxide, 10-30 parts of calcium carbonate, 5-7 parts of calcium stearate, 5-15 parts of zeolite powder, 5-15 parts of activated carbon, 15-30 parts of polyvinyl alcohol, acrylamide are 10-30 parts.
2. a kind of clean reagent in drinking water of high phenol removal rate according to claim 1, it is characterised in that including following weight Part component:15 parts of sodium metasilicate, 20 parts of sodium peroxydisulfates, 20 parts of iron oxide, 10 parts of calcium carbonate, 5 parts of calcium stearates, 5 parts of zeolite powders, 5 Part activated carbon, 15 parts of polyvinyl alcohol, 10 parts of acrylamides.
3. a kind of clean reagent in drinking water of high phenol removal rate according to claim 1, it is characterised in that including following weight Part component:25 parts of sodium metasilicate, 40 parts of sodium peroxydisulfates, 50 parts of iron oxide, 30 parts of calcium carbonate, 7 parts of calcium stearates, 15 parts of zeolite powders, 15 parts of activated carbon, 30 parts of polyvinyl alcohol, 30 parts of acrylamides.
4. a kind of clean reagent in drinking water of high phenol removal rate according to claim 1, it is characterised in that including following weight Part component:20 parts of sodium metasilicate, 30 parts of sodium peroxydisulfates, 30 parts of iron oxide, 30 parts of calcium carbonate, 6 parts of calcium stearates, 8 parts of zeolite powders, 10 Part activated carbon, 20 parts of polyvinyl alcohol, 20 parts of acrylamides.
5. a kind of preparation method of the clean reagent in drinking water of phenol removal rate high as described in any one of Claims 1-4, its feature It is, comprises the following steps:Following components is weighed by weight ratio:Sodium metasilicate, sodium peroxydisulfate, iron oxide, calcium carbonate, firmly Resin acid calcium, zeolite powder, said components are dried processing, crush and be uniformly mixed by activated carbon at 110-140 DEG C.
CN201711181201.6A 2017-11-23 2017-11-23 A kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof Withdrawn CN107954498A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711181201.6A CN107954498A (en) 2017-11-23 2017-11-23 A kind of clean reagent in drinking water of high phenol removal rate and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039454A (en) * 2019-12-24 2020-04-21 嘉兴市禾晟生物制品有限公司 Industrial water purifying agent
CN111389355A (en) * 2020-03-23 2020-07-10 福建滤冠新型材料科技有限公司 Graphene nano carbon fiber composite water purification material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039454A (en) * 2019-12-24 2020-04-21 嘉兴市禾晟生物制品有限公司 Industrial water purifying agent
CN111389355A (en) * 2020-03-23 2020-07-10 福建滤冠新型材料科技有限公司 Graphene nano carbon fiber composite water purification material and preparation method thereof

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Application publication date: 20180424