CN102505570B - Chinese paper with uvioresistant and moistureproof functions and manufacturing method thereof - Google Patents
Chinese paper with uvioresistant and moistureproof functions and manufacturing method thereof Download PDFInfo
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- CN102505570B CN102505570B CN 201110343214 CN201110343214A CN102505570B CN 102505570 B CN102505570 B CN 102505570B CN 201110343214 CN201110343214 CN 201110343214 CN 201110343214 A CN201110343214 A CN 201110343214A CN 102505570 B CN102505570 B CN 102505570B
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- 238000004519 manufacturing process Methods 0.000 title claims description 25
- 230000006870 function Effects 0.000 title abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 13
- 241000416162 Astragalus gummifer Species 0.000 claims abstract description 9
- 235000006040 Prunus persica var persica Nutrition 0.000 claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- 229920001615 Tragacanth Polymers 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- 235000010487 tragacanth Nutrition 0.000 claims abstract description 9
- 239000000196 tragacanth Substances 0.000 claims abstract description 9
- 229940116362 tragacanth Drugs 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 238000004513 sizing Methods 0.000 claims abstract description 7
- 229940070527 tourmaline Drugs 0.000 claims abstract description 7
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 7
- 239000011032 tourmaline Substances 0.000 claims abstract description 7
- 108010010803 Gelatin Proteins 0.000 claims abstract description 6
- 239000008273 gelatin Substances 0.000 claims abstract description 6
- 229920000159 gelatin Polymers 0.000 claims abstract description 6
- 235000019322 gelatine Nutrition 0.000 claims abstract description 6
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 6
- 229940037003 alum Drugs 0.000 claims abstract description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 4
- KDKJYYNXYAZPIK-UHFFFAOYSA-J aluminum potassium disulfate hydrate Chemical compound O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KDKJYYNXYAZPIK-UHFFFAOYSA-J 0.000 claims abstract 3
- 241000209094 Oryza Species 0.000 claims description 28
- 235000007164 Oryza sativa Nutrition 0.000 claims description 28
- 235000009566 rice Nutrition 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 239000011268 mixed slurry Substances 0.000 claims description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 244000144730 Amygdalus persica Species 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 206010053615 Thermal burn Diseases 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 229940044927 ceric oxide Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000001238 wet grinding Methods 0.000 claims description 3
- 230000032696 parturition Effects 0.000 claims description 2
- 238000010422 painting Methods 0.000 abstract description 4
- 231100000614 poison Toxicity 0.000 abstract description 3
- 230000007096 poisonous effect Effects 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 2
- 230000009286 beneficial effect Effects 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 abstract 1
- 240000006413 Prunus persica var. persica Species 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 238000001514 detection method Methods 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 231100001240 inorganic pollutant Toxicity 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- 235000010413 sodium alginate Nutrition 0.000 abstract 1
- 239000000661 sodium alginate Substances 0.000 abstract 1
- 229940005550 sodium alginate Drugs 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 150000001450 anions Chemical class 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000011941 photocatalyst Substances 0.000 description 8
- 240000005809 Prunus persica Species 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- -1 alum Chemical compound 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Paper (AREA)
- Catalysts (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention provides Chinese paper with uvioresistant and moistureproof functions. The Chinese paper is prepared from raw Chinese paper, active ingredients, auxiliary materials and gelatin alum water, wherein the active ingredients comprise 14-50% of nano TiO2, 9-34% of nano cerium dioxide, 14-28% of tourmaline, 3-12% of ferrous chloride, 0.5-2% of sodium dodecyl sulfate and 10-30% of deionzied water; the auxiliary materials comprise 14-40% of tragacanth, 12-40% of peach gum and 25-48% of surface sizing starch; and the gelatin alum water comprises 6-19% of gelatin, 4-15% of sodium alginate, 3-10% of alum and 59-80% of deionized water. Through detection, the Chinese paper can generate a large amount of negative ions beneficial to improving environment and human health, and is free of poisonous and harmful organic and inorganic pollutants. According to the invention, the manufactured Chinese paper is flexible and firm, has the moistureproof, mildewproof and mothproof actions, and can effectively resist ultraviolet and maintain the bright color of painting and calligraphy for long time; and due to release of negative ions, the Chinese paper can eliminate free radicals, purity air, eliminate off-odor and poisonous and harmful gases, refresh air in studio, eliminate working fatigue and is beneficial to health.
Description
Technical field
The present invention relates to cultural goods, be specifically related to paper, relate in particular to a kind of rice paper and manufacture method thereof with uvioresistant and moisture-proof function.
Background technology
In daily life, paper is that the mankind must indispensable cultural goods, in study, work, the each side such as movable, purposes is widely arranged.Paper is one of four invents by China, and the appearance of paper has promoted the progress of human civilization, has changed the human lives, to the mankind, brings great convenience.From communication to publishing books, newspaper, magazine etc., paper is a kind of carrier of transmission of information.People are by reading newspaper, magazine understanding news; Read novel after leisure, not only, as pastime, can also enrich one's knowledge; Students, by study and learning knowledge, increases technical ability.Rice paper is of close texture, and clean mark is soft tough and tensile, and hundred foldings do not damage, and light is not and sliding, and water suction profit China ink, should should draw by book, anticorrosion mothproof, therefore " thousand paper longevity ", " king's in paper " laudatory title is arranged.Successive dynasties men of literature and writing's painting and calligraphy famous expert invariably treasures happiness and uses.With the rice paper autograph, draw a picture, Mo Yun is clear, well arranged, and moral integrity is double to be held, and imposing manner is overflow elegant, and dense and not muddy, light and not grey, its picture of its word, show forth in one's writing, in high spirit, flies order and blaze, and produces special plentiful artistic effect.But remain weak point: (1) is year in and year out, special under the irradiation that contains ultraviolet daylight or light, easily variable color. fade. and the rapid wear that becomes fragile, (2) are without the value of environmental protection.Therefore, above weak point is urgently improved.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned weak point, and research and design is conducive to environmental protection, carries high-quality rice paper.The invention provides a kind of rice paper with uvioresistant and moisture-proof function.
Rice paper of the present invention is by giving birth to rice paper, active component, and auxiliary material and Jiao Fanshui make.
Active component of the present invention is by photocatalyst (P), rare earth element (R), transition elements (T), the light-catalyzed reaction system that Tourmaline (T) forms (being called for short the PRTT reaction system).
(1) photocatalyst (P) irradiates the electron-hole effect occurs through ultraviolet ray, produces redox reaction, and light energy conversion is chemical energy, bacterium for degrading, and virus, the harmful substances such as formaldehyde and ammonia, reach the purpose that purifies air; Another important function is that the highly active electronics e of photocatalyst surface has very strong reducibility, can produce the anion that a large amount of being conducive to improves environmental and human health impacts.
(2) rare earth element (R), under multiband (ultraviolet, visible ray, even faint light) condition, has simultaneously and purifies air and antibacterial functions, and can activate the ability of Tourmaline (T) anion releasing; Improve the surface-activity of photocatalyst, enlarge the photoresponse scope of photocatalyst.
(3) transition element (T) has the characteristic of appraising at the current rate, and its contention to electronics has reduced the compound of photocatalyst surface light induced electron e and photohole h+, thereby has improved the surface-activity of photocatalyst.
(4) Tourmaline (T) has strong surface field, is conducive to the electron-hole pair separation that photocatalyst produces, and improves quantum efficiency, and can provide the generation anion required energy.
The present invention selects soft fine and closely woven, pure white uniform living rice paper.
The constituent that the present invention makes active component is following percentage by weight:
The constituent that the present invention makes auxiliary material is following percentage by weight:
Become decigram %
Western tragacanth 14-40
Peach gum 12-40
Surface sizing starch 20-48.
The constituent that the present invention makes Jiao Fanshui is following percentage by weight:
Another object of the present invention has been to provide a kind of manufacture method with rice paper of uvioresistant and moisture-proof function, and the method comprises the following steps:
(1) select paper: select softness fine and closely woven, pure white uniform living rice paper, be put on platform and flatten;
(2) manufacture of active component slurry:
Manufacture method:
(1) the Tourmaline preheating is 300 ℃, continues 4h, cooling rear and nano-TiO
2nano ceric oxide (CeO
2), ferrous oxide (FeO), lauryl sodium sulfate and deionized water evenly mix;
(2) mixture of (1) is put into to ball mill, use wet grinding 6-8h, stand-by;
(3) manufacture of auxiliary material slurry:
Formula:
Become decigram %
Western tragacanth 14-40
Peach gum 12-40
Surface sizing starch 20-48;
Manufacture method: evenly mix stand-by by western tragacanth, peach gum and starch;
(4) (two) and (three) are mixed into to mixed slurry with the ratio uniform stirring of 3: 1 W/W;
(5) manufacture of Jiao Fanshui:
Formula:
Manufacture method: gelatin, marine alga formic acid, alum, deionized water are uniformly mixed into to Jiao Fanshui;
(6) Jiao Fanshui step (five) made is sprayed on living rice paper equably with flush coater, after airing, flattens;
(7) mixed slurry step (four) made is sprayed on the rice paper that step (six) processed equably with flush coater, after airing, flattens;
(8) repeating step (six) and (seven) twice;
(9) rice paper that will complete above-mentioned steps (eight) is placed on and scalds on the paper machine, in the temperature of 80 ℃-90 ℃, plates, and cuts and can make finished product.
The present invention has reached following effect: can produce the anion that a large amount of being conducive to improves environmental and human health impacts.Not containing poisonous and hazardous organic matter and inorganic pollution.The present invention make rice paper pliable and tough firmly, there is protection against the tide, mildew-resistant, mothproof effect.Effective uvioresistant, reach and do not keep in dark place, nondiscolouring, do not fade, the effect that keeps lastingly the painting and calligraphy bright color to adopt.Due to anion releasing, eliminate free radical, can also purify air, eliminate peculiar smell and toxic and harmful, make studio with fresh air, eliminate work fatigue, healthy.
The specific embodiment
Embodiment of the present invention material therefor specification and supplier
Embodiment 1
(1) select paper: select softness fine and closely woven, pure white uniform living rice paper, be put on platform and flatten;
(2) manufacture of active component slurry:
Formula: 100 grams
Manufacture method:
(1) the Tourmaline preheating is 300 ℃, continues 4h, cooling rear and nano-TiO
2nano ceric oxide (CeO
2), ferrous oxide (FeO), lauryl sodium sulfate and deionized water evenly mix;
(2) mixture of (1) is put into to ball mill, use wet grinding 6-8h, stand-by;
(3) manufacture of auxiliary material slurry:
Formula: 100 grams
Become decigram
Western tragacanth 40
Peach gum 40
Surface sizing starch 20;
Manufacture method: evenly mix stand-by by western tragacanth, peach gum and starch;
(4) (two) and (three) are mixed into to mixed slurry with the ratio uniform stirring of 3: 1 W/W;
(5) manufacture of Jiao Fanshui:
Formula: 100 grams
Manufacture method: gelatin, marine alga formic acid, alum, deionized water are uniformly mixed into to Jiao Fanshui;
(6) Jiao Fanshui step (five) made is sprayed on living rice paper equably with flush coater, after airing, flattens;
(7) mixed slurry step (four) made is sprayed on step equably with flush coater
(6), on the rice paper of processing, after airing, flatten;
(8) repeating step (six) and (seven) twice;
(9) rice paper that will complete above-mentioned steps (eight) is placed on and scalds on the paper machine, in the temperature of 80 ℃-90 ℃, plates, and cuts and can make finished product.
Embodiment 2
(1) active component slurry:
Formula: 100 grams
；
(2) auxiliary material slurry:
Formula: 100 grams
Become decigram
Western tragacanth 14
Peach gum 38
Surface sizing starch 48;
(3) Jiao Fanshui:
Formula: 100 grams
Manufacture method is with embodiment 1.
Embodiment 3
(1) active component slurry:
Formula: 100 grams
(2) auxiliary material slurry:
Formula: 100 grams
Become decigram
Western tragacanth 40
Peach gum 15
Surface sizing starch 45;
(3) Jiao Fanshui:
Formula: 100 grams
Manufacture method is with embodiment 1.
The testing result that above-described embodiment makes product is as follows:
" the negative aeroion tester " that embodiment 1-3 produces with camphor tree state consecutive victories Electronics Co., Ltd. (model: 6A232), static method is measured, and records the anion incidence and is:
Detect distance (m) anion (individual/cm3) 24h formaldehyde elimination factor (%)
Embodiment 1 0.5 1,000 98
Embodiment 2 0.5 900 96
Embodiment 3 0.5 850 96
The above results shows that rice paper of the present invention can produce the anion that a large amount of being conducive to improves environmental and human health impacts.There is protection against the tide, mildew-resistant, mothproof effect.Effective uvioresistant, reach and do not keep in dark place, nondiscolouring, do not fade, the effect that keeps lastingly the painting and calligraphy bright color to adopt.Due to anion releasing, eliminate free radical, can also purify air, the formaldehyde elimination factor is high, can also purify air, and eliminates peculiar smell and toxic and harmful.
Claims (2)
1. the rice paper with uvioresistant and moisture-proof function, is characterized in that, described rice paper is by giving birth to rice paper, active component, and auxiliary material and Jiao Fanshui make; The constituent of described active component is following percentage by weight:
The constituent of described auxiliary material is following percentage by weight:
Each constituent of described Jiao Fanshui is following percentage by weight:
2. the manufacture method with rice paper of uvioresistant and moisture-proof function as claimed in claim 1, is characterized in that, the method comprises the following steps:
(1) select paper: select softness fine and closely woven, pure white uniform living rice paper, be put on platform and flatten;
(2) manufacture of active component slurry:
The constituent of described active component is following percentage by weight:
Manufacture method:
(1) the Tourmaline preheating is 300 ℃, continues 4h, with nano TiO 2 nano ceric oxide, ferrous oxide, lauryl sodium sulfate and deionized water, evenly mixes after cooling;
(2) mixture of (1) is put into to ball mill, use wet grinding 6-8h, stand-by;
(3) manufacture of auxiliary material slurry:
The constituent of described auxiliary material is following percentage by weight:
Manufacture method: evenly mix stand-by by western tragacanth, peach gum and surface sizing starch;
(4) (two) and (three) are mixed into to mixed slurry with the ratio uniform stirring of 3:1W/W;
(5) manufacture of Jiao Fanshui:
Each constituent of described Jiao Fanshui is following percentage by weight:
Manufacture method: gelatin, marine alga formic acid, alum and deionized water are uniformly mixed into to Jiao Fanshui;
(6) Jiao Fanshui step (five) made is sprayed on living rice paper equably with flush coater, after airing, flattens;
(7) mixed slurry step (four) made is sprayed on the rice paper that step (six) processed equably with flush coater, after airing, flattens;
(8) repeating step (six) and (seven) twice;
(9) rice paper that will complete above-mentioned steps (eight) is placed on and scalds on the paper machine, in the temperature of 80 ℃-90 ℃, plates, and cuts and can make finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110343214 CN102505570B (en) | 2011-11-03 | 2011-11-03 | Chinese paper with uvioresistant and moistureproof functions and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110343214 CN102505570B (en) | 2011-11-03 | 2011-11-03 | Chinese paper with uvioresistant and moistureproof functions and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102505570A CN102505570A (en) | 2012-06-20 |
| CN102505570B true CN102505570B (en) | 2013-12-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110343214 Active CN102505570B (en) | 2011-11-03 | 2011-11-03 | Chinese paper with uvioresistant and moistureproof functions and manufacturing method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102505570B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105568757B (en) * | 2015-12-16 | 2017-09-29 | 青岛大学 | A kind of paper document is guaranteed the quality liquid |
| CN105344510B (en) * | 2015-12-16 | 2017-11-14 | 青岛大学 | A kind of paper document is guaranteed the quality processing unit |
| CN105568756B (en) * | 2015-12-16 | 2017-09-29 | 青岛大学 | A kind of paper document is guaranteed the quality liquid and preparation method thereof |
| CN105568766B (en) * | 2015-12-16 | 2017-11-10 | 青岛大学 | A kind of paper document is guaranteed the quality processing method |
| CN107011712B (en) * | 2017-06-02 | 2019-04-05 | 中国科学院包头稀土研发中心 | A kind of Chinese painting color and preparation method thereof containing rare earth element |
| CN114134750A (en) * | 2021-06-17 | 2022-03-04 | 常德集智生物科技有限公司 | Rice paper and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101498114A (en) * | 2008-02-02 | 2009-08-05 | 王国喜 | Negative ion release paper and method of producing the same |
| CN101871182A (en) * | 2010-06-18 | 2010-10-27 | 成都新柯力化工科技有限公司 | Thermoplasticity environmentally-friendly stone paper and preparation method |
-
2011
- 2011-11-03 CN CN 201110343214 patent/CN102505570B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101498114A (en) * | 2008-02-02 | 2009-08-05 | 王国喜 | Negative ion release paper and method of producing the same |
| CN101871182A (en) * | 2010-06-18 | 2010-10-27 | 成都新柯力化工科技有限公司 | Thermoplasticity environmentally-friendly stone paper and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 刘仁庆.论宣纸_古纸研究之六.《纸和造纸》.2011,第30卷(第3期), |
| 论宣纸_古纸研究之六;刘仁庆;《纸和造纸》;20110331;第30卷(第3期);第68-72页 * |
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Effective date of registration: 20240112 Address after: 214000 Hongxing Road 8-2-202, Liangxi District, Wuxi City, Jiangsu Province Patentee after: Jiangsu Yuneng Environmental Protection Technology Co.,Ltd. Address before: Room 101, Building 4, Jinlian Huayuan, Chezhan Avenue, Wenzhou City, Zhejiang Province, 325000 Patentee before: Wang Xuzhen Patentee before: Yao Dingshan |