CN106189568A - A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof - Google Patents
A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof Download PDFInfo
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- CN106189568A CN106189568A CN201610545437.2A CN201610545437A CN106189568A CN 106189568 A CN106189568 A CN 106189568A CN 201610545437 A CN201610545437 A CN 201610545437A CN 106189568 A CN106189568 A CN 106189568A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Organic Chemistry (AREA)
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- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The present invention relates to a kind of interior wall coating, be specifically related to environment-friendly interior wall coating of a kind of absorption degradation indoor formaldehyde and preparation method thereof.Described coating is made up of the raw material of following parts by weight: modified porous filler: 12 18%;Vinyl acetate acrylic acid ester emulsion: 38 52%;Silanol class nonionic surfactant: 0.05 0.5%;Cosolvent: 4 8%;Pigment: 1.5 4%;Hexa methoxy tripolycyanamide: 0.05 2%;Auxiliary agent: 1 3%;Water: surplus;The interior wall coating purifying formaldehyde rate that the present invention provides is high, and quality is hard, and hardening time is short, and weatherability is strong, and paint film is smooth, without foaming phenomena.
Description
Technical field
The present invention relates to a kind of interior wall coating, be specifically related to a kind of absorption degradation indoor formaldehyde environment-friendly interior wall coating and
Preparation method.
Background technology
Formaldehyde be a kind of colourless, have the gas of special penetrating odor, abnormal smells from the patient irritant to human eye, nose etc., modern
Medical evidence, formaldehyde is harmful to nervous system, immune system, liver etc..Formaldehyde mainly has as what indoor hardware fitting produced
Poison noxious pollutant, drastically influence the house and health of the mankind.Show according to report on Epidemiological, Long Term Contact formaldehyde
People, can cause the cancer of nasal cavity, throat, skin and digestive tract etc..
Indoor are the topmost activity spaces of the mankind, every day people at indoor work and life-time at least above 10
Hour, room air has extremely important impact to human health.Indoor coating as a kind of emulsion paint fitted up, it
Major function is decoration and protection inner wall surface, sets up a beautiful and comfortable living environment.Interior wall coating should have following property
Can: color is fine and smooth, abundant, coordination;Alkaline-resisting, water resistance good, be not pulverized easily;Good breathability, moisture absorption dehumidifying, brushing side
Just, recoatability is good;Nontoxic, pollution-free, environmental protection.Along with improving constantly of people's living standard, " green consumption " is rooted in the hearts of the people.
In terms of household, people the most only value attractive in appearance and fashion, more emphasize health environment-friendly, and have environment purification, can remove
The product of evil gas.But interior wall coating of the prior art, does not have the harmful gass such as effective absorption degradation indoor formaldehyde
Effect, it is impossible to Improvement room air.
Summary of the invention
For the deficiencies in the prior art, the environment protection interior wall that the invention provides a kind of energy active adsorption degraded indoor formaldehyde is coated with
Material, and its preparation method.
For realizing object above, the present invention is achieved by the following technical programs:
The environment-friendly interior wall coating of a kind of energy active adsorption degraded indoor formaldehyde, is made up of the raw material of following parts by weight:
Modified porous filler 12-18%;
Vinyl acetate-acrylate copolymer emulsion 38-52%;
Silanol class nonionic surfactant 0.05-0.5%;
Cosolvent 4-8%;
Pigment 1.5-4%;
Hexa methoxy tripolycyanamide 0.05-2%;
Auxiliary agent 1-3%;
Water surplus.
Further, described modified porous filler is selected from activated carbon, and activated alumina, activated silica, Graphene, in kieselguhr
At least two and nano titanium oxide constitute compositions.
Further, described cosolvent is selected from ethanol, methyl Cellosolve, the one of which in diethylene glycol dimethyl ether.
Further, described pigment be selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, in graphite wherein
A kind of.
Further, described auxiliary agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, prevents
Rotten agent, antifungus agent, anti-blushing agent, antifreezing agent and defoamer.
The preparation method of the environment-friendly interior wall coating of a kind of energy indoor free formaldehyde of active adsorption degraded, comprises the steps:
(1) each raw material is weighed respectively by formula, standby;
(2) putting in dispersion cylinder by water, rotating speed is set to 150-200r/min, is sequentially added into auxiliary agent, silanol class non-ionic surface
Activating agent, hexa methoxy tripolycyanamide and cosolvent, adjustment rotating speed is 500-800r/min, stirs 8-10min;
(3) adding modified porous filler and pigment, adjustment rotating speed is 1800-2500r/min, stirs 15-25min;
(4) vinyl acetate-acrylate copolymer emulsion is added, same direction stirring 8-15min, obtain product.
The invention have the benefit that the present invention is by by modified porous filler, vinyl acetate-acrylate copolymer emulsion, silicon
Alcohols nonionic surfactant, cosolvent, pigment, hexa methoxy tripolycyanamide, auxiliary agent and water organic composite so that the present invention
The free formaldehyde of the interior wall coating energy active adsorption provided and degraded indoor, after tested, after 24h, purifying formaldehyde rate be up to 48% with
On.The interior wall coating quality that the present invention provides is hard, and hardening time is short, and weatherability is strong, and paint film is smooth, without foaming phenomena;Additionally,
The preparation technology that the present invention provides is simple, and labor intensity is low, can realize mechanization and automatically produce.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the enforcement of the present invention
Example, is clearly and completely described the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
The environment-friendly interior wall coating of a kind of energy active adsorption degraded indoor formaldehyde, is made up of the raw material of following parts by weight:
Activated silica 7%;
Graphene 2%;
Kieselguhr 5%;
Nano titanium oxide 2%;
Vinyl acetate-acrylate copolymer emulsion 43%;
Silanol class nonionic surfactant 0.2%;
Ethanol 6.5%;
Pigment 2.5%;
Hexa methoxy tripolycyanamide 0.5%;
Auxiliary agent 2%;
Water 29.3%.
In the present embodiment, pigment is selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, wherein in graphite
Kind, auxiliary agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, preservative, antifungus agent, protection against the tide
Agent, antifreezing agent and defoamer.
Its preparation method, comprises the steps:
(1) each raw material is weighed respectively by formula, standby;
(2) putting in dispersion cylinder by water, rotating speed is set to 150-200r/min, is sequentially added into auxiliary agent, silanol class non-ionic surface
Activating agent, hexa methoxy tripolycyanamide and cosolvent, adjustment rotating speed is 500-800r/min, stirs 8-10min;
(3) adding modified porous filler and pigment, adjustment rotating speed is 1800-2500r/min, stirs 15-25min;
(4) vinyl acetate-acrylate copolymer emulsion is added, same direction stirring 8-15min, obtain product.
Embodiment 2:
The environment-friendly interior wall coating of a kind of energy active adsorption degraded indoor formaldehyde, is made up of the raw material of following parts by weight:
Activated carbon 10%;
Activated silica 8%;
Nano titanium oxide 3%;
Vinyl acetate-acrylate copolymer emulsion 38%;
Silanol class nonionic surfactant 0.5%;
Methyl Cellosolve 4%;
Pigment 4%;
Hexa methoxy tripolycyanamide 0.05%;
Auxiliary agent 3%;
Water 36.15%.
In the present embodiment, pigment is selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, wherein in graphite
Kind, auxiliary agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, preservative, antifungus agent, protection against the tide
Agent, antifreezing agent and defoamer.
Its preparation method is with embodiment 1.
Embodiment 3:
Plant the environment-friendly interior wall coating of energy active adsorption degraded indoor formaldehyde, be made up of the raw material of following parts by weight:
Activated alumina 8%;
Graphene 2%;
Nano titanium oxide 2%;
Vinyl acetate-acrylate copolymer emulsion 52%;
Silanol class nonionic surfactant 0.05%;
Diethylene glycol dimethyl ether 8%;
Pigment 1.5%;
Hexa methoxy tripolycyanamide 2%;
Auxiliary agent 1%;
Water 23.45%.
In the present embodiment, pigment is selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, wherein in graphite
Kind, auxiliary agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, preservative, antifungus agent, protection against the tide
Agent, antifreezing agent and defoamer.
Its preparation method is with embodiment 1.
Embodiment 4:
Plant the environment-friendly interior wall coating of energy active adsorption degraded indoor formaldehyde, be made up of the raw material of following parts by weight:
Graphene 3%;
Kieselguhr 7%;
Nano titanium oxide 5%;
Vinyl acetate-acrylate copolymer emulsion 46%;
Silanol class nonionic surfactant 0.3%;
Methyl Cellosolve 5%;
Pigment 3%;
Hexa methoxy tripolycyanamide 1.2%;
Auxiliary agent 1.8%;
Water 27.7%.
In the present embodiment, pigment is selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, wherein in graphite
Kind, auxiliary agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, preservative, antifungus agent, protection against the tide
Agent, antifreezing agent and defoamer.
Its preparation method is with embodiment 1.
The indices of the coating being provided embodiment 1-4 detects.Wherein, main performance test is with reference to GB/
T9756-2009 interior wall coating national standard, purifying formaldehyde rate method of testing performs JC/T1074-2008 " indoor air purification merit
Can coating material purification function " I class that specifies requires to test.
The invention have the benefit that
The present invention by by modified porous filler, vinyl acetate-acrylate copolymer emulsion, silanol class nonionic surfactant, help
Solvent, pigment, hexa methoxy tripolycyanamide, auxiliary agent and water organic composite so that the interior wall coating that the present invention provides can effectively be inhaled
Echoing the formaldehyde that degraded indoor are free, after tested, after 24h, purifying formaldehyde rate is up to more than 48%.The interior wall that the present invention provides is coated with
Material quality is hard, and hardening time is short, and weatherability is strong, and paint film is smooth, without foaming phenomena;Additionally, the preparation technology that the present invention provides
Simply, labor intensity is low, can realize mechanization and automatically produce.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment
The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or
Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. one kind can the environment-friendly interior wall coating of active adsorption degraded indoor formaldehyde, it is characterised in that former by following parts by weight
Material composition:
Modified porous filler 12-18%;
Vinyl acetate-acrylate copolymer emulsion 38-52%;
Silanol class nonionic surfactant 0.05-0.5%;
Cosolvent 4-8%;
Pigment 1.5-4%;
Hexa methoxy tripolycyanamide 0.05-2%;
Auxiliary agent 1-3%;
Water surplus.
2. as claimed in claim 1 can the environment-friendly interior wall coating of active adsorption degraded indoor formaldehyde, it is characterised in that described in change
Property porous aggregate selected from activated carbon, activated alumina, activated silica, Graphene, at least two in kieselguhr and nanometer titanium dioxide
The compositions that titanium is constituted.
3. as claimed in claim 1 can the environment-friendly interior wall coating of active adsorption degraded indoor formaldehyde, it is characterised in that described in help
Solvent selected from ethanol, methyl Cellosolve, the one of which in diethylene glycol dimethyl ether.
4. the environment-friendly interior wall coating of energy active adsorption degraded indoor formaldehyde as claimed in claim 1, it is characterised in that described face
Material is selected from titanium dioxide, lithopone, lead chromate yellow, iron oxide red, ultramarine, white carbon black, the one of which in graphite.
5. as claimed in claim 1 can the environment-friendly interior wall coating of active adsorption degraded indoor formaldehyde, it is characterised in that described in help
Agent includes levelling agent, thickening agent, pigment dispersing agent, plasticizer, drier, stabilizer, preservative, antifungus agent, and anti-blushing agent is antifreeze
Agent and defoamer.
6. the environment-friendly interior wall coating of the energy active adsorption degraded indoor formaldehyde that a kind is prepared as according to any one of claim 1-5
Method, it is characterised in that comprise the steps:
(1) each raw material is weighed respectively by formula, standby;
(2) putting in dispersion cylinder by water, rotating speed is set to 150-200r/min, is sequentially added into auxiliary agent, silanol class non-ionic surface
Activating agent, hexa methoxy tripolycyanamide and cosolvent, adjustment rotating speed is 500-800r/min, stirs 8-10min;
(3) adding modified porous filler and pigment, adjustment rotating speed is 1800-2500r/min, stirs 15-25min;
(4) vinyl acetate-acrylate copolymer emulsion is added, same direction stirring 8-15min, obtain product.
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CN201610545437.2A CN106189568A (en) | 2016-07-07 | 2016-07-07 | A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof |
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CN201610545437.2A CN106189568A (en) | 2016-07-07 | 2016-07-07 | A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof |
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CN201610545437.2A Pending CN106189568A (en) | 2016-07-07 | 2016-07-07 | A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof |
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Cited By (3)
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CN108439863A (en) * | 2018-05-28 | 2018-08-24 | 白山大金谷矿业有限公司 | A kind of anti-dropout inner-outer wall Black Warrior slime paint and preparation method thereof |
CN109749540A (en) * | 2019-01-21 | 2019-05-14 | 桐城市桐佳装饰有限公司 | A kind of paste interior wall coating preparation method |
CN110791202A (en) * | 2019-11-12 | 2020-02-14 | 河南煜和智能科技有限公司 | Formaldehyde-removing wall coating added with graphene |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108439863A (en) * | 2018-05-28 | 2018-08-24 | 白山大金谷矿业有限公司 | A kind of anti-dropout inner-outer wall Black Warrior slime paint and preparation method thereof |
CN108439863B (en) * | 2018-05-28 | 2021-01-05 | 白山大金谷新型材料科技股份有限公司 | Anti-drop basalt coating for interior and exterior walls and preparation method thereof |
CN109749540A (en) * | 2019-01-21 | 2019-05-14 | 桐城市桐佳装饰有限公司 | A kind of paste interior wall coating preparation method |
CN110791202A (en) * | 2019-11-12 | 2020-02-14 | 河南煜和智能科技有限公司 | Formaldehyde-removing wall coating added with graphene |
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