CN104877427A - Diatom ooze coating and preparation method thereof - Google Patents

Diatom ooze coating and preparation method thereof Download PDF

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Publication number
CN104877427A
CN104877427A CN201510285577.6A CN201510285577A CN104877427A CN 104877427 A CN104877427 A CN 104877427A CN 201510285577 A CN201510285577 A CN 201510285577A CN 104877427 A CN104877427 A CN 104877427A
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Prior art keywords
parts
xylogen
diatom ooze
ooze coating
lignin
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CN201510285577.6A
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Chinese (zh)
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王宇
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TONGCHENG HUIQI INDUSTRY AND TRADE Co Ltd
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TONGCHENG HUIQI INDUSTRY AND TRADE Co Ltd
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Publication of CN104877427A publication Critical patent/CN104877427A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The invention discloses a diatom ooze coating which is made of raw materials comprising, by weight, 15-25 parts of water, 0.6-2.6 parts of lignin or lignin derivatives, 10-15 parts of tourmalines, 0.1-0.3 part of silver oxide, 10-15 parts of titanium dioxide, 3-6 parts of precipitated barium sulphate, 5-15 parts of kaoline, 5-10 parts of sea-foam stone powder, 30-45 parts of nano diatomite, 0.5-1.5 parts of palladium, 5-10 parts of nanometer titania, 0.4-0.6 part of leveling agents, 1.5-4 parts of thickening agents, 0.6-1.2 parts of mildew preventives, 1-5 parts of active carbon nanoparticles, 0.5-3 parts of net-flavor emulsions, 8-15 parts of dispersible adhesive powder and 0-3 parts of pigment. The diatom ooze coating is excellent in breathability and moisture absorption, gas ion negatively charged can be released, human body synthesis and vitamin storage can be promoted, and human immune ability is improved; functions of sterilization, mold prevention, deodorization, air purification and fire prevention are achieved; the preparation method is simple, easy to operate and convenient for large-scale production.

Description

A kind of diatom ooze coating and preparation method thereof
Technical field
The present invention relates to paint field, be specifically related to a kind of diatom ooze coating and preparation method thereof.
Background technology
Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating, it is made up of filmogen, film forming subsidiary material matter and auxiliary film forming matter three kinds of base substances.Existing coating, adopt potassium silicate solution as filmogen, potassium silicate provides excellent bond properties, but due to the existence of alkalimetal ion, makes coating adhesion inadequate, simultaneously due to the existence of alkalimetal ion, make the water tolerance of coating on the low side; Present coating also exists can not reduce formaldehyde in air content, mildew-resistant, antibacterial, diatom ooze coating cohesive force is poor, the problem of easy dry linting.
Summary of the invention
The object of the invention is to propose a kind of diatom ooze coating and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of diatom ooze coating, is made up of the raw material of following weight part:
A kind of diatom ooze coating, is characterized in that, be made up of the raw material of following weight part:
15 ~ 25 parts, water, xylogen or lignin derivative 0.6 ~ 2.6 part, 10 ~ 15 parts, tourmalinite, silver suboxide 0.1 ~ 0.3 part, titanium dioxide 10 ~ 15 parts, process white 3 ~ 6, kaolin 5 ~ 15, sepiolite powder 5 ~ 10, nano diatomite 30 ~ 45 parts, palladium 0.5 ~ 1.5 part, nano titanium oxide 5 ~ 10 parts, flow agent 0.4 ~ 0.6 part, thickening material 1.5 ~ 4 parts, mould inhibitor 0.6 ~ 1.2 part, active carbon nanoparticles 1 ~ 5 part, clean taste emulsion 0.5 ~ 3 part, re-dispersible glue powder 8 ~ 15 parts, pigment 0 ~ 3 part.
Preferably, described a kind of diatom ooze coating, is made up of the raw material of following weight part: 20 parts, water, xylogen or lignin derivative 1.2 parts, 13 parts, tourmalinite, silver suboxide 0.2 part, titanium dioxide 13 parts, process white 4.5 parts, kaolin 10 parts, sepiolite powder 8 parts, nano diatomite 37 parts, palladium 1 part, nano titanium oxide 6 parts, flow agent 0.5 part, thickening material 2.5 parts, mould inhibitor 0.9 part, active carbon nanoparticles 3 parts, clean taste emulsion 1.5 parts, re-dispersible glue powder 11 parts, pigment 2 parts.
Preferably, described re-dispersible glue powder is any one or the multiple combination in the multipolymer of ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, acrylic copolymer.
Preferably, described tourmalinite, nano titanium oxide and palladium are Powdered.
Preferably, described a kind of diatom ooze coating, described xylogen is the one in ligninsulfonate, hydrochloric acid xylogen, Milled wood lignin, alkali lignin, enzymolysis xylogen, steam explosion xylogen and ethanol xylogen; Described lignin derivative is the one in sulfonation modifying xylogen, epoxide modified xylogen, amination modifying xylogen, methylolation modified lignin resin, graft modification xylogen.
Preferably, described a kind of diatom ooze coating, its preparation method comprises the following steps:
(1) xylogen or lignin derivative are dissolved in the NaOH solution of 1.5%, cross and filter insoluble impurities, obtain filtrate, filtrate pH to 3 is regulated to make xylogen coagulation sedimentation, filter, obtain xylogen or the lignin derivative of purifying, airflow drying is to weight, then grinding sieves, and chooses xylogen or lignin derivative that granularity is 80 ~ 100 object purifying;
(2) weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 5min with the stirring velocity of 450r/min;
(3) tourmalinite, titanium dioxide, process white, kaolin, sepiolite powder, nano diatomite, nano titanium oxide are added in stirred vessel, stir 30min with the stirring velocity of 1200r/min;
(4) silver suboxide and palladium are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
(5) flow agent, thickening material, mould inhibitor, clean taste emulsion, re-dispersible glue powder are added in stirred vessel, stir 10min with the stirring velocity of 500r/min;
(6) in stirred vessel, add pigment, stir, obtain product.
Compared with prior art, the invention has the advantages that: the present invention take Pd/TiO2 as catalyzer, at pollutents such as catalyze oxidation of formaldehyde under no light condition, the object purified air can be realized, therefore there is application prospect widely.
The present invention is added with diatomite, therefore there is excellent ventilation property, water absorbability, diatomite has the structure of special porous, add active carbon nanoparticles simultaneously, possesses extremely strong physisorption, can the pollutent such as formaldehyde in absorbed air, more accelerate the conversion rate of the pollutents such as formaldehyde, its cohesiveness can be improved again.The present invention can discharge electronegative gaseous ion, human body can be facilitated to synthesize and vitamin storage, be conducive to blood Oxygen deliver simultaneously, have promotion human metabolism, improve human immunological competence, regulate the effect of human body function balance; , the re-dispersible glue powder added can improve liquidity, improve workability.Improve force of cohesion, extend the open hour and strengthen water-retentivity coating of the present invention and also there is sterilization, mildew-resistant, deodorizing, purify air and fire-proof function; Preparation method of the present invention is simple, easy to operate, is convenient to realize scale operation.
Embodiment
Embodiment 1
A kind of diatom ooze coating, it is made up of the following component according to weight part:
15 parts, water, xylogen or lignin derivative 0.6 part, 10 parts, tourmalinite, silver suboxide 0.1 part, titanium dioxide 10 parts, process white 3 parts, kaolin 5 parts, sepiolite powder 5 parts, nano diatomite 30 parts, palladium 0.5 part, nano titanium oxide 5 parts, flow agent 0.4 part, thickening material 1.5 parts, mould inhibitor 0.6 part, active carbon nanoparticles 1 part, clean taste emulsion 0.5 part, re-dispersible glue powder 8 parts, pigment 1 part.
Described xylogen is the one in ligninsulfonate, hydrochloric acid xylogen, Milled wood lignin, alkali lignin, enzymolysis xylogen, steam explosion xylogen and ethanol xylogen; Described lignin derivative is the one in sulfonation modifying xylogen, epoxide modified xylogen, amination modifying xylogen, methylolation modified lignin resin, graft modification xylogen.
Described tourmalinite, nano titanium oxide and palladium are Powdered, and described Mierocrystalline cellulose is one or more the mixing in lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, Polyanionic Cellulose, sodium polyacrylate ethyl cellulose, methylcellulose gum and calcium mercaptoacetate polyoxyethylene glycol Vltra tears.
Described re-dispersible glue powder is any one or multiple combination in the multipolymer of ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, acrylic copolymer.
Tourmalinite is with the addition of in the present invention, tourmalinite can produce negative ion, micro-electric current and far infrared rays, under the multiple excitation of tourmalinite, Pd/TiO2 can realize a kind of brand-new catalysis energy under no light condition, thus reach the target of the pollutents such as catalyze oxidation of formaldehyde, therefore there is application prospect widely.
Described a kind of diatom ooze coating, its preparation method in turn includes the following steps:
(1) xylogen or lignin derivative are dissolved in the NaOH solution of 1.5%, cross and filter insoluble impurities, obtain filtrate, filtrate pH to 3 is regulated to make xylogen coagulation sedimentation, filter, obtain xylogen or the lignin derivative of purifying, airflow drying is to weight, then grinding sieves, and chooses xylogen or lignin derivative that granularity is 80 ~ 100 object purifying;
(2) weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 5min with the stirring velocity of 450r/min;
(3) tourmalinite, titanium dioxide, process white, kaolin, sepiolite powder, nano diatomite, nano titanium oxide are added in stirred vessel, stir 30min with the stirring velocity of 1200r/min;
(4) silver suboxide and palladium are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
(5) by flow agent, thickening material, mould inhibitor, clean taste breast re-dispersible glue powder, add in stirred vessel, stir 10min with the stirring velocity of 500r/min;
(6) in stirred vessel, add pigment, stir, obtain product.
Embodiment 2
The difference of the present embodiment and embodiment 1 is only,
20 parts, water, xylogen or lignin derivative 1.2 parts, 13 parts, tourmalinite, silver suboxide 0.2 part, titanium dioxide 13 parts, process white 4.5 parts, kaolin 10 parts, sepiolite powder 8 parts, nano diatomite 37 parts, palladium 1 part, nano titanium oxide 6 parts, flow agent 0.5 part, thickening material 2.5 parts, mould inhibitor 0.9 part, active carbon nanoparticles 3 parts, clean taste emulsion 1.5 parts, re-dispersible glue powder 11 parts, pigment 2 parts.
Embodiment 3
The difference of the present embodiment and embodiment 1 is only,
25 parts, water, xylogen or lignin derivative 2.6 parts, 15 parts, tourmalinite, silver suboxide 0.3 part, titanium dioxide 15 parts, process white 6, kaolin 15, sepiolite powder 10, nano diatomite 45 parts, palladium 1.5 parts, nano titanium oxide 10 parts, flow agent 0.6 part, thickening material 4 parts, mould inhibitor 1.2 parts, active carbon nanoparticles 5 parts, clean taste emulsion 2 parts, re-dispersible glue powder 13 parts, pigment 2.5 parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (6)

1. a diatom ooze coating, is characterized in that, is made up of the raw material of following weight part:
15 ~ 25 parts, water, xylogen or lignin derivative 0.6 ~ 2.6 part, 10 ~ 15 parts, tourmalinite, silver suboxide 0.1 ~ 0.3 part, titanium dioxide 10 ~ 15 parts, process white 3 ~ 6, kaolin 5 ~ 15, sepiolite powder 5 ~ 10, nano diatomite 30 ~ 45 parts, palladium 0.5 ~ 1.5 part, nano titanium oxide 5 ~ 10 parts, flow agent 0.4 ~ 0.6 part, thickening material 1.5 ~ 4 parts, mould inhibitor 0.6 ~ 1.2 part, active carbon nanoparticles 1 ~ 5 part, clean taste emulsion 0.5 ~ 3 part, re-dispersible glue powder 8 ~ 15 parts, pigment 0 ~ 3 part.
2. a kind of diatom ooze coating according to claim 1, it is characterized in that, be made up of the raw material of following weight part: 20 parts, water, xylogen or lignin derivative 1.2 parts, 13 parts, tourmalinite, silver suboxide 0.2 part, titanium dioxide 13 parts, process white 4.5 parts, kaolin 10 parts, sepiolite powder 8 parts, nano diatomite 37 parts, palladium 1 part, nano titanium oxide 6 parts, flow agent 0.5 part, thickening material 2.5 parts, mould inhibitor 0.9 part, active carbon nanoparticles 3 parts, clean taste emulsion 1.5 parts, re-dispersible glue powder 11 parts, pigment 2 parts.
3. a kind of diatom ooze coating according to claim 1, is characterized in that, described re-dispersible glue powder is any one or multiple combination in the multipolymer of ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, acrylic copolymer.
4. a kind of diatom ooze coating according to claim 1, is characterized in that, described tourmalinite, nano titanium oxide and palladium are Powdered.
5. a kind of diatom ooze coating according to claim 1, is characterized in that, described xylogen is the one in ligninsulfonate, hydrochloric acid xylogen, Milled wood lignin, alkali lignin, enzymolysis xylogen, steam explosion xylogen and ethanol xylogen; Described lignin derivative is the one in sulfonation modifying xylogen, epoxide modified xylogen, amination modifying xylogen, methylolation modified lignin resin, graft modification xylogen.
6. a kind of diatom ooze coating according to any one of claim 1-5, it is characterized in that, its preparation method comprises the following steps:
(1) xylogen or lignin derivative are dissolved in the NaOH solution of 1.5%, cross and filter insoluble impurities, obtain filtrate, filtrate pH to 3 is regulated to make xylogen coagulation sedimentation, filter, obtain xylogen or the lignin derivative of purifying, airflow drying is to weight, then grinding sieves, and chooses xylogen or lignin derivative that granularity is 80 ~ 100 object purifying;
(2) weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 5min with the stirring velocity of 450r/min;
(3) tourmalinite, titanium dioxide, process white, kaolin, sepiolite powder, nano diatomite, nano titanium oxide are added in stirred vessel, stir 30min with the stirring velocity of 1200r/min;
(4) silver suboxide and palladium are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
(5) flow agent, thickening material, mould inhibitor, clean taste emulsion, re-dispersible glue powder are added in stirred vessel, stir 10min with the stirring velocity of 500r/min;
(6) in stirred vessel, add pigment, stir, obtain product.
CN201510285577.6A 2015-05-29 2015-05-29 Diatom ooze coating and preparation method thereof Pending CN104877427A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105400304A (en) * 2015-12-15 2016-03-16 上海源由纳米科技有限公司 Nano composite diatom ooze coating and preparation method thereof
CN105504902A (en) * 2016-02-25 2016-04-20 陈丽娜 Diatom mud mixture and method for preparing same
CN105750486A (en) * 2016-04-27 2016-07-13 霍邱县鑫瑞金属制品有限责任公司 Water-based lost foam casting coating with active carbon nanoparticles for magnesium alloy casting and preparation method thereof
CN106189568A (en) * 2016-07-07 2016-12-07 山东冬瑞高新技术开发有限公司 A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof
CN106883649A (en) * 2017-04-12 2017-06-23 程艳青 A kind of multi-functional environment-protection water paint and preparation method thereof
CN107189563A (en) * 2017-08-02 2017-09-22 合肥安力电力工程有限公司 A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof
CN107244878A (en) * 2017-05-23 2017-10-13 欧亚绿邦(北京)科技有限公司 High scrubbing resistance diatom ooze and preparation method thereof
CN107418265A (en) * 2017-09-30 2017-12-01 安徽琦家科技股份有限公司 A kind of antibacterial diatom ooze coating and preparation method thereof
CN107572871A (en) * 2017-10-20 2018-01-12 孙立民 One kind is used for environmental friendly indoor type sea bubble slime paint
CN107674465A (en) * 2017-11-28 2018-02-09 黄宇 A kind of preparation method for strengthening environmentally friendly diatom ooze coating
CN108329778A (en) * 2018-01-26 2018-07-27 德马科起重机械有限公司 A kind of production technology of diatom ooze, the compound indoor decorative paint of activated carbon
CN109111182A (en) * 2018-08-22 2019-01-01 浙江理工大学 A kind of modified diatom ooze coating of alloy network reinforcement type and its application method
CN109133784A (en) * 2018-08-31 2019-01-04 东莞市爱乐居环保科技有限公司 A kind of easily dry diatom ooze coating easy to clean
CN110342861A (en) * 2019-06-17 2019-10-18 福建追随者实业有限公司 A kind of diatom ooze coating

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CN101633782A (en) * 2009-08-21 2010-01-27 赵东育 Liquid active carbon colloid emulsion
CN104475094A (en) * 2014-12-10 2015-04-01 哈尔滨澳宝硅藻新材料有限公司 Diatom ooze wall material applied to non-photo-catalysis purification of formaldehyde in air at room temperature

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CN101633782A (en) * 2009-08-21 2010-01-27 赵东育 Liquid active carbon colloid emulsion
CN104475094A (en) * 2014-12-10 2015-04-01 哈尔滨澳宝硅藻新材料有限公司 Diatom ooze wall material applied to non-photo-catalysis purification of formaldehyde in air at room temperature

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105400304A (en) * 2015-12-15 2016-03-16 上海源由纳米科技有限公司 Nano composite diatom ooze coating and preparation method thereof
CN105504902A (en) * 2016-02-25 2016-04-20 陈丽娜 Diatom mud mixture and method for preparing same
CN105750486A (en) * 2016-04-27 2016-07-13 霍邱县鑫瑞金属制品有限责任公司 Water-based lost foam casting coating with active carbon nanoparticles for magnesium alloy casting and preparation method thereof
CN106189568A (en) * 2016-07-07 2016-12-07 山东冬瑞高新技术开发有限公司 A kind of environment-friendly interior wall coating of absorption degradation indoor formaldehyde and preparation method thereof
CN106883649A (en) * 2017-04-12 2017-06-23 程艳青 A kind of multi-functional environment-protection water paint and preparation method thereof
CN107244878A (en) * 2017-05-23 2017-10-13 欧亚绿邦(北京)科技有限公司 High scrubbing resistance diatom ooze and preparation method thereof
CN107189563A (en) * 2017-08-02 2017-09-22 合肥安力电力工程有限公司 A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof
CN107418265A (en) * 2017-09-30 2017-12-01 安徽琦家科技股份有限公司 A kind of antibacterial diatom ooze coating and preparation method thereof
CN107572871A (en) * 2017-10-20 2018-01-12 孙立民 One kind is used for environmental friendly indoor type sea bubble slime paint
CN107674465A (en) * 2017-11-28 2018-02-09 黄宇 A kind of preparation method for strengthening environmentally friendly diatom ooze coating
CN109251562B (en) * 2017-11-28 2020-09-25 盐池县荣桂昌食品科技有限公司 Preparation process of reinforced environment-friendly diatom ooze coating
CN107674465B (en) * 2017-11-28 2018-10-09 宁夏锐盛明杰知识产权咨询有限公司 A kind of preparation method of the environmentally friendly diatom ooze coating of enhancing
CN108659587A (en) * 2017-11-28 2018-10-16 天津中天精科科技有限公司 A kind of preparation process of the environmentally friendly diatom ooze coating of enhancing
CN109082147A (en) * 2017-11-28 2018-12-25 天津中天精科科技有限公司 It is a kind of for enhance environmental protection diatom ooze coating preparation method
CN108659587B (en) * 2017-11-28 2020-10-02 盐池县荣桂昌食品科技有限公司 Preparation process of reinforced environment-friendly diatom ooze coating
CN109082147B (en) * 2017-11-28 2020-10-02 吉林省绿森林环保科技有限公司 Preparation method of diatom ooze coating for enhancing environmental protection
CN109251562A (en) * 2017-11-28 2019-01-22 天津中天精科科技有限公司 Enhance the manufacture craft of environmentally friendly diatom ooze coating
WO2019104816A1 (en) * 2017-11-28 2019-06-06 黄宇 Method for preparing enhanced environmentally friendly diatom ooze coating
CN108329778A (en) * 2018-01-26 2018-07-27 德马科起重机械有限公司 A kind of production technology of diatom ooze, the compound indoor decorative paint of activated carbon
CN109111182A (en) * 2018-08-22 2019-01-01 浙江理工大学 A kind of modified diatom ooze coating of alloy network reinforcement type and its application method
CN109111182B (en) * 2018-08-22 2020-12-22 浙江理工大学 Alloy mesh reinforced modified diatom ooze coating and application method thereof
CN109133784A (en) * 2018-08-31 2019-01-04 东莞市爱乐居环保科技有限公司 A kind of easily dry diatom ooze coating easy to clean
CN110342861A (en) * 2019-06-17 2019-10-18 福建追随者实业有限公司 A kind of diatom ooze coating

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