CN107189563A - A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof - Google Patents
A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof Download PDFInfo
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- CN107189563A CN107189563A CN201710650141.1A CN201710650141A CN107189563A CN 107189563 A CN107189563 A CN 107189563A CN 201710650141 A CN201710650141 A CN 201710650141A CN 107189563 A CN107189563 A CN 107189563A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses the decorative material for wall surface that a kind of environmental protection removes formaldehyde, include the component of following weight proportion：20 40 parts of ethylene-vinyl acetate latex powder, 15 25 parts of polymer dispersion powder, 30 40 parts of dicalcium powder, 20 30 parts of perforate expanded perlite, 10 30 parts of diatom ooze, 15 30 parts of talcum powder, 10 20 parts of nano titanium oxide, 5 15 parts of nano silicon, 15 25 parts of active carbon nanoparticles, 5 10 parts of carboxylic and ylmethyl cellulose, 28 parts of tourmaline powder, 5 10 parts of modified meerschaum powder, 5 15 parts of surfactant, 38 parts of water reducer, 5 15 parts of defoamer, 40 60 parts of 4 10 parts of thickener and water.The present invention can effectively remove the pernicious gases such as formaldehyde, and environment friendly and pollution-free, with excellent water resistance, scrub resistance, thermal and insulating performance, the requirement of industry enough be met, with preferable application prospect.
Description
Technical field
The present invention relates to decorative material for wall surface technical field, and in particular to it is a kind of environmental protection except formaldehyde decorative material for wall surface and
Its preparation method.
Background technology
The time of people daily an average of about more than 80% is spent indoors.It is more existing with life style with producing
Dai Hua, more work and sports entertainment can all be carried out indoors, and the indoor activity time of such people is just more, even
Up to more than 93%.Therefore, IAQ just seems more closely more important to the relation of health.
With the indoor furniture manufactured more and more using composite board, floor, the material that interior decoration is used is more next
More complicated, the formaldehyde in these finishing materials, floor, furniture etc. can be evaporated into slowly in air, and influence is produced on health.
At present, the harmless treatment that interior decoration is carried out, is referred to by a series of measure at normal temperatures formaldehyde, benzene
Carbon dioxide and water are decomposed into Deng pollutant, non-secondary pollution.Current interior wall top grade decoration is main with various work except methanal paint
Property charcoal fire bamboo charcoal agent negative ion photocatalyst class emulsion paint, diatom ooze coating, based on artistic texture coating.And diatom ooze coating and work
Property charcoal class coating, except formaldehyde mainly uses the pure physisorption of activated carbon, its adsorb effective time it is short, absorptive capacity
It is small, it is difficult to rapidly and efficiently remove the pernicious gases such as formaldehyde, ammonia, benzene；And negative ion photocatalyst class coating is dense because of the release of anion
Degree and persistence are unstable, meanwhile, the mesh of air can just be played except formaldehyde and purified to the irradiation that photocatalyst needs stabilized light source
's.Therefore, these remove the defect that methanal paint all has DeGrain, it is difficult to meet market demands.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided the wall decoration material that a kind of environmental protection removes formaldehyde
Material and preparation method thereof, the ornament materials can effectively remove the pernicious gases such as formaldehyde, while the release anion beneficial to human body,
And it is environment friendly and pollution-free, with excellent water resistance, scrub resistance, thermal and insulating performance, the requirement of industry is enough met, with preferable
Application prospect.
The present invention is in order to solve the above technical problems, adopt the following technical scheme that：
A kind of environmental protection removes the decorative material for wall surface of formaldehyde, includes the component of following weight proportion：Ethene-vinyl acetate latex powder
20-40 parts, 15-25 parts of polymer dispersion powder, 30-40 parts of dicalcium powder, 20-30 parts of perforate expanded perlite, diatom ooze 10-30
Part, 15-30 parts of talcum powder, 10-20 parts of nano titanium oxide, 5-15 parts of nano silicon, 15-25 parts of active carbon nanoparticles, carboxylic
And 5-10 parts of ylmethyl cellulose, 2-8 parts of tourmaline powder, 5-10 parts of modified meerschaum powder, 5-15 parts of surfactant, water reducer
40-60 parts of 3-8 parts, 5-15 parts of defoamer, 4-10 parts of thickener and water.
It is preferred that, 30 parts of the ethene-vinyl acetate latex powder, 20 parts of polymer dispersion powder, 35 parts of dicalcium powder, perforate are swollen
Swollen 25 parts of perlite, 20 parts of diatom ooze, 23 parts of talcum powder, 15 parts of nano titanium oxide, 10 parts of nano silicon, nano active
20 parts of charcoal, carboxylic and 7.5 parts of ylmethyl cellulose, 5 parts of tourmaline powder, 7.5 parts of modified meerschaum powder, 10 parts of surfactant, subtract
50 parts of 5.5 parts of aqua, 10 parts of defoamer, 7 parts of thickener and water.
It is preferred that, the average grain diameter of the nano titanium oxide is 50-70nm；The average grain diameter of the nano silicon
For 40-60nm；The average grain diameter of the active carbon nanoparticles is 20-30nm.
It is preferred that, the preparation method of the modified meerschaum powder is：Sepiolite is placed in 300-500 DEG C of kiln kiln roasting 1-
3h, attrition grinding into 100-200 mesh powder, it is finely ground after produce modified meerschaum powder.
It is preferred that, the surfactant is that octyl phenyl polyoxyethylene ether, cetyl trimethylammonium bromide or two are pungent
Base sodium sulfosuccinate.
It is preferred that, the water reducer is modified polycarboxylic acid fan.
It is preferred that, the defoamer is polysiloxanes.
It is preferred that, the thickener is that one or both of cellulose ether, starch ether, polyacrylamide are mixed above
Thing.
A kind of environmental protection comprises the following steps except the preparation method of the decorative material for wall surface of formaldehyde：
（1）Dicalcium powder, perforate expanded perlite, diatom ooze, talcum powder, nano titanium oxide, nano silicon, nanometer are lived
Property charcoal, tourmaline powder and modified meerschaum powder are put into ball mill, and then ball milling product is transferred to mixing by ball milling 20-40min
In stirring, the water and surfactant of 2/3 mass are added, 1-2h is stirred with 1000-1200r/min rotating speed, is taken out, then surpass
Sound disperses 20-40min, obtains dispersion liquid；
（2）By step（1）Gained dispersion liquid is placed in reactor, is heated to 70-80 DEG C, 10-20min is kept at this temperature,
Ethene-vinyl acetate latex powder is slow added into, with 1500-1600r/min stirring reaction 1-3h, dispersible breast is slow added into
Rubber powder, 70-80 DEG C of back flow reaction 40-60min of keeping temperature, is then cooled to room temperature, obtains compound；
（3）In step（2）The water of other 1/3 mass is added in gained compound, stir, add surfactant, water reducer,
Defoamer and thickener, 30-50min is stirred with 800-1000r/min, produces the wall decoration material that described environmental protection removes formaldehyde
Material.
Compared with prior art, the present invention has following beneficial effect：The present invention provides the wall that a kind of environmental protection removes formaldehyde
Face ornament materials and preparation method thereof, can effectively remove the pernicious gases such as formaldehyde, while the release anion beneficial to human body, and
It is environment friendly and pollution-free, with excellent water resistance, scrub resistance, thermal and insulating performance, the requirement of industry is enough met, with preferable
Application prospect, concrete condition is as follows：
（1）The environmental protection of the present invention is except the perforate expanded perlite in the decorative material for wall surface of formaldehyde by addition, nanometer titanium dioxide
Titanium, nano silicon, active carbon nanoparticles and modified meerschaum powder, can effectively remove harmful gas such as formaldehyde, ammonia, benzene in air
Body, while the tourmaline powder added, which can discharge, is beneficial to the anion of health, makes indoor air away from pollution；
（2）The present invention environmental protection except formaldehyde decorative material for wall surface in most of compositions be inorganic material, it is environmentally safe, together
When reinforcement material the performance such as intensity, water resistance, scrub resistance, insulation；
（3）The environmental protection of the present invention is good except the decorative material for wall surface application property of formaldehyde, and adhesive force is strong, can be directly used for various base materials,
Surfacing after use, construction is directly smeared, color is natural.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
A kind of environmental protection removes the decorative material for wall surface of formaldehyde, includes the component of following weight proportion：Ethene-vinyl acetate latex powder 30
Part, 20 parts of polymer dispersion powder, 35 parts of dicalcium powder, 25 parts of perforate expanded perlite, 20 parts of diatom ooze, talcum powder 23 part, nanometer
15 parts of titanium dioxide, 10 parts of nano silicon, 20 parts of active carbon nanoparticles, carboxylic and 7.5 parts of ylmethyl cellulose, tourmaline powder 5
Part, 7.5 parts of modified meerschaum powder, 10 parts of surfactant, 5.5 parts of water reducer, 10 parts of defoamer, 7 parts of thickener and 50 parts of water.
Wherein, the average grain diameter of the nano titanium oxide is 60nm；The average grain diameter of the nano silicon is
50nm；The average grain diameter of the active carbon nanoparticles is 25nm.
Wherein, the preparation method of the modified meerschaum powder is：Sepiolite is placed in 400 DEG C of kiln kiln roasting 2h, crushed
Grind to form 150 mesh powder, it is finely ground after produce modified meerschaum powder.
Wherein, the surfactant is octyl phenyl polyoxyethylene ether, cetyl trimethylammonium bromide or dioctyl
Sodium sulfosuccinate.
Wherein, the water reducer is modified polycarboxylic acid fan.
Wherein, the defoamer is polysiloxanes.
Wherein, the thickener is one or both of cellulose ether, starch ether, polyacrylamide thing mixed above.
A kind of environmental protection comprises the following steps except the preparation method of the decorative material for wall surface of formaldehyde：
（1）Dicalcium powder, perforate expanded perlite, diatom ooze, talcum powder, nano titanium oxide, nano silicon, nanometer are lived
Property charcoal, tourmaline powder and modified meerschaum powder are put into ball mill, and then ball milling product is transferred to mixing and stirred by ball milling 30min
In mixing, the water and surfactant of 2/3 mass are added, 1.5h is stirred with 1100r/min rotating speed, is taken out, then ultrasonic disperse
30min, obtains dispersion liquid；
（2）By step（1）Gained dispersion liquid is placed in reactor, is heated to 75 DEG C, and 15min is kept at this temperature, then slowly
Ethene-vinyl acetate latex powder is added, with 1550r/min stirring reaction 2h, polymer dispersion powder, keeping temperature is slow added into
75 DEG C of back flow reaction 50min, are then cooled to room temperature, obtain compound；
（3）In step（2）The water of other 1/3 mass is added in gained compound, stir, add surfactant, water reducer,
Defoamer and thickener, 40min is stirred with 900r/min, produces the decorative material for wall surface that described environmental protection removes formaldehyde.
Embodiment 2
A kind of environmental protection removes the decorative material for wall surface of formaldehyde, includes the component of following weight proportion：Ethene-vinyl acetate latex powder 20
Part, 15 parts of polymer dispersion powder, 30 parts of dicalcium powder, 20 parts of perforate expanded perlite, 10 parts of diatom ooze, talcum powder 15 part, nanometer
10 parts of titanium dioxide, 5 parts of nano silicon, 15 parts of active carbon nanoparticles, carboxylic and 5 parts of ylmethyl cellulose, 2 parts of tourmaline powder,
40 parts of 5 parts of modified meerschaum powder, 5 parts of surfactant, 3 parts of water reducer, 5 parts of defoamer, 4 parts of thickener and water.
Wherein, the average grain diameter of the nano titanium oxide is 50nm；The average grain diameter of the nano silicon is
40nm；The average grain diameter of the active carbon nanoparticles is 20nm.
Wherein, the preparation method of the modified meerschaum powder is：Sepiolite is placed in 300 DEG C of kiln kiln roasting 1h, crushed
Grind to form 100 mesh powder, it is finely ground after produce modified meerschaum powder.
Wherein, the surfactant is octyl phenyl polyoxyethylene ether, cetyl trimethylammonium bromide or dioctyl
Sodium sulfosuccinate.
Wherein, the water reducer is modified polycarboxylic acid fan.
Wherein, the defoamer is polysiloxanes.
Wherein, the thickener is one or both of cellulose ether, starch ether, polyacrylamide thing mixed above.
A kind of environmental protection comprises the following steps except the preparation method of the decorative material for wall surface of formaldehyde：
（1）Dicalcium powder, perforate expanded perlite, diatom ooze, talcum powder, nano titanium oxide, nano silicon, nanometer are lived
Property charcoal, tourmaline powder and modified meerschaum powder are put into ball mill, and then ball milling product is transferred to mixing and stirred by ball milling 20min
In mixing, the water and surfactant of 2/3 mass are added, 1-2h is stirred with 1000r/min rotating speed, is taken out, then ultrasonic disperse
20min, obtains dispersion liquid；
（2）By step（1）Gained dispersion liquid is placed in reactor, is heated to 70 DEG C, 10-20min is kept at this temperature, then delay
It is slow to add ethene-vinyl acetate latex powder, with 1500r/min stirring reaction 1h, polymer dispersion powder is slow added into, temperature is kept
70 DEG C of back flow reaction 40min are spent, room temperature is then cooled to, obtains compound；
（3）In step（2）The water of other 1/3 mass is added in gained compound, stir, add surfactant, water reducer,
Defoamer and thickener, 30min is stirred with 800r/min, produces the decorative material for wall surface that described environmental protection removes formaldehyde.
Embodiment 3
A kind of environmental protection removes the decorative material for wall surface of formaldehyde, includes the component of following weight proportion：Ethene-vinyl acetate latex powder 40
Part, 25 parts of polymer dispersion powder, 40 parts of dicalcium powder, 30 parts of perforate expanded perlite, 30 parts of diatom ooze, talcum powder 30 part, nanometer
20 parts of titanium dioxide, 15 parts of nano silicon, 25 parts of active carbon nanoparticles, carboxylic and 10 parts of ylmethyl cellulose, tourmaline powder 8
Part, 10 parts of modified meerschaum powder, 15 parts of surfactant, 8 parts of water reducer, 15 parts of defoamer, 10 parts of thickener and 60 parts of water.
Wherein, the average grain diameter of the nano titanium oxide is 70nm；The average grain diameter of the nano silicon is
60nm；The average grain diameter of the active carbon nanoparticles is 30nm.
Wherein, the preparation method of the modified meerschaum powder is：Sepiolite is placed in 500 DEG C of kiln kiln roasting 3h, crushed
Grind to form 200 mesh powder, it is finely ground after produce modified meerschaum powder.
Wherein, the surfactant is octyl phenyl polyoxyethylene ether, cetyl trimethylammonium bromide or dioctyl
Sodium sulfosuccinate.
Wherein, the water reducer is modified polycarboxylic acid fan.
Wherein, the defoamer is polysiloxanes.
Wherein, the thickener is one or both of cellulose ether, starch ether, polyacrylamide thing mixed above.
A kind of environmental protection comprises the following steps except the preparation method of the decorative material for wall surface of formaldehyde：
（1）Dicalcium powder, perforate expanded perlite, diatom ooze, talcum powder, nano titanium oxide, nano silicon, nanometer are lived
Property charcoal, tourmaline powder and modified meerschaum powder are put into ball mill, and then ball milling product is transferred to mixing and stirred by ball milling 40min
In mixing, the water and surfactant of 2/3 mass are added, 2h is stirred with 1200r/min rotating speed, is taken out, then ultrasonic disperse
40min, obtains dispersion liquid；
（2）By step（1）Gained dispersion liquid is placed in reactor, is heated to 80 DEG C, and 20min is kept at this temperature, then slowly
Ethene-vinyl acetate latex powder is added, with 1600r/min stirring reaction 3h, polymer dispersion powder, keeping temperature is slow added into
80 DEG C of back flow reaction 60min, are then cooled to room temperature, obtain compound；
（3）In step（2）The water of other 1/3 mass is added in gained compound, stir, add surfactant, water reducer,
Defoamer and thickener, 50min is stirred with 1000r/min, produces the decorative material for wall surface that described environmental protection removes formaldehyde.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (9)
1. a kind of environmental protection removes the decorative material for wall surface of formaldehyde, it is characterised in that include the component of following weight proportion：Ethene-vinegar
Sour 20-40 parts of ethene latex powder, 15-25 parts of polymer dispersion powder, 30-40 parts of dicalcium powder, 20-30 parts of perforate expanded perlite,
10-30 parts of diatom ooze, 15-30 parts of talcum powder, 10-20 parts of nano titanium oxide, 5-15 parts of nano silicon, active carbon nanoparticles
15-25 parts, carboxylic and 5-10 parts of ylmethyl cellulose, 2-8 parts of tourmaline powder, 5-10 parts of modified meerschaum powder, surfactant 5-
40-60 parts of 15 parts, 3-8 parts of water reducer, 5-15 parts of defoamer, 4-10 parts of thickener and water.
2. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the ethyl vinyl acetate second
30 parts of alkene latex powder, 20 parts of polymer dispersion powder, 35 parts of dicalcium powder, 25 parts of perforate expanded perlite, 20 parts of diatom ooze, talcum powder
7.5 parts of 23 parts, 15 parts of nano titanium oxide, 10 parts of nano silicon, 20 parts of active carbon nanoparticles, carboxylic and ylmethyl cellulose,
5 parts of tourmaline powder, 7.5 parts of modified meerschaum powder, 10 parts of surfactant, 5.5 parts of water reducer, 10 parts of defoamer, 7 parts of thickener
With 50 parts of water.
3. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the nano titanium oxide
Average grain diameter be 50-70nm；The average grain diameter of the nano silicon is 40-60nm；The active carbon nanoparticles are averaged
Particle diameter is 20-30nm.
4. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the modified meerschaum powder
Preparation method be：Sepiolite is placed in 300-500 DEG C of kiln kiln roasting 1-3h, attrition grinding is finely ground into 100-200 mesh powder
After produce modified meerschaum powder.
5. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the surfactant is
Octyl phenyl polyoxyethylene ether, cetyl trimethylammonium bromide or dioctyl succinate disulfonate acid.
6. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the water reducer is modification
Polycarboxylic acids fan.
7. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the defoamer is poly- silicon
Oxygen alkane.
8. environmental protection according to claim 1 removes the decorative material for wall surface of formaldehyde, it is characterised in that the thickener is fiber
One or both of plain ether, starch ether, polyacrylamide thing mixed above.
9. a kind of environmental protection according to claim any one of 1-8 is except the preparation method of the decorative material for wall surface of formaldehyde, it is special
Levy and be, comprise the following steps：
（1）Dicalcium powder, perforate expanded perlite, diatom ooze, talcum powder, nano titanium oxide, nano silicon, nanometer are lived
Property charcoal, tourmaline powder and modified meerschaum powder are put into ball mill, and then ball milling product is transferred to mixing by ball milling 20-40min
In stirring, the water and surfactant of 2/3 mass are added, 1-2h is stirred with 1000-1200r/min rotating speed, is taken out, then surpass
Sound disperses 20-40min, obtains dispersion liquid；
（2）By step（1）Gained dispersion liquid is placed in reactor, is heated to 70-80 DEG C, 10-20min is kept at this temperature,
Ethene-vinyl acetate latex powder is slow added into, with 1500-1600r/min stirring reaction 1-3h, dispersible breast is slow added into
Rubber powder, 70-80 DEG C of back flow reaction 40-60min of keeping temperature, is then cooled to room temperature, obtains compound；
（3）In step（2）The water of other 1/3 mass is added in gained compound, stir, add surfactant, water reducer,
Defoamer and thickener, 30-50min is stirred with 800-1000r/min, produces the wall decoration material that described environmental protection removes formaldehyde
Material.
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| CN201710650141.1A CN107189563A (en) | 2017-08-02 | 2017-08-02 | A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof |
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| CN201710650141.1A CN107189563A (en) | 2017-08-02 | 2017-08-02 | A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof |
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| CN108166330A (en) * | 2017-12-29 | 2018-06-15 | 重庆家宝装饰材料有限公司 | One kind is except formaldehyde PVC wallpaper and preparation method thereof |
| CN108329778A (en) * | 2018-01-26 | 2018-07-27 | 德马科起重机械有限公司 | A kind of production technology of diatom ooze, the compound indoor decorative paint of activated carbon |
| CN108342130A (en) * | 2018-01-26 | 2018-07-31 | 德马科起重机械有限公司 | A kind of diatom Fender formaldehyde indoor coating preparation process |
| CN108691093A (en) * | 2018-06-21 | 2018-10-23 | 冷纯廷 | A kind of pavement and its production technology containing nano-powder material |
| CN108854266A (en) * | 2018-07-18 | 2018-11-23 | 大连神润新材料有限公司 | The preparation method of nana intelligent integrated filter used for automobile air conditioning |
| CN109130373A (en) * | 2018-07-27 | 2019-01-04 | 大连神润新材料有限公司 | The preparation method of the nonmetallic gadget material of nana intelligent automobile inside |
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| CN108329778A (en) * | 2018-01-26 | 2018-07-27 | 德马科起重机械有限公司 | A kind of production technology of diatom ooze, the compound indoor decorative paint of activated carbon |
| CN108342130A (en) * | 2018-01-26 | 2018-07-31 | 德马科起重机械有限公司 | A kind of diatom Fender formaldehyde indoor coating preparation process |
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