CN109054559A - A kind of preparation method of the ventilative multicolor finish of high adsorption - Google Patents

A kind of preparation method of the ventilative multicolor finish of high adsorption Download PDF

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Publication number
CN109054559A
CN109054559A CN201810882587.1A CN201810882587A CN109054559A CN 109054559 A CN109054559 A CN 109054559A CN 201810882587 A CN201810882587 A CN 201810882587A CN 109054559 A CN109054559 A CN 109054559A
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China
Prior art keywords
powder
preparation
ball milling
added
high adsorption
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Pending
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CN201810882587.1A
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Chinese (zh)
Inventor
王志忠
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Dewitt Coatings Ltd
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Dewitt Coatings Ltd
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Priority to CN201810882587.1A priority Critical patent/CN109054559A/en
Publication of CN109054559A publication Critical patent/CN109054559A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D197/00Coating compositions based on lignin-containing materials
    • C09D197/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses a kind of preparation method of the ventilative multicolor finish of high adsorption, after crushing after wood waste material and sawdust are recycled, enzymatic hydrolysis alkali bubble is carried out, wood powder is made in drying;Sepiolite, active powdered carbon etc. are mixed with silane coupling agent simultaneously, atoleine ball milling, which is added, adds water to be prepared by mixing into suspension, by suitable adjuvant mixed dissolution, it is stirred evenly with acrylic acid ester emulsion, colored paint is added under low speed ball milling after filtering, it breathes freely multicolor finish with the wood powder of preparation and absorption particle ball milling to get high adsorption.The present invention recycles wood waste material and sawdust is prepared into the wood powder of anti-corruption, and the paint colors being mixed with using sepiolite and anion powder etc. are vivid, can carry out the harmful substance in absorption air, extend the service life of coating, has decorative well.

Description

A kind of preparation method of the ventilative multicolor finish of high adsorption
Technical field
The invention belongs to coating manufacture fields, and in particular to a kind of preparation method of the ventilative multicolor finish of high adsorption.
Background technique
Timber is a kind of biomaterial easy to process, intensity is relatively high, as industry and life material than purposes of the same race Other materials can more highlight the superiority of carbon fixation and emission reduction, low-carbon energy-saving, to be widely used in a variety of applications.Existing timber plantation Growth be difficult to meet ever-increasing Wood demand.The residue that wood waste material and sawdust are processed as timber, also with Timber usage amount is continuously increased and increases, and recycle can economize on resources.Sepiolite is a kind of tool layer chain structure Aqueous rich magnesium silicate clay mineral, sepiolite has the performances such as extremely strong absorption, decoloration and dispersion, also has high heat steady Qualitative, it is a kind of natural environmental-protective powder that for heat-resisting quantity up to 1500 ~ 1700 DEG C, formative nature, insulating properties, salt resistance degree are all very good Decorative material for wall surface is the upgraded product of diatom ooze, is widely used in the wall decoration of tooling and house ornamentation.
Summary of the invention
The present invention provides a kind of preparation method of ventilative multicolor finish of high adsorption, and the present invention recycles wood waste material and sawdust It is prepared into the wood powder of anti-corruption, the paint colors being mixed with using sepiolite and anion powder etc. are vivid, can be adsorbed Harmful substance in air extends the service life of coating, has decorative well.
The present invention is achieved by the following technical solutions:
A kind of preparation method of the ventilative multicolor finish of high adsorption, which comprises the following steps:
(1) wood waste material and sawdust recycling and reusing
A) it after being recycled wood waste material and sawdust, is ground into after wood powder after drying the stirring of starch solution high speed being added, adds Enter cellulase and after lipase immersion 2-4 hours, is dried after filtering;
B) wood powder dried after filtering is impregnated 2-4 hours in plant ash solution, is neutralized later with dilute hydrochloric acid, is washed till with clear water Neutrality dries and wood powder is made;
(2) preparation of particle is adsorbed
A) by sepiolite, active powdered carbon, graphene oxide, negative ion powder, bentonite and nano-sized clay and silane coupling agent After being mixed, suitable atoleine progress ball milling is added and crosses 200 meshes;
B) by the powder after ball milling with 1:(3-4) solid-liquid ratio add water to mix, be sufficiently stirred to form suspension at room temperature;
(3) lotion is prepared
A) it is low that suitable anti-settling agent, reactive diluent, diatomite, defoaming agent and the suitable water dispenser tool of levelling agent mixing addition are weighed Speed stirring to solid is completely dissolved;
B) mixing liquid dissolved with anti-settling agent etc. is added to acrylic acid ester emulsion to be added in agitator tank, is stirred evenly, then plus Enter thickener, regulation system moderate viscosity, filtering is for use;
(4) coating is prepared
The resulting filtered lotion of step (3) is then added in ball mill, colored paint is added under low speed ball milling, adds step Suddenly (1) and step (2) gains, high speed ball milling until system is uniform, breathe freely multicolor finish to get high adsorption by moderate viscosity.
The negative ion powder is ultra-fine negative ion powder, nanometer anion powder or combinations thereof.
The low speed ball milling is 20-50 revs/min of ball, is at a high speed 200-500 revs/min.
The defoaming agent is organic silicon defoaming agent, mineral oil defoaming agent or combinations thereof.
The invention has the advantages that
After the present invention crushes after recycling wood waste material and sawdust, enzymatic hydrolysis alkali bubble is carried out, dries and wood powder is made;It simultaneously will be extra large Afrodite, active powdered carbon etc. are mixed with silane coupling agent, atoleine ball milling are added, water is added to be prepared by mixing into suspension, will be suitable Adjuvant mixed dissolution, stirs evenly with acrylic acid ester emulsion, and colored paint is added under low speed ball milling after filtering, with the wood powder of preparation with Absorption particle ball milling is breathed freely multicolor finish to get high adsorption.After the present invention recycles wood waste material and sawdust crushing, with oxygen Change starch solution mixing, increase its fluffy degree, by the grease of cellulase and lipase treatment removal wood powder, is conducive to improve The anti-corruption performance of wood powder, extends the service life of entire coating, has better feel, sepiolite clay after the coating use made The poisonous and hazardous nanoscale small molecule polar substances such as benzene, ammonia in air can be adsorbed with active carbon, anion powder, and Anion powder can also sustained release anion, can effectively improve indoor air quality, dispel formaldehyde in indoor air, toluene, To adsorb particle after the harmful pollutants such as ammonia, with atoleine ball milling with apparent hydrophobicity, the colored paint of addition It may make the coating of preparation that there is dicoration, the present invention recycles wood waste material and sawdust is prepared into the wood powder of anti-corruption, utilizes sea The paint colors that afrodite and anion powder etc. are mixed with are vivid, can carry out the harmful substance in absorption air, extend coating Service life, have decorative well.
Specific embodiment
A kind of preparation method of the ventilative multicolor finish of high adsorption, which comprises the following steps:
(1) wood waste material and sawdust recycling and reusing
A) it after being recycled wood waste material and sawdust, is ground into after wood powder after drying the stirring of starch solution high speed being added, adds Enter cellulase and after lipase immersion 2-4 hours, is dried after filtering;
B) wood powder dried after filtering is impregnated 2-4 hours in plant ash solution, is neutralized later with dilute hydrochloric acid, is washed till with clear water Neutrality dries and wood powder is made;
(2) preparation of particle is adsorbed
A) by sepiolite, active powdered carbon, graphene oxide, negative ion powder, bentonite and nano-sized clay and silane coupling agent After being mixed, suitable atoleine progress ball milling is added and crosses 200 meshes;
B) by the powder after ball milling with 1:(3-4) solid-liquid ratio add water to mix, be sufficiently stirred to form suspension at room temperature;
(3) lotion is prepared
A) it is low that suitable anti-settling agent, reactive diluent, diatomite, defoaming agent and the suitable water dispenser tool of levelling agent mixing addition are weighed Speed stirring to solid is completely dissolved;
B) mixing liquid dissolved with anti-settling agent etc. is added to acrylic acid ester emulsion to be added in agitator tank, is stirred evenly, then plus Enter thickener, regulation system moderate viscosity, filtering is for use;
(4) coating is prepared
The resulting filtered lotion of step (3) is then added in ball mill, colored paint is added under low speed ball milling, adds step Suddenly (1) and step (2) gains, high speed ball milling until system is uniform, breathe freely multicolor finish to get high adsorption by moderate viscosity.
The negative ion powder is ultra-fine negative ion powder, nanometer anion powder or combinations thereof.
The low speed ball milling is 20-50 revs/min of ball, is at a high speed 200-500 revs/min.
The defoaming agent is organic silicon defoaming agent, mineral oil defoaming agent or combinations thereof.

Claims (4)

  1. The preparation method of multicolor finish 1. a kind of high adsorption is breathed freely, which comprises the following steps:
    (1) wood waste material and sawdust recycling and reusing
    A) it after being recycled wood waste material and sawdust, is ground into after wood powder after drying the stirring of starch solution high speed being added, adds Enter cellulase and after lipase immersion 2-4 hours, is dried after filtering;
    B) wood powder dried after filtering is impregnated 2-4 hours in plant ash solution, is neutralized later with dilute hydrochloric acid, is washed till with clear water Neutrality dries and wood powder is made;
    (2) preparation of particle is adsorbed
    A) by sepiolite, active powdered carbon, graphene oxide, negative ion powder, bentonite and nano-sized clay and silane coupling agent After being mixed, suitable atoleine progress ball milling is added and crosses 200 meshes;
    B) by the powder after ball milling with 1:(3-4) solid-liquid ratio add water to mix, be sufficiently stirred to form suspension at room temperature;
    (3) lotion is prepared
    A) it is low that suitable anti-settling agent, reactive diluent, diatomite, defoaming agent and the suitable water dispenser tool of levelling agent mixing addition are weighed Speed stirring to solid is completely dissolved;
    B) mixing liquid dissolved with anti-settling agent etc. is added to acrylic acid ester emulsion to be added in agitator tank, is stirred evenly, then plus Enter thickener, regulation system moderate viscosity, filtering is for use;
    (4) coating is prepared
    The resulting filtered lotion of step (3) is then added in ball mill, colored paint is added under low speed ball milling, adds step Suddenly (1) and step (2) gains, high speed ball milling until system is uniform, breathe freely multicolor finish to get high adsorption by moderate viscosity.
  2. 2. the preparation method of the ventilative multicolor finish of a kind of high adsorption according to claim 1, which is characterized in that the anion Powder is ultra-fine negative ion powder, nanometer anion powder or combinations thereof.
  3. 3. the preparation method of the ventilative multicolor finish of a kind of high adsorption according to claim 1, which is characterized in that the low speed ball Mill is 20-50 revs/min of ball, is at a high speed 200-500 revs/min.
  4. 4. the preparation method of the ventilative multicolor finish of a kind of high adsorption according to claim 1, which is characterized in that the defoaming agent For organic silicon defoaming agent, mineral oil defoaming agent or combinations thereof.
CN201810882587.1A 2018-08-06 2018-08-06 A kind of preparation method of the ventilative multicolor finish of high adsorption Pending CN109054559A (en)

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CN201810882587.1A CN109054559A (en) 2018-08-06 2018-08-06 A kind of preparation method of the ventilative multicolor finish of high adsorption

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810882587.1A CN109054559A (en) 2018-08-06 2018-08-06 A kind of preparation method of the ventilative multicolor finish of high adsorption

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Publication Number Publication Date
CN109054559A true CN109054559A (en) 2018-12-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110586032A (en) * 2019-09-17 2019-12-20 胡子林 Indoor air purification material for removing formaldehyde and generating negative ions and preparation thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674530A (en) * 2017-10-18 2018-02-09 佛山市金蓝领教育科技有限公司 A kind of colorful imitative exterior wall tile coating containing anion powder and preparation method thereof
CN107779026A (en) * 2017-11-10 2018-03-09 清远市思晴新材料科技有限公司 A kind of colorful imitative green inner wall paint of Pesticidal and sterilizing and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674530A (en) * 2017-10-18 2018-02-09 佛山市金蓝领教育科技有限公司 A kind of colorful imitative exterior wall tile coating containing anion powder and preparation method thereof
CN107779026A (en) * 2017-11-10 2018-03-09 清远市思晴新材料科技有限公司 A kind of colorful imitative green inner wall paint of Pesticidal and sterilizing and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110586032A (en) * 2019-09-17 2019-12-20 胡子林 Indoor air purification material for removing formaldehyde and generating negative ions and preparation thereof

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Application publication date: 20181221