CN106833237A - A kind of photocatalysis dope for inner wall of architecture and preparation method thereof - Google Patents

A kind of photocatalysis dope for inner wall of architecture and preparation method thereof Download PDF

Info

Publication number
CN106833237A
CN106833237A CN201710197214.6A CN201710197214A CN106833237A CN 106833237 A CN106833237 A CN 106833237A CN 201710197214 A CN201710197214 A CN 201710197214A CN 106833237 A CN106833237 A CN 106833237A
Authority
CN
China
Prior art keywords
parts
preparation
photocatalysis
dope
architecture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710197214.6A
Other languages
Chinese (zh)
Inventor
王子龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Hongye Energy Technology Co Ltd
Original Assignee
Guangxi Hongye Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Hongye Energy Technology Co Ltd filed Critical Guangxi Hongye Energy Technology Co Ltd
Priority to CN201710197214.6A priority Critical patent/CN106833237A/en
Publication of CN106833237A publication Critical patent/CN106833237A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/02—Cellulose; Modified cellulose
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1618—Non-macromolecular compounds inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Abstract

The present invention discloses a kind of photocatalysis dope for inner wall of architecture and preparation method thereof, and the photocatalysis dope for inner wall of architecture is mainly made up of following raw material：Nano composite material, silicone acrylic emulsion, titanium dioxide, corundum-mullite sand, haydite, defoamer, coalescents, lepidolite, rhodonite, paper pulp, oxidized paraffin wax soap, binding agent；The water is 1 with base-material ratio：1.0~1.2.Its preparation method is：The preparation of nano composite material；The preparation of finished product.It is characteristic of the invention that：Coating of the present invention can be decomposed or be oxidized to water and carbon dioxide etc. to various organic or inorganic pollutants at room temperature using light, and energy consumption is low, easy to operate, except cleanliness is high, and flintiness is big, and will not shell peeling, and luster performance does not take off change for a long time.

Description

A kind of photocatalysis dope for inner wall of architecture and preparation method thereof
【Technical field】
The present invention relates to construction material, more particularly to a kind of photocatalysis dope for inner wall of architecture and preparation method thereof.
【Background technology】
With the improvement of people ' s living standards, the room for being caused by the indoor life of interior decoration, furniture material and people Environment pollution problem increasingly causes the extensive attention and concern of people, and indoor pollution is increasingly becoming social hotspots.Existing market On, it is most of also to rest on the release for there was only a small amount of volatile toxic substance for the environmental protection of indoor wall coating Wall covering, and for the environment-friendly type coating of requirements at the higher level, in the market is still more rare.
Light catalyzed coating can directly utilize the ultraviolet light including various approach including sunshine, at room temperature to various organic Or inorganic pollution is decomposed or aoxidized, water and carbon dioxide etc. are made, reach the effect for removing these pollutants.Light Catalysis activity coating is to be combined nano-particle phase and coating composition and obtain, and has the properties of many uniquenesses due to nano material, Such as small-size effect, skin effect, quantum size effect, so that assigning coating is different from conventional optics, electricity and magnetics Performance, but also the mechanical properties such as intensity, hardness, wearability, the scoring resistance of coating can be improved.Simultaneously because nano material Photocatalytic activity, in coating introduce nano-particle phase so that coating also obtains photocatalytic activity, reached with this environmental protection Purpose.But the photochemical catalyst in the light catalyzed coating of in the market loses photocatalytic due to being covered by coating composition mostly Energy.
【The content of the invention】
It is an object of the invention to provide a kind of photocatalysis dope for inner wall of architecture and preparation method thereof, the coating can be utilized Light is decomposed or is oxidized to water and carbon dioxide etc. to various organic or inorganic pollutants at room temperature, energy consumption is low, easy to operate, Except cleanliness is high, pollutant especially special to some has very prominent removal effect, and non-secondary pollution.
A kind of technical scheme of photocatalysis dope for inner wall of architecture of the present invention is realized in：A kind of photocatalysis inner wall of building Coating, including base-material and water, the base-material are mainly made up of by weight following material：20~30 parts of nano composite material, silicon 60~80 parts of acrylic emulsion, 30~40 parts of titanium dioxide, 20~28 parts of corundum-mullite sand, 15~25 parts of haydite, 2~4 parts of defoamer, 4~8 parts of coalescents, 15~25 parts of lepidolite, 10~20 parts of rhodonite, 20~32 parts of paper pulp, oxidized paraffin wax soap 6~12 Part, 40~64 parts of binding agent；The water is 1 with base-material ratio：1.0~1.2.
And, the weight portion of the photocatalysis dope for inner wall of architecture is preferably：26 parts of nano composite material, silicone acrylic emulsion 70 Part, 38 parts of titanium dioxide, 26 parts of corundum-mullite sand, 20 parts of haydite, 4 parts of defoamer, 6 parts of coalescents, 18 parts of lepidolite, rose 15 parts of pyroxene, 28 parts of paper pulp, 10 parts of oxidized paraffin wax soap, 56 parts of binding agent；The water is 1 with base-material ratio：1.1.
Above-mentioned nano composite material is：10~16 parts of nano titanium oxide, 20~32 parts of dispersant, 5~7 parts of water, the third two 3~5 parts of alcohol.
Above-mentioned photocatalysis dope for inner wall of architecture is through the following steps that to realize：
(1) preparation of nano composite material：Nano titanium oxide, dispersant, propane diols and water are fully ground and are stirred Mix and obtain；
(2) preparation of finished product：Titanium dioxide, corundum-mullite sand, water, haydite, defoamer are put into ball mill and are stirred 3.5h；Coalescents, silicone acrylic emulsion, paper pulp, oxidized paraffin wax soap are subsequently adding, continue to stir 1h；It is eventually adding defoamer, bonds Agent, nano composite material continue to stir 1h, finished product.
Preferably, the nano silicon in step (1) is obtained using sol-gel process：With metatitanic acid fourth fat：Absolute ethyl alcohol =1：5 (volume ratios) are mixed into solution A, absolute ethyl alcohol：Glacial acetic acid：Water=4：1：1 (volume ratio) is mixed into solution B, by solution A It is slowly dropped into solution B and is stirred vigorously, can obtain nano-TiO2 hydrosol, standing becomes gel time for 18h, obtained gel In 400 DEG C of calcination 1h it is then that can obtain nano titanium oxide with Muffle furnace in 65 DEG C of dryings to constant weight.
Preferably, the rotating speed of ball mill is 660r/min in step (2).
Compared with prior art, the present invention has advantages below：
(1) present invention employs nano composite material, with environmental protection, health is protected, with long-term to interior The advantages of killing bacterium, virus, absorb decomposing organic pollutant, non-secondary pollution；
(2) adhesive force is strong, and flintiness is big, and will not shell peeling, and luster performance does not take off change for a long time；
Base-material selected by the present invention is silicone acrylic emulsion, it except have pure-acrylic emulsion and organic siliconresin concurrently characteristic (such as Good fast light weatherability, resistance to acids and bases) also have outward fabulous stain resistant resistance to ag(e)ing, high temperature not after tack the features such as.
【Specific embodiment】
The following examples can help those skilled in the art that the present invention is more completely understood, but cannot be with any Mode limits the present invention.
Embodiment 1
A kind of photocatalysis dope for inner wall of architecture, including base-material and water, the base-material are main by following material composition：Nanometer is multiple 20 parts of condensation material, 60 parts of silicone acrylic emulsion, 40 parts of titanium dioxide, 20 parts of corundum-mullite sand, 25 parts of haydite, 2 parts of defoamer, film forming are helped 4 parts of agent, 25 parts of lepidolite, 10 parts of rhodonite, 20 parts of paper pulp, 12 parts of oxidized paraffin wax soap, 40 parts of binding agent；The water and base-material Than being 1：1.0.
Above-mentioned photocatalysis dope for inner wall of architecture is through the following steps that to realize：
(1) preparation of nano composite material：By 10 parts of 20 parts of nano titanium oxide, 40 parts of dispersant, 6 parts of propane diols and water Fully it is ground stirring and obtains；
(2) preparation of finished product：Titanium dioxide, corundum-mullite sand, water, haydite, defoamer are put into ball mill and are stirred 3.5h, rotating speed is 660r/min；Coalescents, silicone acrylic emulsion, paper pulp, oxidized paraffin wax soap are subsequently adding, continue to stir 1h；Finally Defoamer, binding agent, nano composite material is added to continue to stir 1h, finished product.
Embodiment 2
A kind of photocatalysis dope for inner wall of architecture, including base-material and water, the base-material are main by following material composition：Nanometer is multiple 30 parts of condensation material, 80 parts of silicone acrylic emulsion, 30 parts of titanium dioxide, 28 parts of corundum-mullite sand, 15 parts of haydite, 4 parts of defoamer, film forming are helped 8 parts of agent, 15 parts of lepidolite, 20 parts of rhodonite, 32 parts of paper pulp, 6 parts of oxidized paraffin wax soap, 64 parts of binding agent；The water and base-material Than being 1：1.2.
Above-mentioned photocatalysis dope for inner wall of architecture is through the following steps that to realize：
(1) preparation of nano silicon：With metatitanic acid fourth fat：Absolute ethyl alcohol=1：5 (volume ratios) are mixed into solution A, nothing Water-ethanol：Glacial acetic acid：Water=4：1：1 (volume ratio) is mixed into solution B, and solution A is slowly dropped into solution B and is stirred vigorously, Nano-TiO2 hydrosol is can obtain, standing becomes gel time for 18h, and obtained gel, to constant weight, then uses horse in 65 DEG C of dryings Not stove is that can obtain nano titanium oxide in 400 DEG C of calcination 1h；
(2) preparation of nano composite material：By 7 parts of 16 parts of nano titanium oxide, 32 parts of dispersant, 5 parts of propane diols and water Fully it is ground stirring and obtains；
(3) preparation of finished product：Titanium dioxide, corundum-mullite sand, water, haydite, defoamer are put into ball mill and are stirred 3.5h, rotating speed is 660r/min；Be subsequently adding coalescents, silicone acrylic emulsion, paper pulp, oxidized paraffin wax soap, continue stir 1h；Most Defoamer, binding agent, nano composite material is added to continue to stir 1h, finished product afterwards.
Embodiment 3
A kind of photocatalysis dope for inner wall of architecture, including base-material and water, the base-material are main by following material composition：Nanometer is multiple 26 parts of condensation material, 70 parts of silicone acrylic emulsion, 38 parts of titanium dioxide, 26 parts of corundum-mullite sand, 20 parts of haydite, 4 parts of defoamer, film forming are helped 6 parts of agent, 18 parts of lepidolite, 15 parts of rhodonite, 28 parts of paper pulp, 10 parts of oxidized paraffin wax soap, 56 parts of binding agent；The water and base-material Than being 1：1.1.
Above-mentioned photocatalysis dope for inner wall of architecture is through the following steps that to realize：
(1) preparation of nano silicon：With metatitanic acid fourth fat：Absolute ethyl alcohol=1：5 (volume ratios) are mixed into solution A, nothing Water-ethanol：Glacial acetic acid：Water=4：1：1 (volume ratio) is mixed into solution B, and solution A is slowly dropped into solution B and is stirred vigorously, Nano-TiO2 hydrosol is can obtain, standing becomes gel time for 18h, and obtained gel, to constant weight, then uses horse in 65 DEG C of dryings Not stove is that can obtain nano titanium oxide in 400 DEG C of calcination 1h；
(2) preparation of nano composite material：By 7 parts of 13 parts of nano titanium oxide, 25 parts of dispersant, 4 parts of propane diols and water Fully it is ground stirring and obtains；
(3) preparation of finished product：Titanium dioxide, corundum-mullite sand, water, haydite, defoamer are put into ball mill and are stirred 3.5h, rotating speed is 660r/min；Coalescents, silicone acrylic emulsion, paper pulp, oxidized paraffin wax soap are subsequently adding, continue to stir 1h；Finally Defoamer, binding agent, nano composite material is added to continue to stir 1h, finished product.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (6)

1. a kind of photocatalysis dope for inner wall of architecture, it is characterised in that including base-material and water, the base-material is mainly pressed by following material Weight portion is constituted：20~30 parts of nano composite material, 60~80 parts of silicone acrylic emulsion, 30~40 parts of titanium dioxide, corundum-mullite sand 20~28 parts, 15~25 parts of haydite, 2~4 parts of defoamer, 4~8 parts of coalescents, 15~25 parts of lepidolite, rhodonite 10~ 20 parts, 20~32 parts of paper pulp, 6~12 parts of oxidized paraffin wax soap, 40~64 parts of binding agent；The water is 1 with base-material ratio：1.0~ 1.2。
2. photocatalysis dope for inner wall of architecture as claimed in claim 1, it is characterised in that the base-material is mainly pressed by following material Weight portion is constituted：26 parts of nano composite material, 70 parts of silicone acrylic emulsion, 38 parts of titanium dioxide, 26 parts of corundum-mullite sand, haydite 20 Part, 4 parts of defoamer, 6 parts of coalescents, 18 parts of lepidolite, 15 parts of rhodonite, 28 parts of paper pulp, 10 parts of oxidized paraffin wax soap, bonding 56 parts of agent；The water is 1 with base-material ratio：1.1.
3. photocatalysis dope for inner wall of architecture as claimed in claim 1 or 2, it is characterised in that the nano composite material is main It is composed of the following raw materials by weight：10~16 parts of nano titanium oxide, 20~32 parts of dispersant, 5~7 parts of water, propane diols 3~5 Part.
4. the preparation method of photocatalysis dope for inner wall of architecture described in claim 1 or 2, it is characterised in that comprise the following steps：
(1) preparation of nano composite material：By nano titanium oxide, dispersant, propane diols and water be fully ground stirring and ；
(2) preparation of finished product：Titanium dioxide, corundum-mullite sand, water, haydite, defoamer are put into ball mill and stir 3.5h；So Coalescents, silicone acrylic emulsion, paper pulp, oxidized paraffin wax soap are added afterwards, continue to stir 1h；It is eventually adding defoamer, binding agent, nanometer Composite continues to stir 1h, finished product.
5. the preparation method of photocatalysis dope for inner wall of architecture as claimed in claim 4, it is characterised in that the nanometer in step (1) Silica is obtained using sol-gel process.
6. the preparation method of photocatalysis dope for inner wall of architecture as claimed in claim 4, it is characterised in that ball mill in step (2) Rotating speed be 660r/min.
CN201710197214.6A 2017-03-29 2017-03-29 A kind of photocatalysis dope for inner wall of architecture and preparation method thereof Pending CN106833237A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710197214.6A CN106833237A (en) 2017-03-29 2017-03-29 A kind of photocatalysis dope for inner wall of architecture and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710197214.6A CN106833237A (en) 2017-03-29 2017-03-29 A kind of photocatalysis dope for inner wall of architecture and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106833237A true CN106833237A (en) 2017-06-13

Family

ID=59140972

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710197214.6A Pending CN106833237A (en) 2017-03-29 2017-03-29 A kind of photocatalysis dope for inner wall of architecture and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106833237A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216760A (en) * 2017-07-08 2017-09-29 佛山市正略信息科技有限公司 A kind of indoor wall smooth surface coating and preparation method thereof
CN108795203A (en) * 2018-07-11 2018-11-13 合肥信亚达智能科技有限公司 A kind of photocatalysis air-cleaning interior wall coating and preparation method thereof
CN112126304A (en) * 2020-09-22 2020-12-25 东莞市龙晟电子科技有限公司 Preparation method of nano titanium dioxide ultraviolet light catalytic purification coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191235A (en) * 1998-03-17 1998-08-26 孙枝荣 Internal wall paint and products thereof
WO2009074120A2 (en) * 2007-12-11 2009-06-18 Advanced Materials- Jtj S.R.O. Multifunctional photocatalytic and sanitary paints and the method of application thereof
CN104231774A (en) * 2014-10-13 2014-12-24 会泽县威利奇建材涂料厂 Nanometer interior wall decorative coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191235A (en) * 1998-03-17 1998-08-26 孙枝荣 Internal wall paint and products thereof
WO2009074120A2 (en) * 2007-12-11 2009-06-18 Advanced Materials- Jtj S.R.O. Multifunctional photocatalytic and sanitary paints and the method of application thereof
CN104231774A (en) * 2014-10-13 2014-12-24 会泽县威利奇建材涂料厂 Nanometer interior wall decorative coating

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王国建等: "《建筑防火材料》", 30 June 2006, 中国石化出版社 *
贾丽华等: "《化学工程与工艺综合实验》", 30 September 2009, 哈尔滨工程大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216760A (en) * 2017-07-08 2017-09-29 佛山市正略信息科技有限公司 A kind of indoor wall smooth surface coating and preparation method thereof
CN108795203A (en) * 2018-07-11 2018-11-13 合肥信亚达智能科技有限公司 A kind of photocatalysis air-cleaning interior wall coating and preparation method thereof
CN112126304A (en) * 2020-09-22 2020-12-25 东莞市龙晟电子科技有限公司 Preparation method of nano titanium dioxide ultraviolet light catalytic purification coating

Similar Documents

Publication Publication Date Title
CN100534956C (en) Nano stone protectant and preparation method thereof
CN106833237A (en) A kind of photocatalysis dope for inner wall of architecture and preparation method thereof
CN105271954B (en) A kind of ornament materials containing diatom ooze
CN104449205A (en) Antibacterial and scrubbing-resistant waterborne coating for glass door and preparation method of waterborne coating
CN104263101A (en) Indoor building coating
CN103589254A (en) Environment-friendly reflective insulation heat-preserving coating
CN104745052B (en) A kind of preparation method of the Nano self-cleaning coating material of high adhesion force
CN107189563A (en) A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof
CN107867810A (en) Purification of air, damping are self-cleaning, antibacterial health-care type oyster shell whiting biomass dry powder paint
CN102702807A (en) Photo-catalytic composite coating and preparation method thereof
CN106497358A (en) A kind of environmental protection coating material and preparation method thereof
KR20180110740A (en) Nature friendly mud paint and the manufacturing method thereof
CN105689006A (en) Nano-photocatalyst and preparation method thereof
CN102308047A (en) Filler material for a floor, and method for producing filler material for a floor
CN107129709A (en) A kind of compound finished product diatom ooze of potassium silicate and preparation method thereof
CN101974263A (en) Coating for removing formaldehyde in indoor air
CN105647322A (en) Environment-friendly interior wall coating
CN107793866A (en) A kind of nano-TiO2Modified pure acrylic acid exterior wall negative ion paint and preparation method thereof
CN103436166B (en) Building surface nano protecting liquid and preparation method thereof
CN105273443A (en) Nanometer self-cleaning, anti-fog and sterilization glass coating and preparation method thereof
CN101874978A (en) Decorative material for removing formaldehyde
CN103468049A (en) Formaldehyde-removing coating with absorption function and decomposition function and preparation method thereof
CN106242455A (en) A kind of composite multi-functional meerschaum/kieselguhr basic ring protects chamber interior walls material
CN102190860A (en) Impregnation composition for functional stone manufacture and functional stone using that
CN103114693B (en) Negative ion formaldehyde-resistance ecological leather carving soft packaging and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170613

WD01 Invention patent application deemed withdrawn after publication