CN102190860A - Impregnation composition for functional stone manufacture and functional stone using that - Google Patents

Impregnation composition for functional stone manufacture and functional stone using that Download PDF

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Publication number
CN102190860A
CN102190860A CN2010102965735A CN201010296573A CN102190860A CN 102190860 A CN102190860 A CN 102190860A CN 2010102965735 A CN2010102965735 A CN 2010102965735A CN 201010296573 A CN201010296573 A CN 201010296573A CN 102190860 A CN102190860 A CN 102190860A
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weight parts
spice
perfume
lithotome
composition
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金宗佑
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NANOSTONE CO Ltd
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NANOSTONE CO Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/015—Biocides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/007—Fragrance additive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to an impregnation composition for functional stone manufacture and the functional stone using that. The stone which is colored in the invention comprises fragrant matters and has the functions of fragrance generation and deodorization. The impregnation composition is also provided with antibacterial material, etc. and has a function of pollutant decomposition. The invention relates to the impregnation composition used for manufacturing the stone and the functional stone using that. The impregnation composition comprises a dye, a colorant of an organic pigment, a fragrance generation agent and polymers in an organic solvent; and furthermore comprises nanometer antimicrobial agents such as nanometer powder, titanium dioxide nanometer powder and copper nanometer powder. The invention relates to a method for manufacturing the functional stone with the impregnation composition and the functional stone which is manufactured accordingly.

Description

For making the composition and utilize the functional lithotome that its makes of soaking of functional lithotome
Technical field
Lithotome painted among the present invention contains fragrant material, has the function of sending out perfume (or spice) and deodorization.Also have to resist materials such as all reaching bactericidal properties, have the function of decomposing pollutant matter.The invention relates to the composition and utilize the functional lithotome that its makes of soaking in order to make that this lithotome uses.This composition that soaks is for to contain dyestuff in organic solvent, the tinting material of mineral dye is sent out the composition or also comprise nanometer powder of soaking of pastil and polymkeric substance, and titanic oxide nano powder is with functional composition that soaks of nano antibacterial agents such as nanometer powder.The invention relates to the functional lithotome that utilizes such composition that soaks to make the method for functional lithotome and manufacture.
Background technology
In the building in modern times, lithotome can increase the structure of buildings and attractive in appearance, uses on interior dress and exterior material.Along with the increase of population and the influence of industrialization, the demand of buildings also increases day by day, and and then the requirement of lithotome is also increasing.The people that used lithotome in the past be for use attractive in appearance it, but utilize now the people of lithotome just be not limited in attractive in appearance on, beautiful color also will be arranged.In order to satisfy the demand of the multicolour of right stone material and to give more function, constantly carry out these research and development.
Being documented in Korean Patent is for 10-0767737 number about the antibiotic stone material of the gelationus metal nanoparticle of foundation and the making method of antibiotic timber.Its feature has: stone material and timber are heated in heating container, make its in-house moisture evaporation or discharge, maintain dry status.Is the above-mentioned concentration that is immersed in the nanoparticle of the gluey special thin silver that contains 1～20nm or titanium oxide by exsiccant stone material and timber 100～10, in the aqueous immersion of 000ppm.Heated above-mentioned stone material and timber are in the refrigerative process, and above-mentioned colloidal metallic nanoparticle can invade stone material and timber inside.Present technique is by above-mentioned formation, can obtain antibiotic and function that remove bacillary taste, but remove these other function very a little less than, so need more research and development, draw functional lithotome.
Summary of the invention
The present invention finds out for the problem that solves above-described manufacturing technology in the past.
Making can be satisfied the problem of the environmentally friendly functional lithotome of needs in buildings.In the past, just there was not to use lithotome at the internal and external ornament of buildings at all.Generally making have send out Xiang Gong can painted lithotome the time, be physical strength and the characteristic that satisfies the material of construction needs, problems such as coat the coating that contains fragrant material on the surface of material of construction, such coating has at the fragrance of originally dispersing too dense, and a fragrant time is short too.
The present invention studies in order to solve above problem.Constituting of its composition that soaks:
In organic solvent 100 weight parts, 0.1～15 weight part tinting material is arranged, contain dyestuff, more than one tinting material in the mineral dye; 0.1 the pastil that～20 weight parts are made of fragrant material; The size of particles that 1～50 weight part comprises a kind of polymkeric substance in Resins, epoxy, urethane, acrylate (PMMA), silica gel, the polyvinyl butyral acetal or add 0.1～10 weight part again in the above-mentioned composition that soaks is the nano antibacterial agent of 50～400nm.The invention provides so functional lithotome that soaks composition and make of it.
Effect
The invention solves technical problem in the past: making can be satisfied the problem of the environmentally friendly functional lithotome of needs in buildings.In the past, just there was not to use lithotome at the internal and external ornament of buildings at all.Generally making have send out Xiang Gong can painted lithotome the time, be physical strength and the characteristic that satisfies the material of construction needs, problems such as coat the coating that contains fragrant material on the surface of material of construction, such coating has at the fragrance of originally dispersing too dense, and a fragrant time is short too.Soak together to the inside of lithotome by sending out pastil and wedding agent, have and keep the effect of sending out the fragrant time.In the composition that soaks, add nano antibacterial agent again and make lithotome have antibiotic and sterilization effect, prevent the breeding of mould and microorganism, decompose the formaldehyde that is used for solvent, toluene, volatile organic gas such as benzene (VOCs), it is the reason material that causes cancer.The self-purification that also has room air.
Description of drawings
Fig. 1 shows this organization chart according to the formation of the composition that soaks in inventive embodiment.
Embodiment
The invention relates to the composition and utilize the functional lithotome that its makes of soaking of making functional lithotome.
In organic solvent 100 weight parts, it is the tinting material of 50～400nm0 nanometer that 0.1～15 weight part size of particles is arranged, and contains dyestuff, more than one tinting material in the mineral dye; 0.1 the pastil that～20 weight parts are made of fragrant material; The size of particles that 1～50 weight part comprises a kind of polymkeric substance in Resins, epoxy, urethane, acrylate (PMMA), silica gel, the polyvinyl butyral acetal or add 0.1～10 weight part again in the above-mentioned composition that soaks is the nano antibacterial agent of 50～400nm.The invention provides so functional lithotome that soaks composition and make of it.
Below be to specify the present invention with reference to accompanying drawing 1.
For ethanol, methyl alcohol, Virahol, ethyl acetate, butanone, acetone, N-BUTYL ACETATE, mibk, toluene, in more than one organic solvent 100 weight parts in the iso-butylene dimethylbenzene, it is the tinting material of 50～400nm0 nanometer that 0.1～15 weight part size of particles is arranged, contain dyestuff, more than one tinting material in the mineral dye; 0.1～20 weight parts contain rosin, cypress perfume (or spice), white birch perfume (or spice), bamboo perfume (or spice), plant perfume (or spice), fruit perfume (or spice), fragrance, the pastil that more than one material constitutes in the cloves; 1～50 weight part comprises Resins, epoxy, urethane, acrylate (PMMA), silica gel, a kind of polymkeric substance or at the above-mentioned composition that soaks in the polyvinyl butyral acetal.The present invention is by such composition that soaks being immersed in the pore of lithotome, being used in the material of construction, having the effect of sending natural perfume (or spice).
Specifically, the lithotome that was used for material of construction in the past is directly to be used in the interior dress of buildings and to load onto outward with state of nature, or tinting materials such as dyestuff are immersed in the pore of lithotome, be used in painted lithotome architectural again, draw better aesthetic, but above-mentioned the present invention is more progressive than these technology, has multiple color, distributes natural fragrance.Reach utilization of the present invention in general organic solvent 100 weight parts, containing 0.1～15 weight part size of particles is the tinting material of 50～400nm0 nanometer, contains dyestuff, more than one tinting material in the mineral dye; 0.1～20 weight parts contain rosin, cypress perfume (or spice), and white birch perfume (or spice), bamboo perfume (or spice), plant perfume (or spice), fruit perfume (or spice), fragrance, a pastil of more than one material formation in the cloves has been realized simultaneously a tinting material and a pastil being immersed in the interior formation of lithotome pore.
At this moment, the size of the inside and outside pore of the lithotome that is dipped into is most of for below the 450nm, so can be immersed in effectively in the pore in order to make above-mentioned tinting material and to send out pastil, their size is less than the size of pore, utilizes the dye compositions and the fragrant material of 50～400nm size.If at this moment the size of dye compositions and fragrant material is less than 50, can not be dispersed in effectively in the composition that soaks, if greater than 400, can not effectively be immersed in pore inside.Also have, use to be above-mentioned size of particles the dye compositions of 50～400nm and the organic solvent of fragrant material effectively, and it has ethanol, methyl alcohol, Virahol, ethyl acetate, butanone, acetone, N-BUTYL ACETATE, mibk, toluene, iso-butylene dimethylbenzene etc.
Be combined in effectively in the pore of lithotome in order to make tinting material and to send out pastil, to on molecular structure, comprise the tinting material of nanometer size and send out pastil, use a kind of polymkeric substance in the Resins, epoxy outstanding, urethane, acrylate (PMMA), silica gel, the polyvinyl butyral acetal with the bonding force of lithotome, kind according to a toner and a pastil, the amount of utilizing is different, is suitable from 1～50 weight part.If be less than 1 weight part, the effect of wedding agent can be very small, if greater than 50 weight parts, the viscosity of the composition that soaks can raise, and causes the immersion rate to descend.
In order to mix above-mentioned solvent uniformly, tinting material is sent out pastil and wedding agent and will be carried out 1～24 hour stirring and obscure in 25～100 ℃ temperature.According to the present invention, according to the kind of composition, provide suitable active-energy, add 25～100 ℃ heat energy, add 1～24 hour physical energy, to make size of particles be the tinting material of nanometer and send out a pastil and disperse effectively-be combined in solvent and the wedding agent.The solvent of definite use that will be continuous, tinting material, the optimal activated temperature of a pastil and wedding agent in being no more than the scope of boundary's point, stirs at leisure.
In the present invention, for make send out pastil effectively with solvent, tinting material and wedding agent dispersions-combination, continue scentetd, can be by the stage of one pastil pre-treatment.The above-mentioned composition that soaks of similar mixing is the same, is containing ethanol, methyl alcohol, Virahol, ethyl acetate, butanone, acetone, N-BUTYL ACETATE, mibk, toluene, in more than one organic solvent 100 weight parts in the iso-butylene dimethylbenzene, comprise and contain rosin, cypress perfume (or spice), white birch perfume (or spice), bamboo perfume (or spice), plant perfume (or spice), fruit perfume (or spice), fragrance, the size of particles that more than one material constitutes in the cloves is fragrant material 30～60 weight parts of 50～400nm; Resins, epoxy, urethane, a kind of polymkeric substance 40～70 weight parts in acrylate (PMMA), silica gel, the polyvinyl butyral acetal carry out 0.5～2 hour mix under 25～100 ℃ of temperature, the pre-treatment of sending out pastil in the composition that soaks.For solvent 100 weight parts for obtaining using as the above-mentioned composition that soaks, the fragrant material that in wedding agent 40～70 weight parts, comprises 30～60 weight parts with high density, with before tinting material mixes, mix prior to wedding agent, make fragrant material more effective, a pastil more effectively is combined in the pore of lithotome for the dispersion-combination of wedding agent.At this moment, heterogeneous for the chemistry of sending out pastil and other compositions that soak through pre-treatment, the solvent of use and the kind of wedding agent are identical with the composition that soaks.
Lithotome with above-mentioned formation of multiple color and natural perfume (or spice) has such effect: making can be satisfied the problem of the environmentally friendly functional lithotome of needs in buildings.In the past, just there was not to use lithotome at the internal and external ornament of buildings at all.Generally making have send out Xiang Gong can painted lithotome the time, be physical strength and the characteristic that satisfies the material of construction needs, problems such as coat the coating that contains fragrant material on the surface of material of construction, such coating has at the fragrance of originally dispersing too dense, and a fragrant time is short too.Soak together to the inside of lithotome by sending out pastil and wedding agent, have and keep the effect of sending out the fragrant time.
In the present invention, very and when soaking composition,, comprise the mica powder that comprises of 0.1～5 weight part, zinc oxide for solvent 100 weight parts, Cs2O, magnesium oxide, tin-oxide, aluminum oxide, titanium dioxide, silicon oxide layer, magnesium silicate, silicon nitride, agent is cut off in the ultraviolet ray of kaolin etc.The environmentally friendly lithotome that its solve to be made is subjected to the ultraviolet ray of sunlight and problems such as breakage.For this reason, if for 100 weight parts, its content is lower than 0.1, and effect is cut off in ultraviolet ray can be very small, can influence the dispersion-keying action of other compositions that soak if surpass 5, so will maintain between 0.1～5.Pore opening as above-mentioned lithotome is generally 450nm, so the size that agent is cut off in above-mentioned ultraviolet ray is 50～400nm.If less than 50, too small because of particle, be difficult to make ultraviolet ray to cut off agent and be dispersed in the composition that soaks, excessive if greater than 400 because of particle, can not be immersed in the pore of lithotome.
Contain above-mentioned solvent among the present invention, tinting material is sent out pastil, in the composition that soaks of wedding agent, also contain nano antibacterial agents such as silver powder, titania powder, copper powder, it makes lithotome have antibiotic and sterilization effect, prevent the breeding of mould and microorganism, decompose the formaldehyde that is used for solvent, toluene, volatile organic gas such as benzene (VOCs), it is the reason material that causes cancer.The self-purification that also has room air.At this moment, the ratio of components of nano antibacterial agent has 0.1～5 weight part for the solvent of 100 weight parts, does not therefore influence the dispersion-cohesive process of other compositions that soak.As above-mentioned tinting material, the size of fragrant material also should be between 50～400nm.
Titanium dioxide has the ultraviolet ray that utilizes sunlight and carries out light-catalysed effect in nano antibacterial agent, remove the pollution substance in the atmosphere, bacterium, the effect of mould and microorganism, if, in the composition that soaks, can not comprise ultraviolet ray and cut off agent so use titania powder to make antiseptic-germicide.
Below be that the utilization composition that soaks is immersed in lithotome and draws the political example of functional lithotome according to the present invention, the example and the experimental result of comparing in addition with technology in the past.
[preparation stone material]
Is long * wide * height the granite of 900 * 300 * 50nm branch that classifies in three categories, and prepares 3 natural granite experiment materials.
[example 1]
1. ethanol 300g, mineral dye (BASF NEOJAPON) 24g, cloves powder (Britain Fragrance oils company, perfume lilac) 24g, Resins, epoxy 60g mixes mutually, under 30 ℃ temperature, stirs 3 hours and draws the composition that soaks.
2. the back water being ground on the grouan surface of ready 300 * 300 * 30nm cleans.
3. granite being immersed to pH value is in 4 the hydrochloric acid soln, soaked 10 hours, and the organism in the stripping stone material, ferrous components is removed with towel.
4. for carrying out pore expansion, in the stove, heat gradually in a vacuum, carry out 4 hours air porous expanded at 250 ℃.
5. the composition of preparing in 1 stage that soaks is heated to 70 ℃, the granite in 4 stage processing is soaked in the composition solution that soaks, shelved 24 hours at 70 ℃.
6. remove the unnecessary composition that soaks on the painted surface of granite with towel.
7. in 60 ℃ water-soluble thermosetting resin solution, sink to the granite of the above-mentioned composition that soaks that soaks, shelved 8 hours, add thermoinitiators.
8. the granite of handle immersion stiffening agent 170 ℃ of thermal treatments of carrying out 2 hours, makes the coloured composition sclerosis in electric furnace.
[example 2]
1. ethanol 300g, the particle mean size is mineral dye (BASFNEOJAPON) 24g of 350nm, the particle mean size is cloves powder (the Britain Fragrance oils company of 400nm, perfume lilac) 24g, Resins, epoxy 60g mixes mutually, under 30 ℃ temperature, stirred 3 hours and draw the composition that soaks.
2～8 stages of as above stating example 1 with the next stage are the same.
[comparative example]
1. (mineral dye 15g and urethane resin wedding agent (KCC, urethane) 45g mixes for KCC, 037U) 240g, prepares coloured composition thinner.
2～8 stages are the same with example 1.
[result]
Example 1, example 2 reaches the lithotome of making in the comparative example and respectively carries out rerum natura according to test method, sends out the test of perfume (or spice) and germ resistance, draws table 1, the result of table 2.As table 1, be immersed in the pore of lithotome containing the composition that soaks of sending out pastil, as example 2, be immersed in the pore of lithotome containing the composition that soaks of sending out pastil and nano antibacterial agent, then example 1 and example 2 compared with the comparative example that uses technology in the past, its compression is strong as can be seen, rerum natura and accelerated deteriorations such as density, send out perfume (or spice), germ resistance, all character such as weather resistance is all very outstanding.As shown in table 2, in the composition that soaks of lithotome, contain send out fragrant and example 1 and example 2 when comparing with comparative example, have a better perfume (or spice), in the composition that soaks, contain the example 2 of nano antibacterial agent, ratio 1 and comparative example have more outstanding germ resistance.
Table 1
* specific absorption (%) is meant soak composition or all specific absorptioies of coloured composition for stone material.
Patent: 10-0956033
Table 2
* international and domesticly not have the relevant fragrant lattice of establishing rules of sending out, so when a perfume is tested, used and on the tester (Japanese GASTECH, 801) of generally use, combined a plurality of general test kits of using that can detected gas.
Above-mentionedly relate to embodiments of the invention, but the invention is not restricted to the embodiments described, the people who has for the common knowledge of technical field of the present invention is not departing under the main points of the present invention, can carry out various distortion in scope.

Claims (4)

1. the composition that soaks is characterized in that,
With respect to organic solvent 100 weight parts, under 25～100 ℃ temperature, mix 1～24 hour following material:
0.1 the tinting material of～15 weight parts, it contains in fuel, the mineral dye more than one;
0.1～20 weight parts send out pastil by what fragrant material constituted;
0.1 the nano antibacterial agent of more than one in the silver-colored nanometer powder of～10 weight parts, titanic oxide nano powder, the copper nano powder; And
A kind of polymeric binders in 1～50 parts by weight of epoxy resin, urethane, acrylate, silica gel, the polyvinyl butyral acetal,
Wherein, the size of particles of dyestuff, mineral dye, fragrant material and the nano antibacterial agent in the above-mentioned tinting material is 50～400nm;
An above-mentioned pastil is for more than one organic solvent 100 weight parts in ethanol, methyl alcohol, Virahol, ethyl acetate, butanone, acetone, N-BUTYL ACETATE, mibk, toluene, the iso-butylene dimethylbenzene, comprises fragrant material 30～60 weight parts; A kind of polymkeric substance 40～70 weight parts in Resins, epoxy, urethane, acrylate, silica gel, the polyvinyl butyral acetal carry out 0.5～2 hour the generation that mixes under 25～100 ℃ of temperature.
2. the composition that soaks as claimed in claim 1, wherein, described fragrant material is more than one a material in rosin, cypress perfume (or spice), white birch perfume (or spice), bamboo perfume (or spice), plant perfume (or spice), fruit perfume (or spice), fragrance, the cloves.
3. a functional lithotome is characterized in that, will contain in the pore that the composition that soaks of sending out pastil is immersed in lithotome and make, wherein, the described composition that soaks,
With respect to organic solvent 100 weight parts, under 25～100 ℃ temperature, mix 1～24 hour following material:
0.1 the tinting material of～15 weight parts, it contains in fuel, the mineral dye more than one;
0.1～20 weight parts send out pastil by what fragrant material constituted;
0.1 the nano antibacterial agent of more than one in the silver-colored nanometer powder of～10 weight parts, titanic oxide nano powder, the copper nano powder; And
A kind of polymeric binders in 1～50 parts by weight of epoxy resin, urethane, acrylate, silica gel, the polyvinyl butyral acetal,
Wherein, the size of particles of dyestuff, mineral dye, fragrant material and the nano antibacterial agent in the above-mentioned tinting material is 50～400nm;
An above-mentioned pastil is for more than one organic solvent 100 weight parts in ethanol, methyl alcohol, Virahol, ethyl acetate, butanone, acetone, N-BUTYL ACETATE, mibk, toluene, the iso-butylene dimethylbenzene, comprises fragrant material 30～60 weight parts; A kind of polymkeric substance 40～70 weight parts in Resins, epoxy, urethane, acrylate, silica gel, the polyvinyl butyral acetal carry out 0.5～2 hour the generation that mixes under 25～100 ℃ of temperature.
4. functional lithotome as claimed in claim 3, wherein, fragrant material is the material that contains in rosin, cypress perfume (or spice), white birch perfume (or spice), bamboo perfume (or spice), plant perfume (or spice), fruit perfume (or spice), fragrance, the cloves more than one.
CN2010102965735A 2009-11-30 2010-09-29 Impregnation composition for functional stone manufacture and functional stone using that Pending CN102190860A (en)

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* Cited by examiner, † Cited by third party
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KR101738824B1 (en) * 2016-10-12 2017-05-22 (주)아이에스세라텍 Composition for coloring granite stone construction material and the manufacturing method thereof
KR102214709B1 (en) * 2019-10-24 2021-02-10 주식회사 옥산석물 Granite slab with strong thermal barrier to alleviate heat island and method for manufacturing the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478810A (en) * 2002-08-28 2004-03-03 周维文 Perfume antibacteria degradation polyolefin composition and its preparation method and use

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004314503A (en) * 2003-04-17 2004-11-11 Matsushita Electric Works Ltd Functional building material
KR100767737B1 (en) 2004-01-14 2007-10-17 나노폴리(주) Method for manufacturing antibiotic stone and lumber by using nano-metal particle of colloid state

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478810A (en) * 2002-08-28 2004-03-03 周维文 Perfume antibacteria degradation polyolefin composition and its preparation method and use

Cited By (1)

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CN108623326A (en) * 2018-03-31 2018-10-09 广西华洋矿源材料有限公司 A kind of granitic choosing method

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