CN107418332A - A kind of exterior coating for building and preparation method thereof - Google Patents

A kind of exterior coating for building and preparation method thereof Download PDF

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Publication number
CN107418332A
CN107418332A CN201710557340.8A CN201710557340A CN107418332A CN 107418332 A CN107418332 A CN 107418332A CN 201710557340 A CN201710557340 A CN 201710557340A CN 107418332 A CN107418332 A CN 107418332A
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parts
crushed
exterior coating
shale
mesh
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CN201710557340.8A
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孙洁
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of exterior coating for building, it is made up of following raw material according to parts by weight:48 parts of 10 16 parts of water-based acrylic resin, 6 10 parts of aqueous epoxy resins, 36 parts of waterglass, 25 34 parts of haydite, 48 parts of schmigel, 25 parts of land plaster, 0.5 2 parts of lignocellulosic, 0.1 0.5 parts of hydrophobic powder, 28 parts of titanium dioxide, 24 parts of dispersant, 15 25 parts of dimethylbenzene, 8 14 parts of duckweed, 5 12 parts of reed and shale.The present invention also disclosed the preparation method of the coating.Raw material sources of the present invention are extensive, and preparation technology is simple, suitable for large-scale industrial production;Each component plays synergy in the present invention, not only use intensity, water resistance and good anti-bacterial effect, and the term of validity is grown, and is not in the aging phenomena such as cracking, peeling, peeling, cracking, meets the use demand of people.

Description

A kind of exterior coating for building and preparation method thereof
Technical field
The present invention relates to a kind of coating, specifically a kind of exterior coating for building.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or emulsion, adds or does not add face Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or talcum powder.Paint finishing is in body surface It can very well be bonded with matrix material and form the material of complete and tough and tensile diaphragm, referred to as coating.Coating is with without exception with paint Read.Paint is people's custom title used for a long time, after introducing China, is just utilized always in building trade.The effect of coating can To be summarised as three aspects:Protective effect, decoration function and specific function effect.Wall covering refers to that being used for building wall plays dress Decorations and protection, make building wall beautiful and clean, while can also play protection building wall, extend the effect of its service life. Wall covering includes interior wall coating and exterior coating two large divisions by building wall classification.Interior wall coating focuses on decoration and environmental protection; Exterior coating focus on protection and it is durable.
Exterior coating has necessarily required water repelling property, but the water resistance of existing exterior coating is insufficient, and anti-microbial property is poor, This just brings inconvenience for the maintenance and use of people.
The content of the invention
It is an object of the invention to provide a kind of exterior coating for building, is asked with solve to propose in above-mentioned background technology Topic.
To achieve the above object, the present invention provides following technical scheme:
A kind of exterior coating for building, is made up of following raw material according to parts by weight:Water-based acrylic resin 10-16 parts, water Property epoxy resin 6-10 parts, waterglass 3-6 parts, haydite 25-34 parts, schmigel 4-8 parts, land plaster 2-5 parts, lignocellulosic 0.5-2 parts, hydrophobic powder 0.1-0.5 parts, titanium dioxide 2-8 parts, dispersant 2-4 parts, dimethylbenzene 15-25 parts, duckweed 8-14 parts, reed 5-12 parts and shale 4-8 parts.
As the further scheme of the present invention:Hydrophobic powder uses organosilicon hydrophobic powder.
As the further scheme of the present invention:The particle diameter of haydite is 8-45um, and the granularity of schmigel and land plaster is 270- 360 mesh.
The preparation method of the exterior coating for building, is comprised the following steps that:
Step 1, duckweed is dried to water content and is not higher than 3%, it is molten to be then immersed in the acetic acid that mass fraction is 5-8% 10-20 minutes are soaked in liquid, then are immersed in immersion 2-6 hours in saturation Kocide SD solution, after taking-up under 45-65 degrees Celsius Dry and be crushed to 200-280 mesh, then crushed products are put into the mixed solution of sodium hydroxide and methylcellulose, heat up To 40-50 degrees Celsius and stir 45-70 minutes, filter and filtration product is washed with deionized water to neutrality, obtain modified floating Duckweed;
Step 2, reed is dried and is crushed to 200-240 mesh, then returned in 65-80 degrees Celsius of ethanol solution Stream extraction 1.5-3 hours, filtrate is filtrated to get, shale is crushed to 80-150nm, then slate flour is added into filtrate simultaneously And stirring 50-70 minutes, then low temperature drying, obtains being modified shale;
Step 3, water-based acrylic resin and aqueous epoxy resins are crushed to 100-150 mesh and mixed, then thereto Waterglass and appropriate water are added, dissolves at high temperature for liquid, obtains the first mixed solution, it is standby;
Step 4, haydite is crushed to 360-480 mesh, then by land plaster, schmigel, lignocellulosic, titanium dioxide, scattered Agent, dimethylbenzene and haydite powder are added in the first mixed solution and stirred, and obtain the second mixed solution;
Step 5, modified duckweed, modified shale, the second mixed solution and hydrophobic powder are mixed, stirs, is heated to 150-180 degrees Celsius and 3-6 hours are incubated, are furnace-cooled to 50-70 degrees Celsius, be incubated 1.5-3 hours, be again heated to 120-135 Degree Celsius, 1-2 hours are incubated, then it is air-cooled to normal temperature, you can obtain finished product.
As the further scheme of the present invention:Modified shale is added in paraffin, ultrasonic disperse 15-30 minutes, then mistake Filter and dry.
As the further scheme of the present invention:The ratio between mole of sodium hydroxide and methylcellulose is 1 in step 1:1.
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, and preparation technology is simple, fit For large-scale industrial production;Each component plays synergy in the present invention, not only use intensity, water resistance and antibacterial effect Fruit is good, and the term of validity is grown, and is not in the aging phenomena such as cracking, peeling, peeling, cracking, meets the use demand of people.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of exterior coating for building, is made up of following raw material according to parts by weight:10 parts of water-based acrylic resin, water-based ring 6 parts of oxygen tree fat, 3 parts of waterglass, 25 parts of haydite, 4 parts of schmigel, 2 parts of land plaster, 0.5 part of lignocellulosic, organosilicon hydrophobic powder 4 parts of 0.1 part, 2 parts of titanium dioxide, 2 parts of dispersant, 15 parts of dimethylbenzene, 8 parts of duckweed, 5 parts of reed and shale.
The preparation method of the exterior coating for building, is comprised the following steps that:
Step 1, duckweed is dried to water content and is not higher than 3%, be then immersed in the acetum that mass fraction is 5% Middle immersion 10 minutes, then is immersed in saturation Kocide SD solution and soak 3 hours, is dried after taking-up under 48 degrees Celsius and powder Be broken to 200 mesh, then crushed products be put into the mixed solution of sodium hydroxide and methylcellulose, be warming up to 40 degrees Celsius and Stirring 45 minutes, filter and filtration product is washed with deionized water to neutrality, obtain being modified duckweed;
Step 2, reed is dried and is crushed to 200 mesh, then the refluxing extraction in 65 degrees Celsius of ethanol solution 1.5 hours, filtrate is filtrated to get, shale is crushed to 80nm, then slate flour is added into filtrate and stirred 50 minutes, Then low temperature drying, obtain being modified shale;
Step 3, water-based acrylic resin and aqueous epoxy resins are crushed to 100-150 mesh and mixed, then thereto Waterglass and appropriate water are added, dissolves at high temperature for liquid, obtains the first mixed solution, it is standby;
Step 4, haydite is crushed to 360 mesh, then by land plaster, schmigel, lignocellulosic, titanium dioxide, dispersant, Dimethylbenzene and haydite powder are added in the first mixed solution and stirred, and obtain the second mixed solution;
Step 5, modified duckweed, modified shale, the second mixed solution and organosilicon hydrophobic powder are mixed, stirs, adds Heat is to 150 degrees Celsius and is incubated 3 hours, is furnace-cooled to 50 degrees Celsius, is incubated 1.5 hours, is again heated to 120 degrees Celsius, insulation 1 Hour, then it is air-cooled to normal temperature, you can obtain finished product.
Embodiment 2
A kind of exterior coating for building, is made up of following raw material according to parts by weight:12 parts of water-based acrylic resin, water-based ring 8 parts of oxygen tree fat, 4 parts of waterglass, 29 parts of haydite, 6 parts of schmigel, 3 parts of land plaster, 1 part of lignocellulosic, 0.3 part of hydrophobic powder, titanium 6 parts of 5 parts of white powder, 2.5 parts of dispersant, 18 parts of dimethylbenzene, 10 parts of duckweed, 8 parts of reed and shale.The particle diameter of haydite is 20um, just The granularity of beautiful powder and land plaster is 280 mesh.
The preparation method of the exterior coating for building, is comprised the following steps that:
Step 1, duckweed is dried to water content and is not higher than 3%, be then immersed in the acetum that mass fraction is 7% Middle immersion 14 minutes, then is immersed in saturation Kocide SD solution and soak 3 hours, is dried after taking-up under 54 degrees Celsius and powder Be broken to 240 mesh, then crushed products be put into the mixed solution of sodium hydroxide and methylcellulose, be warming up to 46 degrees Celsius and Stirring 60 minutes, filter and filtration product is washed with deionized water to neutrality, obtain being modified duckweed;
Step 2, reed is dried and is crushed to 210 mesh, then the refluxing extraction in 74 degrees Celsius of ethanol solution 2.5 hours, filtrate is filtrated to get, shale is crushed to 110nm, then slate flour is added into filtrate and stirs 65 points Clock, then low temperature drying, obtains being modified shale;
Step 3, water-based acrylic resin and aqueous epoxy resins are crushed to 125 mesh and mixed, then added thereto Waterglass and appropriate water, dissolve at high temperature for liquid, obtain the first mixed solution, it is standby;
Step 4, haydite is crushed to 420 mesh, then by land plaster, schmigel, lignocellulosic, titanium dioxide, dispersant, Dimethylbenzene and haydite powder are added in the first mixed solution and stirred, and obtain the second mixed solution;
Step 5, modified shale is added in paraffin, ultrasonic disperse 24 minutes, then filters and dries, will be modified floating Modification shale, the second mixed solution after duckweed, ultrasonic disperse and the mixing of hydrophobic powder, stir, be heated to 165 degrees Celsius and Insulation 5 hours, 60 degrees Celsius are furnace-cooled to, are incubated 2.5 hours, be again heated to 125 degrees Celsius, be incubated 1.5 hours, then it is air-cooled to normal Temperature, you can obtain finished product.
Embodiment 3
A kind of exterior coating for building, is made up of following raw material according to parts by weight:15 parts of water-based acrylic resin, water-based ring 10 parts of oxygen tree fat, 6 parts of waterglass, 32 parts of haydite, 8 parts of schmigel, 5 parts of land plaster, 2 parts of lignocellulosic, organosilicon hydrophobic powder 8 parts of 0.5 part, 7 parts of titanium dioxide, 4 parts of dispersant, 23 parts of dimethylbenzene, 13 parts of duckweed, 11 parts of reed and shale.The particle diameter of haydite is The granularity of 30um, schmigel and land plaster is 320 mesh.
The preparation method of the exterior coating for building, is comprised the following steps that:
Step 1, duckweed is dried to water content and is not higher than 3%, be then immersed in the acetum that mass fraction is 8% Middle immersion 20 minutes, then is immersed in saturation Kocide SD solution and soak 6 hours, is dried at 60 c after taking-up and powder 270 mesh are broken to, then crushed products are put into the mixed solution of sodium hydroxide and methylcellulose, sodium hydroxide and Methyl cellulose The ratio between mole of element is 1:1, it is warming up to 48 degrees Celsius and stirs 65 minutes, filters and filtration product is washed with deionized water To neutrality, obtain being modified duckweed;
Step 2, reed is dried and is crushed to 240 mesh, then the refluxing extraction 3 in 80 degrees Celsius of ethanol solution Hour, filtrate is filtrated to get, shale is crushed to 140nm, then slate flour is added into filtrate and stirs 70 minutes, so Low temperature drying afterwards, obtain being modified shale;
Step 3, water-based acrylic resin and aqueous epoxy resins are crushed to 150 mesh and mixed, then added thereto Waterglass and appropriate water, dissolve at high temperature for liquid, obtain the first mixed solution, it is standby;
Step 4, haydite is crushed to 450 mesh, then by land plaster, schmigel, lignocellulosic, titanium dioxide, dispersant, Dimethylbenzene and haydite powder are added in the first mixed solution and stirred, and obtain the second mixed solution;
Step 5, modified shale is added in paraffin, ultrasonic disperse 25 minutes, then filters and dries, will be modified floating Modification shale, the second mixed solution and the mixing of organosilicon hydrophobic powder after duckweed, ultrasonic disperse, stir, it is Celsius to be heated to 180 Spend and be incubated 6 hours, be furnace-cooled to 70 degrees Celsius, be incubated 3 hours, be again heated to 130 degrees Celsius, be incubated 2 hours, then it is air-cooled extremely Normal temperature, you can obtain finished product.
The present invention operation principle be:By shale, ultrasonic disperse is to be filtered to the reed being attached on shale in paraffin Liquid carries out sealing, prevents it to be quickly lost in, extends the expiration date.Dimethylbenzene is good to each component solute effect as organic solvent, and And be free from side effects, coating will not be had a negative impact.Lignocellulosic can improve the adhesive force of coating after drying, will not There is the aging phenomena such as cracking, peeling, peeling, cracking, modified duckweed, water-based acrylic resin, aqueous epoxy resins, water glass Glass, modified shale and haydite are used cooperatively, and not only use intensity and antibacterial action are good, and are added with hydrophobic powder, water resistance It is good.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (6)

1. a kind of exterior coating for building, it is characterised in that be made up of following raw material according to parts by weight:Water-based acrylic resin 10-16 parts, aqueous epoxy resins 6-10 parts, waterglass 3-6 parts, haydite 25-34 parts, schmigel 4-8 parts, land plaster 2-5 parts, wood Matter cellulose 0.5-2 parts, hydrophobic powder 0.1-0.5 parts, titanium dioxide 2-8 parts, dispersant 2-4 parts, dimethylbenzene 15-25 parts, duckweed 8- 14 parts, reed 5-12 parts and shale 4-8 parts.
2. exterior coating for building according to claim 1, it is characterised in that the hydrophobic powder uses organosilicon hydrophobic Powder.
3. exterior coating for building according to claim 1 or 2, it is characterised in that the particle diameter of the haydite is 8-45um, The granularity of schmigel and land plaster is 270-360 mesh.
A kind of 4. preparation method of exterior coating for building as described in claim 1-3 is any, it is characterised in that specific steps It is as follows:
Step 1, duckweed is dried to water content and is not higher than 3%, be then immersed in the acetum that mass fraction is 5-8% 10-20 minutes are soaked, then are immersed in immersion 2-6 hours in saturation Kocide SD solution, are dried after taking-up under 45-65 degrees Celsius And 200-280 mesh is crushed to, then crushed products are put into the mixed solution of sodium hydroxide and methylcellulose, is warming up to 40-50 degrees Celsius and stir 45-70 minutes, filter and simultaneously filtration product is washed with deionized water to neutrality, obtain being modified duckweed;
Step 2, reed is dried and is crushed to 200-240 mesh, then being flowed back in 65-80 degrees Celsius of ethanol solution carries 1.5-3 hours are taken, are filtrated to get filtrate, shale is crushed to 80-150nm, then slate flour is added into filtrate and stirred 50-70 minutes are mixed, then low temperature drying, obtain being modified shale;
Step 3, water-based acrylic resin and aqueous epoxy resins are crushed to 100-150 mesh and mixed, then added thereto Waterglass and appropriate water, dissolve at high temperature for liquid, obtain the first mixed solution, it is standby;
Step 4, haydite is crushed to 360-480 mesh, then by land plaster, schmigel, lignocellulosic, titanium dioxide, dispersant, Dimethylbenzene and haydite powder are added in the first mixed solution and stirred, and obtain the second mixed solution;
Step 5, modified duckweed, modified shale, the second mixed solution and hydrophobic powder are mixed, stirs, is heated to 150- 180 degrees Celsius and 3-6 hours are incubated, are furnace-cooled to 50-70 degrees Celsius, be incubated 1.5-3 hours, it is Celsius to be again heated to 120-135 Degree, 1-2 hours are incubated, then it is air-cooled to normal temperature, you can obtain finished product.
5. the preparation method of exterior coating for building according to claim 4, it is characterised in that described to add modified shale Enter in paraffin, ultrasonic disperse 15-30 minutes, then filter and dry.
6. the preparation method of the exterior coating for building according to claim 4 or 5, it is characterised in that in the step 1 The ratio between mole of sodium hydroxide and methylcellulose is 1:1.
CN201710557340.8A 2017-07-10 2017-07-10 A kind of exterior coating for building and preparation method thereof Pending CN107418332A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294389A (en) * 2018-08-03 2019-02-01 安徽省凯丽方化工有限公司 A kind of exterior wall non-toxic coatings and its preparation process
CN109867992A (en) * 2018-12-21 2019-06-11 常熟市方塔涂料化工有限公司 A kind of cryogenic curing corrosion-resistant epoxy paint

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993623A (en) * 2009-08-05 2011-03-30 赢创德固赛有限公司 Microstructured multifunctional inorganic coating additives for preventing fouling (growth of biofilm) in aquatic applications
CN104263174A (en) * 2014-09-16 2015-01-07 青岛市高科专利技术转移平台有限公司 Environment-friendly nontoxic wood paint formula
CN106348705A (en) * 2016-08-18 2017-01-25 安徽省双龙木质纤维素有限公司 Wood fiber mixture for wall coatings
CN106752559A (en) * 2016-10-28 2017-05-31 芜湖浩权建筑工程有限公司 A kind of environment-friendly type building water paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993623A (en) * 2009-08-05 2011-03-30 赢创德固赛有限公司 Microstructured multifunctional inorganic coating additives for preventing fouling (growth of biofilm) in aquatic applications
CN104263174A (en) * 2014-09-16 2015-01-07 青岛市高科专利技术转移平台有限公司 Environment-friendly nontoxic wood paint formula
CN106348705A (en) * 2016-08-18 2017-01-25 安徽省双龙木质纤维素有限公司 Wood fiber mixture for wall coatings
CN106752559A (en) * 2016-10-28 2017-05-31 芜湖浩权建筑工程有限公司 A kind of environment-friendly type building water paint and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294389A (en) * 2018-08-03 2019-02-01 安徽省凯丽方化工有限公司 A kind of exterior wall non-toxic coatings and its preparation process
CN109867992A (en) * 2018-12-21 2019-06-11 常熟市方塔涂料化工有限公司 A kind of cryogenic curing corrosion-resistant epoxy paint
CN109867992B (en) * 2018-12-21 2021-04-27 常熟市方塔涂料化工有限公司 Ultralow-temperature curing epoxy anticorrosive paint

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