CN104449281A - Heat-insulating and mildew-resistant water-based paint for glass door and preparation method of water-based paint - Google Patents
Heat-insulating and mildew-resistant water-based paint for glass door and preparation method of water-based paint Download PDFInfo
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- CN104449281A CN104449281A CN201410568671.8A CN201410568671A CN104449281A CN 104449281 A CN104449281 A CN 104449281A CN 201410568671 A CN201410568671 A CN 201410568671A CN 104449281 A CN104449281 A CN 104449281A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a heat-insulating and mildew-resistant water-based paint for a glass door. The water-based paint is characterized by being prepared from the following raw materials in parts by weight: 23-26 parts of an epoxy resin emulsion, 40-45 parts of water-based amino-alkyd resin, 0.3-0.5 part of a flatting agent BYK-307, 1-2 parts of zinc powder, 0.5-1.0 part of a silane coupling agent NQ-71, 0.2-0.3 part of nanometer ground calcium carbonate, 0.2-0.4 part of a polyacrylate thickener, 0.4-0.7 part of hollow glass powder, 0.2-0.3 part of polyoxyethylene monoleate, 0.3-0.5 part of ceramic powder microsphere, 0.1-0.3 part of polymeric microspheres, 0.2-0.4 part of sodium diacetate, 2-3 parts of butyl carbitol, 0.2-0.4 part of liquid paraffin, 2-3 parts of ethylene glycol monobutyl ether, 0.1-0.3 part of fatty acid polyethylene glycol ester, 3-5 parts of a modified nanometer titanium dioxide photocatalyst, 1-2 parts of a pigment and 12-15 parts of deionized water. The added modified titanium dioxide photocatalyst has the functions of effectively purifying air, removing stink and odor, killing a plurality of bacteria and preventing mildew; a good thermal insulation effect is achieved by combined action of added hollow glass powder, ceramic powder microspheres and polymeric microspheres; the production cost of the paint is reduced; and the paint disclosed by the invention is excellent in various performances, does not contain a special odor, is safe and non-toxic, and can be widely applied to glass for home decoration.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, glass door use coating of particularly a kind of heat insulation mildew-resistant and preparation method thereof.
Background technology
Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings, using water as dispersion medium, only adopts a small amount of hypotoxicity alcohol ether organic solvent, safety and environmental protection, economizes on resources, and eliminates the danger of presence of fire during construction, is conducive to reducing topsoil.Water-borne coatings is very good to material surface adaptability, and can construct equally at wet environment, coating adhesion is strong.Glass and glasswork, because of attractive in appearance and needs that are performance, coating need be applied thereon, glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, the requirement having surmounted traditional decoration far away and beautified, the performances such as wear-resistant to it, anti-zoned quarter, weathering resistance propose requirements at the higher level.
Nano photo-catalytic refers under light illumination, there is not chemical transformation in self, but the material of chemical reaction can be promoted, nano TiO 2 is topmost photocatalyst material, when after the energy that it absorbs in sunlight or other light sources, a series of reaction occurs can become harmless carbonic acid gas and water by oxygenolysis such as most of organism, pollutent, foul smell, bacteriums.If but dispersing technology is not good in the product for nano-titania photocatalyst, thus cause reunion.This reunion directly has influence on photocatalyst activity, reduces the photo-catalysis capability of product, and then loses pollution degraded effect.Binchotan and diatomite support process according to this situation by the present invention, increase specific surface area, nano photo-catalytic is adsorbed on carrier, and utilize cupric ion, silver ions and rare earth element to carry out modification to nano photo-catalytic, increase the function such as sterilization, sterilization, avoid nano photocatalyst catalytic material in coating, disperse uneven generation to reunite and lose light-catalysed ability.
Summary of the invention
Glass door use coating that the object of this invention is to provide a kind of heat insulation mildew-resistant and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of glass door use coating of heat insulation mildew-resistant, be made up of the raw material of following weight part: epoxy resin latex 23-26, water-based alkyd melamine 40-45, flow agent BYK-3070.3-0.5, zinc powder 1-2, silane coupling agent NQ-710.5-1.0, nano heavy calcium carbonate 0.2-0.3, Polyacrylate thickeners 0.2-0.4, hollow glass powder 0.4-0.7, Aceonon 300 MO 0.2-0.3, ceramics powder microballoon 0.3-0.5, polymer microballoon 0.1-0.3, sodium Diacetate 0.2-0.4, diethylene glycol monobutyl ether 2-3, whiteruss 0.2-0.4, ethylene glycol monobutyl ether 2-3, fatty acid polyglycol ester 0.1-0.3, modified nano-titanium dioxide photocatalyst 3-5, pigment 1-2, deionized water 12-15,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part: nano-titania photocatalyst 40-50, nano silicon 15-20, nano-tourmaline 10-15, binchotan 10-15, rare earth element 0.5-1.0, copper powder 0.7-1.4, silver powder 0.6-1.2, cobalt oxide powder 0.4-0.8, diatomite 8-12, alkylphenol polyoxyethylene 0.6-1.2, Silane coupling agent KH550 0.7-1.4, the salpeter solution 20-40 of 20%, the sodium hydroxide solution 20-40 of 30%, polyvinyl alcohol 1-2, st-yrax n-butyl ether 0.3-0.5, ferric acetyl acetonade 0.2-0.4, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
The glass door use coating of a kind of heat insulation mildew-resistant of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-307, sodium Diacetate, whiteruss, fatty acid polyglycol ester, diethylene glycol monobutyl ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds ethylene glycol monobutyl ether, Aceonon 300 MO stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds epoxy resin latex, water-based alkyd melamine stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent NQ-71, pigment, zinc powder, hollow glass powder, ceramics powder microballoon, polymer microballoon, modified nano-titanium dioxide photocatalyst, nano heavy calcium carbonate uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: the modified nano-titanium dioxide photocatalyst that the present invention adds can effectively purify air, deodorizing taste removal, kill the function of various bacteria and mildew-resistant, the hollow glass powder added, ceramics powder microballoon, polymer microballoon triple combination effect, reach good heat-blocking action, and reduce the production cost of coating, coating various aspects of performance of the present invention is excellent, and not containing special odor, safety non-toxic, can be widely used in the glass such as family decoration.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of glass door use coating of heat insulation mildew-resistant, be made up of the raw material of following weight part (kilogram): epoxy resin latex 25, water-based alkyd melamine 45, flow agent BYK-3070.4, zinc powder 2, silane coupling agent NQ-711.0, nano heavy calcium carbonate 0.3, Polyacrylate thickeners 0.3, hollow glass powder 0.5, Aceonon 300 MO 0.3, ceramics powder microballoon 0.4, polymer microballoon 0.2, sodium Diacetate 0.4, diethylene glycol monobutyl ether 3, whiteruss 0.4, ethylene glycol monobutyl ether 3, fatty acid polyglycol ester 0.2, modified nano-titanium dioxide photocatalyst 3, pigment 1, deionized water 14,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part (kilogram): nano-titania photocatalyst 44, nano silicon 16, nano-tourmaline 12, binchotan 14, rare earth element 0.5, copper powder 0.8, silver powder 0.7, cobalt oxide powder 0.5, diatomite 10, alkylphenol polyoxyethylene 0.8, Silane coupling agent KH550 0.8, the salpeter solution 36 of 20%, the sodium hydroxide solution 34 of 30%, polyvinyl alcohol 1, st-yrax n-butyl ether 0.3, ferric acetyl acetonade 0.3, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
The glass door use coating of a kind of heat insulation mildew-resistant of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-307, sodium Diacetate, whiteruss, fatty acid polyglycol ester, diethylene glycol monobutyl ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds ethylene glycol monobutyl ether, Aceonon 300 MO stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds epoxy resin latex, water-based alkyd melamine stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent NQ-71, pigment, zinc powder, hollow glass powder, ceramics powder microballoon, polymer microballoon, modified nano-titanium dioxide photocatalyst, nano heavy calcium carbonate uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Glass paint sticking power experiment (frame method) of the present invention≤1 grade, snappiness experiment≤1mm, impact experiment: 50cm, hardness: 2H, water tolerance test (leaching distilled water 480 hours): without exception, resistance to boiling water experiment (100 ° of C >=12 hour): unchanged, ethanol-tolerant experiment (90% soaks 24 hours): without exception, artificial ageing resistance is tested: 1000 hours non-foaming, do not peel off, flawless.
Claims (2)
1. the glass door use coating of a heat insulation mildew-resistant, it is characterized in that, be made up of the raw material of following weight part: epoxy resin latex 23-26, water-based alkyd melamine 40-45, flow agent BYK-3070.3-0.5, zinc powder 1-2, silane coupling agent NQ-710.5-1.0, nano heavy calcium carbonate 0.2-0.3, Polyacrylate thickeners 0.2-0.4, hollow glass powder 0.4-0.7, Aceonon 300 MO 0.2-0.3, ceramics powder microballoon 0.3-0.5, polymer microballoon 0.1-0.3, sodium Diacetate 0.2-0.4, diethylene glycol monobutyl ether 2-3, whiteruss 0.2-0.4, ethylene glycol monobutyl ether 2-3, fatty acid polyglycol ester 0.1-0.3, modified nano-titanium dioxide photocatalyst 3-5, pigment 1-2, deionized water 12-15,
Described modified nano-titanium dioxide photocatalyst is made up of the raw material of following weight part: nano-titania photocatalyst 40-50, nano silicon 15-20, nano-tourmaline 10-15, binchotan 10-15, rare earth element 0.5-1.0, copper powder 0.7-1.4, silver powder 0.6-1.2, cobalt oxide powder 0.4-0.8, diatomite 8-12, alkylphenol polyoxyethylene 0.6-1.2, Silane coupling agent KH550 0.7-1.4, the salpeter solution 20-40 of 20%, the sodium hydroxide solution 20-40 of 30%, polyvinyl alcohol 1-2, st-yrax n-butyl ether 0.3-0.5, ferric acetyl acetonade 0.2-0.4, distilled water 100, diatomite is ground into particle and binchotan to be added in the salpeter solution of 20% and to soak 20 minutes by preparation method after high-temperature calcination, wash with water in neutral, to be immersed in the solution of the sodium hydroxide of 30% 30 minutes again, wash with water and add copper powder in neutral post-drying, silver powder, it is for subsequent use that cobalt oxide powder and 10-30% Silane coupling agent KH550 grind to form fine powder, again alkylphenol polyoxyethylene is added in distilled water and dissolves, raised temperature to 85 ° about C, add the above-mentioned fine powder worn under 1000-1200 rev/min, stir the uniform mixed solution of formation, add nano-titania photocatalyst again, nano silicon, st-yrax n-butyl ether, ferric acetyl acetonade, rare earth element and remaining Silane coupling agent KH550 grinding distribution 0.5-1.0 hour, dry.
2. the glass door use coating of a kind of heat insulation mildew-resistant according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-307, sodium Diacetate, whiteruss, fatty acid polyglycol ester, diethylene glycol monobutyl ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds ethylene glycol monobutyl ether, Aceonon 300 MO stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds epoxy resin latex, water-based alkyd melamine stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent NQ-71, pigment, zinc powder, hollow glass powder, ceramics powder microballoon, polymer microballoon, modified nano-titanium dioxide photocatalyst, nano heavy calcium carbonate uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568671.8A CN104449281A (en) | 2014-10-23 | 2014-10-23 | Heat-insulating and mildew-resistant water-based paint for glass door and preparation method of water-based paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568671.8A CN104449281A (en) | 2014-10-23 | 2014-10-23 | Heat-insulating and mildew-resistant water-based paint for glass door and preparation method of water-based paint |
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| CN104449281A true CN104449281A (en) | 2015-03-25 |
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| CN201410568671.8A Pending CN104449281A (en) | 2014-10-23 | 2014-10-23 | Heat-insulating and mildew-resistant water-based paint for glass door and preparation method of water-based paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090242A (en) * | 2017-06-16 | 2017-08-25 | 广东东华光电科技有限公司 | A kind of complete mute white paint of environmentally friendly minute surface |
| CN108485407A (en) * | 2018-02-01 | 2018-09-04 | 东莞市佳乾新材料科技有限公司 | A kind of indoor purifying air type water paint |
| CN115260837A (en) * | 2022-08-03 | 2022-11-01 | 福建泰新泉科技有限公司 | Pigment treatment method and water-based high-temperature-resistant ink composition |
| CN115537061A (en) * | 2022-09-23 | 2022-12-30 | 四川宏凯化工科技有限公司 | Water-based paint odor scavenger and preparation method thereof |
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| CN101050065A (en) * | 2007-05-15 | 2007-10-10 | 朱建强 | Composition of insulating mold coating in use for glass, and preparation method |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN101812269A (en) * | 2010-04-12 | 2010-08-25 | 刘清华 | Solar heat radiation reflection coating |
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2014
- 2014-10-23 CN CN201410568671.8A patent/CN104449281A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050065A (en) * | 2007-05-15 | 2007-10-10 | 朱建强 | Composition of insulating mold coating in use for glass, and preparation method |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN101812269A (en) * | 2010-04-12 | 2010-08-25 | 刘清华 | Solar heat radiation reflection coating |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090242A (en) * | 2017-06-16 | 2017-08-25 | 广东东华光电科技有限公司 | A kind of complete mute white paint of environmentally friendly minute surface |
| CN108485407A (en) * | 2018-02-01 | 2018-09-04 | 东莞市佳乾新材料科技有限公司 | A kind of indoor purifying air type water paint |
| CN115260837A (en) * | 2022-08-03 | 2022-11-01 | 福建泰新泉科技有限公司 | Pigment treatment method and water-based high-temperature-resistant ink composition |
| CN115260837B (en) * | 2022-08-03 | 2023-06-06 | 福建泰新泉科技有限公司 | Pigment treatment method and water-based high-temperature-resistant ink composition |
| CN115537061A (en) * | 2022-09-23 | 2022-12-30 | 四川宏凯化工科技有限公司 | Water-based paint odor scavenger and preparation method thereof |
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Application publication date: 20150325 |
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