CN107674465A - A kind of preparation method for strengthening environmentally friendly diatom ooze coating - Google Patents
A kind of preparation method for strengthening environmentally friendly diatom ooze coating Download PDFInfo
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- CN107674465A CN107674465A CN201711213094.0A CN201711213094A CN107674465A CN 107674465 A CN107674465 A CN 107674465A CN 201711213094 A CN201711213094 A CN 201711213094A CN 107674465 A CN107674465 A CN 107674465A
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- Prior art keywords
- parts
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- diatom ooze
- environmentally friendly
- ooze coating
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Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 35
- 238000000576 coating method Methods 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000005728 strengthening Methods 0.000 title claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims abstract description 39
- 229920000728 polyester Polymers 0.000 claims abstract description 32
- 230000004913 activation Effects 0.000 claims abstract description 31
- 229920005610 lignin Polymers 0.000 claims abstract description 27
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 16
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 16
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000002500 ions Chemical class 0.000 claims abstract description 11
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 11
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims abstract description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 5
- 230000002708 enhancing effect Effects 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 44
- 239000002002 slurry Substances 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 30
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 28
- 235000014676 Phragmites communis Nutrition 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 24
- 239000008187 granular material Substances 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 24
- 150000001450 anions Chemical class 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 23
- 239000013530 defoamer Substances 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 239000002270 dispersing agent Substances 0.000 claims description 20
- 239000011159 matrix material Substances 0.000 claims description 20
- 239000010453 quartz Substances 0.000 claims description 19
- 241000589517 Pseudomonas aeruginosa Species 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000002893 slag Substances 0.000 claims description 17
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims description 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
- 239000001294 propane Substances 0.000 claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 14
- 239000000919 ceramic Substances 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 7
- 241000233805 Phoenix Species 0.000 claims description 7
- 240000008042 Zea mays Species 0.000 claims description 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 230000003213 activating effect Effects 0.000 claims description 7
- 239000001110 calcium chloride Substances 0.000 claims description 7
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 7
- 235000005822 corn Nutrition 0.000 claims description 7
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000011081 inoculation Methods 0.000 claims description 7
- 239000002054 inoculum Substances 0.000 claims description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 7
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 7
- 229920000053 polysorbate 80 Polymers 0.000 claims description 7
- 229910052573 porcelain Inorganic materials 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 238000004062 sedimentation Methods 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 7
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 238000001238 wet grinding Methods 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229940125782 compound 2 Drugs 0.000 claims description 3
- 230000033228 biological regulation Effects 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims 1
- 239000001963 growth medium Substances 0.000 claims 1
- 239000002609 medium Substances 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 20
- 239000001301 oxygen Substances 0.000 abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 abstract description 8
- 239000000377 silicon dioxide Substances 0.000 abstract description 5
- 235000013312 flour Nutrition 0.000 abstract description 4
- -1 oxygen ion Chemical class 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000000855 fermentation Methods 0.000 abstract description 2
- 230000004151 fermentation Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 230000000813 microbial effect Effects 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000006872 improvement Effects 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 235000019256 formaldehyde Nutrition 0.000 description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 229920001568 phenolic resin Polymers 0.000 description 5
- 239000005011 phenolic resin Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 239000011032 tourmaline Substances 0.000 description 2
- 229940070527 tourmaline Drugs 0.000 description 2
- 229910052613 tourmaline Inorganic materials 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 108010029541 Laccase Proteins 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 239000012675 alcoholic extract Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000013632 homeostatic process Effects 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229920006150 hyperbranched polyester Polymers 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000010563 solid-state fermentation Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The present invention provides a kind of preparation method for strengthening environmentally friendly diatom ooze coating, by preparing activation lignin and phenol reactant part fortified phenol with microbial fermentation, using hyper-branched polyester as medium, using porous material silica flour load negative ion powder and lignin fortified phenol and formaldehyde, then it is mixed with and obtains under high speed with diatomite, hydroxyethyl cellulose, inorganic pigment, calcium hydroxide.Enhancing environmental protection diatom ooze coating abrasion resistance prepared by the present invention is high, and curing rate is fast, while the burst size of harmful substance formaldehyde is few, with air contact energy releasing negative oxygen ion, with good air-filtering ability, belong to environment-friendly type macromolecule material, possess outstanding development potentiality.
Description
Technical field
The invention belongs to chemical field of polymer material preparing technology, more particularly to a kind of environmentally friendly diatom ooze coating of enhancing
Preparation method.
Background technology
With the continuous improvement of people's living standards, the requirement to domestic environment is also increasingly paid attention to, for the dress in house
Effect after repairing and fitting up also is paid close attention to.A kind of green inner wall decoration wall material using diatomite as main raw material(s) of diatom ooze.
It, which has, eliminates the work(such as formaldehyde, purification air, regulation humidity, releasing negative oxygen ion, fire protection flame retarding, the self-cleaning, deodorization and sterilization of metope
Energy.But the aggregate that the making of existing diatom ooze decorative wall material uses is quartz or dolomite, and specific surface area is small, absorb-discharge humid
Energy and purification of air performance are all very low.The anti-crack fiber of existing product intensity deficiency, is coated onto on wall over time because plasticity is big
It will ftracture.And the easy mould growth of cellulose fibre, the antiseptic used is calcium hydroxide, calcium hydroxide and two in air
Carbonoxide slow reaction generates calcium carbonate, anti-microbial property will be lost after certain time, although the vapor partial pressure of organic antibacterial agent
It is smaller, but also have certain toxicity, IAQ can be influenceed.Also it is exactly to show product merely using diatomite as formaldehyde catching
Agent, kieselguhr adsorption are desorption and the homeostasis process of absorption, are also being discharged while absorption.Therefore say at present in reality
The diatom ooze decorative wall material of middle application is less desirable.
Patent of invention CN201310628130.5, a kind of Ecological diatom ooze decorative wall material, by diatomite, inorganic pigment,
Calcined zeolite, ethene-vinyl acetate redispersible rubber powder, attapulgite powder, tourmaline load nano-titanium dioxide, polyester are fine
Dimension, adipic dihydrazide etc. mix.The primary functional components of the invention are diatomite, because diatomite has porous knot
Structure, there is heat-insulation and heat-preservation function, the relative humidity of the interior space can be made to be automatically adjusted in 40%~70%；The tourmaline of use
Anion caused by load nano-titanium dioxide has sterilizing function, adsorbable resolving harmful gas, using calcined zeolite conduct
Aggregate, it is because it has the characteristics of loose structure, specific surface area is big, improves moisture adsorption and releasing and purify the function of air；Using
Polyester fiber adds intensity, improves anti-crack ability, and will not go mouldy as anti-crack fiber；Use calcium perborate for
Bactericide is long-acting nontoxic.Solve the problems, such as that existing decoration wall material is present, and method is simple, it is easy to implement..
Patent of invention CN201510888573.7, a kind of new liquid diatom ooze wall material and preparation method thereof, the wall material
It is made up of the composition of following mass fraction：Diatomite 35 ~ 45%, mesohole nano-titanium dioxide 15 ~ 20%, new sustained release glass
Microballoon 5 ~ 8%, Paris white 3.5 ~ 10%, plant cellulose 2 ~ 3%, defoamer 0.1 ~ 0.3%, deionized water surplus.The preparation
Method is using modification of the sodium alginate to sustained release glass microsphere surface so that and microballoon has good dispersiveness in the base, and
Sodium alginate also acts as the effect of dispersant and binding agent in wall material, and without another bonus point powder and binding agent, not only environmental protection is gone back
Save the energy；Also, the release fragrance that glass microsphere can be permanent is sustained, makes wall material that there is long-term bactericidal, insect prevention to prevent
It is mould and other effects, solve the drawbacks of diatom ooze wall material hygroscopicity is big, easily mouldy.In addition, new liquid made from the preparation method
Diatom ooze wall material, has a permanent storage stability, not stratified in Storage period, and storage and transport are easy in gel..
Patent of invention CN201510574339.7, a kind of environmentally friendly diatom ooze composite and preparation method thereof, by diatomite
30 ~ 50%, dicalcium powder 3 ~ 12%, quartz sand 8 ~ 20%, pH adjusting agent 10 ~ 15%, calcined kaolin 6 ~ 10%, talcum powder 4 ~
10%th, sepiolite 5 ~ 10%, pigment 2 ~ 5%, pre-gelatinized starch 2 ~ 4%, hydroxypropyl methyl cellulose 1 ~ 3%, dispersibility breast
Glue 1 ~ 2%, starch ether 1 ~ 2%, sodium tripolyphosphate 0.5 ~ 2%, calgon 0.5 ~ 2%, polyvinyl alcohol 0.5 ~ 1%, Guar
Glue 0.1 ~ 0.5% and nano titanium oxide 0.1 ~ 3% form.The invention preparation method is simple, and construction is easy, and diatomite is porous
Material, can adsorb with the harmful substance such as decomposing formaldehyde, toluene, while there is humidity conditioning function, remove odor function.
In the prior art, the diatom ooze of preparation possesses miscellaneous function, but it is low wearability to be still present, is harmful to
The shortcomings of gas formaldehyde burst size is more, and detergent power is weak.
The content of the invention
The deficiency existing for the diatom ooze coating for preparing in the prior art, the present invention, which provides, a kind of strengthens environmentally friendly diatom ooze
The preparation method of coating.
The present invention is achieved by the following technical solutions：
A kind of preparation method for strengthening environmentally friendly diatom ooze coating, is prepared by following steps：
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 60 ~ 70%, add reed slag
The Tween-80 of amount 0.05 ~ 0.15%, packed after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 ~ 3 days,
Cultivation matrix is obtained, then in being inoculated with phoenix tail mushroom on cultivation matrix, is persistently cultivated 12 ~ 16 days, cultivation temperature is maintained at 37 ~ 45
℃；
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3 ~ 3.5, under normal temperature
45 ~ 60min is reacted, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）40 ~ 50 parts of water, 0.5 ~ 0.7 part of dispersant, 5040,0.2 ~ 0.3 parts of defoamer A10 are mixed by ratio of weight and the number of copies, first
It is scattered to stir and evenly mix, add powder quartz ore and ball milling is carried out into porcelain mill, control the solid-to-liquid ratio to be（2~5）:1, choose ball
Expect that ratio is（3~5）:1 Ceramic Balls, sequentially add 0.3% dispersant and 0.1% defoamer, and rotating speed is 70 revs/min, ball milling
Time is 3.0 ~ 4.0h, prepares konilite slurry, then adds hydroxyethyl cellulose, prevents the sedimentation of konilite slurry, obtains
The konilite slurry arrived；
（2）40 ~ 50 parts of water, 5 ~ 10 parts of hydroxy ethyl fiber solution mixing are taken by ratio of weight and the number of copies, by negative ion powder according to solid-to-liquid ratio
For 1:1 ratio adds, and is then transferred to vertical mixing mill, ratio of grinding media to material is（3~5）:1 Ceramic Balls, sequentially add 0.3% it is scattered
The defoamer A10 of agent 5040 and 0.1%, 1 ~ 2h of ball milling, obtain anion agent slurry；
（3）It is according to mass ratio by konilite slurry and anion slurry（12~25）:1 mixing, is added to sand mill, ratio of grinding media to material
For（3~5）：1 zirconium ball 30 ~ 60min of wet grinding, is fitted into centrifuge tube, is washed with deionized 3 ~ 4 times, is air-dried under normal temperature,
Obtain quartz-anion composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 20 ~ 30 parts of propane, constant temperature melts in 210 DEG C of oil baths
Melt, trimesic acid is added, with 0.1 ~ 0.5 part of stannous octoate；After 3.0 ~ 5.0h of heating stirring, vacuumize and keep strong stirring
1.0 ~ 2.0h is reacted, reaction is poured into methanol and precipitated, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol while hot after terminating,
40 ~ 60h is dried at 100 DEG C, obtains hyper-branched polyester solid；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, 10 ~ 15 parts of lignin of activation is taken, quartz -12 ~ 24 parts of anion composite granule, hyper-branched polyester is solid
1 ~ 3 part of body, 6 ~ 10 parts of phenol, 1 ~ 4 part of sodium hydroxide, 10 ~ 12 parts of formaldehyde, 10 ~ 24 parts of water, it is well mixed and adds in reactor,
80 ~ 100 DEG C are warming up to, 1 ~ 2h of isothermal reaction obtains compound, and 20 ~ 46 parts of diatomite, ethoxy are then added in compound
2 ~ 5 parts of cellulose, 5 ~ 10 parts of inorganic pigment, 2 ~ 5 parts of calcium hydroxide, 60 ~ 100min is mixed under 800 ~ 1000rpm, you can
To the environmentally friendly diatom ooze coating of enhancing.
Pseudomonas aeruginosa and phoenix-tail mushroom solid state fermentation reed slag, it can effectively decompose cellulose in reed slag and wooden
Element；Rhamnolipid caused by pseudomonas aeruginosa fermentation can promote decomposition of the phoenix-tail mushroom secretion laccase to reed slag lignin, living
Change and improve methylol, phenolic hydroxyl group, alcoholic extract hydroxyl group content on lignin molecule, so as to improve lignin and the phenolic resin degree of polymerization.
Quartzy main component is silica, has porous performance, can load more negative oxygen ions, adsorbs free formaldehyde
And phenol, while negative ion powder contacts with moisture in air or oxygen, releasing negative oxygen ion after ionizing, and improves air matter
Amount；The many combination hyper-branched polyesters of quartzy loose structure energy, further improve the degree of polymerization of phenolic resin adhesive.Bear from
Sub- addition be 4 ~ 8% between when, purifying formaldehyde rate changes small, but anion between 91 ~ 94%, more than 8% after-purification rate
The Percentage bound of powder and silica flour reduces with the increase of negative ion powder addition, therefore is best with 4 ~ 8%.
Hyper-branched polyester has highly branched molecular structure, and radical species are more, and solubility high viscosity is low, can effectively carry
The polymerization speed of high phenolic resin, improve the intensity of resin glue；The characteristics of its radical species is more simultaneously, can more it combine free
Phenol and formaldehyde, reduce the release of phenol and formaldehyde so as to improve Environmental security；On the other hand, phenolic resin is due to lignin
With the addition of silica flour complex, gel-forming property is influenceed, this influence can be eliminated using hyper-branched polyester.
As a further improvement on the present invention, step 1（1）Described pseudomonas aeruginosa fills liquid prior to activation medium
Measure in the conical flask for 20%, inoculum concentration 5%, 37 DEG C, 12 ~ 16h of activation culture under 200rpm.
As a further improvement on the present invention, the activation medium is prepared by following density component material：Vegetable seed
Oily 30g/L, Dried Corn Steep Liquor Powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L,
CaCl20.05g/L, NaCl 1.5g/L, adjust pH to 6.5 ~ 7.0.
In best medium, the rhamnolipid average product that pseudomonas aeruginosa ferments to obtain is 30.41 ~ 34.52g/L.
As a further improvement on the present invention, step 2（1）Described powder quartz ore fineness is 200 ~ 300 mesh.
The granule size of konilite determines its dispersive property and absorption property, and granularity is smaller to disperse better but adsorption capacity
It is low, therefore in order to preferably disperse to adsorb negative ion powder simultaneously, the silica flour using 200 ~ 300 mesh is best.
As a further improvement on the present invention, the double [4- of 2,2- described in step 3（2- hydroxy ethoxies）Phenyl] propane with
The mol ratio of benzenetricarboxylic acid is（2~4）:1.
The mol ratio of two kinds of monomers influences hyper-branched polyester molecular weight and the dissaving polymer of terminal groups, and 2,2- is double
[4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:Terminal groups dispersiveness big poly- can be obtained when 1
Ester, there are more binding sites（Group）, so as to promote the intensity of resin reaction polymerization speed and resin, anti-wear performance.
As a further improvement on the present invention, the quartz described in step 4-anion composite granule is consolidated with hyper-branched polyester
Body amount ratio is（8~15）：1.
The content of hyper-branched polyester influences resin integrally curing conversion ratio, and content high resin solidification conversion ratio is low, and content is low
Resin bonding strength and anti-wear performance are low, when hyperbranched poly ester content is 5 ~ 15%, the solidification conversion ratio of phenolic resin for 95 ~
98%, anti-wear performance and bond strength rate of change are small, overall resin property are influenceed little.
As a further improvement on the present invention, the viscosity of the hydroxyethyl cellulose described in step 4 is 5000 ~ 8000.
Hydroxyethyl cellulose can play thickening, protection hydrate colloid, the smear strengthened adhesive power, improve slurry
Effect, while the anti-wear performance for improving coating can be combined with hyper-branched polyester, viscosity is too high to accelerate paint adhesion speed.
Beneficial effects of the present invention：
1st, preparation technology of the present invention requires low, it is not necessary to high capital equipment and raw material, has good economic benefit；
2nd, the diatom ooze coating that is prepared into of the present invention is safe and reliable, and burst size of methanal is low, at the same can also discharge beneficial negative oxygen from
Son, environmental pollution is low, meets demand of the people to environment-friendly materials；
3rd, the diatom ooze coating abrasion resistance for preparing of the present invention is high, and curing rate is fast, and bonding strength is high, has excellent water-fast resistance to
Climate performance.
Embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 60%, add reed slag quality
0.05% Tween-80, pack after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 days, cultivated
Matrix, then in being inoculated with phoenix tail mushroom on cultivation matrix, persistently cultivate 12 days, cultivation temperature is maintained at 37 DEG C；
In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component material：Rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L, adjust pH to 6.5；
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, it is 3 to add acetic acid to pH, is reacted under normal temperature
45min, solid residue is then filtered to remove, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）40 parts of water, 0.5 part of dispersant, 5040,0.2 parts of defoamer A10 are mixed by ratio of weight and the number of copies, it is mixed first to disperse stirring
It is even, add the powder quartz ore that fineness is 200 mesh and ball milling is carried out into porcelain mill, it is 2 to control solid-to-liquid ratio:1, choose ball material
Than for 3:1 Ceramic Balls, 0.3% dispersant and 0.1% defoamer are sequentially added, rotating speed is 70 revs/min, Ball-milling Time is
3.0h, konilite slurry is prepared, then adds hydroxyethyl cellulose, prevent the sedimentation of konilite slurry, obtained konilite
Slurry；
（2）40 parts of water, the mixing of 5 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1 by negative ion powder:1
Ratio adds, and is then transferred to vertical mixing mill, ratio of grinding media to material 3:1 Ceramic Balls, sequentially add 0.3% He of dispersant 5040
0.1% defoamer A10, ball milling 1h, obtain anion agent slurry；
（3）According to mass ratio it is 12 by konilite slurry and anion slurry：1 mixing, is added to sand mill, ratio of grinding media to material 3：1
Zirconium ball wet grinding 30min, be fitted into centrifuge tube, be washed with deionized 3 ~ 4 times, under normal temperature air-dry, obtain quartz-bear from
Sub- composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 20 parts of propane, constant temperature melts in 210 DEG C of oil baths,
Add trimesic acid（2,2- double [4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:1）, with 0.1
Part stannous octoate；After heating stirring 3.0h, vacuumize and keep strong stirring to react 1.0h, reaction pours into methanol while hot after terminating
Middle precipitation, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol, 40h is dried at 100 DEG C, hyper-branched polyester is obtained and consolidates
Body；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take and activate 10 parts of lignin, quartz -12 parts of anion composite granule, 1 part of hyper-branched polyester solid,
6 parts of phenol, 1 part of sodium hydroxide, 10 parts of formaldehyde, 10 parts of water, it is well mixed and adds in reactor, be warming up to 80 ~ 100 DEG C, constant temperature
Reaction 1h obtains compound, and 20 parts of diatomite, 2 parts of hydroxyethyl cellulose, 5 parts of inorganic pigment, hydrogen are then added in compound
2 parts of calcium oxide, mixes 60min at 800 rpm, you can obtains strengthening environmentally friendly diatom ooze coating.
Embodiment 2
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 70%, add reed slag quality
0.15% Tween-80, pack after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, cultivated
Matrix, then in being inoculated with phoenix tail mushroom on cultivation matrix, persistently cultivate 16 days, cultivation temperature is maintained at 45 DEG C；
In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 16h under 200rpm；The activation medium is prepared by following density component material：Rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L, adjust pH to 7.0
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.5, anti-under normal temperature
60min is answered, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）50 parts of water, 0.7 part of dispersant, 5040,0.3 parts of defoamer A10 are mixed by ratio of weight and the number of copies, it is mixed first to disperse stirring
It is even, add the powder quartz ore that fineness is 300 mesh and ball milling is carried out into porcelain mill, it is 5 to control solid-to-liquid ratio:1, choose ball material
Than for 5:1 Ceramic Balls, 0.3% dispersant and 0.1% defoamer are sequentially added, rotating speed is 70 revs/min, Ball-milling Time is
4.0h, konilite slurry is prepared, then adds hydroxyethyl cellulose, prevent the sedimentation of konilite slurry, obtained konilite
Slurry；
（2）50 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1 by negative ion powder:1
Ratio add, be then transferred to vertical mixing mill, ratio of grinding media to material 5:1 Ceramic Balls, sequentially add 0.3% He of dispersant 5040
0.1% defoamer A10, ball milling 2h, obtain anion agent slurry；
（3）According to mass ratio it is 25 by konilite slurry and anion slurry:1 mixing, is added to sand mill, ratio of grinding media to material 5：1
Zirconium ball wet grinding 60min, be fitted into centrifuge tube, be washed with deionized 3 ~ 4 times, under normal temperature air-dry, obtain quartz-bear from
Sub- composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 30 parts of propane, constant temperature melts in 210 DEG C of oil baths,
Add trimesic acid（2,2- double [4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:1）, with 0.5
Part stannous octoate；After heating stirring 5.0h, vacuumize and keep strong stirring to react 2.0h, reaction pours into methanol while hot after terminating
Middle precipitation, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol, 60h is dried at 100 DEG C, hyper-branched polyester is obtained and consolidates
Body；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take and activate 15 parts of lignin, quartz -24 parts of anion composite granule, 3 parts of hyper-branched polyester solid,
10 parts of phenol, 4 parts of sodium hydroxide, 12 parts of formaldehyde, 24 parts of water, it is well mixed and adds in reactor, be warming up to 100 DEG C, constant temperature is anti-
Answer 2h to obtain compound, 46 parts of diatomite, 5 parts of hydroxyethyl cellulose, 10 parts of inorganic pigment, hydrogen-oxygen are then added in compound
Change 5 parts of calcium, mix 100min under 1000rpm, you can obtain strengthening environmentally friendly diatom ooze coating.
Embodiment 3
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 65%, add reed slag quality
0.1% Tween-80, packed after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, obtain cultivation base
Matter, then in being inoculated with phoenix tail mushroom on cultivation matrix, persistently cultivate 14 days, cultivation temperature is maintained at 40 DEG C；
In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 14h under 200rpm；The activation medium is prepared by following density component material：Rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L, adjust pH to 6.5 ~ 7.0
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.3, anti-under normal temperature
50min is answered, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）45 parts of water, 0.6 part of dispersant, 5040,0.25 parts of defoamer A10 are mixed by ratio of weight and the number of copies, it is mixed first to disperse stirring
It is even, add the powder quartz ore that fineness is 220 mesh and ball milling is carried out into porcelain mill, it is 3 to control solid-to-liquid ratio:1, choose ball material
Than for 4:1 Ceramic Balls, 0.3% dispersant and 0.1% defoamer are sequentially added, rotating speed is 70 revs/min, Ball-milling Time is
3.5h, konilite slurry is prepared, then adds hydroxyethyl cellulose, prevent the sedimentation of konilite slurry, obtained konilite
Slurry；
（2）45 parts of water, the mixing of 8 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1 by negative ion powder:1
Ratio adds, and is then transferred to vertical mixing mill, ratio of grinding media to material 4:1 Ceramic Balls, sequentially add 0.3% He of dispersant 5040
0.1% defoamer A10, ball milling 1.5h, obtain anion agent slurry；
（3）According to mass ratio it is 20 by konilite slurry and anion slurry:1 mixing, is added to sand mill, ratio of grinding media to material 4：1
Zirconium ball wet grinding 50min, be fitted into centrifuge tube, be washed with deionized 3 ~ 4 times, under normal temperature air-dry, obtain quartz-bear from
Sub- composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 25 parts of propane, constant temperature melts in 210 DEG C of oil baths,
Add trimesic acid（2,2- double [4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:1）, with 0.4
Part stannous octoate；After heating stirring 4.0h, vacuumize and keep strong stirring to react 1.5h, reaction pours into methanol while hot after terminating
Middle precipitation, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol, 50h is dried at 100 DEG C, hyper-branched polyester is obtained and consolidates
Body；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take and activate 12 parts of lignin, quartz -18 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
8 parts of phenol, 2 parts of sodium hydroxide, 11 parts of formaldehyde, 17 parts of water, it is well mixed and adds in reactor, be warming up to 80 ~ 100 DEG C, constant temperature
Reaction 2h obtains compound, and 22 parts of diatomite, 3 parts of hydroxyethyl cellulose, 5 parts of inorganic pigment, hydrogen are then added in compound
3 parts of calcium oxide, 80min is mixed under 900rpm, you can obtains strengthening environmentally friendly diatom ooze coating.
Embodiment 4
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 62%, add reed slag quality
0.15% Tween-80, pack after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 days, cultivated
Matrix, then in being inoculated with phoenix tail mushroom on cultivation matrix, persistently cultivate 16 days, cultivation temperature is maintained at 40 DEG C；
In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component material：Rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L, adjust pH to 6.5 ~ 7.0
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.3, anti-under normal temperature
50min is answered, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）42 parts of water, 0.5 part of dispersant, 5040,0.3 parts of defoamer A10 are mixed by ratio of weight and the number of copies, it is mixed first to disperse stirring
It is even, add the powder quartz ore that fineness is 220 mesh and ball milling is carried out into porcelain mill, it is 2 to control solid-to-liquid ratio:1, choose ball material
Than for 5:1 Ceramic Balls, 0.3% dispersant and 0.1% defoamer are sequentially added, rotating speed is 70 revs/min, Ball-milling Time is
3.0h, konilite slurry is prepared, then adds hydroxyethyl cellulose, prevent the sedimentation of konilite slurry, obtained konilite
Slurry；
（2）40 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1 by negative ion powder:1
Ratio add, be then transferred to vertical mixing mill, ratio of grinding media to material 5:1 Ceramic Balls, sequentially add 0.3% He of dispersant 5040
0.1% defoamer A10, ball milling 2.0h, obtain anion agent slurry；
（3）According to mass ratio it is 15 by konilite slurry and anion slurry:1 mixing, is added to sand mill, ratio of grinding media to material 5：1
Zirconium ball wet grinding 60min, be fitted into centrifuge tube, be washed with deionized 3 ~ 4 times, under normal temperature air-dry, obtain quartz-bear from
Sub- composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 25 parts of propane, constant temperature melts in 210 DEG C of oil baths,
Add trimesic acid（2,2- double [4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:1）, with 0.4
Part stannous octoate；After heating stirring 5.0h, vacuumize and keep strong stirring to react 1.0h, reaction pours into methanol while hot after terminating
Middle precipitation, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol, 40h is dried at 100 DEG C, hyper-branched polyester is obtained and consolidates
Body；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take and activate 12 parts of lignin, quartz -20 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
8 parts of phenol, 2 parts of sodium hydroxide, 10 parts of formaldehyde, water 15, it is well mixed and adds in reactor, be warming up to 80 ~ 100 DEG C, constant temperature is anti-
Answer 1.5h to obtain compound, 22 parts of diatomite, 3 parts of hydroxyethyl cellulose, 10 parts of inorganic pigment, hydrogen are then added in compound
5 parts of calcium oxide, 100min is mixed under 1000rpm, you can obtains strengthening environmentally friendly diatom ooze coating.
Embodiment 5
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 65%, add reed slag quality
0.15% Tween-80, pack after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 3 days, cultivated
Matrix, then in being inoculated with phoenix tail mushroom on cultivation matrix, persistently cultivate 16 days, cultivation temperature is maintained at 40 DEG C；
In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
Activation culture 12h under 200rpm；The activation medium is prepared by following density component material：Rapeseed oil 30g/L, corn
Paste dry powder 6g/L, NaNO36g/L, K2HPO40.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L,
NaCl 1.5g/L, adjust pH to 6.5；
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3.5, anti-under normal temperature
60min is answered, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）45 parts of water, 0.7 part of dispersant, 5040,0.3 parts of defoamer A10 are mixed by ratio of weight and the number of copies, it is mixed first to disperse stirring
It is even, add the powder quartz ore that fineness is 300 mesh and ball milling is carried out into porcelain mill, it is 4 to control solid-to-liquid ratio:1, choose ball material
Than for 4:1 Ceramic Balls, 0.3% dispersant and 0.1% defoamer are sequentially added, rotating speed is 70 revs/min, Ball-milling Time is
4.0h, konilite slurry is prepared, then adds hydroxyethyl cellulose, prevent the sedimentation of konilite slurry, obtained konilite
Slurry；
（2）45 parts of water, the mixing of 10 parts of hydroxy ethyl fiber solution are taken by ratio of weight and the number of copies, according to solid-to-liquid ratio are 1 by negative ion powder:1
Ratio add, be then transferred to vertical mixing mill, ratio of grinding media to material 5:1 Ceramic Balls, sequentially add 0.3% He of dispersant 5040
0.1% defoamer A10, ball milling 2h, obtain anion agent slurry；
（3）According to mass ratio it is 15 by konilite slurry and anion slurry：1 mixing, is added to sand mill, ratio of grinding media to material 3：1
Zirconium ball wet grinding 50min, be fitted into centrifuge tube, be washed with deionized 3 ~ 4 times, under normal temperature air-dry, obtain quartz-bear from
Sub- composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 30 parts of propane, constant temperature melts in 210 DEG C of oil baths,
Add trimesic acid（2,2- double [4-（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is 2:1）, with 0.5
Part stannous octoate；After heating stirring 4.0h, vacuumize and keep strong stirring to react 2.0h, reaction pours into methanol while hot after terminating
Middle precipitation, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol, 48h is dried at 100 DEG C, hyper-branched polyester is obtained and consolidates
Body；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, take and activate 15 parts of lignin, quartz -18 parts of anion composite granule, 2 parts of hyper-branched polyester solid,
8 parts of phenol, 2 parts of sodium hydroxide, 12 parts of formaldehyde, 22 parts of water, it is well mixed and adds in reactor, be warming up to 90 DEG C, isothermal reaction
1.5h obtains compound, and 44 parts of diatomite, 4 parts of hydroxyethyl cellulose, 8 parts of inorganic pigment, hydrogen-oxygen are then added in compound
Change 5 parts of calcium, mix 100min under 1000rpm, you can obtain strengthening environmentally friendly diatom ooze coating.
Diatom ooze coating prepared by comprehensive detection embodiment 1 ~ 5, its performance such as table 1.
Table 1 strengthens environmentally friendly diatom ooze coating performance table
As shown in Table 1, the environmentally friendly diatom ooze coating that prepared by the present invention meets safe mark, has good performance and purification of air
Ability.
Above example is only the exemplary embodiment of the present invention, is not used in the limitation present invention, protection scope of the present invention
It is defined by the claims.Those skilled in the art can make various repair to the present invention in the essence and protection domain of the present invention
Change or equivalent substitution, this modification or equivalent substitution also should be regarded as being within the scope of the present invention.
Claims (7)
1. a kind of preparation method for strengthening environmentally friendly diatom ooze coating, it is characterised in that be prepared by following steps：
First, activation lignin is prepared
（1）Take reed stems and leaves, be ground into reed slag, sprinkle water it is moistened to water content be 60 ~ 70%, add reed slag
The Tween-80 of amount 0.05 ~ 0.15%, packed after well mixed, after inoculation pseudomonas aeruginosa carries out sterile solid culture 2 ~ 3 days,
Cultivation matrix is obtained, then in being inoculated with phoenix tail mushroom on cultivation matrix, is persistently cultivated 12 ~ 16 days, cultivation temperature is maintained at 37 ~ 45
℃；
（2）Take culture ripe and extract the cultivation matrix after phoenix-tail mushroom, be milled to powder, addition acetic acid to pH is 3 ~ 3.5, under normal temperature
45 ~ 60min is reacted, is then filtered to remove solid residue, obtains activating lignin；
2nd, quartz-anion composite granule is prepared
（1）40 ~ 50 parts of water, 0.5 ~ 0.7 part of dispersant, 5040,0.2 ~ 0.3 parts of defoamer A10 are mixed by ratio of weight and the number of copies, first
It is scattered to stir and evenly mix, add powder quartz ore and ball milling is carried out into porcelain mill, control the solid-to-liquid ratio to be（2~5）:1, choose ball
Expect that ratio is（3~5）:1 Ceramic Balls, sequentially add 0.3% dispersant and 0.1% defoamer, and rotating speed is 70 revs/min, ball milling
Time is 3.0 ~ 4.0h, prepares konilite slurry, then adds hydroxyethyl cellulose, prevents the sedimentation of konilite slurry, obtains
The konilite slurry arrived；
（2）40 ~ 50 parts of water, 5 ~ 10 parts of hydroxy ethyl fiber solution mixing are taken by ratio of weight and the number of copies, by negative ion powder according to solid-to-liquid ratio
For 1:1 ratio adds, and is then transferred to vertical mixing mill, ratio of grinding media to material is（3~5）:1 Ceramic Balls, sequentially add 0.3% it is scattered
The defoamer A10 of agent 5040 and 0.1%, 1 ~ 2h of ball milling, obtain anion agent slurry；
（3）It is according to mass ratio by konilite slurry and anion slurry（12~25）:1 mixing, is added to sand mill, ratio of grinding media to material
For（3~5）：1 zirconium ball 30 ~ 60min of wet grinding, is fitted into centrifuge tube, is washed with deionized 3 ~ 4 times, is air-dried under normal temperature,
Obtain quartz-anion composite granule；
3rd, hyper-branched polyester is prepared
By quality parts ratio, the double [4- of 2,2- are taken（2- hydroxy ethoxies）Phenyl] 20 ~ 30 parts of propane, constant temperature melts in 210 DEG C of oil baths
Melt, trimesic acid is added, with 0.1 ~ 0.5 part of stannous octoate；After 3.0 ~ 5.0h of heating stirring, vacuumize and keep strong stirring
1.0 ~ 2.0h is reacted, reaction is poured into methanol and precipitated, tetrahydrofuran is dissolved in after filtering and is precipitated again in methanol while hot after terminating,
40 ~ 60h is dried at 100 DEG C, obtains hyper-branched polyester solid；
4th, preparing strengthens environmentally friendly diatom ooze coating
By ratio of weight and the number of copies, 10 ~ 15 parts of lignin of activation is taken, quartz -12 ~ 24 parts of anion composite granule, hyper-branched polyester is solid
1 ~ 3 part of body, 6 ~ 10 parts of phenol, 1 ~ 4 part of sodium hydroxide, 10 ~ 12 parts of formaldehyde, 10 ~ 24 parts of water, it is well mixed and adds in reactor,
80 ~ 100 DEG C are warming up to, 1 ~ 2h of isothermal reaction obtains compound, and 20 ~ 46 parts of diatomite, ethoxy are then added in compound
2 ~ 5 parts of cellulose, 5 ~ 10 parts of inorganic pigment, 2 ~ 5 parts of calcium hydroxide, 60 ~ 100min is mixed under 800 ~ 1000rpm, you can
To the environmentally friendly diatom ooze coating of enhancing.
A kind of 2. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 1, it is characterised in that：Step 1
（1）In the conical flask that described pseudomonas aeruginosa is 20% prior to activation medium liquid amount, inoculum concentration 5%, 37 DEG C,
12 ~ 16h of activation culture under 200rpm.
A kind of 3. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 1, it is characterised in that：Step 2
（1）Described powder quartz ore fineness is 200 ~ 300 mesh.
A kind of 4. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 1, it is characterised in that：Step 3 institute
Double [the 4- of 2,2- stated（2- hydroxy ethoxies）Phenyl] mol ratio of propane and trimesic acid is（2~4）:1.
A kind of 5. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 1, it is characterised in that：Step 4 institute
The quartz stated-anion composite granule is with hyper-branched polyester solid amount ratio（8~15）：1.
A kind of 6. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 1, it is characterised in that：Step 4 institute
The viscosity for the hydroxyethyl cellulose stated is 5000 ~ 8000.
A kind of 7. preparation method for strengthening environmentally friendly diatom ooze coating according to claim 2, it is characterised in that：The activation
Culture medium is prepared by following density component material：Rapeseed oil 30g/L, Dried Corn Steep Liquor Powder 6g/L, NaNO36g/L, K2HPO4
0.9g/L, NaH2PO40.6g/L, MgSO40.3g/L, CaCl20.05g/L, NaCl 1.5g/L, regulation pH to 6.5 ~ 7.0 are
Can.
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| CN201810940858.4A CN108659587B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
| CN201810939847.4A CN109082147B (en) | 2017-11-28 | 2017-11-28 | Preparation method of diatom ooze coating for enhancing environmental protection |
| CN201810939846.XA CN109251562B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
| CN201711213094.0A CN107674465B (en) | 2017-11-28 | 2017-11-28 | A kind of preparation method of the environmentally friendly diatom ooze coating of enhancing |
| PCT/CN2018/000046 WO2019104816A1 (en) | 2017-11-28 | 2018-01-25 | Method for preparing enhanced environmentally friendly diatom ooze coating |
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| CN201810939846.XA Division CN109251562B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
| CN201810939847.4A Division CN109082147B (en) | 2017-11-28 | 2017-11-28 | Preparation method of diatom ooze coating for enhancing environmental protection |
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| CN201810939847.4A Active CN109082147B (en) | 2017-11-28 | 2017-11-28 | Preparation method of diatom ooze coating for enhancing environmental protection |
| CN201810939846.XA Active CN109251562B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
| CN201711213094.0A Expired - Fee Related CN107674465B (en) | 2017-11-28 | 2017-11-28 | A kind of preparation method of the environmentally friendly diatom ooze coating of enhancing |
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| CN201810939846.XA Active CN109251562B (en) | 2017-11-28 | 2017-11-28 | Preparation process of reinforced environment-friendly diatom ooze coating |
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| CN109127076A (en) * | 2017-09-01 | 2019-01-04 | 江西理工大学 | A kind of super low energy consumption grinding process of nonferrous metals ore |
| CN109722099A (en) * | 2018-12-28 | 2019-05-07 | 徐州众恒淀粉科技有限公司 | A kind of preparation method of the environmentally friendly diatom ooze coating compound by converted starch |
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| CN112794664A (en) * | 2021-01-13 | 2021-05-14 | 爱上佳环保新材料有限公司 | Long-acting dual-purification material added into diatom ooze and preparation method thereof |
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| CN104877427A (en) * | 2015-05-29 | 2015-09-02 | 桐城市慧琦工贸有限公司 | Diatom ooze coating and preparation method thereof |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
| CN106542773A (en) * | 2016-11-02 | 2017-03-29 | 东莞市爱乐居环保科技有限公司 | A kind of polyester fiber strengthens resistance and splits type diatom mud material and preparation method thereof |
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| CN103613321B (en) * | 2013-11-18 | 2015-06-24 | 贵州联和新型建材有限公司 | Konilite wet ball milling-paint integrated preparation method |
| CN105131739A (en) * | 2015-09-01 | 2015-12-09 | 天长市银狐漆业有限公司 | Environment-friendly humidifying diatom ooze coating |
| CN105153766A (en) * | 2015-10-24 | 2015-12-16 | 洪其祥 | Quick-dry diatom ooze paint |
| CN105524528A (en) * | 2016-02-02 | 2016-04-27 | 贵州联和新型建材有限公司 | Ecological and environment-friendly coating and preparation method thereof |
| CN106673595A (en) * | 2016-12-29 | 2017-05-17 | 欧亚绿邦（北京）科技有限公司 | Water-based diatom ooze coating and preparation method thereof |
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| CN104877427A (en) * | 2015-05-29 | 2015-09-02 | 桐城市慧琦工贸有限公司 | Diatom ooze coating and preparation method thereof |
| CN105542630A (en) * | 2016-01-22 | 2016-05-04 | 立邦工业涂料(上海)有限公司 | Waterborne coil coating polyester rear face paint and preparation method thereof |
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| CN109127076A (en) * | 2017-09-01 | 2019-01-04 | 江西理工大学 | A kind of super low energy consumption grinding process of nonferrous metals ore |
| CN109722099A (en) * | 2018-12-28 | 2019-05-07 | 徐州众恒淀粉科技有限公司 | A kind of preparation method of the environmentally friendly diatom ooze coating compound by converted starch |
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| Publication number | Publication date |
|---|---|
| WO2019104816A1 (en) | 2019-06-06 |
| CN109251562B (en) | 2020-09-25 |
| CN108659587A (en) | 2018-10-16 |
| CN109082147B (en) | 2020-10-02 |
| CN109251562A (en) | 2019-01-22 |
| CN107674465B (en) | 2018-10-09 |
| CN109082147A (en) | 2018-12-25 |
| CN108659587B (en) | 2020-10-02 |
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