CN107686290A - Purify antimicrobial form diatom ooze wall material - Google Patents
Purify antimicrobial form diatom ooze wall material Download PDFInfo
- Publication number
- CN107686290A CN107686290A CN201710791912.9A CN201710791912A CN107686290A CN 107686290 A CN107686290 A CN 107686290A CN 201710791912 A CN201710791912 A CN 201710791912A CN 107686290 A CN107686290 A CN 107686290A
- Authority
- CN
- China
- Prior art keywords
- wall material
- parts
- diatom ooze
- antimicrobial form
- ooze wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/386—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/46—Rock wool ; Ceramic or silicate fibres
- C04B14/4618—Oxides
- C04B14/4625—Alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1066—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
Abstract
The present invention relates to one kind to purify antimicrobial form diatom ooze wall material, and it includes the component of following parts by weight：25~45 parts of diatomite；5~8 parts of attapulgite；2~18 parts of antiseptic；1~2 part of rubber powder；20~38 parts of sodium carboxymethyl starch；1~5 part of Sodium Polyacrylate；0.05~0.1 part of polyvinyl alcohol；3~5 parts of talcum powder；15~30 parts of calcium carbonate；0.1~3 part of modified composite fiber.Purification antimicrobial form diatom ooze wall material of the present invention, using the formula of uniqueness, utilize bactericide and diatomite, the synergy of attapulgite, so that the wall material can not only have certain inner wall decoration effect, and with being firmly bonded, production is simple, the features such as facilitating, the pernicious gases such as formaldehyde in indoor air, benzene can also be effectively dispelled, purifying air improves human respiratory, beneficial to health.
Description
Technical field
The present invention relates to construction engineering technical field, and in particular to one kind purification antimicrobial form diatom ooze wall material.
Background technology
With the development of the society, requirement of the people to finishing yet more and more higher, do not require nothing more than beautiful attractive in appearance, also require environmental protection
Health.After finishing, some peculiar smell are had indoors and the gas being detrimental to health is present, such as formaldehyde.Generally use
The method of windowing ventilation comes discharge of noxious gases and peculiar smell, or reduces indoor dirt using methods such as adsorbent, cultivation flowers and plants
Dye, but above-mentioned method can not be inherently eliminated pollution, and efficiency is low, and cost is high, and the operating time is longer.
Diatom ooze is as a kind of new environment friendly inorganic interior decoration wall material, and it has, and density is low, specific surface area is big, hole
Rate is high, adsorptive liquid ability is strong, chemical stability is high, fusing point is high, matter is soft, sound insulation, many excellent properties such as wear-resisting, heat-resisting,
Main function in coating is absorption and regulation humidity, can effectively adsorb the harmful substances such as the formaldehyde to dissociate in air, benzene, and
It can purify in air because of peculiar smell caused by pet, smoking, rubbish etc..
In conventional art, most diatom ooze wall material is using nano titanium oxide as photochemical catalyst, in illumination condition
Harmful substance including lower catalytic decomposition absorption.In the range of UV absorption, titanium dioxide has photocatalytic activity, and its principle is
Titanium dioxide will be had an electronics from valence to conduction band during light radiation, while a hole is produced in valence band, so
Caused hole is good oxidant, and most photochemical catalysts are all the oxidabilities that make use of hole, and move to photocatalysis
The electronics on agent surface is good reducing agent.By photochemical catalyst use in coating, using its redox ability, degradable sky
Pollution organic gas in gas.Titanium dioxide is a kind of wide bandgap semiconductor, and the energy gap of its anatase titanium dioxide is
3.2eV, only wavelength shorter ultraviolet light (300~400nm) just can be absorbed and utilize, and significantly limit nano-silica
Change the application of titanium photochemical catalyst.
Photocatalysis efficiency be present using nano titanium oxide as titanium dioxide in the diatom ooze wall material of photochemical catalyst in above-mentioned
It is low, only under ultraviolet light conditions play photocatalysis, it is poor to the spectral response of visible ray, to the adsorptivity of harmful substance also compared with
The shortcomings of poor, diatom ooze wall material purification air effect is caused not ensure, therefore most of such diatom ooze wall materials can only achieve
Partial adsorbates harmful substance, decomposing harmful substances ability is weak, and antibacterial ability is also weaker, it is difficult to meets that people inhale for persistent high efficiency
The active demand of the harmful substances such as attached decomposing formaldehyde.
The content of the invention
Based on this, the present invention provides a kind of purification antimicrobial form diatom ooze wall material, and the wall material has the harmful physical capacity of absorption
By force, strong antibacterial, it is environment friendly and pollution-free the advantages that.
In order to realize the purpose of the present invention, the present invention uses following technical scheme：
One kind purification antimicrobial form diatom ooze wall material, include the component of following parts by weight：
Purification antimicrobial form diatom ooze wall material of the present invention, using the formula of uniqueness, utilize bactericide and diatomite, recessed
The synergy of the materials such as convex rod soil so that the wall material can not only have certain inner wall decoration effect, and with bonding
Firmly, simple, the features such as facilitating is produced, the pernicious gases such as formaldehyde in indoor air, benzene can also be effectively dispelled, purify air
Improve human respiratory, beneficial to health.The compositions such as diatomite, attapulgite have abundance, biological degradability good
It is good, do not easily cause secondary pollution, it is safe and non-toxic the advantages that, harm to the human body is smaller.The wall material and traditional wall material phase of the present invention
Compare, its product quality brushed not chip off-falling not alice, not mouldy, bubble, not colour-fast, fire-retardant, and the same day brushes, and the same day moves in
Nonpoisonous and tasteless without noxious materials such as formaldehyde, VOC, service life is more than 20 years.
In wherein some embodiments, the purification antimicrobial form diatom ooze wall material includes the component of following parts by weight：
In wherein some embodiments, the antiseptic is modification infusorial earth load nano-titanium dioxide composite.
In wherein some embodiments, the modification infusorial earth is 10 by mass ratio:3:5 diatomite, calcium oxide and oxygen
Change magnesium to be process by high-temperature calcination.
In wherein some embodiments, modification infusorial earth in the antiseptic：The mass ratio of nano titanium oxide is 5:1~
10。
In wherein some embodiments, the rubber powder is that vinylacetate is total to ethene and higher aliphatic vinyl acetate ternary
Poly- rubber powder.
In wherein some embodiments, vinylacetate in the ternary polymerization rubber powder：Ethene：Higher aliphatic vinyl acetate
Mass ratio be 3：1：5.
In wherein some embodiments, the preparation method of the modified composite fiber is：
Carbon fiber and alumina fibre are processed into composite fibre, composite fibre is immersed in containing vinyl triethoxyl
In the mixed liquor of silane, monoethanolamine benzoate and ethanol, a hypoglyph is covered on the surface of composite fibre, then above-mentioned is contained
The composite fibre for having counterdie is immersed in the tetrahydrofuran solution containing lauryl methacrylate-styrol copolymer, one section
Above-mentioned composite fibre is put into drying machine drying after time, the modified composite fiber of powder is finally ground into by pulverizer.
In wherein some embodiments, the particle size range of the modified composite fiber is 10nm~500nm.
In wherein some embodiments, the purification antimicrobial form diatom ooze wall material also includes 0.1~20 part of pigment.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps
More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make
Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention
The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
In a wherein embodiment, the purification antimicrobial form diatom ooze wall material includes the component of following parts by weight：
Specifically, the antiseptic is modification infusorial earth load nano-titanium dioxide composite, the modification infusorial earth be by
Using mass ratio as 10:3:5 diatomite, calcium oxide and magnesia is process by high-temperature calcination, and the modification infusorial earth is more
The siliceous powder body material in hole；The preparation method of the antiseptic is：Nano titanium oxide is added drop-wise in cosolvent, is equipped to molten containing zinc
Liquid, modification infusorial earth is then added into water stirring pulping, then zinc-containing solution is added in above-mentioned modification infusorial earth slurries and formed
The slurries of titaniferous are wrapped up with the diatomite of core shell structure, finally add pH value conditioning agent, and by filtering, washing, drying and forging
Burn, produce modification infusorial earth load nano-titanium dioxide photocatalysis composite.Wherein, the particle size range of nano titanium oxide is
10nm~20nm, modification infusorial earth：The mass ratio of nano titanium oxide is 5:1~10；Cosolvent can be that acidic materials can also
For alkaline matter.
Optionally, diatomite is the purpose of 300 mesh~900 used by the diatomite and modification infusorial earth that are added in wall material
Diatomite, diatomaceous moisture content are less than 0.5%, and diatomaceous specific surface area is 40m2/g~65m2/g.
In another embodiment, rubber powder is vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder,
Vinylacetate in the ternary polymerization rubber powder：Ethene：The mass ratio of higher aliphatic vinyl acetate is 3：1：5 are copolymerized instead by high temperature
It should form；The preparation method of modified composite fiber is：Carbon fiber and alumina fibre are processed into composite fibre, by composite fibre
It is immersed in the mixed liquor containing VTES, monoethanolamine benzoate and ethanol, on the surface of composite fibre
A hypoglyph is covered, then the above-mentioned composite fibre containing counterdie is immersed in common containing lauryl methacrylate-styrene
In the tetrahydrofuran solution of polymers, above-mentioned composite fibre is put into drying machine drying after a period of time, finally by pulverizer powder
It is broken to the modified composite fiber of 10nm~500nm powder.Wherein, the mass ratio of carbon fiber and alumina fibre is 4~8:1,
The mass ratio of mixed liquor medium vinyl triethoxysilane, monoethanolamine benzoate and ethanol is 3:1:2, in tetrahydrofuran solution
The mass ratio of tetrahydrofuran and lauryl methacrylate-styrol copolymer is：5：1~6.
In another embodiment, the purification antimicrobial form diatom ooze wall material includes the component of following parts by weight：
Specifically, the particle size range of the pigment is the mesh of 500 mesh~5000, from coloring earth, the coloring earth is green pine
One kind in stone, malachite, cinnabar, garnet, realgar, hedenbergite, obsidian, calcite, alunite.
A kind of preparation method for purifying antimicrobial form diatom ooze wall material, comprises the following steps：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and rubber powder, stir, and then sequentially add attapulgite and diatomite, stir, then to above-mentioned molten
Liquid adds antiseptic, finally sequentially adds modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity, further according to product
The color needed, appropriate pigment corresponding to addition.
Purification antimicrobial form diatom ooze wall material of the present invention, using the formula of uniqueness, utilize bactericide and diatomite, recessed
The synergy of the materials such as convex rod soil so that the wall material can not only have certain inner wall decoration effect, and with bonding
Firmly, simple, the features such as facilitating is produced, the pernicious gases such as formaldehyde in indoor air, benzene can also be effectively dispelled, purify air
Improve human respiratory, beneficial to health.The compositions such as diatomite, attapulgite have abundance, biological degradability good
It is good, do not easily cause secondary pollution, it is safe and non-toxic the advantages that, harm to the human body is smaller.The wall material and traditional wall material phase of the present invention
Compare, its product quality brushed not chip off-falling not alice, not mouldy, bubble, not colour-fast, fire-retardant, and the same day brushes, and the same day moves in
Nonpoisonous and tasteless without noxious materials such as formaldehyde, VOC, service life is more than 20 years.
Wherein, diatom soil pores is more, specific surface area is high, and adsorptivity is strong, can play elimination peculiar smell, is harmful in adsorption cleaning room
The effect of gas.Calcium carbonate plays a part of binder materials, it is ensured that the later strength of wall material, reduces organic cementing material
Usage amount.Re-dispersible glue powder can improve mobility, improve workability, improve cohesive force, extend open hour and enhancing
Water-retaining property, wall material can be made there are enough cohesive forces to ensure that upper wall is constructed, while can ensure slurry at initial stage on wall
Adhesive strength.By being modified to the composite fibre formed with two kinds of fibers of carbon fiber and alumina fibre, with simple two
Kind fiber addition, the composite fibre can form network-like filament layer, further improve the cracking resistance of wall material, and improving should
The service life of wall material.Attapulgite receives moisture, discharge performance is strong, does not expand indeformable, adhesive property is good, light toughness
Greatly, have the function that heat-insulation warm keeping, sound absorption, can Anti-moth-eating, anti-sag is strong, adapts to the change of air themperature, and indeformable, change
Inertia is learned, it is pollution-free, suppress growth of microorganism, absorb poisonous volatile ingredient, it is green.Nanometer is loaded using modification infusorial earth
Composite titania material, the photocatalysis performance of nano titanium oxide is improved, the degradation rate of PARA FORMALDEHYDE PRILLS(91,95) reaches under visible light conditions
More than 90%, and make its deodorization and sterilization effect stronger.
Technical scheme will be further illustrated by several embodiments below.
Embodiment 1：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
25 parts of diatomite；5 parts of attapulgite；2 parts of modification infusorial earth load nano-titanium dioxide composite；Vinyl acetate
Ester and 1 part of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；20 parts of sodium carboxymethyl starch；1 part of Sodium Polyacrylate；Poly- second
0.05 part of enol；3 parts of talcum powder；15 parts of calcium carbonate；0.1 part of modified composite fiber.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 5:1；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 4:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 2：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
35 parts of diatomite；6.5 parts of attapulgite；10 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid
Vinyl acetate and 1.5 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；29 parts of sodium carboxymethyl starch；Sodium Polyacrylate 3
Part；0.5 part of polyvinyl alcohol；4 parts of talcum powder；22.5 parts of calcium carbonate；1.5 parts of modified composite fiber.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 5:6；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 6:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 3：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
45 parts of diatomite；8 parts of attapulgite；18 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid second
Alkene ester and 2 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；38 parts of sodium carboxymethyl starch；5 parts of Sodium Polyacrylate；It is poly-
0.1 part of vinyl alcohol；5 parts of talcum powder；30 parts of calcium carbonate；3 parts of modified composite fiber.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 2:1；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 8:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 4：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
30 parts of diatomite；5 parts of attapulgite；5 parts of modification infusorial earth load nano-titanium dioxide composite；Vinyl acetate
Ester and 1 part of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；25 parts of sodium carboxymethyl starch；1 part of Sodium Polyacrylate；Poly- second
0.05 part of enol；3 parts of talcum powder；15 parts of calcium carbonate；0.1 part of modified composite fiber.Wherein, modification infusorial earth load nanometer two
Modification infusorial earth in titanium oxide composite material：The mass ratio of nano titanium oxide is 5:1；Carbon fiber in modified composite fiber：Oxygen
The mass ratio for changing aluminum fiber is 4:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 5：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
40 parts of diatomite；8 parts of attapulgite；15 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid second
Alkene ester and 2 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；30 parts of sodium carboxymethyl starch；5 parts of Sodium Polyacrylate；It is poly-
0.1 part of vinyl alcohol；5 parts of talcum powder；30 parts of calcium carbonate；3 parts of modified composite fiber.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 2:1；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 8:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 6：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
20 parts of diatomite；6.5 parts of attapulgite；10 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid
Vinyl acetate and 1.5 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；27.5 parts of sodium carboxymethyl starch；Sodium Polyacrylate
3 parts；0.5 part of polyvinyl alcohol；4 parts of talcum powder；22.5 parts of calcium carbonate；1.5 parts of modified composite fiber.Wherein, the modification infusorial earth
Modification infusorial earth in load nano-titanium dioxide composite：The mass ratio of nano titanium oxide is 5:6；In modified composite fiber
Carbon fiber：The mass ratio of alumina fibre is 6:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 7：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
30 parts of diatomite；5 parts of attapulgite；5 parts of modification infusorial earth load nano-titanium dioxide composite；Vinyl acetate
Ester and 1 part of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；25 parts of sodium carboxymethyl starch；1 part of Sodium Polyacrylate；Poly- second
0.05 part of enol；3 parts of talcum powder；15 parts of calcium carbonate；0.1 part of modified composite fiber；0.1 part of malachite.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 5:1；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 4:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, modified composite fiber, calcium carbonate and talcum powder are finally sequentially added, stirring mediation viscosity, is needed further according to product
Color, appropriate pigment corresponding to addition.
Embodiment 8：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
40 parts of diatomite；8 parts of attapulgite；15 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid second
Alkene ester and 2 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；30 parts of sodium carboxymethyl starch；5 parts of Sodium Polyacrylate；It is poly-
0.1 part of vinyl alcohol；5 parts of talcum powder；30 parts of calcium carbonate；3 parts of modified composite fiber；10 parts of garnet.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 2:1；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 8:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, finally sequentially add modified composite fiber, calcium carbonate and talcum powder, stirring mediation viscosity.
Embodiment 9：
The purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight：
20 parts of diatomite；6.5 parts of attapulgite；10 parts of modification infusorial earth load nano-titanium dioxide composite；Acetic acid
Vinyl acetate and 1.5 parts of ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder；27.5 parts of sodium carboxymethyl starch；Sodium Polyacrylate
3 parts；0.5 part of polyvinyl alcohol；4 parts of talcum powder；22.5 parts of calcium carbonate；1.5 parts of modified composite fiber；20 parts of turquoise.
Wherein, modification infusorial earth in the modification infusorial earth load nano-titanium dioxide composite：Nano titanium oxide
Mass ratio is 5:6；Carbon fiber in modified composite fiber：The mass ratio of alumina fibre is 6:1.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is：
Sodium carboxymethyl starch is first dissolved in water, is stirred at room temperature to dissolving, then polypropylene is sequentially added into above-mentioned solution
Sour sodium, polyvinyl alcohol and vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder, stir, Ran Houyi
Secondary addition attapulgite and diatomite, stir, then add modification infusorial earth load nano-titanium dioxide to above-mentioned solution and answer
Condensation material, modified composite fiber, calcium carbonate and talcum powder are finally sequentially added, stirring mediation viscosity, is needed further according to product
Color, pigment corresponding to addition.
Comparative example (conventional art)：
A kind of diatom ooze wall material, consisting of 40% diatomite, 10% titanium dioxide, 30% vinylacetate with
Ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder and 20% calcium carbonate, by vinylacetate and ethene and higher aliphatic
Vinyl acetate ternary polymerization rubber powder is dissolved in water, adds diatomite and titanium dioxide,
It is eventually adding calcium carbonate stirring mediation viscosity.
The performance test results of diatom ooze wall material obtained by the embodiment 1 to 6 and comparative example are as shown in table 1 below.
Table 1
Note：The purifying property test experiments are that the wall material of the wall material and comparative example that are coated with the present invention respectively is placed in 1m3
Space in, and injecting formaldehyde and toluene makes the concentration of the two be respectively 1.7mg/m3And 2.0mg/m3, pass through gas chromatography root
The coating PARA FORMALDEHYDE PRILLS(91,95) and toluene are tested according to JC/T 1074-2008 " function of purifying indoor air coating material purifying property "
Purification efficiency.
By above comparative analysis, the wall material of embodiments of the invention 1~6 is compared with the wall material of comparative example, coating
Outward appearance significantly improves, and formaldehyde, toluene purification efficiency have obvious improvement, wherein, the best results of embodiment 6.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. one kind purification antimicrobial form diatom ooze wall material, it is characterised in that include the component of following parts by weight：
2. purification antimicrobial form diatom ooze wall material according to claim 1, it is characterised in that include the group of following parts by weight
Point：
3. purification antimicrobial form diatom ooze wall material according to claim 2, it is characterised in that the antiseptic is modified diatom
Native load nano-titanium dioxide composite.
4. purification antimicrobial form diatom ooze wall material according to claim 3, it is characterised in that the modification infusorial earth is by quality
Than for 10:3:5 diatomite, calcium oxide and magnesia is process by high-temperature calcination.
5. according to the purification antimicrobial form diatom ooze wall material described in claim 4, it is characterised in that modified silicon in the antiseptic
Diatomaceous earth：The mass ratio of nano titanium oxide is 5:1~10.
6. purification antimicrobial form diatom ooze wall material according to claim 2, it is characterised in that the rubber powder is vinylacetate
With ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder.
7. purification antimicrobial form diatom ooze wall material according to claim 6, it is characterised in that vinegar in the ternary polymerization rubber powder
Vinyl acetate：Ethene：The mass ratio of higher aliphatic vinyl acetate is 3：1：5.
8. purification antimicrobial form diatom ooze wall material according to claim 2, it is characterised in that the system of the modified composite fiber
Preparation Method is：
Carbon fiber and alumina fibre are processed into composite fibre, composite fibre is immersed in containing vinyl triethoxyl silicon
In the mixed liquor of alkane, monoethanolamine benzoate and ethanol, a hypoglyph is covered on the surface of composite fibre, then above-mentioned is contained
The composite fibre of counterdie is immersed in the tetrahydrofuran solution containing lauryl methacrylate-styrol copolymer, at one section
Between after above-mentioned composite fibre is put into drying machine drying, the modified composite fiber of powder is finally ground into by pulverizer.
9. purification antimicrobial form diatom ooze wall material according to claim 8, it is characterised in that the grain of the modified composite fiber
Footpath scope is 10nm~500nm.
10. according to the purification antimicrobial form diatom ooze wall material described in any one of claim 1 to 9, it is characterised in that described net
Changing antimicrobial form diatom ooze wall material also includes 0.1~20 part of pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710791912.9A CN107686290A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form diatom ooze wall material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710791912.9A CN107686290A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form diatom ooze wall material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107686290A true CN107686290A (en) | 2018-02-13 |
Family
ID=61155972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710791912.9A Pending CN107686290A (en) | 2017-09-05 | 2017-09-05 | Purify antimicrobial form diatom ooze wall material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107686290A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109880407A (en) * | 2019-03-25 | 2019-06-14 | 营口盼盼硅藻材料集团有限公司 | Konilite interior wall wall material and its production and construction method |
| CN112876282A (en) * | 2021-02-02 | 2021-06-01 | 山东电盾科技股份有限公司 | Preparation method of air purification ceramic plate |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100994787B1 (en) * | 2010-08-05 | 2010-11-17 | 빌드켐 주식회사 | Diatomite based wall-finishing material composition containing activated carbon fiber and diatomite based wall-finishing material comprising the same |
| CN103613328A (en) * | 2013-11-23 | 2014-03-05 | 营口盼盼环保硅藻材料有限公司 | Ecological diatom ooze decorative wall material |
-
2017
- 2017-09-05 CN CN201710791912.9A patent/CN107686290A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100994787B1 (en) * | 2010-08-05 | 2010-11-17 | 빌드켐 주식회사 | Diatomite based wall-finishing material composition containing activated carbon fiber and diatomite based wall-finishing material comprising the same |
| CN103613328A (en) * | 2013-11-23 | 2014-03-05 | 营口盼盼环保硅藻材料有限公司 | Ecological diatom ooze decorative wall material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109880407A (en) * | 2019-03-25 | 2019-06-14 | 营口盼盼硅藻材料集团有限公司 | Konilite interior wall wall material and its production and construction method |
| CN112876282A (en) * | 2021-02-02 | 2021-06-01 | 山东电盾科技股份有限公司 | Preparation method of air purification ceramic plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103861421B (en) | A kind of air purifying preparation | |
| CN104263049B (en) | A kind of interior sheet material seam eliminates the unusual smell putty paste and preparation method thereof | |
| CN103613328B (en) | A kind of Ecological diatom ooze decorative wall material | |
| WO2008049315A1 (en) | An environment-protecting polyurethane composition used for environment-friendly synthetic leather, a synthetic leather therefrom and its preparation | |
| CN104446283A (en) | Diatom ooze wall material capable of efficiently purifying air or resisting against bacteria or automatically humidifying and preparation method of diatom ooze wall material | |
| CN107698230A (en) | Wall material in a kind of composite multifunction room of damping antibacterial purifying air release anion | |
| CN105524513B (en) | A kind of diatom ooze powder of lacquer putty for use on of multifunction environment-protection type | |
| CN106007633A (en) | Air-purification diatomite internal wall decoration powder paint and preparation method thereof | |
| CN108014360A (en) | A kind of air purifying preparation containing catalyst | |
| CN109651906A (en) | A kind of suction taste coating and its preparation method and application | |
| CN105622017B (en) | Unburned diatom ecological brick and its production method | |
| CN107867810A (en) | Purification of air, damping are self-cleaning, antibacterial health-care type oyster shell whiting biomass dry powder paint | |
| CN103011696A (en) | Environment-friendly wall material for interior wall decoration and preparation method of wall material | |
| CN107686290A (en) | Purify antimicrobial form diatom ooze wall material | |
| CN108373300A (en) | A kind of novel diatom ooze environmental protection wall material and preparation method thereof | |
| CN107252699A (en) | A kind of indoor air purification storage light photocatalyst microballoon and preparation method | |
| CN107417174A (en) | Utility model high-efficient purification diatom ooze wall material and its preparation and construction method | |
| CN107722700B (en) | A kind of functional paint that indoor air purification is self-cleaning and preparation method | |
| CN106242455B (en) | A kind of composite multi-functional sepiolite/diatomite basic ring protects indoor wall material | |
| CN107674465A (en) | A kind of preparation method for strengthening environmentally friendly diatom ooze coating | |
| CN107399130B (en) | A kind of automobile cabin decorative panel | |
| CN111647373A (en) | Glutinous rice glue with formaldehyde removing and mildew preventing performances and preparation method thereof | |
| CN111841518A (en) | Composite photocatalyst and photocatalyst material | |
| CN105419555B (en) | A kind of formaldehyde for woodwork plate is closed precious | |
| CN106045464A (en) | Wall material having high content of diatomaceous earth and capable of purifying volatile organic compound gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180213 |