CN109133784A - A kind of easily dry diatom ooze coating easy to clean - Google Patents

A kind of easily dry diatom ooze coating easy to clean Download PDF

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Publication number
CN109133784A
CN109133784A CN201811014470.8A CN201811014470A CN109133784A CN 109133784 A CN109133784 A CN 109133784A CN 201811014470 A CN201811014470 A CN 201811014470A CN 109133784 A CN109133784 A CN 109133784A
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China
Prior art keywords
parts
diatom ooze
easily dry
drier
clean
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CN201811014470.8A
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Chinese (zh)
Inventor
李绍龙
唐世家
吴沁
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Dongguan Environmental Protection Technology Co Ltd
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Dongguan Environmental Protection Technology Co Ltd
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Priority to CN201811014470.8A priority Critical patent/CN109133784A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00508Cement paints

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The embodiment of the invention discloses a kind of easily dry diatom ooze coating easy to clean, the components including following parts by weight: 25-35 parts of diatom ooze, 5-10 parts of calcium hydroxide, 3-8 parts of white cement, 1-3 parts of redispersable latex powder, 1-3 parts of nanometer titanium dioxide titanium valve, 1-3 parts of sodium chloride, 5-10 parts of nitrocellulose, 5-10 parts of drier, 3-6 parts of formaldehyde absorbent, 4-8 parts of alkali lignin, 3-5 parts of modified polyester fiber, 25-35 parts of water.The embodiment of the present invention has carried out a large amount of research to drier, obtains the composite drier that zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper are compounded with specific proportion;Each component in the embodiment of the present invention is mutually synergistic, and raw material uses few, energy conservation and environmental protection; obtained coating surface drying time and to do solid work the time shorter; and when being applied to various building surfaces, also have that pollution resistance is good, easy to clean, washability, good protection and decorative effect can be played to wall.

Description

A kind of easily dry diatom ooze coating easy to clean
Technical field
The present invention relates to decorative paint technical fields, and in particular to a kind of easily dry diatom ooze coating easy to clean.
Background technique
It is just greatly developing from stemness coating both at home and abroad at present, this is just needed using to drier, and most of drier is ring Alkanoic acid salt can play oxidation catalysis and promote polymerization, accelerate paint film dry.Existing diatom ooze coating raw material is numerous, does At wall be also easily stained or even fall off, easily lose powder, scrubbing resistance, service life is not short.
Summary of the invention
Of the existing technology in order to solve the problems, such as, the embodiment of the present invention is designed to provide a kind of easily dry silicon easy to clean Algal gel coating.
To achieve the above object, the technical solution of the embodiment of the present invention are as follows:
A kind of easily dry diatom ooze coating easy to clean, the component including following parts by weight: 25-35 parts of diatom ooze, hydroxide 5-10 parts of calcium, 3-8 parts of white cement, 1-3 parts of redispersable latex powder, 1-3 parts of nanometer titanium dioxide titanium valve, 1-3 parts of sodium chloride, nitric acid 5-10 parts of cellulose, 5-10 parts of drier, 3-6 parts of formaldehyde absorbent, 4-8 parts of alkali lignin, 3-5 parts of modified polyester fiber, water 25-35 parts.
Further, the component including following parts by weight: 26 parts of diatom ooze, 8 parts of calcium hydroxide, 4 parts of white cement, can be again 2 parts of dispersed latex powder, 1 part of nanometer titanium dioxide titanium valve, 1 part of sodium chloride, 6 parts of nitrocellulose, 7 parts of drier, formaldehyde absorbent 4 Part, 5 parts of alkali lignin, 4 parts of modified polyester fiber, 32 parts of water.
Further, the component including following parts by weight: 28 parts of diatom ooze, 5 parts of calcium hydroxide, 5 parts of white cement, can be again 2 parts of dispersed latex powder, 2 parts of nanometer titanium dioxide titanium valve, 2 parts of sodium chloride, 6 parts of nitrocellulose, 6 parts of drier, formaldehyde absorbent 5 Part, 6 parts of alkali lignin, 3 parts of modified polyester fiber, 30 parts of water.
Further, the weight content of diatomite is 65-85% in the diatom ooze, and the partial size of the diatomite is 400- 800 mesh.
Further, the redispersable latex powder includes the copolymer of ethylene/vinyl acetate, vinyl acetate/tertiary carbon One of the copolymer of sour ethylene, acrylic copolymer are a variety of.
Further, the partial size of the nanometer titanium dioxide titanium valve is 1000-4000 mesh.
Further, the drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.1- 0.2:0.5-0.8.
Further, the formaldehyde absorbent includes one or both of bamboo charcoal, coconut husk charcoal.
Further, the diatom ooze coating preparation method the following steps are included:
1) component of corresponding parts by weight is weighed, it is spare;
2) diatom ooze is added in agitator tank and sequentially adds hydrogen under conditions of low whipping speed is 400-600 revs/min Calcium oxide, redispersable latex powder, nanometer titanium dioxide titanium valve, sodium chloride, nitrocellulose, alkali lignin, is modified and gathers white cement Ester fiber stirs 15-20 minutes;
3) under conditions of low whipping speed is 800-1000 revs/min, add water, continue stirring 20-30 minutes, until system Uniform soilless sticking;
4) drier is added under conditions of being 200-400 revs/min in low whipping speed, continues stirring 5-10 minutes, until System is at body of paste to get easily dry diatom ooze coating easy to clean.
The effect of main component used in the embodiment of the present invention is described below:
Diatom ooze: diatom is a kind of unicellular alga occurred on earth earliest, is survived in seawater or lake water, shape Body is extremely small, and generally only several microns to more than ten microns.Diatom can be carried out photosynthesis, organic matter be made by oneself, usually with surprising Growth rate breeding, its remains deposit to form diatomite.Diatom ooze using diatomite as main raw material(s), diatomite mainly at Dividing is silicic acid matter, and there are countless pores on surface, and peculiar smell adsorbable, in decomposition air has damping, deodorization functions.Using diatom Soil is raw material building materials produced, not only has the characteristics that non-ignitable, dehumidifying, deodorization and permeability are good, but also can purify sky Gas, sound insulation, waterproof and heat-insulated, and cost is not also high.The weight content of diatomite is in diatom ooze in the embodiment of the present invention 65-85%, the partial size of the diatomite are 400-800 mesh, can retain the microcellular structure of diatomite itself, play abundant damping and Absorb the effect of decomposing formaldehyde.
Calcium hydroxide: being a kind of white powdery solids.Chemical formula Ca (OH)2, it is commonly called as white lime, calcium hydroxide, aqueous solution Referred to as clarify limewash.Calcium hydroxide has the general character of alkali, is a kind of highly basic.Carbon dioxide reaction in calcium hydroxide and air Calcium carbonate is generated, the whiteness of coating, hardness can be improved and is helped solidifying.
White cement: all raw material with proper composition are burnt to partial melting, and be able to calcium silicates is main component, irony content Suitable gypsum is added in few clinker, and levigate manufactured white hydraulic cementing materials, referred to as (abbreviation is white for white portland cement Cement).It is typically characterised by that there is very high whiteness, bright color.The whiteness of white cement in the embodiment of the present invention is greater than 87%, Strength grade is 42.5.
Redispersable latex powder: for water-soluble redispersible powder, manufactured powder adhesive after spray drying.This powder Body redisperse can have high cementitiousness and unique performance at lotion quickly after contact with water, such as: water-resistance, construction Property and thermal insulation etc..
Nanometer titanium dioxide titanium valve: environment harmful gas can be divided into indoor harmful gas and Pollution Gas.It is indoor harmful Gas mainly has methyl mercaptan, hydrogen sulfide and the ammonia etc. generated in the formaldehyde and living environment of the releasings such as ornament materials.Nanometer two Titanium oxide can be aoxidized these substance decompositions for being adsorbed in its surface by photocatalysis, to make these substances in air Concentration reduces, and environment sense of discomfort is mitigated or eliminated.In addition, TiO2The inhibition to microorganism in environment or killing are made under light illumination With therefore, nano-titanium dioxide can purify air, have deodorization functions.
Sodium chloride: addition sodium chloride solution is conducive to the emulsification of redispersable latex powder and nitrocellulose, to obtain Finely dispersed system.
Nitrocellulose: being a kind of common chemical raw material, it is the nitrate of cellulose, and general nitrogen content is in 10- 14% or so.Abbreviation NC.Nitrocellulose is a kind of white fibrous polymer, water-fast, resistance to diluted acid, resistance to weak base and various oil Class.The degree of polymerization is different, and intensity is also different, but is all thermoplastic.
Drier: being the auxiliary agent often added in coatings industry, can accelerate the oxidation, polymerization and drying of coating.The present invention is real The zirconium iso-octoate used in example, manganese iso-octoate and isooctyl acid copper are applied by being used cooperatively, to the hardness of dope layer, adhesive force, resistance to It is aqueous to have greatly improved.
Formaldehyde absorbent: the formaldehyde absorbent in the embodiment of the present invention is the active carbon for including bamboo charcoal and/or coconut husk charcoal, living Property charcoal there is biggish specific surface area and flourishing gap structure, so adsorption capacity is significant.And the property of active carbon is stablized, Acidproof, alkaline-resisting and invariance under the high temperature conditions.
Alkali lignin: being the lignin extracted from plant tissue with alkali, and by the effect of alkali certain journey is occurred for lignin The basic hydrolysis of degree, degree of making it dissolve increases, and is extracted, and through precipitation and separation, obtained lignin is known as alkali lignin. Lignin is exactly the natural polymers extracted in plant, is a kind of substance being made of the aromatic alcohol polymerizeing, exists In lignum, main function is secondary wall main component by forming intertexture net come sclereid wall.Play resistance to compression consolidation Effect.
Modified polyester fiber: using the method for graft copolymerization, hydrophilic radical (amide groups, ammonia are introduced in macromolecular structure Base etc.) increase fiber wet transmitting performance.Pass through polymerization in the modified polyester fiber used in the embodiment of the present invention for polypropylene Acid esters is connected on polyester fiber in chemical bonding method, is excluded heat by moisture absorption, is improved the saturation water imbibition of fabric.
The embodiment of the present invention has the advantages that
The embodiment of the present invention has carried out a large amount of research to drier, obtains zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper The composite drier compounded with specific proportion;Each component in the embodiment of the present invention is mutually synergistic, and raw material uses less, Energy conservation and environmental protection, obtained coating surface drying time and to do solid work the time shorter, and when being applied to various building surfaces, also with anti-pollution Good, the easy to clean, washability of property, can play good protection and decorative effect to wall.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
The diatom ooze used in the embodiment of the present invention is purchased from Qingdao Chuanyi Diatomite Co., Ltd.;Calcium hydroxide is purchased from Guangdong Comet Chemical Co., Ltd.;White cement is purchased from Jiangxi Yin Shan white cement Co., Ltd;Redispersable latex powder is purchased from Tai'an Tian Run Trade Co., Ltd. of Guomei;Nanometer titanium dioxide titanium valve is purchased from Hebei Mai Sen titanium dioxide Co., Ltd;Sodium chloride is deep purchased from Guangzhou River Chemical Industry Science Co., Ltd;Nitrocellulose is purchased from Shandong section Xinghua work Co., Ltd;Drier is purchased from Hangzhou Jesse Block Chemical Co., Ltd.;Formaldehyde absorbent is purchased from the rising sun Chemical Co., Ltd. in Nanjing wilderness overgrown with grass;Alkali lignin is purchased from Guangzhou illuminate Shengization Work Co., Ltd;Modified polyester fiber is purchased from Jiaxing Hao Xuan engineering material Co., Ltd.
Embodiment 1
One kind of the present embodiment easily dry diatom ooze coating easy to clean, the component including following parts by weight: 25 parts of diatom ooze, 5 parts of calcium hydroxide, 8 parts of white cement, ethylene/vinyl acetate 1 part of 1 part of 3 parts of copolymer, nanometer titanium dioxide titanium valve, sodium chloride, 5 parts of nitrocellulose, 10 parts of drier, 3 parts of bamboo charcoal, 6 parts of alkali lignin, 3 parts of modified polyester fiber, 25 parts of water.
Wherein, the weight content of diatomite is 65% in diatom ooze, and the partial size of diatomite is 400 mesh, nano-titanium dioxide The partial size of powder is 2000 mesh, and drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.1:0.6.
The preparation method of the diatom ooze coating of the present embodiment the following steps are included:
1) component of corresponding parts by weight is weighed, it is spare;
2) diatom ooze is added in agitator tank and sequentially adds hydroxide under conditions of low whipping speed is 500 revs/min Calcium, white cement, redispersable latex powder, nanometer titanium dioxide titanium valve, sodium chloride, nitrocellulose, alkali lignin, modified poly ester are fine Dimension stirs 15 minutes;
3) under conditions of low whipping speed is 1000 revs/min, add water, stir 25 minutes, until the uniform soilless sticking of system;
4) drier is added under conditions of being 300 revs/min in low whipping speed, stirs 5 minutes, until system is at paste Body is to get easily dry diatom ooze coating easy to clean.
Embodiment 2
One kind of the present embodiment easily dry diatom ooze coating easy to clean, the component including following parts by weight: 26 parts of diatom ooze, 8 parts of calcium hydroxide, 4 parts of white cement, 2 parts of vinyl acetate/versatic acid ethylene copolymer, 1 part of nanometer titanium dioxide titanium valve, sodium chloride 1 part, 6 parts of nitrocellulose, 7 parts of drier, 4 parts of coconut husk charcoal, 5 parts of alkali lignin, 4 parts of modified polyester fiber, 32 parts of water.
Wherein, the weight content of diatomite is 85% in diatom ooze, and the partial size of diatomite is 700 mesh, nano-titanium dioxide The partial size of powder is 2600 mesh, and drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.15:0.7.
The preparation method is the same as that of Example 1 for the diatom ooze coating of the present embodiment.
Embodiment 3
One kind of the present embodiment easily dry diatom ooze coating easy to clean, the component including following parts by weight: 35 parts of diatom ooze, 5 parts of calcium hydroxide, 3 parts of white cement, copolymer 1 part of ethylene/vinyl acetate, 3 parts of nanometer titanium dioxide titanium valve, 2 parts of sodium chloride, 5 parts of nitrocellulose, 5 parts of drier, 3 parts of bamboo charcoal, 8 parts of alkali lignin, 5 parts of modified polyester fiber, 30 parts of water.
Wherein, the weight content of diatomite is 70% in diatom ooze, and the partial size of diatomite is 800 mesh, nano-titanium dioxide The partial size of powder is 1000 mesh, and drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.2:0.6.
The preparation method is the same as that of Example 1 for the diatom ooze coating of the present embodiment.
Embodiment 4
One kind of the present embodiment easily dry diatom ooze coating easy to clean, which is characterized in that the component including following parts by weight: 28 parts of diatom ooze, 5 parts of calcium hydroxide, 5 parts of white cement, 2 parts of acrylic copolymer, 2 parts of nanometer titanium dioxide titanium valve, 2 parts of sodium chloride, 6 parts of nitrocellulose, 6 parts of drier, 2 parts of bamboo charcoal, 3 parts of coconut husk charcoal, 6 parts of alkali lignin, 3 parts of modified polyester fiber, 30 parts of water.
Wherein, the weight content of diatomite is 75% in diatom ooze, and the partial size of diatomite is 800 mesh, nano-titanium dioxide The partial size of powder is 4000 mesh, and drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.18:0.8.
The preparation method is the same as that of Example 1 for the diatom ooze coating of the present embodiment.
Embodiment 5
One kind of the present embodiment easily dry diatom ooze coating easy to clean, the component including following parts by weight: 30 parts of diatom ooze, 10 parts of calcium hydroxide, 5 parts of white cement, copolymer 1 part of ethylene/vinyl acetate, 3 parts of nanometer titanium dioxide titanium valve, sodium chloride 3 Part, 10 parts of nitrocellulose, 10 parts of drier, 6 parts of coconut husk charcoal, 4 parts of alkali lignin, 3 parts of modified polyester fiber, 35 parts of water.
Wherein, the weight content of diatomite is 80% in diatom ooze, and the partial size of diatomite is 600 mesh, nano-titanium dioxide The partial size of powder is 3200 mesh, and drier includes zirconium iso-octoate, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.12:0.5.
The preparation method is the same as that of Example 1 for the diatom ooze coating of the present embodiment.
Test case
There is easy stemness energy easy to clean in order to illustrate the diatom ooze coating of the embodiment of the present invention, the present invention has carried out following survey Examination.
Diatom ooze coating made from embodiment 1-5 is such as coated or is sprayed at table to be coated according to this field usual manner Face forms film after dry.
The performance test results of film are shown in Table 1.
Table 1
Test item As a result
Appearance of film Film is uniform, no blistering, corrugation
Surface drying/minute ≤20
Do solid work/h ≤6
Adhesive force/grade ≤1
Pencil hardness ≥2H
Pollution resistance >=99%
Abrasion resistance " GB/T9266-88 " >=10000 times
The paint spraying effect of the embodiment of the present invention is outstanding, pollution resistance is good, easy to clean, washability, can play very to wall Good protection and decorative effect.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore, These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.

Claims (9)

1. a kind of easily dry diatom ooze coating easy to clean, which is characterized in that the component including following parts by weight: diatom ooze 25-35 Part, 5-10 parts of calcium hydroxide, 3-8 parts of white cement, 1-3 parts of redispersable latex powder, 1-3 parts of nanometer titanium dioxide titanium valve, sodium chloride 1-3 parts, 5-10 parts of nitrocellulose, 5-10 parts of drier, 3-6 parts of formaldehyde absorbent, 4-8 parts of alkali lignin, modified poly ester fibre 3-5 parts, 25-35 parts of water of dimension.
2. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the group including following parts by weight Point: 26 parts of diatom ooze, 8 parts of calcium hydroxide, 4 parts of white cement, 2 parts of redispersable latex powder, 1 part of nanometer titanium dioxide titanium valve, chlorination 1 part of sodium, 6 parts of nitrocellulose, 7 parts of drier, 4 parts of formaldehyde absorbent, 5 parts of alkali lignin, 4 parts of modified polyester fiber, water 32 Part.
3. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the group including following parts by weight Point: 28 parts of diatom ooze, 5 parts of calcium hydroxide, 5 parts of white cement, 2 parts of redispersable latex powder, 2 parts of nanometer titanium dioxide titanium valve, chlorination 2 parts of sodium, 6 parts of nitrocellulose, 6 parts of drier, 5 parts of formaldehyde absorbent, 6 parts of alkali lignin, 3 parts of modified polyester fiber, water 30 Part.
4. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that diatomite in the diatom ooze Weight content is 65-85%, and the partial size of the diatomite is 400-800 mesh.
5. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the redispersable latex powder packet Include one of copolymer, vinyl acetate/versatic acid ethylene copolymer, acrylic copolymer of ethylene/vinyl acetate or It is a variety of.
6. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the nanometer titanium dioxide titanium valve Partial size is 1000-4000 mesh.
7. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the drier includes isooctyl acid Zirconium, manganese iso-octoate and isooctyl acid copper, weight ratio 1:0.1-0.2:0.5-0.8.
8. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the formaldehyde absorbent includes bamboo One or both of charcoal, coconut husk charcoal.
9. easily dry diatom ooze coating easy to clean according to claim 1, which is characterized in that the preparation of the diatom ooze coating Method the following steps are included:
1) component of corresponding parts by weight is weighed, it is spare;
2) diatom ooze is added in agitator tank and sequentially adds hydroxide under conditions of low whipping speed is 400-600 revs/min Calcium, white cement, redispersable latex powder, nanometer titanium dioxide titanium valve, sodium chloride, nitrocellulose, alkali lignin, modified poly ester are fine Dimension stirs 15-20 minutes;
3) under conditions of low whipping speed is 800-1000 revs/min, add water, continue stirring 20-30 minutes, until system is uniform Soilless sticking;
4) drier is added under conditions of being 200-400 revs/min in low whipping speed, continues stirring 5-10 minutes, until system At body of paste to get easily dry diatom ooze coating easy to clean.
CN201811014470.8A 2018-08-31 2018-08-31 A kind of easily dry diatom ooze coating easy to clean Pending CN109133784A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877427A (en) * 2015-05-29 2015-09-02 桐城市慧琦工贸有限公司 Diatom ooze coating and preparation method thereof
CN105153766A (en) * 2015-10-24 2015-12-16 洪其祥 Quick-dry diatom ooze paint
CN105236881A (en) * 2015-09-06 2016-01-13 三棵树涂料股份有限公司 Diatom ooze internal wall decorative material and preparation method of same
CN105645861A (en) * 2015-12-30 2016-06-08 重庆发顺化工有限责任公司 Scrub resistant diatom ooze coating
CN106007559A (en) * 2016-05-17 2016-10-12 杭州美多乐环保新材料有限公司 Environment-friendly diatom ooze decorative wall material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877427A (en) * 2015-05-29 2015-09-02 桐城市慧琦工贸有限公司 Diatom ooze coating and preparation method thereof
CN105236881A (en) * 2015-09-06 2016-01-13 三棵树涂料股份有限公司 Diatom ooze internal wall decorative material and preparation method of same
CN105153766A (en) * 2015-10-24 2015-12-16 洪其祥 Quick-dry diatom ooze paint
CN105645861A (en) * 2015-12-30 2016-06-08 重庆发顺化工有限责任公司 Scrub resistant diatom ooze coating
CN106007559A (en) * 2016-05-17 2016-10-12 杭州美多乐环保新材料有限公司 Environment-friendly diatom ooze decorative wall material

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Application publication date: 20190104