CN107523158A - A kind of enough persistently release anion and far infrared interior wall coating and preparation method - Google Patents

A kind of enough persistently release anion and far infrared interior wall coating and preparation method Download PDF

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Publication number
CN107523158A
CN107523158A CN201710719804.0A CN201710719804A CN107523158A CN 107523158 A CN107523158 A CN 107523158A CN 201710719804 A CN201710719804 A CN 201710719804A CN 107523158 A CN107523158 A CN 107523158A
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interior wall
far infrared
wall coating
emulsion
release anion
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张延奎
张粉霞
彭世劳
常海
刘翰锋
董翔
朱洪波
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Luoyang Shuangrui Corrosion Prevention Engineering Technology Co Ltd
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Luoyang Shuangrui Corrosion Prevention Engineering Technology Co Ltd
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Publication of CN107523158A publication Critical patent/CN107523158A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
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  • Plant Pathology (AREA)
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Abstract

A kind of enough persistently release anion and far infrared interior wall coating and preparation method, the percentage by weight of the raw material composition of coating are：Acrylic emulsion and modified acrylic acid emulsion 20 ~ 30%, ethylene glycol 1 ~ 2%, defoamer 0.2 ~ 0.5%, wetting dispersing agent 0.2 ~ 0.3%, coalescents 0.8 ~ 1.2%, coarse whiting 10 ~ 20%, titanium dioxide 10 ~ 15%, tourmaline 10 ~ 15%, Anionic initiation agent 0.8 ~ 1.2%, kaolin 8 ~ 12%, thickener 0.2 ~ 0.8%, bactericide 0.1 ~ 0.2%, tertiary effluent 20 ~ 40%.The present invention, as anion-generating material, is triggered by initiator and ionized, is added in interior wall coating, form anion occurring source indoors from tourmaline；Product meets GB6566 2010《Radioactive material radionuclides limitation》Requirement to building standard.

Description

A kind of enough persistently release anion and far infrared interior wall coating and preparation method
Technical field
The present invention relates to interior wall coating technical field, more particularly to a kind of enough persistently release anions and remote red Outside line interior wall coating and preparation method.
Background technology
Anion in air is suspended in toxic and harmful gas, dust in air to elimination, suppresses bacterium mould, purification Air, good health and a long life and ecological environment to people have extremely important effect, are described as " air vitamin " and " in air Longevity element ", anion concentration turn into air cleaner degree important indicator.
But with the quickening of process of industrialization, problem of environmental pollution becomes increasingly conspicuous, and the aerial content of anion is gradual Reduce, especially with the commonly used of decoration material, substantial amounts of chemical finishing material, chemical building material are got in, together When due to the use of door and window closing, air-conditioning, household electrical appliance etc., architecture indoor negative aeroion is rare.According to statistics, all one's life of people is big About 70% time is to spend indoors, but according to reports indicate that, at present negative ion concentration as little as 0-50 in the room of city/ cm3, seriously threaten human health.
In order to solve the above problems, the patent of invention of Application No. 201510393521.2 discloses a kind of anion dry powder Interior wall coating and preparation method thereof, although having used negative ion powder to refer to as anion source of release in invention and not yet explicitly Whether up to standard go out the negative aeroion amount of inducing, radionuclides limitation.Patent CN 104497692 is released using terbium oxide as anion Source is put, anion highest burst size is 960/cm3, radionuclides limitation detection is not carried out to lanthanide series terbium in invention.It is above-mentioned All without reference to the release of far infrared in patent.
The content of the invention
Reduce problem to solve air pollution and anion, the invention provides a kind of enough persistently release anions and Far infrared interior wall coating and preparation method, from crude tourmaline as anion-generating material, electricity is triggered by initiator From, it is added in interior wall coating, forms anion occurring source indoors, anion can be discharged, formaldehyde can be removed, so as to The indoor environment of health is provided；And product of the present invention meets GB6566-2010《Radioactive material radionuclides limitation》To building materials The requirement of standard.
The present invention is that technical scheme is used by solving the above problems：A kind of enough persistently release anion and far infrared Line interior wall coating, the percentage by weight of the raw material composition of the coating are：Emulsion 20 ~ 30%, ethylene glycol 1 ~ 2%, defoamer 0.2 ~ 0.5%, wetting dispersing agent 0.2 ~ 0.3%, coalescents 0.8 ~ 1.2%, coarse whiting 10 ~ 20%, titanium dioxide 10 ~ 15%, tourmaline 10 ~ 15%, Anionic initiation agent 0.8 ~ 1.2%, kaolin 8 ~ 12%, thickener 0.2 ~ 0.8%, bactericide 0.1 ~ 0.2%, tertiary effluent 20 ~ 40%。
In the present invention, described emulsion is acrylic emulsion and/or modified acrylic acid emulsion.
In the present invention, the acrylic emulsion is one kind in styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion Or two kinds of combinations.
In the present invention, the Anionic initiation agent be alumina silicate, ferrosilite, calcium silicates, magnesium silicate, potassium silicate, sodium metasilicate, One or several kinds of combinations in sodium metaaluminate.
In the present invention, the defoamer is one or two kinds of group in Tego810, BYK-024, BASF SI-2292 Close.
In the present invention, the wetting dispersing agent is BYK-190, BYK-012, Tego760w, Tego757w, Disponer One or several kinds of combinations in W-519, DOW-x405.
In the present invention, the coalescents are one kind in alcohol ester 12, diethylene glycol monobutyl ether, propylene glycol monomethyl ether.
In the present invention, the thickener is RM-12W, RM-2020W, aerosil AEROSIL200, BASF- 1190th, one or several kinds of combinations in hydroxy ethyl fiber HEC30000.
A kind of enough persistently preparation methods of release anion and far infrared interior wall coating, comprise the following steps：
Step 1: weigh each raw material according to the percentage by weight of raw material in claim 1, then by tertiary effluent, tourmaline, bear from Sub- initiator, ethylene glycol, wetting dispersing agent are added in agitator, are stirred 10min with 1200-1500r/min rotating speed, are mixed Liquid is closed, it is standby；
D50≤200nm is ground to Step 2: mixed liquor made from step 1 is added in grinder, filtering and discharging, is ground Liquid, it is standby；
Step 3: the lapping liquid that step 2 is obtained is poured into agitator, coarse whiting, titanium dioxide, kaolin, defoamer are added, with After 1200-1500r/min rotating speed stirs 20 ~ 30min, agitator speed is adjusted to 500 ~ 600r/min, added while stirring Emulsion, is eventually adding coalescents, bactericide, thickener, and stirring 10min obtains coating, filtered and packaged standby.
Wherein, in step 2, mixed liquor made from step 1 is added into grinder, abrasive media is 0.6 ~ 0.8 μm of particle diameter Zirconium oxide, grinding linear velocity is 12m/s, and secondary grinder is used when being ground to D50≤700nm, changes abrasive media particle diameter as 0.3 ~ 0.4 μm of zirconium oxide, grinding linear velocity are 12m/s, are ground when being ground to D50≤400nm using three-level, change grinding medium plasmid Footpath is 0.2 μm of zirconium oxide, and grinding linear velocity is 12m/s, is ground to D50≤200nm.
Beneficial effect：（1）, in step 2, mixed liquor is ground to D50≤200nm, the present invention is natural using nanoscale Anion-generating material, the anion and far infrared of the high concentration beneficial to human body can be persistently discharged, human body can be promoted Metabolism, improve immunity.In the present invention diluent, Environmental Safety, VOC free, suitable interior decoration are done using water.
（2）, by the present invention in that triggering tourmaline to ionize with initiator, enough anion release is persistently provided, close Close in calm space and be coated with this product, according to GB/T28628-2012《Material induces air ion weight testing method》Measure： Anion concentration can reach 3800 ~ 6800ions/s.cm2, find that this product being capable of persistently enough offers by long-term test Anion.
（3）, the present invention using tertiary effluent as decentralized medium, it is environmentally safe, to direct labor and construction worker without body Harm, transport storage safety.
（4）, according to JC/T1074-2008《Function of purifying indoor air coating material purifying property》Test to obtain purifying formaldehyde Efficiency can persistently discharge the far infrared beneficial to human body up to more than 95%；This product is according to GB6566-2010《Building wood Expect radionuclide limitation》Test, External Exposure Index are 1/10th of standard limitation, and Outreach services are the four of standard limitation / mono-, meet requirement of the country to building standard.
（5）, according to HG/T3950-2007《Antibiotic paint》Test, this product anti-microbial property is up to 100%.
Embodiment
With reference to specific embodiment, the invention will be further described, so that those skilled in the art can be more preferable Understand the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
A kind of enough persistently release anion and far infrared interior wall coating, the weight percent of the raw material composition of the coating Than for：Emulsion 20 ~ 30%, ethylene glycol 1 ~ 2%, defoamer 0.2 ~ 0.5%, wetting dispersing agent 0.2 ~ 0.3%, coalescents 0.8 ~ 1.2%, coarse whiting 10 ~ 20%, titanium dioxide 10 ~ 15%, tourmaline 10 ~ 15%, Anionic initiation agent 0.8 ~ 1.2%, kaolin 8 ~ 12%, increase Thick dose 0.2 ~ 0.8%, bactericide 0.1 ~ 0.2%, tertiary effluent 20 ~ 40%.
Preferably, Anionic initiation agent is alumina silicate, ferrosilite, calcium silicates, magnesium silicate, potassium silicate, sodium metasilicate, meta-aluminic acid One or several kinds of combinations in sodium.
Preferably, described emulsion is acrylic emulsion and/or modified acrylic acid emulsion.Acrylic emulsion is phenylpropyl alcohol breast One or two kinds of combination in liquid, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion.
Preferably, one or two kinds of combination in defoamer Tego810, BYK-024, BASF SI-2292.
Preferably, wetting dispersing agent BYK-190, BYK-012, Tego760w, Tego757w, Disponer W-519, One or several kinds of combinations in DOW-x405.
Preferably, coalescents are one kind in alcohol ester 12, diethylene glycol monobutyl ether, propylene glycol monomethyl ether.
Preferably, thickener RM-12W, RM-2020W, aerosil AEROSIL200, BASF-1190, hydroxyl second One or several kinds of combinations in base fiber HEC30000.
A kind of enough persistently preparation methods of release anion and far infrared interior wall coating, comprise the following steps：
Step 1: each raw material is weighed according to the percentage by weight of raw material, then by tertiary effluent, tourmaline, Anionic initiation agent, second Glycol, wetting dispersing agent are added in agitator, are stirred 10min with 1200-1500r/min rotating speed, are obtained mixed liquor, standby；
Step 2: mixed liquor made from step 1 is added in grinder, abrasive media is the zirconium oxide of 0.6 ~ 0.8 μm of particle diameter, Grinding linear velocity is 12m/s, and secondary grinder is used when being ground to D50≤700nm, and it is 0.3 ~ 0.4 μm to change abrasive media particle diameter Zirconium oxide, grinding linear velocity are 12m/s, are ground when being ground to D50≤400nm using three-level, change abrasive media particle diameter as 0.2 μm Zirconium oxide, grinding linear velocity is 12m/s, is ground to D50≤200nm, filtering and discharging, obtains lapping liquid, standby；
Step 3: the lapping liquid that step 2 is obtained is poured into agitator, coarse whiting, titanium dioxide, kaolin, defoamer are added, with After 1200-1500r/min rotating speed stirs 20 ~ 30min, agitator speed is adjusted to 500 ~ 600r/min, added while stirring Emulsion, is eventually adding coalescents, bactericide, thickener, and stirring 10min obtains coating, filtered and packaged standby.
Wetting dispersing agent, kaolin particle interface oppositely charged, after dispersant ionization are added with the raw material of the present invention Kaolin surface is attached to, makes kaolin surface mutually exclusive with identical charges, improves the mobility of coating products.Meanwhile Contain micro accessory mineral-tourmaline in kaolin, can be with initiator sustained response.
Titanium dioxide is added with the raw material of the present invention, in coating article, titanium dioxide is covered in tourmaline surface, Neng Gouti High tourmaline anion release rate, meanwhile, it is capable to improve the whiteness of coating article.
The same above-mentioned steps of preparation method of embodiment 1 to embodiment 4, the weight percent such as table of embodiment 1 to embodiment 4 Shown in 1：
The embodiment 1 of table 1 to the raw material of embodiment 4 percentage by weight
Wherein, acrylic emulsion is respectively adopted in the emulsion of embodiment 1- embodiments 4；Acrylic emulsion and modified acrylic acid emulsion； The modified acrylic acid emulsion that scrub resistance protrudes；One kind in styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion or Two kinds of combinations.
Wherein, the Anionic initiation agent of embodiment 1- embodiments 4 is respectively alumina silicate；Magnesium silicate；Sodium metasilicate；Ferrosilite, One or several kinds of combinations in calcium silicates, potassium silicate, sodium metaaluminate.
Wherein, the defoamer of example example 1- embodiments 4 is respectively Tego 810；BYK-024、BASF SI-2292；Tego 810。
Wherein, the wetting dispersing agent of example example 1- embodiments 4 is respectively BYK-190；BYK-012；Tego 760w；Tego One or several kinds of combinations in 757w, Disponer W-519, DOW-x405.
Wherein, the coalescents of example example 1- embodiments 4 are respectively alcohol ester 12；Diethylene glycol monobutyl ether；Propane diols first Ether；Alcohol ester 12.
Wherein, the thickener of example example 1- embodiments 4 is respectively RM-12W；RM-2020W and hydroxy ethyl fiber HEC 30000；Aerosil AEROSIL200；BASF-1190.
The present invention other selections enumerated or the emulsion combined, Anionic initiation agent, defoamer, wetting point can also be selected Powder, coalescents and thickener.
Performance detection is carried out to coating made from embodiment 1 to embodiment 4, wherein, the result of the negative aeroion amount of inducing As shown in table 2；The result of radionuclide detection is as shown in table 3；The result of far infrared release rate is as shown in table 4；Formaldehyde is net Change efficiency and antibacterium results of property is as shown in table 5.
The embodiment 1 of table 2 to coating made from embodiment 4 the negative aeroion amount of inducing
The embodiment 1 of table 3 to the radionuclide of coating made from embodiment 4 detects
The embodiment 1 of table 4 to coating made from embodiment 4 far infrared release rate
The embodiment 1 of table 5 to coating made from embodiment 4 purifying formaldehyde efficiency and bacteria resistance energy
In above-described embodiment, it is thus understood that be merely to illustrate all protection domains of the present invention rather than the present invention, reading After the present invention, those skilled in the art can be slightly modified to the present invention, and these equivalent modifications are equally limited in the present invention In fixed scope.

Claims (10)

1. a kind of enough persistently release anion and far infrared interior wall coating, it is characterised in that：The raw material composition of the coating Percentage by weight be：
Emulsion 20 ~ 30%,
Ethylene glycol 1 ~ 2%,
Defoamer 0.2 ~ 0.5%,
Wetting dispersing agent 0.2 ~ 0.3%,
Coalescents 0.8 ~ 1.2%,
Coarse whiting 10 ~ 20%,
Titanium dioxide 10 ~ 15%,
Tourmaline 10 ~ 15%,
Anionic initiation agent 0.8 ~ 1.2%,
Kaolin 8 ~ 12%,
Thickener 0.2 ~ 0.8%,
Bactericide 0.1 ~ 0.2%,
Tertiary effluent 20 ~ 40%.
2. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute The emulsion stated is acrylic emulsion and/or modified acrylic acid emulsion.
3. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 2, it is characterised in that：Institute Acrylic emulsion is stated as one or two kinds of combination in styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion.
4. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute State Anionic initiation agent for alumina silicate, ferrosilite, calcium silicates, magnesium silicate, potassium silicate, sodium metasilicate, one kind in sodium metaaluminate or Several combinations of person.
5. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute Defoamer is stated as one or two kinds of combination in Tego810, BYK-024, BASF SI-2292.
6. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute Wetting dispersing agent is stated as one in BYK-190, BYK-012, Tego760w, Tego757w, Disponer W-519, DOW-x405 Kind or several combinations.
7. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute Coalescents are stated as one kind in alcohol ester 12, diethylene glycol monobutyl ether, propylene glycol monomethyl ether.
8. a kind of enough persistently release anion and far infrared interior wall coating as claimed in claim 1, it is characterised in that：Institute Thickener is stated as RM-12W, RM-2020W, aerosil AEROSIL200, BASF-1190, hydroxy ethyl fiber HEC One or several kinds of combinations in 30000.
9. a kind of enough persistently methods of release anion and far infrared interior wall coating as claimed in claim 1 are prepared, its It is characterised by, comprises the following steps：
Step 1: weigh each raw material according to the percentage by weight of raw material in claim 1, then by tertiary effluent, tourmaline, bear from Sub- initiator, ethylene glycol, wetting dispersing agent are added in agitator, are stirred 10min with 1200-1500r/min rotating speed, are mixed Liquid is closed, it is standby；
D50≤200nm is ground to Step 2: mixed liquor made from step 1 is added in grinder, filtering and discharging, is ground Liquid, it is standby；
Step 3: the lapping liquid that step 2 is obtained is poured into agitator, coarse whiting, titanium dioxide, kaolin, defoamer are added, with After 1200-1500r/min rotating speed stirs 20 ~ 30min, agitator speed is adjusted to 500 ~ 600r/min, added while stirring Emulsion, is eventually adding coalescents, bactericide, thickener, and stirring 10min obtains coating, filtered and packaged standby.
10. a kind of enough persistently methods of release anion and far infrared interior wall coating are prepared as claimed in claim 9, its It is characterised by：In step 2, mixed liquor made from step 1 is added into grinder, abrasive media is the oxygen of 0.6 ~ 0.8 μm of particle diameter Change zirconium, grinding linear velocity is 12m/s, and secondary grinder is used when being ground to D50≤700nm, changes abrasive media particle diameter as 0.3 ~ 0.4 μm zirconium oxide, grinding linear velocity is 12m/s, is ground when being ground to D50≤400nm using three-level, changing abrasive media particle diameter is 0.2 μm of zirconium oxide, grinding linear velocity are 12m/s, are ground to D50≤200nm.
CN201710719804.0A 2017-08-21 2017-08-21 A kind of enough persistently release anion and far infrared interior wall coating and preparation method Pending CN107523158A (en)

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CN108384359A (en) * 2018-02-28 2018-08-10 湖南辰砾新材料有限公司 A kind of emulsion paint and preparation method thereof of release anion and far infrared
CN108727612A (en) * 2018-06-29 2018-11-02 海南省先进天然橡胶复合材料工程研究中心有限公司 A kind of preparation method of latex compound ingredient dispersion
CN108822638A (en) * 2018-06-13 2018-11-16 安庆越球建筑防水材料有限公司 A kind of environment-friendly waterproof paint discharging anion
CN109054551A (en) * 2018-07-03 2018-12-21 广西神灯涂料有限公司 A kind of tourmaline wall finiss capable of releasing far infrared ray and preparation method thereof
CN109095798A (en) * 2018-05-22 2018-12-28 洛阳双瑞防腐工程技术有限公司 Persistently induces anion and discharge the intermediary material and preparation method of far infrared
CN109281188A (en) * 2018-11-12 2019-01-29 南通薇星纺织科技有限公司 The efficiently PVC artificial leather and preparation method thereof of release anion
CN109294366A (en) * 2018-08-20 2019-02-01 洛阳双瑞防腐工程技术有限公司 A kind of long-term negative ion release and far infrared remove aldehyde scavenging solution and preparation method
CN109852123A (en) * 2019-02-19 2019-06-07 杭州琻泰环境科技有限公司 Titania modified anion fireproof coating and preparation method thereof
CN109943168A (en) * 2019-02-28 2019-06-28 江苏佑宝家居科技有限公司 One kind is except transparent overlay coating of aldehyde and preparation method thereof
CN110408323A (en) * 2019-08-20 2019-11-05 李秀霞 A kind of production method that can discharge anion, far infrared interior wall paint
CN114262545A (en) * 2022-01-07 2022-04-01 陈学 Emulsion paint containing negative oxygen ions and preparation method thereof

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CN104513572A (en) * 2014-11-27 2015-04-15 浙江大学自贡创新中心 Negative ion based paint

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CN102604539A (en) * 2012-03-14 2012-07-25 吴尚泉 Interior wall coating capable of releasing far infrared rays and anions and preparation method thereof
CN104513572A (en) * 2014-11-27 2015-04-15 浙江大学自贡创新中心 Negative ion based paint

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384359A (en) * 2018-02-28 2018-08-10 湖南辰砾新材料有限公司 A kind of emulsion paint and preparation method thereof of release anion and far infrared
CN109095798A (en) * 2018-05-22 2018-12-28 洛阳双瑞防腐工程技术有限公司 Persistently induces anion and discharge the intermediary material and preparation method of far infrared
CN108822638A (en) * 2018-06-13 2018-11-16 安庆越球建筑防水材料有限公司 A kind of environment-friendly waterproof paint discharging anion
CN108727612A (en) * 2018-06-29 2018-11-02 海南省先进天然橡胶复合材料工程研究中心有限公司 A kind of preparation method of latex compound ingredient dispersion
CN109054551A (en) * 2018-07-03 2018-12-21 广西神灯涂料有限公司 A kind of tourmaline wall finiss capable of releasing far infrared ray and preparation method thereof
CN109294366A (en) * 2018-08-20 2019-02-01 洛阳双瑞防腐工程技术有限公司 A kind of long-term negative ion release and far infrared remove aldehyde scavenging solution and preparation method
CN109281188A (en) * 2018-11-12 2019-01-29 南通薇星纺织科技有限公司 The efficiently PVC artificial leather and preparation method thereof of release anion
CN109852123A (en) * 2019-02-19 2019-06-07 杭州琻泰环境科技有限公司 Titania modified anion fireproof coating and preparation method thereof
CN109852123B (en) * 2019-02-19 2021-04-30 杭州琻泰环境科技有限公司 Titanium dioxide modified negative ion fireproof coating and preparation method thereof
CN109943168A (en) * 2019-02-28 2019-06-28 江苏佑宝家居科技有限公司 One kind is except transparent overlay coating of aldehyde and preparation method thereof
CN110408323A (en) * 2019-08-20 2019-11-05 李秀霞 A kind of production method that can discharge anion, far infrared interior wall paint
CN114262545A (en) * 2022-01-07 2022-04-01 陈学 Emulsion paint containing negative oxygen ions and preparation method thereof

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Application publication date: 20171229