CN108384359A - A kind of emulsion paint and preparation method thereof of release anion and far infrared - Google Patents
A kind of emulsion paint and preparation method thereof of release anion and far infrared Download PDFInfo
- Publication number
- CN108384359A CN108384359A CN201810168600.7A CN201810168600A CN108384359A CN 108384359 A CN108384359 A CN 108384359A CN 201810168600 A CN201810168600 A CN 201810168600A CN 108384359 A CN108384359 A CN 108384359A
- Authority
- CN
- China
- Prior art keywords
- parts
- far infrared
- powder
- release anion
- anion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of emulsion paints and preparation method thereof of release anion and far infrared, and in parts by weight, composition is as follows：250 300 parts of lotion, 8 10 parts of the periporate of self-control release anion and far infrared, 0.5 1 parts of power supply subtype catalyst, poly- 36 parts of hexamethylene diamine adipic acid acyl acid anhydride powder, 400 450 parts of deionized water, 80 120 parts of filler, 10 15 parts of coalescents, 24 parts of wetting dispersing agent, 12 parts of levelling agent, 35 parts of thickener, 0.5 1 parts of antifoaming agent.The periporate of the self-control release anion and far infrared is that the mixed silicate that will be synthesized is obtained through calcining and alkaline etching, there is the electron-donating group and complex anion group of conjugation in the power supply subtype catalyst, the transition metal that can be catalyzed in negative ion powder changes from rare earth metal between different oxidation state, it is negative oxygen ion by dioxygen oxidation, accelerate anion rate of release, the energy discharged in the process is far infrared, has higher antibiotic property.
Description
Technical field
The present invention relates to a kind of emulsion paint more particularly to a kind of emulsion paints and its system of release anion and far infrared
Preparation Method belongs to artificial building stones technical field.
Technical background
Anion, i.e. negative oxygen ion, are referred to as " air vitamin ", have ten to the vital movement of human body and other biological
Divide important influence.Medical research shows in air that electronegative particle makes oxygen content in blood increase, be conducive to blood oxygen conveying,
It absorbs and utilizes, have and promote human metabolism, improve human immunological competence, enhance human body flesh energy, it is flat to adjust body function
The effect of weighing apparatus.
Among natural negative ion powder (calcium carbide powder etc.) is added to emulsion paint by prior art generally existing, to increase anion
Release function, but that there are impurity is more for the prior art, thereby increases and it is possible to there are harmful radioactive substances.
For example, Chinese patent CN201210093555.6 is related to a kind of antibiotic emulsion paint containing natural jade powder and its preparation
Method, the antibiotic emulsion paint contain the ingredient of following parts by weight：50-150 parts of natural jade powder, nano inorganic negative-ion auxiliary agent
5-15 parts, the wherein grain size of natural jade powder is 3000-6000 mesh.The emulsion paint that the invention provides can be painted on metope and wood
On material, paint film has the characteristics that smell is light, VOC is low, covering power is good, adhesive force is good, resistance to shampooing, while can effectively kill room
Between the harmful levels of pathogens that contacts of brushing metope, and at low cost, application property is good, and environmental-protecting performance is good, is mainly used in wall, the tables such as timber
The decoration in face and protection.That there are anion burst sizes is low for the emulsion paint, the shortcomings of having a single function.
Far infrared due to the vibration frequency of its vibration frequency and human inner cell's molecule it is closest and be referred to as life it
Light.Far infrared itself has significant temperature control effect, resonance effects and fuel factor, it can promote skin inner layer temperature to increase, blood
The expansion of pipe accelerates the outer row of internal metabolic toxicities to promote the cycle of blood, improves the microenvironment of body interior cell, by force
Change the metabolism between each tissue, increase the power of regeneration of tissue, improve the immunocompetence of body, the exception for adjusting spirit is emerging
It puts forth energy state, to achieve the purpose that medical treatment and prevention and health care.There are the rate of release of far infrared wave is low for existing negative ion powder
Disadvantage.
Invention content
The shortcomings that overcome the prior art and deficiency, the present invention is intended to provide a kind of breast of release anion and far infrared
Shellac varnish.
A kind of emulsion paint of release anion and far infrared, in parts by weight, composition is as follows：It is 250-300 parts of lotion, more
Powder 8-10 parts of hole, power supply 0.5-1 parts of subtype catalyst, poly- 3-6 parts of hexamethylene diamine adipic acid acyl acid anhydride powder, 400-450 parts of deionized water,
80-120 parts of filler, 10-15 parts of coalescents, 2-4 parts of wetting dispersing agent, 1-2 parts of levelling agent, 3-5 parts of thickener, antifoaming agent
0.5-1 parts.
The power supply subtype catalyst is diphenyl trimethoxy phosphorus -3- sodium sulfonates, 1,1 '-bis- (diphenyl-phosphinomethyls)
It is one or more in three biphenyl sodium disulfonate, triphenylphosphine sulfonate sodiums.
The lotion is one or more in silicone acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion.
The coalescents are one or more in alcohol ester-12, glycol monoethyl ether, ethylene glycol monobutyl ether.
The relative molecular weight of the poly- hexamethylene diamine adipic acid acyl acid anhydride powder is 10000-50000；The filler be coarse whiting,
One or more in fine particle calcium carbonate, barium sulfate, titanium dioxide, talcum powder, mica powder, the grain size of filler is -1250 mesh of 600 mesh.
The wetting dispersing agent is polyocarboxy acid type anionic dispersing agents, one kind in organosilicon aqueous dispersion or more
Kind；The levelling agent is organosilicon levelling agent；The antifoaming agent is preferably polyurethanes antifoaming agent, phosphoric acid ester defoaming
It is one or more in agent, silylated polyether class antifoaming agent；The thickener is preferably modified cellulose class thickener, hydrophobic changes
It is one or more in the swollen acrylic thickener of property alkali soluble, association type polyurethane thickener.
The poly- hexamethylene diamine adipic acid acyl acid anhydride powder can directly be bought in market.
The periporate is the periporate of homemade release anion and far infrared, and preparation method is：
(1) preparation of mixed silicate powder：Successively by the 1-2mol/L of the deionized water of 30-50 parts by weight, 1-2 parts by weight
Hydrochloric acid, the rare earth element chloride of 5-10 parts by weight, the period 4 transition metal chloride of 5-10 parts by weight be added to instead
It answers in kettle, stirring and dissolving is uniform, is heated to 80-90 DEG C, and 10-20 parts by weight 20%-30% mass fractions are added dropwise dropwise thereto
Sodium silicate solution, have Precipitation at this time, after being added dropwise, stirring nature is down to room temperature, centrifuges solid；Then it is added
To ball milling 2-3h in ball mill, 800 mesh screens obtain mixed silicate powder.
(2) calcination processing：Mixed silicate powder is added in calcining furnace, then 800-900 DEG C of calcining 8-12h is cooled down
To room temperature, system calcining powder is derived from.
(3) preparation of the periporate of self-control release anion and far infrared：The self-control of 20 parts by weight is taken to calcine powder, 20 weights
Amount part water, 10-20 parts by weight 20-30% sodium hydroxide solutions are added in reaction kettle, and 60-70 DEG C of reaction is heated under stirring
18-24h most through cooling, centrifugation and filters precipitation, deionized water water washing and precipitating 3-5 times, vacuum drying afterwards, it is negative to derive from system release
The periporate of ion and far infrared.
The rare earth element chloride is yttrium chloride (III), Europium chloride (III), samarium trichloride (II), samarium trichloride (III), chlorine
Change one or more in europium (II), Europium chloride (III), cerium chloride (III), cerium chloride (IV).
The period 4 transition metal chloride is one in iron chloride (III), manganese chloride (II), chromium chloride (III)
Kind is a variety of.
The emulsion paint of the release anion and far infrared, is prepared by following methods：
Deionized water, wetting dispersing agent, levelling agent, coalescents are sequentially added in dispersion cylinder, are uniformly dispersed, and then will
Rotating speed improves to >=1200r/min close to reactor bottom in dispersion disk center in dispersion cylinder, by homemade release anion with
Periporate, filler, the poly- hexamethylene diamine adipic acid acyl acid anhydride powder of far infrared sequentially add fully dispersed uniform in dispersion cylinder；It reduces and turns
It is fast to sequentially add lotion, power subtype catalyst, thickener, antifoaming agent to≤1000r/min, fully dispersed uniformly rear use
The filter screen filtration of 400-800 mesh is to get the emulsion paint of the present invention for discharging anion and far infrared.
Compared with the existing technology, the present invention has following advantages：(1) it is prepared for the negative ion powder with porous structure, is compared
Surface area bigger, transition metal and rare earth metal are easier ingress of air, it is easier to discharge anion and far infrared；(2) institute
The periporate for self-control anion and the far infrared release stated through high-temperature calcination technique, calcining be remarkably improved transition metal with it is dilute
The low temperature and far infrared transmission performance of soil metal oxide, the present invention have higher far infrared releasing effect；(3) air
In, in the present invention there is the electron-donating group and complex anion group of conjugation in power supply subtype catalyst, can be catalyzed anion
Transition metal in powder changes from rare earth metal between different oxidation state, to be negative oxygen ion by dioxygen oxidation, accelerates
Anion rate of release, the energy discharged in the process are far infrared；It (4) can after poly- hexamethylene diamine adipic acid acyl acid anhydride film forming
Increase emulsion paint scratch resistance and wear-resisting property；(5) anion and far infrared release performance, the present invention based on the present invention have
Higher antibiotic property.
Specific implementation mode
A kind of release anion of the present invention and the emulsion paint of far infrared are further retouched with reference to embodiment
It states.It is understood that specific embodiment described herein is used only for explaining related invention, rather than the limit to the invention
It is fixed.
Embodiment 1
A kind of emulsion paint of release anion and far infrared, in parts by weight, composition is as follows：300 parts of silicone acrylic emulsion, from
10 parts of the periporate of system release anion and far infrared, gathers oneself at 1,1 '-bis- 1 part of (diphenyl-phosphinomethyl) biphenyl sodium disulfonates
3 parts of diammonium adipate acyl acid anhydride powder, 450 parts of deionized water, 120 parts of talcum powder, 15 parts of alcohol ester-12, polyocarboxy acid type anionic dispersant
2 parts of agent, 2 parts of organosilicon levelling agent, 5 parts of acrylic thickener of hydrophobically-modified alkali swelling, 1 part of silylated polyether class antifoaming agent.
The preparation method of periporate of self-control release anion and far infrared described in the present embodiment is：
(1) preparation of mixed silicate powder：Successively by the salt of the 1mol/L of the deionized water of 40 parts by weight, 1.8 parts by weight
Acid, the Europium chloride (III) of 7 parts by weight, 9 parts by weight iron chloride (III) be added in reaction kettle, stirring and dissolving is uniform, is heated to
85 DEG C, the sodium silicate solution of 16 parts by weight, 24% mass fraction is added dropwise dropwise thereto, there is Precipitation at this time, is added dropwise
Afterwards, stirring nature is down to room temperature, centrifuges solid；Then the ball milling 2.5h into ball mill is added, 800 mesh screens must mix
Silicate powder.
(2) calcination processing：Mixed silicate powder is added in calcining furnace, 850 DEG C of calcining 9h are then cooled to room temperature,
Powder is calcined derived from system.
(3) preparation of the periporate of self-control release anion and far infrared：The self-control of 20 parts by weight is taken to calcine powder, 20 weights
Amount part water, 14 parts by weight, 23% sodium hydroxide solution are added in reaction kettle, and 68 DEG C of reaction 20h are heated under stirring, are most passed through afterwards
It is cooling, centrifuge and filter precipitation, deionized water water washing and precipitating 4 times, vacuum drying, derive from system release anion and far infrared
Periporate.
Embodiment 2
A kind of emulsion paint of release anion and far infrared, in parts by weight, composition is as follows：250 parts of pure-acrylic emulsion, from
0.5 part of sulfonate sodium, poly- hexamethylene diamine adipic acid acyl between 8 parts of the periporate of system release anion and far infrared, triphenylphosphine three
6 parts of acid anhydride powder, 400 parts of deionized water, 80 parts of fine particle calcium carbonate, 10 parts of glycol monoethyl ether, 4 parts of organosilicon aqueous dispersion, organosilicon stream
1 part of flat agent, 3 parts of association type polyurethane thickener, 0.5 part of polyurethanes antifoaming agent.
The preparation method of periporate of self-control release anion and far infrared described in the present embodiment is：
(1) preparation of mixed silicate powder：Successively by the hydrochloric acid of the 2mol/L of the deionized water of 30 parts by weight, 1 parts by weight,
The samarium trichloride (II) of 5 parts by weight, the chromium chloride (III) of 5 parts by weight are added in reaction kettle, and stirring and dissolving is uniform, is heated to 80
DEG C, the sodium silicate solution of 20 parts by weight, 20% mass fraction is added dropwise dropwise thereto, there is Precipitation at this time, after being added dropwise,
Stirring nature is down to room temperature, centrifuges solid；Then the ball milling 2h into ball mill is added, 800 mesh screens must mix silicic acid
Salt fines.
(2) calcination processing：Mixed silicate powder is added in calcining furnace, 800 DEG C of calcining 12h are then cooled to room temperature,
Powder is calcined derived from system.
(3) preparation of the periporate of self-control release anion and far infrared：The self-control of 20 parts by weight is taken to calcine powder, 20 weights
Amount part water, 10 parts by weight, 30% sodium hydroxide solution are added in reaction kettle, and 60 DEG C of reactions are heated under stirring for 24 hours, are most passed through afterwards
It is cooling, centrifuge and filter precipitation, deionized water water washing and precipitating 5 times, vacuum drying, derive from system release anion and far infrared
Periporate.
Embodiment 3
A kind of emulsion paint of release anion and far infrared, in parts by weight, composition is as follows：290 parts of styrene-acrylic emulsion, from
System release anion and 9 parts of the periporate of far infrared, 0.6 part of diphenyl trimethoxy phosphorus -3- sodium sulfonates, poly- hexamethylene diamine oneself two
Sour 5 parts of acyl acid anhydride powder, 440 parts of deionized water, 90 parts of titanium dioxide, 14 parts of ethylene glycol monobutyl ether, polyocarboxy acid type anionic dispersing agents 2.5
Part, 1.4 parts of organosilicon levelling agent, 4 parts of modified cellulose class thickener, 0.6 part of phosphoric acid ester antifoaming agent.
The preparation method of periporate of self-control release anion and far infrared described in the present embodiment is：
(1) preparation of mixed silicate powder：Successively by the salt of the 1.5mol/L of the deionized water of 50 parts by weight, 2 parts by weight
Acid, the cerium chloride (IV) of 10 parts by weight, 10 parts by weight manganese chloride (II) be added in reaction kettle, stirring and dissolving is uniform, heating
To 90 DEG C, the sodium silicate solution of 10 parts by weight, 30% mass fraction is added dropwise dropwise thereto, there is Precipitation at this time, is added dropwise
Afterwards, stirring nature is down to room temperature, centrifuges solid；Then the ball milling 3h into ball mill is added, 800 mesh screens must mix silicon
Hydrochlorate powder.
(2) calcination processing：Mixed silicate powder is added in calcining furnace, 900 DEG C of calcining 8h are then cooled to room temperature,
Powder is calcined derived from system.
(3) preparation of the periporate of self-control release anion and far infrared：The self-control of 20 parts by weight is taken to calcine powder, 20 weights
Amount part water, 20 parts by weight, 20% sodium hydroxide solution are added in reaction kettle, and 70 DEG C of reaction 18h are heated under stirring, are most passed through afterwards
It is cooling, centrifuge and filter precipitation, deionized water water washing and precipitating 3 times, vacuum drying, derive from system release anion and far infrared
Periporate.
The emulsion paint of the release anion and far infrared described in embodiment 1-3, is prepared by following methods：
Deionized water, wetting dispersing agent, levelling agent, coalescents are sequentially added in dispersion cylinder, are uniformly dispersed, and then will
Disperse disk center close to reactor bottom, improves rotating speed (being more than 1200r/min), self-control anion and far infrared are discharged
Periporate, filler, poly- hexamethylene diamine adipic acid acyl acid anhydride powder sequentially add fully dispersed uniform in dispersion cylinder；Rotating speed is reduced (to be less than
1000r/min), sequentially add lotion, power supply subtype catalyst, thickener, antifoaming agent, it is fully dispersed uniformly after use 400-800
Purpose filter screen filtration is up to the emulsion paint of the present invention for discharging anion and far infrared.
The emulsion paint of the release anion of the embodiment of the present invention and far infrared and the release of Guangdong Jiangmen brand is negative
The sterilization white interior wall latex finishing coat (comparative example) of ion imposes on inner wall surface under the same conditions, detects under the same conditions
The traditional performance of emulsion paint, testing result such as following table：
Although the present invention has been explained in detail and has referred to embodiment, for those of ordinary skill in the art, show
Various schemes, modification and the change that can so make as specified above, should be construed as being included within the scope of the claims.
Claims (10)
1. a kind of emulsion paint of release anion and far infrared, which is characterized in that in parts by weight, composition is as follows：Lotion
250-300 parts, 8-10 parts of periporate, power supply 0.5-1 parts of subtype catalyst, poly- 3-6 parts of hexamethylene diamine adipic acid acyl acid anhydride powder, deionization
400-450 parts of water, 80-120 parts of filler, 10-15 parts of coalescents, 2-4 parts of wetting dispersing agent, 1-2 parts of levelling agent, thickener 3-
5 parts, 0.5-1 parts of antifoaming agent.
2. the emulsion paint of a kind of release anion and far infrared according to claim 1, which is characterized in that the breast
Liquid is one or more in silicone acrylic emulsion, styrene-acrylic emulsion, pure-acrylic emulsion.
3. the emulsion paint of a kind of release anion and far infrared according to claim 1, which is characterized in that the confession
Electron type catalyst is diphenyl trimethoxy phosphorus -3- sodium sulfonates, 1,1 '-bis- (diphenyl-phosphinomethyl) biphenyl sodium disulfonates, three
It is one or more in three sulfonate sodiums of Phenylphosphine；Coalescents are alcohol ester-12, glycol monoethyl ether, ethylene glycol monobutyl ether
In it is one or more.
4. the emulsion paint of a kind of release anion and far infrared according to claim 1, which is characterized in that described fills out
Material is one or more in coarse whiting, fine particle calcium carbonate, barium sulfate, titanium dioxide, talcum powder, mica powder, and the grain size of filler is 600 mesh-
1250 mesh；The relative molecular weight of the poly- hexamethylene diamine adipic acid acyl acid anhydride powder is 10000-50000.
5. the emulsion paint of a kind of release anion and far infrared according to claim 1, which is characterized in that the profit
Hygroscopic water powder is one or more in polyocarboxy acid type anionic dispersing agents, organosilicon aqueous dispersion；The levelling agent is
Organosilicon levelling agent.
6. the emulsion paint of a kind of release anion and far infrared according to claim 1, which is characterized in that described disappears
Infusion is one or more in polyurethanes antifoaming agent, phosphoric acid ester antifoaming agent, silylated polyether class antifoaming agent；The thickening
Agent is one kind in modified cellulose class thickener, hydrophobically-modified alkali swelling acrylic thickener, association type polyurethane thickener
Or it is a variety of.
7. the emulsion paint of a kind of release anion and far infrared according to claim 1, it is characterised in that described is more
The preparation method of hole powder is：
(1) preparation of mixed silicate powder：In parts by weight, successively by 30-50 parts of deionized water, 1-2 parts of 1-2mol/L
Hydrochloric acid, 5-10 parts of rare earth element chloride, 5-10 parts of period 4 transition metal chloride be added in reaction kettle, stir
It mixes and is uniformly dissolved, be heated to 80-90 DEG C, the sodium silicate solution of 10-20 parts of 20%-30% mass fractions is added dropwise dropwise thereto,
There is Precipitation at this time, after being added dropwise, stirring nature is down to room temperature, centrifuges solid；Then the ball into ball mill is added
2-3h is ground, 800 mesh screens obtain mixed silicate powder；
(2) calcination processing：Mixed silicate powder is added in calcining furnace, 800-900 DEG C of calcining 8-12h is subsequently cooled to room
Temperature derives from system calcining powder；
(3) preparation of periporate：In parts by weight, 20 parts of self-control is taken to calcine powder, 20 parts of water, 10-20 parts of 20-30% hydroxides
Sodium solution is added in reaction kettle, be heated under stirring 60-70 DEG C reaction 18-24h, most afterwards through cooling, centrifugation and filter precipitation,
Deionized water water washing and precipitating 3-5 times, vacuum drying obtain the periporate of homemade release anion and far infrared.
8. the emulsion paint of a kind of release anion and far infrared according to claim 7, which is characterized in that described is dilute
Earth elements chloride is yttrium chloride (III), Europium chloride (III), samarium trichloride (II), samarium trichloride (III), Europium chloride (II), Europium chloride
(III), one or more in cerium chloride (III), cerium chloride (IV).
9. the emulsion paint of a kind of release anion and far infrared according to claim 7, which is characterized in that described the
Four period transition metal chlorides are one or more in iron chloride (III), manganese chloride (II), chromium chloride (III).
10. a kind of preparation method of the emulsion paint of release anion and far infrared as described in claim 1-9, feature exist
In, deionized water, wetting dispersing agent, levelling agent, coalescents are sequentially added in dispersion cylinder, are uniformly dispersed, it then will dispersion
Rotating speed improves to >=1200r/min close to reactor bottom in dispersion disk center in cylinder, by homemade release anion and far red
Periporate, filler, the poly- hexamethylene diamine adipic acid acyl acid anhydride powder of outside line sequentially add fully dispersed uniform in dispersion cylinder；Reduce rotating speed extremely
≤ 1000r/min, sequentially adds lotion, power supply subtype catalyst, thickener, antifoaming agent, it is fully dispersed uniformly after use 400-800
Purpose filter screen filtration is to get the emulsion paint of the present invention for discharging anion and far infrared.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010398933.6A CN111423778A (en) | 2018-02-28 | 2018-02-28 | Preparation method of latex paint capable of releasing negative ions and far infrared rays |
| CN201810168600.7A CN108384359B (en) | 2018-02-28 | 2018-02-28 | Emulsion paint capable of releasing negative ions and far infrared rays and preparation method thereof |
| CN202010398934.0A CN111423747B (en) | 2018-02-28 | 2018-02-28 | Porous powder capable of releasing negative ions and far infrared rays and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810168600.7A CN108384359B (en) | 2018-02-28 | 2018-02-28 | Emulsion paint capable of releasing negative ions and far infrared rays and preparation method thereof |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010398934.0A Division CN111423747B (en) | 2018-02-28 | 2018-02-28 | Porous powder capable of releasing negative ions and far infrared rays and application thereof |
| CN202010398933.6A Division CN111423778A (en) | 2018-02-28 | 2018-02-28 | Preparation method of latex paint capable of releasing negative ions and far infrared rays |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108384359A true CN108384359A (en) | 2018-08-10 |
| CN108384359B CN108384359B (en) | 2020-09-29 |
Family
ID=63068664
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810168600.7A Active CN108384359B (en) | 2018-02-28 | 2018-02-28 | Emulsion paint capable of releasing negative ions and far infrared rays and preparation method thereof |
| CN202010398933.6A Withdrawn CN111423778A (en) | 2018-02-28 | 2018-02-28 | Preparation method of latex paint capable of releasing negative ions and far infrared rays |
| CN202010398934.0A Active CN111423747B (en) | 2018-02-28 | 2018-02-28 | Porous powder capable of releasing negative ions and far infrared rays and application thereof |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010398933.6A Withdrawn CN111423778A (en) | 2018-02-28 | 2018-02-28 | Preparation method of latex paint capable of releasing negative ions and far infrared rays |
| CN202010398934.0A Active CN111423747B (en) | 2018-02-28 | 2018-02-28 | Porous powder capable of releasing negative ions and far infrared rays and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN108384359B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113122084A (en) * | 2020-01-11 | 2021-07-16 | 中科(深圳)微能量科学技术研究院有限公司 | Water-based air purification paint and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112570241A (en) * | 2020-11-30 | 2021-03-30 | 范林 | Negative oxygen ion environment-friendly plastic powder for purifying air and inhibiting bacteria and environment-friendly antibacterial filter screen |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
| CN107163751A (en) * | 2017-06-01 | 2017-09-15 | 侯宇振 | A kind of anion imitates net taste except aldehyde environment friendly emulsion paint and preparation method thereof entirely |
| CN107446393A (en) * | 2017-09-21 | 2017-12-08 | 苏州振振好新型建材科技有限公司 | A kind of environmentally friendly radiation proof interiro wall latex paint |
| CN107523158A (en) * | 2017-08-21 | 2017-12-29 | 洛阳双瑞防腐工程技术有限公司 | A kind of enough persistently release anion and far infrared interior wall coating and preparation method |
| CN107641406A (en) * | 2017-11-23 | 2018-01-30 | 南通蛇类治疗研究所 | Chitin nano green environmental protection coating material |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8198359B2 (en) * | 2009-07-09 | 2012-06-12 | Ninglin Zhou | Multi-functional nanocomposite additive compositions and methods for making and using same |
| CN106316271A (en) * | 2015-06-17 | 2017-01-11 | 上海福岛化工科技发展有限公司 | Visible light photocatalyst internal-wall diatom mud paint |
| CN106566289A (en) * | 2016-10-23 | 2017-04-19 | 徐旭辉 | Rare earth oxide cladded hollow glass bead concrete material |
-
2018
- 2018-02-28 CN CN201810168600.7A patent/CN108384359B/en active Active
- 2018-02-28 CN CN202010398933.6A patent/CN111423778A/en not_active Withdrawn
- 2018-02-28 CN CN202010398934.0A patent/CN111423747B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
| CN107163751A (en) * | 2017-06-01 | 2017-09-15 | 侯宇振 | A kind of anion imitates net taste except aldehyde environment friendly emulsion paint and preparation method thereof entirely |
| CN107523158A (en) * | 2017-08-21 | 2017-12-29 | 洛阳双瑞防腐工程技术有限公司 | A kind of enough persistently release anion and far infrared interior wall coating and preparation method |
| CN107446393A (en) * | 2017-09-21 | 2017-12-08 | 苏州振振好新型建材科技有限公司 | A kind of environmentally friendly radiation proof interiro wall latex paint |
| CN107641406A (en) * | 2017-11-23 | 2018-01-30 | 南通蛇类治疗研究所 | Chitin nano green environmental protection coating material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113122084A (en) * | 2020-01-11 | 2021-07-16 | 中科(深圳)微能量科学技术研究院有限公司 | Water-based air purification paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108384359B (en) | 2020-09-29 |
| CN111423778A (en) | 2020-07-17 |
| CN111423747A (en) | 2020-07-17 |
| CN111423747B (en) | 2021-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105669910B (en) | A kind of polycarboxylic-acid cement grinding aid and preparation method | |
| CN102321426B (en) | Novel high sealing property unsaturated polyester white primer, and preparation method thereof | |
| CN108384359A (en) | A kind of emulsion paint and preparation method thereof of release anion and far infrared | |
| CN107474672A (en) | A kind of Elastic anti-crack artificial granite heat reflection coatings and preparation method thereof | |
| CN103937335B (en) | A kind of water base damping pulp and preparation method thereof | |
| CN101967324A (en) | Luminous antibacterial aqueous inner wall coating and preparation method and application thereof | |
| CN104263014A (en) | Preparing method of high-purity active calcium carbonate used for coating | |
| CN108997853A (en) | A kind of Antimicrobial preservative coating and preparation method thereof | |
| CN109281208A (en) | A kind of cotton fabric low temperature white discharge method | |
| CN107473269B (en) | Ceria-attapulgite-ferroferric oxide magnetic nano composite material preparation method and application | |
| CN106188929B (en) | A kind of modified hydrotalcite and preparation method thereof and its application in polyvinyl chloride processing | |
| CN107022207B (en) | A kind of preparation method of hydroxyapatite@tannic acid-iron/titanium dioxide viridine green containing methylene blue | |
| CN1110523C (en) | Medical stone paint | |
| CN109054463A (en) | A kind of preparation method of the polymolecularity pigment for PVC film structural material | |
| CN104497640A (en) | Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment | |
| CN108610811A (en) | A kind of functionality negative ion paint and preparation method thereof | |
| CN114574046A (en) | Novel biological sound-insulation diatom interior wall coating and preparation method thereof | |
| CN114149701A (en) | Antiviral and formaldehyde-resistant A-grade fireproof interior wall coating and preparation method thereof | |
| CN106590388A (en) | Strong-acid-resisting high-strength hanging beam and preparation method thereof | |
| CN108030947B (en) | A kind of preparation method of modified negative oxygen ion powder | |
| CN105647248B (en) | A kind of basis material and its preparation method and application | |
| CN108893006A (en) | A kind of quantum emulsion paint of efficient release anion | |
| CN108545766A (en) | Hollow alpha-semi water plaster stone super large microballoon and preparation method thereof | |
| CN110305548A (en) | A kind of preparation method of aqueous artistic pearl simulation wall cloth paint | |
| CN110158304A (en) | A kind of fabric nano functional finishing agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200831 Address after: Wang Sheren Zhen Sha Si Cun, Licheng District, Jinan City, Shandong Province Applicant after: Shandong Xinjia Coatings Co.,Ltd. Address before: 410217 Changsha, Changsha City, Hunan Wangcheng economic and Technological Development Zone gold Pioneer Park 4 Building C5 Applicant before: HUNAN CHENLI NEW MATERIAL Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Latex paint releasing negative ion and far infrared ray and preparation method thereof Effective date of registration: 20211223 Granted publication date: 20200929 Pledgee: Jinan Dongzhan sub branch of Qilu Bank Co.,Ltd. Pledgor: Shandong Xinjia Coatings Co.,Ltd. Registration number: Y2021370000152 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230619 Granted publication date: 20200929 Pledgee: Jinan Dongzhan sub branch of Qilu Bank Co.,Ltd. Pledgor: Shandong Xinjia Coatings Co.,Ltd. Registration number: Y2021370000152 |