CN1110523C - Medical stone paint - Google Patents
Medical stone paint Download PDFInfo
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- CN1110523C CN1110523C CN96116255A CN96116255A CN1110523C CN 1110523 C CN1110523 C CN 1110523C CN 96116255 A CN96116255 A CN 96116255A CN 96116255 A CN96116255 A CN 96116255A CN 1110523 C CN1110523 C CN 1110523C
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Abstract
The present invention relates to a novel decorative material for buildings, namely medical stone paint. Medical stone used as a filling material or inert pigment is added to many kinds of paint made from different main film-forming substances, and other secondary film-forming substances and auxiliary film-forming substances. Thus, the medical stone paint combines the function of health care of medical stone with the function of decoration of modern paint so as to form upgrade health-care decorative paint for buildings.
Description
The present invention relates to a kind of novel architecture coating, be specifically related to a kind of medical stone paint.
Technical background:
Traditional building coating, the earliest to calculate lime white, and still using so far, this illustrates that it has unique function and value, also eliminates not fall for the moment.Certain this coatings decoration is poor, of low grade, and along with the development of society, the raising of living standards of the people is used fewer and fewerily.
Existing coating comprises organic solvent based lacquer (oil-in-water-type), water-based paints (water-in-oil-type), and in use organic solvent constantly volatilizees, and can cause indoor pollution, influences HUMAN HEALTH.Therefore more and more cause people's vigilance.For this reason, many people do not contain the free of contamination of organic solvent in exploration, are suitable for the ornamental coating of indoor and outdoor.So occurred with polyvinyl alcohol, water glass be the coating of main binder as 106,107,803 coating, these coating are widely used at present.More novel " water Bao Shui " type coating also come out (referring to patent of invention publication number CN1097782A such as Suzhou City's building materials Shen Chun of Science Institute woodss).This shows that people are preventing and remedying pollution, increasing decoration functions, the entertaining function, very big effort has been made in aspect such as reduce production costs, and novel coating constantly comes out, and is promoting developing rapidly of coatings industry.
The objective of the invention is this progress is more pushed away further, will have the natural medicinal stone that the Ancient Times in China of nourishing function is developed the earliest---during Http makes, decorate and the new coating of nourishing function thereby produce a kind of having concurrently.Particularly provide a kind of free of contamination, have the novel medical stone water-borne coatings of decoration and nourishing function.
Advantage of the present invention:
1. medical stone has very strong adsorption function, as the raw material in the coating, both brought into play its effect as stopping composition and pigment extender, main is the function of its absorption hazardous and noxious substances, gas and bacterium of performance, helps to alleviate modern architecture internal contamination problem.
2. in and function.Medical stone has very strong stripping function, can regulate the pH value of water quality, makes the pH value of the above acidic solution of pH2 bring up to neutrality, and the pH value of the following basic solution of pH11 is reduced.The coating brushing that adds medical stone can play certain neutralizing effect to the metope potential of hydrogen when acid or alkaline metope, it is acid that acid metope is reduced, and makes alkaline metope reduce alkalescence, thus the etch and the pollution that help alleviating potential of hydrogen.
3. infra red radiation function.Because the main component of medical stone is removed SiO
2, Al
2O
3Also has more Fe outward,
2O
3, transition element metal oxides such as MgO, MnO, be applied to metope as coating, at room temperature have certain micro-infrared radiation, be of value to HUMAN HEALTH.This coating is specially adapted to the interior wall of building in the north thing, under the effect of stove, heated kang, heating installation, trace element in the medical stone is in excited state and sends specific hertzian wave and act on human body, produce resonance with the intravital trace element of people, thereby increase its activity, promote the normal catalytic effect of human chitinase, influence heredity is because of base and vital process, can play certain effect that improves health, promotes longevity, also help diseases such as curing general sacroiliitis, rheumatosis.
4. anti-flaming function.Medical stone is a member of earth rock family, belongs to intrusive igneous rocks, is the mixture of multiple silicate minerals, as the coating composition material, has good anti-flaming function.
Description of the invention
The purpose of this invention is to provide a kind of medical stone paint and manufacture craft thereof.
The objective of the invention is to realize in the following manner:
A kind of medical stone paint is characterized in that in different main film forming substance, and in all kinds of coating that other film forming subsidiary material matter and auxiliary film forming matter are formed, medical stone accounts for 1% of prescription gross weight at least as filler.
Detailed description of the invention
One, medical stone selects for use and the preparation of particulate material
1. the home-made medical stone ore of can choosing any one kind of them.Here be example only with Changbai Mountain, Mount Taishan and Song Shan medical stone.Be the chemical composition of each medical stone ore below, represent with weight percentage.
| Chemical composition | The Changbai Mountain medical stone | The Mount Taishan medical stone | Song Shan Hua Gang type medical stone | Song Shan fiber crops stone type medical stone |
| SiO 2 | 63.92 | 75.81-67.90 | 75.98 | 73.28 |
| Al 2O 3 | 16.87 | 13.6-15.75 | 11.87 | 15.22 |
| Fe 2O 3 | 2.44 | 2.82-0.79 | 0.70 | 1.52 |
| FeO | 2.05 | 0.9-0.43 | 0.81 | 1.06 |
| K 2O | 2.14 | 4.86-1.59 | 5.18 | 2.06 |
| Na 2O | 4.35 | 5.45 | 2.24 | 4.54 |
| MgO | 1.66 | 0.66-0.23 | 0.22 | 1.12 |
| CaO | 4.51 | 2.51-0.48 | 0.45 | 2.21 |
| MnO 2 | 0.10 | 0.06-0.02 | 0.01 | 0.05 |
| TiO 2 | 0.64 | 0.32-0.05 | 0.05 | 0.20 |
Annotate: more than be the raw ore chemical constitution, clean and process each component and can change to some extent through pulverizing, should be certificate with the actual parameter therefore.
2. medical stone granule: degree
Polyethenol series coating: the granularity of medical stone is generally selected the 120-320 order for use
Inorganic paint: the granularity of medical stone is generally selected the 20-120 order for use, and should with thick, in,
Thin collocation is used
Cement family coating material: it is coarse particles that the granularity of medical stone is generally selected 3-5mm for use
The 20-80 order is middle particle
120 orders are above to be fine particle
Emulsion paint: it is coarse particles that the granularity of medical stone is generally selected the 20-40 order for use
The 40-120 order is middle particle
120 orders are above to be fine particle
Solvent based coating: the granularity of medical stone is selected the order at 120-320 for use
3. the deironing of medical stone granule: is handled
The medical stone that is applied to white, light-coloured coating should carry out deironing to be handled, and iron-holder is controlled at below 1%, best＜0.5%.
The medical stone that is applied to black, Dark grey and other dark coating can be refused deironing, even also can add other tinting pigment.
Two, all kinds of medical stone paint principles of formulation design
1. polyethenol series medical stone paint principles of formulation design
1. medical stone content: powder≤90%
Thick material≤75%
In thick material≤50%
Thin material≤35%
2. medical stone can be used with other solids constituent raw material, improving the performance of coating, but solids constituent total content powder≤90%
Thick material≤75%
In thick material≤50%
Thin material≤35%
3. polyvinyl alcohol concentration 2-12%
Concentration of sodium silicate 3-10%
4. medical stone fineness: the 120-320 order, select for use as required.
2. mineral-type medical stone paint principles of formulation design
1. main film forming substance can be selected potassium silicate K for use
2O.nSiO
2) or silicon sol, because that potassium silicate prepares price is more expensive, so generally be advisable with silicon sol.
2. medical stone content answers≤70%.
3. can add other raw material as filler improving coating property, but the total content of medical stone and other raw material should≤70%.
4. silicon strength of solution 10-30%.
3. cement is the medical stone paint principles of formulation design
1. cement comprises Portland cement, white cement and colored cement.
2. the medical stone add-on answers≤90%.
3. the medical stone granule: degree is looked actual needs and is selected for use, generally should carse, medium and small collocation, also can select a kind of granularity.
4. water cement ratio (water/cement) 40-65% of the thick material of medical stone (being commonly called as concrete), medical stone largest particle 25mm.
4. emulsion-type medical stone paint principles of formulation design
1. synthetic resin emulsion comprises benzene-acrylic emulsion (latex of copolymer in cinnamic acrylic ester); Vinegar-acrylic emulsion (vinyl acetate-acrylic copolymer emulsion); Chlorine partial emulsion (vinyl chloride-vinylidene chloride copolymer emulsion); Pure-acrylic emulsion (pure acrylic acid copolymer emulsion); The mixed emulsion of one or more in the polyvinyl acetate emulsion.
2. medical stone content≤50%.
3. can select for use other filler and medical stone to use with, to improve coating property.The total solids level of medical stone and other filler answers≤50%.
4. the medical stone granule: degree should be selected for use between the 120-320 order.
The present invention is described in further detail below with reference to specific embodiment, so that advantage of the present invention is more obvious.Embodiment 1-21: polyvinyl alcohol medical stone paint
1. base-material preparation
Polyethenol series medical stone paint base-material preparation prescription (weight %)
2. formulation for coating material (weight %)
3. manufacture craft
A. the water adding is had in the container of agitator and heating unit, be heated to 80-98 ℃, polyvinyl alcohol, urea or ammoniacal liquor or formaldehyde are slowly added, under agitator stirs, progressively be base-material, lay in standby to dissolving.
B. the amount by base-material in the prescription adds blending device, adds entry and water glass under agitator stirs.Filler (medical stone, talcum powder, light calcium carbonate), pigment (zinc sulfide white, ultramarine) and subsidiary material (tributyl phosphate, Sodium hexametaphosphate 99) are progressively added successively, be finished product to stirring, the packing warehouse-in.
C. powder: each component raw material mixing and stirring promptly be can be finished product, during use in powder: the ratio of boiling water=1: 4 stirs fast, and polyvinyl alcohol is all dissolved, and being cooled to normal temperature can use.
D. this is to add other pigment or colored medical stone sintering particle formulation required color in the prescription, also can add the colored medical stone paint of spices preparation band fragrance.
Embodiment 22-25
Inorganic kitchen range medical stone paint
1. formulation for coating material (weight %)
| Raw material/embodiment numbering | Embodiment 22 | Embodiment 23 | Embodiment 24 | Embodiment 25 |
| Silicon sol | 10-20 | 10 | 10-20 | 10 |
| Water-soluble trimeric cyanamide | 0.2-0.5 | 0.3 | 0.2-0.5 | 0.5 |
| Propylene glycol | 1-2 | 2 | / | / |
| Triglycol | / | / | 0.5-1.5 | 1.5 |
| Tributyl phosphate | 2.0 | 2 | 1.5 | 2 |
| Sodium hexametaphosphate 99 | 0.5-1 | 0.5 | 0.5-1 | 0.8 |
| Methylcellulose gum | 0.1-0.2 | 0.2 | 0.1-0.2 | 0.2 |
| Titanium dioxide | 30 | / | 25 | / |
| Light calcium carbonate | 20 | / | 15 | / |
| Medical stone | 20 | 70 | 30 | 70 |
| Colorant | In right amount | In right amount | In right amount | In right amount |
| Water | 14-18 | 15 | 14-18 | 15 |
2. manufacture craft
A. with mixing with water in film coalescence aid propylene glycol or the triglycol adding reactor, fully stir.
B. add and auxiliary agents such as water-soluble trimeric cyanamide, tributyl phosphate, Sodium hexametaphosphate 99.
C. add silicon sol, fully stir.
D. add fleut, fully stir.
E. add color paste toning.
F. will send into sand mill through well-beaten slurries grinds.
G. go out still, filtration, barrelling, warehouse-in.
Embodiment 26-40
Cement is medical stone paint prescription (weight %)
Cement is the thick material of medical stone (being commonly called as concrete):
| The embodiment numbering | Raw material is formed % | |||||
| Cement | Medical stone | Yellow ground | The paper muscle | Water | 107 glue | |
| 26 | 10 | 90 | / | / | In right amount | / |
| 27 | 20 | 80 | / | / | In right amount | 0.6 |
| 28 | 20 | 70 | 10 | / | In right amount | 0.6 |
| 29 | 20 | 60 | 15 | 5 | In right amount | 0.6 |
| 30 | 30 | 70 | / | / | In right amount | 0.9 |
| 31 | 30 | 60 | 10 | / | In right amount | 0.9 |
| 32 | 30 | 50 | 15 | 5 | In right amount | 0.9 |
| 33 | 40 | 60 | / | / | In right amount | 1.2 |
| 34 | 40 | 50 | 10 | / | In right amount | 1.2 |
| 35 | 40 | 40 | 15 | 5 | In right amount | 1.2 |
| 36 | 50 | 50 | / | / | In right amount | 1.5 |
| 37 | 50 | 40 | 10 | / | In right amount | 1.5 |
| 38 | 50 | 30 | 15 | 5 | In right amount | 1.5 |
| 39 | Press cement: medical stone: yellow ground: the paper muscle: water=1: 1: 2: preparation in 0.5: 2 | |||||
| 40 | Press cement: medical stone: water=preparation in 1: 3: 2 | |||||
| The embodiment numbering | Cement | Fine aggregate | Coarse aggregate | Water | Weight % | ||
| Medical stone | Yellow ground | Medical stone | Yellow ground | ||||
| 41 | 15 | 15 | 15 | 24 | 24 | 7 | 100 |
| 42 | 15 | 19 | 19 | 19 | 19 | 9 | 100 |
| 43 | 15 | 30 | / | 48 | / | 7 | 100 |
| 44 | 15 | 38 | / | 38 | / | 9 | 100 |
2. manufacture craft
A. cement is that medical stone paint is made: cement (can be selected from Portland cement, white cement, colored water cement), medical stone, yellow ground and paper muscle limit are added the waterside mix evenly, can use.
B. medical stone---the thick material of cement (concrete) should with medical stone granule: carse, medium and small prepare add in stirrer the inside that the waterside stirs can be standby.
C. dry powder can be stirred back packing of above-mentioned two products is dispatched from the factory, when the user uses again with using behind an amount of water agitation and dilution.Embodiment 45-52 synthetic resin emulsion type medical stone paint
1. emulsion-type medical stone paint prescription (weight %)
| The embodiment numbering | 45 | 46 | 47 | 48 | 49 | 50 | 51 | 52 | |
| (50%) benzene one acrylic emulsion | 40 | 40 | 40 | 40 | 40 | 40 | 10 | 10 | |
| Water | 10 | 10 | 10 | 10 | 10 | 10 | 40 | 40 | |
| Pigment | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | |
| Filler: | Talcum powder | 20 | 10 | 10 | / | 10 | / | / | 10 |
| Wollastonite powder | / | / | 10 | / | / | / | / | 10 | |
| Light calcium carbonate | / | 10 | / | 20 | / | / | / | / | |
| Process white | / | / | / | / | 10 | / | / | / | |
| Medical stone | 15 | 15 | 15 | 15 | 15 | 35 | 30 | 10 | |
| Film coalescence aid: | Propylene glycol | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| Phenylcarbinol | 4 | 4 | 4 | 4 | 4 | 4 | 4 | 4 | |
| Dispersion agent: Sodium hexametaphosphate 99 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | |
| Neutralizing agent: ammoniacal liquor | In right amount | In right amount | In right amount | In right amount | In right amount | In right amount | In right amount | In right amount | |
| Thickening material: (2%) Walocel MT 20.000PV | 5 | 5 | 5 | 5 | 5 | 5 | 10 | 10 | |
2. emulsion-type medical stone paint manufacture craft
In high speed dispersor, do pigment, filler, water pre-dispersed earlier, emulsion and various auxiliary agent are added in the fully dispersive pasting successively, redispersion transfers to the pH value about 7 with ammoniacal liquor again, promptly finished the preparation whole process after the modulation through pre-dispersed---dispersion---, finished product can be packed warehouse-in.
The colorful fragrant coating of emulsion-type medical stone
1. formulation for coating material:
| The embodiment numbering | 53 | 54 |
| Benzene emulsion (50%) | 50 | 50 |
| Propylene glycol | 0.5-1 | 0.5-1 |
| Phenylcarbinol | 5-10 | 5-10 |
| Sodium hexametaphosphate 99 | 0.1 | 0.1 |
| Walocel MT 20.000PV | 5 | 5 |
| Medical stone | 30-35 | / |
| The medical stone color grains | / | 30-35 |
| Colorful pigment | 3-6 | / |
| Spices | 3-5 | 3-5 |
| Ammoniacal liquor | An amount of adjust pH about 7 | An amount of adjust pH about 7 |
2. technology: each component of raw material is added after stirrer fully stirs, send into shredder and grind and be finished product more after filtering and can pack warehouse-in.
Embodiment 55:
Acrylate wall formulation for coating material
| Material name | Weight % |
| Thermoplastic propene's acid esters | 15 |
| Methylethylketone | 60 |
| Pigment | 3 |
| Medical stone | 19 |
| Dibutyl phthalate | 3 |
Manufacture craft
A. acrylate, solvent (methylethylketone) pigment, filler (medical stone), toughner (o-benzoic acid dibutylester) are inserted the ball-grinding machine ball milling.
B. ball milling liquid filters through filter and is finished product, the packing warehouse-in.
Embodiment 56
Solvent-borne type medical stone Floor paint prescription
Annotate: mixed solvent is a toluene: butanols: ring ethyl ketone=4: 3: 3
| Material name | Weight % |
| Supervinyi chloride resin | 7.5 |
| The Semen Lini oil Synolac | 2.5 |
| Maleic resin | 3 |
| Mixed solvent | 64 |
| Dibutyl phthalate | 2.7 |
| Ricinolic acid barium | 0.3 |
| Medical stone (300 order) | 10 |
| Pigment | 10 |
Manufacture craft:
A. 50% supervinyi chloride resin being added twin-screw extruder (being heated to 50-60 ℃) with dibutyl phthalate, ricinolic acid barium, pigment, medical stone rolls repeatedly and is smelt the mixture color chips.
B. mixed solvent and all the other 50% supervinyi chloride resins, Semen Lini oil Synolac, maleic anhydride resin being added reactor is heated to 40-50 ℃ and is stirred to whole dissolvings.
C. again the mixture color chips is added, be stirred to the even resin that reaches and all dissolve, be the finished product packing warehouse-in.
In sum, characteristics of the present invention are that the natural medicinal stone that this Ancient Times in China of medical stone is developed is the earliest introduced modern architecture ornament materials---the manufacturing of coating, be incorporated into one thereby will keep healthy with decoration functions, form the health architectural decoration coating article of new generation of novel concept.
Claims (6)
1. a medical stone paint is characterized in that, in all kinds of coating that different main film forming substance, other film forming subsidiary material matter and auxiliary film forming matter are formed, described medical stone accounts for 1～90% (weight) of prescription total amount as filler.
2. medical stone paint as claimed in claim 1 is characterized in that, in polyethenol series coating, it is powder 15～90% (weight) that medical stone accounts for the prescription total amount as filling adding amount, granularity 120～320 orders.
3. medical stone paint as claimed in claim 1 is characterized in that, in mineral-type coating, it is 20～70% (weight) that medical stone accounts for the prescription total amount as filling adding amount, granularity 20～120 orders.
4. medical stone paint as claimed in claim 1 is characterized in that, in cement family coating material, it is 30～90% (weight) that medical stone accounts for the prescription total amount as filling adding amount, and should be used granularity 20～80 orders by carse, medium and small particle.
5. medical stone paint as claimed in claim 1 is characterized in that, in the emulsion paint, it is 10～50% (weight) that medical stone accounts for the prescription total amount as filling adding amount, granularity 20～120 orders.
6. medical stone paint as claimed in claim 1 is characterized in that, in solvent type coating, medical stone accounts for prescription total amount 10～30% (weight), granularity 120～320 orders as filler or pigment extender add-on.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116255A CN1110523C (en) | 1996-02-17 | 1996-02-17 | Medical stone paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96116255A CN1110523C (en) | 1996-02-17 | 1996-02-17 | Medical stone paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1157841A CN1157841A (en) | 1997-08-27 |
| CN1110523C true CN1110523C (en) | 2003-06-04 |
Family
ID=5123377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96116255A Expired - Fee Related CN1110523C (en) | 1996-02-17 | 1996-02-17 | Medical stone paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1110523C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250342B (en) * | 2008-03-12 | 2012-10-03 | 刘春雨 | Method for preparing inner-outer wall powder paint |
| CN102093791A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Formula process for nano negative ion compound functional coating |
| CN102838893A (en) * | 2012-10-11 | 2012-12-26 | 倪忠臻 | Medical-stone latex putty and preparation method |
| CN102911567A (en) * | 2012-10-30 | 2013-02-06 | 广东华兹卜化学工业有限公司 | Medical stone smart wall paint |
| CN103059592B (en) * | 2013-01-28 | 2015-07-15 | 长安大学 | Environment-friendly flame-retardant asphalt and preparation method thereof |
| CN103351790A (en) * | 2013-06-19 | 2013-10-16 | 天长市金陵电子有限责任公司 | Maifanite powder heat dissipation coating used for LED lights and preparation method thereof |
| CN106752437A (en) * | 2016-11-30 | 2017-05-31 | 安徽惠尔矿用设备有限公司 | A kind of mining ventilating duct heatproof flame-retardant coated cloth |
| CN113354990A (en) * | 2021-06-16 | 2021-09-07 | 苏州天禄建筑工程有限责任公司 | Cold-feel-resistant fluorocarbon coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063230A (en) * | 1991-12-20 | 1992-08-05 | 重庆医科大学附属第一医院 | Chinese herbal medicine paint capable of causing biological effect |
| CN1085974A (en) * | 1992-10-17 | 1994-04-27 | 天津市硅酸盐研究所 | Far-infrared ceramic fabric |
-
1996
- 1996-02-17 CN CN96116255A patent/CN1110523C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063230A (en) * | 1991-12-20 | 1992-08-05 | 重庆医科大学附属第一医院 | Chinese herbal medicine paint capable of causing biological effect |
| CN1085974A (en) * | 1992-10-17 | 1994-04-27 | 天津市硅酸盐研究所 | Far-infrared ceramic fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1157841A (en) | 1997-08-27 |
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