CN111073359A - Inorganic coating and preparation method thereof - Google Patents
Inorganic coating and preparation method thereof Download PDFInfo
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- CN111073359A CN111073359A CN201911396778.8A CN201911396778A CN111073359A CN 111073359 A CN111073359 A CN 111073359A CN 201911396778 A CN201911396778 A CN 201911396778A CN 111073359 A CN111073359 A CN 111073359A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses an inorganic coating, which relates to the technical field of inorganic coatings and comprises the following raw materials in parts by weight: 0.17 to 0.37 portion of hydroxyethyl cellulose; 0.48 to 1.48 portions of dispersant; 4.86 to 10.46 portions of titanium dioxide; 26.32 to 32.32 parts of superfine heavy calcium carbonate; 5.22 to 10.44 portions of talcum powder; 1.24-2.42 parts of negative ion coating additive; 5.24 to 10.42 portions of odor-free emulsion; 12.24 to 20.24 portions of inorganic modified silicate; 1.44-2.64 parts of viscosity stabilizer; 0.50 to 1.50 portions of defoaming agent; 0.25-1.0 part of water-proofing agent; 16.24 to 36.24 portions of deionized water; 0.5-1.0 part of mildew preventive. The invention also discloses a preparation method of the inorganic coating, which has the characteristics of continuously releasing negative oxygen ions, removing coating peculiar smell and purifying air. The invention can continuously release negative ions to remove harmful gases such as formaldehyde, ammonia and benzene, can resist and inhibit bacteria, and can prevent the coating from hardening.
Description
Technical Field
The invention relates to the technical field of inorganic coatings, in particular to an inorganic coating and a preparation method thereof.
Background
The inorganic coating is a coating which takes inorganic materials as main film forming substances, is a short name of all-inorganic mineral coatings, and is widely applied to the daily life fields of buildings, paintings and the like due to high performance.
The inorganic coating is an inorganic polymer coating which is composed of inorganic polymer, metal subjected to dispersion activation, metal oxide nano material and rare earth ultrafine powder, can quickly react with iron atoms on the surface of a steel structure to generate an inorganic polymer anticorrosive coating which has physical and chemical double protection effects and is firmly combined with a matrix through a chemical bond, has no pollution to the environment, long service life and anticorrosive performance reaching the international advanced level, and is a high-tech upgrading product meeting the requirement of environmental protection.
However, the existing inorganic coating is only used as a building material, has single function and no additional function, and has no advantages in the competition of the same type of products.
Disclosure of Invention
The invention aims to provide an inorganic coating to solve the problem that the existing inorganic coating has single function and no additional function.
The basic scheme provided by the invention is as follows: an inorganic coating comprises the following raw materials in parts by weight:
0.17 to 0.37 portion of hydroxyethyl cellulose; 0.48 to 1.48 portions of dispersant; 4.86 to 10.46 portions of titanium dioxide; 26.32 to 32.32 parts of superfine heavy calcium carbonate; 5.22 to 10.44 portions of talcum powder; 1.24-2.42 parts of negative ion coating additive; 5.24 to 10.42 portions of odor-free emulsion; 12.24 to 20.24 portions of inorganic modified silicate; 1.44-2.64 parts of viscosity stabilizer; 0.50 to 1.50 portions of defoaming agent; 0.25-1.0 part of water-proofing agent; 16.24 to 36.24 portions of deionized water; 0.5-1.0 part of mildew preventive.
The scheme has the advantages that:
the inorganic coating adopting the formula not only has the function of the building material of the inorganic coating, but also has the function of emitting negative oxygen ions. The concentration of the negative oxygen ions is closely related to the health of people, and people need the negative oxygen ions at all times, especially in the present day with increasingly serious pollution. According to the research of environmental scientists, people feel tired, dizziness and bloating when the concentration of negative oxygen ions in the air is less than 20 per cubic centimeter; when the number of negative oxygen ions in each cubic centimeter of air is between 1000 and 10000, people can feel calm and calm; when the number of negative oxygen ions in each cubic centimeter of air is more than 10000, people can feel refreshed, comfortable and pleasant; when the number of the negative oxygen ions in the air per cubic centimeter is more than 10 ten thousand, the effects of calming, relieving asthma, eliminating fatigue, regulating nerves and the like can be achieved.
In addition, the mildew preventive is added, so that the mildew of the coating can be effectively prevented. The water-proof agent is added, and can react with the emulsion and potassium silicate to form a firm chemical bond, so that the wrapping capability of the emulsion on pigment and filler is greatly improved, and the physical mechanical strength of a paint film is improved, so that the water resistance, scratch resistance, weather resistance, scrub resistance, wear resistance and the like of the coating are remarkably improved.
Further, the feed comprises the following raw materials in parts by weight:
0.27 part of hydroxyethyl cellulose; 0.98 part of a dispersant; 7.86 parts of titanium dioxide; 29.32 parts of superfine heavy calcium carbonate; 7.72 parts of talcum powder; 1.74 parts of negative ion coating additive; 7.74 parts of odor-free emulsion; 16.24 parts of inorganic modified silicate; 2.04 parts of a viscosity stabilizer; 1.00 part of defoaming agent; 0.35 part of water proofing agent; 26.24 parts of deionized water; 1.00 part of mildew preventive.
The inorganic coating of the formula can exert the best effect.
The invention also provides a preparation method of the inorganic coating, which comprises the following steps:
step one, uniformly mixing deionized water and hydroxyethyl cellulose under a stirring state; stirring the mixture under a new stirring state until the hydroxyethyl cellulose is completely dissolved to obtain hydroxyethyl cellulose liquid;
uniformly mixing hydroxyethyl cellulose liquid, a dispersing agent and a defoaming agent under a stirring state to obtain a dispersion liquid;
step three, uniformly mixing the dispersion liquid, the titanium dioxide, the superfine heavy calcium carbonate, the talcum powder and the negative ion coating additive under a stirring state, and stirring under a new stirring state to obtain negative oxygen ion liquid;
step four, uniformly mixing the negative oxygen ion liquid, the odor-free emulsion, the inorganic modified silicate, the water-resistant agent and the viscosity stabilizer under the stirring state to obtain a stable liquid;
adjusting the viscosity of the stabilizing solution by using deionized water, and filtering to obtain a semi-finished product;
and step six, adding a mildew preventive into the semi-finished product to obtain a finished product.
The scheme has the advantages that:
the inorganic coating prepared by the method has the characteristics of continuously releasing negative oxygen ions, removing coating peculiar smell, purifying air and preventing mildew, can add additional functions to the inorganic coating, and can improve the competitiveness in similar products.
Further, the stirring speed of the stirring state in the first step is 250-350 r/min.
At this stirring speed, the respective materials can be better mixed.
Further, the stirring speed of the new stirring state in the first step is 650-850 r/min.
In the new stirred state, it is better to mix with the original material.
Further, the stirring speed of the stirring state in the second step is 650-850 r/min.
At this stirring speed, a uniform dispersion can be obtained.
Further, the stirring speed of the stirring state in the third step is 650-850 r/min, and the stirring speed of the new stirring state in the third step is 1350-1550 r/min.
The negative oxygen ion liquid can be obtained at this stirring speed.
Further, the fineness of the solid particles in the negative oxygen ion liquid in the third step is less than or equal to 50 μm.
The solid particles in the oxygen anion liquid are smaller, and the uniformity of the liquid in the oxygen anion liquid cannot be influenced.
And the stirring speed of the stirring state in the fourth step is 650-850 r/min. At this stirring speed, a uniform stable liquid can be obtained.
Further, the inorganic modified silicate is potassium lithium silicate.
Compared with the coating formed by the currently used potassium water glass, the coating formed by the potassium silicate glass has poor water resistance, and the lithium potassium silicate used in the scheme has good water resistance.
Further, the viscosity stabilizer is a quaternary ammonium salt.
The quaternary ammonium salt is used as a viscosity stabilizer, and can react with other components in a system through steric hindrance stop silicate, so that the stability of the product is improved, and the occurrence of gelation and hardening is avoided.
Detailed Description
The following is further detailed by way of specific embodiments:
the inorganic coating is a coating which takes odor-free emulsion and inorganic modified silicate as main film-forming substances. The paint film is smooth, bright in color, rich in color and unique in super-strong weather resistance; has petrochemical function, and can chemically react with mineral matrix to form a water-proof and acid-proof silicate rock, which is sterile and can prevent moss from breeding; the flame-retardant plastic has the characteristics of inorganic substances and particularly good temperature resistance, and can not burn at the high temperature of 1200 ℃ and is flame-retardant; the waterproof and high-breathing capacity is provided, so that water in the building can be freely evaporated outwards; meanwhile, the paint has the filtering function of alkali substances, and can prevent the coating from generating bubbles, generating thermal explosion and flaking to peel off, and being polluted by alkali after construction; no odor is beneficial to protecting the ecological environment; continuously releases high-concentration negative oxygen ions (6000-8000/cm 3 in a static state), and efficiently removes chemical pollutants such as formaldehyde, ammonia, benzene and the like in indoor and outdoor air.
The inorganic coating comprises the following raw materials in parts by weight:
0.17 to 0.37 portion of hydroxyethyl cellulose; 0.48 to 1.48 portions of dispersant; 4.86 to 10.46 portions of titanium dioxide; 26.32 to 32.32 parts of superfine heavy calcium carbonate; 5.22 to 10.44 portions of talcum powder; 1.24-2.42 parts of negative ion coating additive; 5.24 to 10.42 portions of odor-free emulsion; 12.24 to 20.24 portions of inorganic modified silicate; 1.44-2.64 parts of viscosity stabilizer; 0.50 to 1.50 portions of defoaming agent; 0.25-1.0 part of water-proofing agent; 16.24 to 36.24 portions of deionized water; 0.5-1.0 part of mildew preventive.
The preparation method of the inorganic coating comprises the following steps:
step one, uniformly mixing deionized water and hydroxyethyl cellulose under a stirring state; stirring the mixture under a new stirring state until the hydroxyethyl cellulose is completely dissolved to obtain hydroxyethyl cellulose liquid;
uniformly mixing hydroxyethyl cellulose liquid, a dispersing agent and a defoaming agent under a stirring state to obtain a dispersion liquid;
step three, uniformly mixing the dispersion liquid, the titanium dioxide, the superfine heavy calcium carbonate, the talcum powder and the negative ion coating additive under a stirring state, and stirring under a new stirring state to obtain negative oxygen ion liquid;
step four, uniformly mixing the negative oxygen ion liquid, the odor-free emulsion, the inorganic modified silicate, the water-resistant agent and the viscosity stabilizer under the stirring state to obtain a stable liquid;
adjusting the viscosity of the stabilizing solution by using deionized water, and filtering to obtain a semi-finished product;
and step six, adding a mildew preventive into the semi-finished product to obtain a finished product.
The specific implementation process is as follows:
the stirring speed of the stirring state in the first step is 250-350 r/min.
The stirring speed of the new stirring state in the first step is 650-850 r/min.
The stirring speed of the stirring state in the second step is 650-850 r/min.
And the stirring speed of the stirring state in the third step is 650-850 r/min, and the stirring speed of the new stirring state in the third step is 1350-1550 r/min.
The fineness of the solid particles in the negative oxygen ion liquid in the third step is less than or equal to 50 mu m.
And the stirring speed of the stirring state in the fourth step is 650-850 r/min.
And the deionized water in the fifth step accounts for 2.0 to 3.0 weight parts.
Example 1
The inorganic coating in the embodiment comprises the following raw materials in parts by weight:
0.17 part of hydroxyethyl cellulose; 0.48 part of a dispersing agent; 4.86 parts of titanium dioxide; 26.32 parts of superfine heavy calcium carbonate; 5.22 parts of talcum powder; 1.24 parts of negative ion coating additive; 5.24 parts of odor-free emulsion; 12.24 parts of inorganic modified silicate; 1.44 parts of viscosity stabilizer; 0.50 part of defoaming agent; 0.25 part of water proofing agent; 16.24 parts of deionized water; 0.5 part of mildew preventive.
When the inorganic coating is prepared, the stirring speed of the stirring state in the step one is 250 r/min. The stirring speed of the new stirring state in the first step is 650 r/min. The stirring speed in the stirring state in the second step is 650 r/min. The stirring speed of the stirring state in the third step is 650r/min, and the stirring speed of the new stirring state in the third step is 1350 r/min. And the fineness of the solid particles in the negative oxygen ion liquid in the step three is equal to 20 microns. The stirring speed in the stirring state in the fourth step is 650 r/min. And the deionized water in the fifth step accounts for 2.0 parts by weight.
Example 2
The inorganic coating in the embodiment comprises the following raw materials in parts by weight:
0.27 part of hydroxyethyl cellulose; 0.98 part of a dispersant; 7.86 parts of titanium dioxide; 29.32 parts of superfine heavy calcium carbonate; 7.72 parts of talcum powder; 1.74 parts of negative ion coating additive; 7.74 parts of odor-free emulsion; 16.24 parts of inorganic modified silicate; 2.04 parts of a viscosity stabilizer; 1.00 part of defoaming agent; 0.35 part of water proofing agent; 26.24 parts of deionized water; 1.00 part of mildew preventive.
When the inorganic coating is prepared, the stirring speed of the stirring state in the first step is 300 r/min. The stirring speed of the new stirring state in the first step is 750 r/min. The stirring speed in the stirring state in the second step is 750 r/min. The stirring speed in the stirring state in the third step is 750r/min, and the stirring speed in the new stirring state in the third step is 1450 r/min. And the fineness of the solid particles in the negative oxygen ion liquid in the step three is equal to 35 mu m. The stirring speed in the stirring state in the fourth step is 750 r/min. And the deionized water in the fifth step accounts for 2.5 parts by weight.
Example 3
The inorganic coating in the embodiment comprises the following raw materials in parts by weight:
0.37 part of hydroxyethyl cellulose; 1.48 parts of a dispersing agent; 10.46 parts of titanium dioxide; 32.32 parts of superfine heavy calcium carbonate; 10.44 parts of talcum powder; 2.42 parts of an anion paint additive; 10.42 parts of odor-free emulsion; 20.24 parts of inorganic modified silicate; 2.64 parts of a viscosity stabilizer; 1.50 parts of a defoaming agent; 1.0 part of water proofing agent; 36.24 parts of deionized water; 1.0 part of mildew preventive.
When the inorganic coating is prepared, the stirring speed of the stirring state in the step one is 350 r/min. The stirring speed of the new stirring state in the first step is 850 r/min. The stirring speed in the stirring state in the second step is 850 r/min. The stirring speed of the stirring state in the third step is 850r/min, and the stirring speed of the new stirring state in the third step is 1550 r/min. And the fineness of the solid particles in the negative oxygen ion liquid in the step three is equal to 50 microns. The stirring speed in the stirring state in the fourth step is 850 r/min. And the deionized water in the fifth step accounts for 3.0 parts by weight.
In the above examples, as the dispersant, a BYK194 type dispersant or a Digao Tego D168 type dispersant of Bike, Germany, and as the defoaming agent, a BYK028 type defoaming agent or a FOAMS TAR A10 type defoaming agent of Kenin, Germany, were used. The mildew preventive is made of mildew preventive of Trojan or Sol. The mildew preventive without formaldehyde replaces the prior preservative containing formaldehyde, so that the coating is more healthy and environment-friendly and is suitable for living.
When the dispersant of examples 1 to 3 was a BYK194 type dispersant and the defoaming agent was a BYK028 type defoaming agent, examples 1 to 3 correspond to the inorganic coating materials of examples3) All are 2000-3000 pieces/cm3And the prepared inorganic coating is odorless. The inorganic coating prepared by the existing method and the corresponding material has the negative oxygen ion air concentration (per cm)3) Only 60-150 pieces, and the prepared inorganic paint has emulsion smell. The data show that the coating of the scheme not only contains the characteristics of good adhesive force, good construction performance, washing resistance, chemical resistance meeting the standard and the like of the existing inorganic coating, but also has lower content of free formaldehyde. The content of the negative oxygen ions is obviously higher than that of the conventional inorganic coating.
Example 4
The difference from the above examples is that the natural latex liquid was added to the mildewcide in this example in an amount of 50%. After the paint is coated, a layer of film can be quickly formed on the surface of the paint for protection, so that the function of mildew prevention and protection is achieved, and physical covering protection is formed on the surface of the paint.
The invention uses the odorless emulsion, the emulsion is self-environment-friendly, the lowest film forming temperature is achieved, the film forming auxiliary agent is not needed, and compared with the common film forming auxiliary agent, the dodecanol ester is an organic volatile matter, the invention does not use the film forming auxiliary agent, reduces the pollution to the air, and is more environment-friendly.
In examples 1 to 4, the odor-free emulsion is obtained by modifying a styrene-acrylic emulsion with an organosilicon monomer, which is referred to as a silicone-styrene-acrylic emulsion for short, and has good oxidation resistance and decomposition resistance. The organic silicon has large molecular volume, small surface tension, low cohesive energy density, good anti-contamination property, air permeability and hydrophobicity. The emulsifier used in the odorless emulsion has good alkali resistance, large particle size, wide distribution and good compatibility with silicate (the silicate is strong alkali).
In examples 1 to 4, the silicate used was modified potassium silicate, and specifically, potassium lithium silicate was used. The water-soluble silicate is commonly called water glass, and includes lithium, sodium, potassium, ammonium water glass and the like. The potassium water glass has better caking property and film forming property than sodium water glass, and has lower price than lithium water glass and ammonium water glass, so the commonly used potassium water glass is used as a film forming substance of the inorganic coating. The conventional potash water glass forms a coating film with poor water resistance, and the improved potassium silicate is used, namely lithium potassium silicate.
In examples 1 to 4, the viscosity stabilizer was a quaternary ammonium salt product, and this positively charged macromolecule covered the negatively charged chain end of the silicate chain, which acted as a protecting group, and sterically blocked the reaction of the Si — O bond, resulting in good stability of the product. Without the addition of such viscosity stabilizers, the silicate reacts with other components of the system over time, which can lead to gelling and hardening.
In the embodiments 1-4, the core material of the anion paint additive is anion, and is formed by processing, refining, compounding and activating a plurality of gem jade spar by a plurality of high-tech means according to the prior art; the production process adopts various advanced process technologies such as sol centrifugal crushing ion exchange doping and the like, so that the negative ion has the functions of purifying air water, resisting electromagnetic radiation and the like, and has the effects of resisting bacteria, inhibiting bacteria, protecting health and the like.
The positive and negative charge centers of each unit body of the negative ion coating additive can not coincide, so that the positive and negative electrodes are formed at the two ends, and a permanent charged body permanent electrode is formed, wherein the positive and negative charges have no symmetric center, namely, dipole moment. When the external temperature or the external pressure changes slightly, the ion distance and the bond angle change to induce dipole moment, so that part of the free charge layer bound on the surface of the unit body is released, the unit body is in an electrified state or forms current in a closed loop, and an electric field and micro-current are formed around the free charge layer.
In examples 1 to 4, the water-resistant agent is polyether-modified organosilicon, and can react with the emulsion and potassium silicate to form a firm chemical bond, thereby greatly improving the wrapping capability of the emulsion on pigments and fillers and improving the physical mechanical strength of a paint film, and further remarkably improving the water resistance, scratch resistance, weather resistance, scrub resistance, wear resistance and the like of the coating. Reacts with the substrate with inorganic surface to form firm SI-o-Si bond, thereby greatly improving the adhesion of the coating to the substrate.
Test 1: burning test
1 kg of each of the inorganic coatings prepared in examples 1 to 4 and a common coating (comparative example 1) sold on the market at present was uniformly coated on a rectangular wood block 50 cm in length, 10 cm in width and 5 cm in thickness, and after the coating was completed, the coating was dried over two days, and the wood block 1, the wood block 2, the wood block 3, the wood block 4 and the wood block 5 formed in accordance with examples 1 to 4 and comparative example 1 were simultaneously ignited in the same room; meanwhile, the wood blocks 1-5 are classified according to the test method in GB/T14402 and the combustion grade in GB/T8624, and the following test results are obtained:
TABLE 1
As can be seen from Table 1, the coatings prepared in examples 1 to 4 are incombustible, have a combustion rating meeting A2 specified in GB/T8624, belong to incombustible materials, while the conventional coating in comparative example 1 is B1, and is a nonflammable material, which fully illustrates that the coating prepared by the present invention has a better incombustible effect than the conventional coating because the main film-forming substance is an inorganic material such as silicate, and can improve the safety of the whole product.
The foregoing is merely an example of the present invention, and common general knowledge in the field of known specific structures and characteristics is not described herein in any greater extent than that known in the art at the filing date or prior to the priority date of the application, so that those skilled in the art can now appreciate that all of the above-described techniques in this field and have the ability to apply routine experimentation before this date can be combined with one or more of the present teachings to complete and implement the present invention, and that certain typical known structures or known methods do not pose any impediments to the implementation of the present invention by those skilled in the art. It should be noted that, for those skilled in the art, without departing from the structure of the present invention, several changes and modifications can be made, which should also be regarded as the protection scope of the present invention, and these will not affect the effect of the implementation of the present invention and the practicability of the patent. The scope of the claims of the present application shall be determined by the contents of the claims, and the description of the embodiments and the like in the specification shall be used to explain the contents of the claims.
Claims (10)
1. An inorganic coating, characterized in that: the composite material comprises the following raw materials in parts by weight:
0.17 to 0.37 portion of hydroxyethyl cellulose; 0.48 to 1.48 portions of dispersant; 4.86 to 10.46 portions of titanium dioxide; 26.32 to 32.32 parts of superfine heavy calcium carbonate; 5.22 to 10.44 portions of talcum powder; 1.24-2.42 parts of negative ion coating additive; 5.24 to 10.42 portions of odor-free emulsion; 12.24 to 20.24 portions of inorganic modified silicate; 1.44-2.64 parts of viscosity stabilizer; 0.50 to 1.50 portions of defoaming agent; 0.25-1.0 part of water-proofing agent; 16.24 to 36.24 portions of deionized water; 0.5-1.0 part of mildew preventive.
2. The inorganic coating material according to claim 1, characterized in that: the composite material comprises the following raw materials in parts by weight:
0.27 part of hydroxyethyl cellulose; 0.98 part of a dispersant; 7.86 parts of titanium dioxide; 29.32 parts of superfine heavy calcium carbonate; 7.72 parts of talcum powder; 1.74 parts of negative ion coating additive; 7.74 parts of odor-free emulsion; 16.24 parts of inorganic modified silicate; 2.04 parts of a viscosity stabilizer; 1.00 part of defoaming agent; 0.35 part of water proofing agent; 26.24 parts of deionized water; 1.00 part of mildew preventive.
3. The preparation method of the inorganic coating is characterized by comprising the following steps:
step one, uniformly mixing deionized water and hydroxyethyl cellulose under a stirring state; stirring the mixture under a new stirring state until the hydroxyethyl cellulose is completely dissolved to obtain hydroxyethyl cellulose liquid;
uniformly mixing hydroxyethyl cellulose liquid, a dispersing agent and a defoaming agent under a stirring state to obtain a dispersion liquid;
step three, uniformly mixing the dispersion liquid, the titanium dioxide, the superfine heavy calcium carbonate, the talcum powder and the negative ion coating additive under a stirring state, and stirring under a new stirring state to obtain negative oxygen ion liquid;
step four, uniformly mixing the negative oxygen ion liquid, the odor-free emulsion, the inorganic modified silicate, the water-resistant agent and the viscosity stabilizer under the stirring state to obtain a stable liquid;
adjusting the viscosity of the stabilizing solution by using deionized water, and filtering to obtain a semi-finished product;
and step six, adding a mildew preventive into the semi-finished product to obtain a finished product.
4. The method for producing an inorganic paint according to claim 3, characterized in that: the stirring speed of the stirring state in the first step is 250-350 r/min.
5. The method for producing an inorganic paint according to claim 4, characterized in that: the stirring speed of the new stirring state in the first step is 650-850 r/min.
6. The method for producing an inorganic paint according to claim 5, characterized in that: and the stirring speed of the stirring state in the second step is 650-850 r/min.
7. The method for producing an inorganic paint according to claim 6, characterized in that: and the stirring speed of the stirring state in the third step is 650-850 r/min, and the stirring speed of the new stirring state in the third step is 1350-1550 r/min.
8. The method for producing an inorganic paint according to claim 6, characterized in that: the fineness of solid particles in the negative oxygen ion liquid in the third step is less than or equal to 50 microns.
9. The method for producing an inorganic paint according to claim 3, characterized in that: the inorganic modified silicate is lithium potassium silicate.
10. The method for producing an inorganic paint according to claim 3, characterized in that: the viscosity stabilizer is quaternary ammonium salt.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911396778.8A CN111073359A (en) | 2019-12-30 | 2019-12-30 | Inorganic coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911396778.8A CN111073359A (en) | 2019-12-30 | 2019-12-30 | Inorganic coating and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534133A (en) * | 2020-06-24 | 2020-08-14 | 思贝克汀(厦门)新型建材有限公司 | Negative oxygen ion inorganic coating and preparation method thereof |
| CN112662212A (en) * | 2020-12-17 | 2021-04-16 | 广东现代涂料科技有限公司 | Inorganic negative ion environment-friendly wall paint and preparation method thereof |
| CN112680098A (en) * | 2020-12-22 | 2021-04-20 | 广东顺德派齐新材料有限公司 | Antifreezing water-based inorganic coating and preparation method thereof |
| CN113549354A (en) * | 2021-08-06 | 2021-10-26 | 中节能(唐山)环保装备有限公司 | Water-based inorganic coating and preparation method thereof |
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| JPH05311091A (en) * | 1992-05-13 | 1993-11-22 | T S B:Kk | Water-resistant inorganic binder |
| CN108047779A (en) * | 2018-01-05 | 2018-05-18 | 吕跃文 | aqueous forest negative oxygen ion inorganic coating and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH05311091A (en) * | 1992-05-13 | 1993-11-22 | T S B:Kk | Water-resistant inorganic binder |
| CN108047779A (en) * | 2018-01-05 | 2018-05-18 | 吕跃文 | aqueous forest negative oxygen ion inorganic coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111534133A (en) * | 2020-06-24 | 2020-08-14 | 思贝克汀(厦门)新型建材有限公司 | Negative oxygen ion inorganic coating and preparation method thereof |
| CN112662212A (en) * | 2020-12-17 | 2021-04-16 | 广东现代涂料科技有限公司 | Inorganic negative ion environment-friendly wall paint and preparation method thereof |
| CN112680098A (en) * | 2020-12-22 | 2021-04-20 | 广东顺德派齐新材料有限公司 | Antifreezing water-based inorganic coating and preparation method thereof |
| CN113549354A (en) * | 2021-08-06 | 2021-10-26 | 中节能(唐山)环保装备有限公司 | Water-based inorganic coating and preparation method thereof |
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