CN105331231B - A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method - Google Patents

A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method Download PDF

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CN105331231B
CN105331231B CN201510749300.4A CN201510749300A CN105331231B CN 105331231 B CN105331231 B CN 105331231B CN 201510749300 A CN201510749300 A CN 201510749300A CN 105331231 B CN105331231 B CN 105331231B
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parts
energy
coating
type composite
composite dope
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CN105331231A (en
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张启伟
邢小健
曹勇兵
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Nantong Lejia Paint Co Ltd
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Nantong Lejia Paint Co Ltd
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Abstract

The true stone-type composite dope of a kind of environmental protection and energy saving disclosed by the invention, is made of finishing coating materials, lacquer middle coating intermediate and subbing, and subbing includes styrene-acrylic emulsion, water, titanium dioxide, special type filler, auxiliary agent C;Lacquer middle coating intermediate includes synthetic resin emulsion, deionized water, functional material A, self-control function smalt, auxiliary agent A;Finishing coating materials include deionized water, synthetic resin emulsion, functional material B, auxiliary agent B.Nano-functional material is applied in lacquer middle coating intermediate, finishing coating materials by composite dope layer of the present invention, creatively the reflective insulation effectiveness of nano-functional material, lacquer middle coating intermediate lithotome decorative effect are organically combined, and the insulating layer for dexterously applying the natural coating layer thickness of lacquer middle coating intermediate to be formed constitutes energy-saving ring fidelity stone-type composite dope layer, it can be achieved energy saving 40~50%, 6~8 DEG C of indoor temperature is reduced, there is significant heat insulation and preservation effect.The invention also discloses the preparation methods and construction method of the true stone-type composite dope of the environmental protection and energy saving.

Description

A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method
Technical field
The invention belongs to decorating building decorative materials technical fields, and in particular to a kind of energy-saving ring fidelity stone-type combination painting Material, and further relate to preparation method and construction method.
Background technology
As is known in the industry, it is directly sticked on the exterior wall of building or cladding such as marble, granite or other classes As material can significantly play decorative effect and certain heat insulation and preservation effect.And with dry hanging on skin Dry-hanging insulation board and so that energy-saving effect possessed by building is come for cladding marble excellent, can be by simultaneously to this The Chinese patent CN101725311A being not limited to(Pearlite fiber composite fire-proof heat insulation board)、CN2352333Y(Complex heat-preservation every Hot plate)、CN2825784Y(Thermal insulation plate for external wall)、CN20138361Y(Exterior wall external insulation decorative flame-retardant thermal insulation board)、 CN102219455A(Inorganic lightweight aggregate thermal insulation sheet material and preparation method thereof)And CN102417327A(External wall is integrally solid Change inorganic heat insulation plate and preparation method thereof)Etc. confirmation, but cladding thermal insulation board is with obvious effects to decorating building inferior Color is in marble.
Whether there is the logical disadvantage for being not limited to be exemplified below in dry-hanging insulation board or marble:First, from great, deposit In security risk;Second is that complicated construction technique, long in time limit;Third, price is high, it is unfavorable for embodying economy principle.In view of this, energy Enough exterior coatings for making up these drawbacks comprehensively gradually have been favored by people, and in published Chinese patent literature not It is weary to be seen in, slightly to enumerate such as CN11152100C(Heat-insulation coating for house), the patent formula is easy for construction, cheap and anti- Aging effect is its strong point well, but due to having used asbestos wool in formula, thus feature of environmental protection safety is affected, and match Acid polyethylene in side(PVA)Water resistance is poor, although being modified with sodium metasilicate, but still is not enough to the water-fast effect that the acquisition phase takes; CN1205279C(Energy saving heat preserving paint)With at low cost and easily excellent place of constructing, but due to as heat-insulated Primary raw material is waste polystyrene foam plastic and expanded perlite, and since the density of waste polystyrene foam plastic can not Ensure, especially when particle diameter is less than 3 ㎜, heat insulation tends to lose, simultaneously because the uncoated place of expanded perlite Reason is easy water suction and its heat insulation is caused to be short of, therefore one side heat insulation and preservation effect is low, and another aspect compression strength is fragile; CN1124320C(A kind of water-repellent paint), the patent formula is famous to become strong point with the anti-aging and cracking resistance stood out from one's fellows, but does not have Heat insulation and preservation effect;CN100344713C(Bicomponent cement base polystyrene foamed particle heat insulation coating)And CN100344714C (Bicomponent gypsum polystyrene foamed particle heat insulation paint)Although respectively there is unique strong point, do not have simulation quality(Emulation Property i.e. refer to imitate stone material)It is its shortcoming.Also, Authorization Notice No. CN1124320C(A kind of water-repellent paint)And CN1152100C(House Thermal insulation coatings)Equally exist the shortcoming.Especially, however it is not limited to which skin coating is equal disclosed in these documents enumerated Without simulated effect, that is, do not have it is muddy as day at imitative stone effect, to decorate effect by shadow to the decoration of building It rings, and the decoration decoration effect of building largely plays the multiple action for promoting image and promoting sight etc..
Further, performance is decorated to improve, starts or be widely used to decorate texture with lithotome currently on the market Aqueous colorful stone-like coating and lacquer or texture coating, and have more and more fiery gesture, while also occurring corresponding special Profit, slightly with enumerate as:Application for a patent for invention publication No. CN102277045A recommendation have " a kind of Waterborne stone-like multicolor coating and Preparation method ", the patent application scheme have that the so-called appearance of coat level in the 0034th column of specification is abundant, three-dimensional sense is strong and Strong point with lithotome decorative pattern, however, since coalescents have used the alcohol ester and butyl glycol ether that weight ratio is 1: 1 Aqueous solution, therefore lose safety and the feature of environmental protection, because butyl glycol ether is to human health damage and suck can be fatal, in addition, Show that reproductive system can be damaged in animal experiment, so to coating of the production containing the composition and using the coating must it is careful again It is careful;Authorization Notice No. CN101338149B(Water-soluble colorful coating and preparation method thereof), (one kind has ZL201010533680.5 Composite dope used in texture coating layer) although overcoming disadvantages mentioned above, it is still it without heat preservation energy-saving effect and lacks Regret.
In recent years, it was promoted with the acceleration of industrialization, urbanization and modernization, the annual town and country newly constructed house in China is built Nearly 2,000,000,000 square metres of area is built, wherein 80% or more builds for high energy consumption, nearly 40,000,000,000 square metres of existing building, 95% or more all Belong to high energy consumption building, energy utilization rate is only 33%, falls behind developed country 20 years.Building energy consumption accounts for the 30% of China's total energy consumption, Building energy conservation will be as the primary aspect of the social energy use efficiency of raising.For this purpose, country pays high attention to simultaneously building energy-saving And a series of relevant regulations about building energy-saving are also put into effect.Energy saving due to building is only difficult to by materials for wall itself Reach desired index such as energy saving 65% or more, thus the skin coating with good energy-saving effect as supplement and It has been to be concerned by more and more people and thinks highly of, wherein integrate energy conservation and environmental protection and help to promote decorating building effect Coating is increasingly in one's favour.
In summary prior art, for developing with environmental protection and energy saving and exactly liking with good simulated effect natural The true stone-type composite dope of stone effect has positive realistic meaning.
Invention content
The primary purpose of the present invention is that offer one kind is suitable for, skin is ornamental to be helped to embody muddy such as day At marble decorative effect, be conducive to show good heat insulating reflecting effect and use the environmental protection for promoting building energy-saving effect Energy saving true stone-type composite dope.Nano-functional material is applied to lacquer middle coating intermediate, finishing coat by composite dope layer of the present invention In coating, the reflective insulation effectiveness of nano-functional material, lacquer middle coating intermediate lithotome decorative effect are subjected to organic knot Altogether, and the insulating layer of the natural coating layer thickness formation of application lacquer middle coating intermediate constitutes the true stone-type combination of environmental protection and energy saving Dope layer can reduce by 6~8 DEG C of indoor temperature, realize energy saving 40~50%, have significant heat insulation and preservation effect;Simultaneously, because The photoextinction of nano-functional material can form natural dumb light film, advantageously reduce difficulty of construction, improve surface simulating degree And surface decoration effect.The invention is suitable for villa, advanced commercial and residential building, Administration Building, shop etc. and both requires naturally Stone decoration effect and the place decoration for requiring energy-saving effect.
Another object of the present invention is to provide the preparation methods of above-mentioned energy-saving ring fidelity stone-type composite dope.
Another object of the present invention is to provide the construction method of above-mentioned energy-saving ring fidelity stone-type composite dope.
Primary and foremost purpose to realize the present invention, technical solution provided by the invention are:
A kind of true stone-type composite dope of environmental protection and energy saving, is made of finishing coating materials, lacquer middle coating intermediate and subbing, Wherein,
The subbing includes following raw materials in part by weight:28~34 parts of synthetic resin emulsion, 26.3~28.1 parts of water, 4.7~4.9 parts of 5~10 parts of titanium dioxide, 25~35 parts of special type filler and auxiliary agent C;
The lacquer middle coating intermediate is made of following raw materials in part by weight:10.0~25.0 parts of synthetic resin emulsion is gone 2.5~3.4 parts of 0.5~11.0 part of ionized water, 3.0~10.0 parts of functional material A, 60.0~78 parts of smalt and auxiliary agent A;It is described Smalt be the self-control function white sand that can cross 10 mesh to 200 mesh sieves at different levels respectively, assorted one kind made by oneself in function color sand or The two or more combinations that required different proportion is prepared by practical model;The function white sand, function color sand are will be inorganic viscous The uniformly mixing according to a certain percentage such as ramming material, one or more kinds of cold pigment, using spray pyrolysis technologies, to required grain The natural white sand of diameter is coated, and by calculating the thermodynamics analysis methods of enthalpy produced in chemical reaction △ H and free energy △ G, is determined Design of material and technology controlling and process, prepare that size uniform, cladding is complete, film thickness is consistent, have excellent sunlight reflection function and excellent Different covering power function color sand, and applied in Project Product, the cold pigment includes the companies such as Dupont, Australia Mei Lilian Golden red type titanium dioxide, the companies such as German Hai Bo chemical companies and U.S.'s Xue Te chemical industry provide the anthracene with excellent reflection function Quinone ketone is red, dark green, aoxidizes the various cold pigment such as titan yellow, blue or green blue, carbon black.
The finishing coating materials are by including that following raw materials in part by weight is constituted:18.8~48.05 parts of deionized water, synthesis tree 5.5~6.2 parts of 40.0~60.0 parts of fat liquor, 3.0~15.0 parts of functional material B and auxiliary agent B.
In the specific embodiment of the present invention, the lacquer middle coating intermediate is phenylpropyl alcohol breast with synthetic resin emulsion One kind in liquid, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion, elastic emulsion or arbitrary two kinds of mixing.
In the specific embodiment of the present invention, the finishing coating materials are pure-acrylic emulsion, silicon with synthetic resin emulsion Acrylic emulsion or fluorine carbon emulsion;
In the specific embodiment of the present invention, the subbing is styrene-acrylic emulsion, pure third breast with synthetic resin emulsion Liquid or silicone acrylic emulsion, comprehensive performance and economy consideration, preferably styrene-acrylic emulsion.
The styrene-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion are respectively in molecule containing styrene monomer, silicon oxygen bond, carbon The acrylic emulsion of fluorine bond grafting.
The pure-acrylic emulsion is the acrylic emulsion of 100% acrylic monomers synthesis.
The elastic emulsion is acrylic emulsion of the film with elongation percentage after film forming.
The styrene-acrylic emulsion can assign excellent water-fast, the alkaline-resisting, stain resistant of film and water-whitening resistance, such as Ahmedabad richness company RS992, Shanghai sunrise company TL668;
The pure-acrylic emulsion, silicone acrylic emulsion also have excellent weather resistance and lasting colour retention, such as Ahmedabad richness company 706T, 996AD, AD15, AD51 etc. of Japanese Showa Corporation.
The elastic emulsion such as 752D of Ahmedabad richness company, Shanghai sunrise company 4369 etc..
In the specific embodiment of the present invention, the synthetic resin emulsion of the lacquer middle coating intermediate is by total emulsion weight The elastic emulsion 752D of amount 10~20% and the pure-acrylic emulsion 706T of total emulsion weight basis 80~90% are mixed.
In another specific embodiment of the present invention, the auxiliary agent A by matching in parts by weight including following Raw material is constituted:0~0.8 part of dispersant, 0~0.5 part of antifoaming agent, 0.1~0.3 part of preservative, resists 0.1~0.3 part of wetting agent Freeze 0.3~1.2 part of 0~1.0 part of agent, 0.1~1.0 part of coalescents and thickener.
The auxiliary agent B including the following raw material matched in parts by weight by constituting:0.3~0.8 part of dispersant, wetting agent 0.1~0.2 part, 0~0.5 part of antifoaming agent, 0.1~0.3 part of preservative, 0.5~2.5 part of antifreeze, coalescents 1.0~4.0 Part, 0.1~1.5 part of thickener.
The auxiliary agent C including following raw material by weight by constituting:0.3~0.5 part of dispersant, wetting agent 0.1~ 0.2 part, 0.2~0.4 part of antifoaming agent, 0.1~0.2 part of preservative, 1.0~1.5 parts of antifreeze, 1.5~2.0 parts of coalescents, 0.7~1.0 part of thickener.
Subbing special type filler includes the mesh silica flour of 100 mesh~200, the hard provided, rough surface, It can assign film excellent ply adhesion.
The dispersant is polyacrylic acid sodium salt, ammonium polyacrylate salt, such as SN5040, SN5027 of Japan Nuo Puke, U.S. The pleased of state's DOW Chemical, 2500D.
The wetting agent selects the CF-11 of Germany BASF, the WT of Germany BASF, US Air gas chemistry painting industry wetting agent DCO1 or US Air gas chemistry painting industry wetting agent 1340.
The thickener selects the sub- RH- across 250HBR, PLUS330 of dragon, the HS30000YP of Clariant, rising sun electrification 420 obtain the mixing of one or more of TT-935 of Dow Chemical.
The preservative selects the LX150 of Shu Mei companies of Germany K40, Shu Mei companies of Germany A28S, Dow Chemical Or the R640 of Dow Chemical.
The antifoaming agent selects the Byk024 of A10, SN8034 or Bi Ke company of Henkel KGaA.
The antifreeze selects ethylene glycol or propylene glycol.
The coalescents select the alcohol ester 12 of Yi Shiman.
In another specific embodiment of the present invention, the functional material A is by including that following parts by weight are matched The raw material of ratio is constituted:Zinc oxide:Barium sulfate:Talcum powder=1:9~15:25~35, especially with zinc oxide:Barium sulfate:Talcum powder=1: 12:30 are preferred;The functional material B is made of the raw material matched including following parts by weight:Hollow ceramic microballon:It is impermeable Bright polymer=1~3:1, especially with hollow ceramic microballon:Opacifying polymers=2:1 is preferred.
The Opacifying polymers include the Unihub-E of Dow Chemical, the Snowtex25 of Ying Zhou foreign firms of South Korea, Snowtex30 or Snowtex45.
Realizing the technical solution of another goal of the invention of the present invention is:A kind of preparation side of the true stone-type composite dope of environmental protection and energy saving Method includes the preparation method of subbing, lacquer middle coating intermediate, finishing coating materials, wherein
The preparation method of the subbing includes the following steps:
26.3~28.1 parts of deionized water is added in coating material production kettle, starts blender, is homogeneously added into formula successively Preservative, dispersant, antifoaming agent, antifreeze, coalescents, the cellulose of amount, 1000~1350 revs/min of high speed dispersions 10 ~15min is slow added into 25~35 parts of 5~10 parts of titanium dioxide and special type filler, and controls the mixing speed 500 when feeding intake ~600 revs/min, and 1000~1350 revs/min of high speed dispersion speed after feeding intake is controlled, high speed dispersion 35~ 45min adds the synthetic resin emulsion of 28~34 parts by weight, thickener is added, reconciles, examines, packaging;
The preparation method of the lacquer middle coating intermediate includes the following steps:
Step 1) base-material produces:0.5~11.0 part of deionized water is added in coating material production kettle, starts blender, 2.5~3.4 parts of auxiliary agent A, 3.0~10.0 parts of functional material A are sequentially added under 500~600 revs/min of mixing speed, Charging finishes, and with 1200~1500 revs/min of speed high speed dispersion 20~40 minutes, adds the conjunction weighed in parts by weight At 10.0~25.0 parts of resin emulsion, stirring is continued 10~15 minutes with 600~1000 revs/min of speed, thickener is added, It stirs evenly, that is, obtains required base-material;
Step 2) lacquer middle coating intermediate produces:
60.0~78 parts of self-control function smalt is added in the base-material of above-mentioned preparation, stirs evenly.
In the present invention and then a specific embodiment, step 1)When feeding intake mixing speed control 500~600 turns/ Minute, speed is too slow, and mixing effect is poor;Speed is too fast, will produce powder and flies upward, causes material waste and environmental pollution;At a high speed Rate of dispersion is controlled at 1200~1500 revs/min, is dispersed to 15 μm hereinafter, jitter time 20~40 minutes.To control dispersion 1350~1450 revs/min of speed, jitter time are preferred for 30 minutes.
In the present invention and then a specific embodiment, step 2)600~1000 revs/min of mixing speed, fed intake Bi Jixu is stirred 10~15 minutes.
The preparation method of the finishing coating materials includes the following steps:
Step 1) function slurry produces:
18.8~48.05 parts of deionized water is added in coating material production kettle, starts blender, governing speed 500~600 Rev/min, 5.55~6.20 parts of auxiliary agent B is added, is stirring evenly and then adding into 3.0~15.0 parts of functional material B, is ground using frequency vibration Function slurry of the fineness control within 15 μm is made in mill method;
Step 2) finishing coating materials produce:
40.0~60.0 parts of synthetic resin emulsion is added in function slurry obtained above, 500~600 revs/min Speed stirs evenly, and thickener is added, stirs evenly, that is, the finishing coating materials with environmental protection and energy saving effect is made.
A kind of construction method of the true stone-type composite dope of environmental protection of the present invention is as follows:
1. basal plane is handled:Levelling and consolidation process, drying are carried out to basal plane, obtain firm flat surfaces;
2. the subbing is stirred evenly, the water for being optionally added into 0~5% adjusts viscosity to 75~80KU, applies In basal plane, dry 4~6h;
3. standing 10~15min after the true stone shape middle coating intermediate is stirred, routinely technique is constructed, dry 24 ~48h or more;
4, with the finishing coating materials, routinely technique carries out overlay treatment
The advantageous effect that the present invention generates:
Nano-functional material is applied in lacquer middle coating intermediate, finishing coating materials by composite dope layer of the present invention, creates Property the reflective insulation effectiveness of nano-functional material, lacquer middle coating intermediate lithotome decorative effect organically combine Come, and the insulating layer for dexterously applying the natural coating layer thickness of lacquer middle coating intermediate to be formed constitutes the true stone-type group of environmental protection and energy saving Dope layer is closed, coating content of volatile organic compound, free formaldehyde content are respectively within 10 g/L, 8 mg/kg, extremely ring It protects, it can be achieved that energy saving 40~50%, reduces by 6~8 DEG C of indoor temperature, there is significant heat insulation and preservation effect;Simultaneously, because nanometer The photoextinction of functional material can form natural dumb light film, advantageously reduce difficulty of construction, improve surface simulating degree and table Face decorative effect.
Description of the drawings
It is further illustrated the present invention below in conjunction with the drawings and specific embodiments.
Fig. 1 is the coating process general flow chart of the present invention.
Figure label:1 is finishing coating materials, and 2 be lacquer middle coating intermediate, and 3 be subbing.
Specific implementation mode
In order to make the technical means, creative features, achievement of purpose and effectiveness of the invention easy to understand, with reference to tool Body embodiment, the present invention is further explained.
Embodiment 1
Finishing coating materials(By weight)
40 parts of pure-acrylic emulsion, 48.05 parts of water, functional material B:6 parts, auxiliary agent B:5.95 part.
Functional material B is the mixture of hollow glass microbead and Opacifying polymers, weight ratio 2.5:1.
Auxiliary agent B includes dispersant, wetting agent, thickener, preservative, antifoaming agent, antifreeze and coalescents.
Dispersant is ammonium polyacrylate salt, such as the pleased of Dow Chemical, and dosage is the 0.5wt% of coating total weight.
It is the 0.15wt% of finishing coating materials total weight that wetting agent, which selects the WT of Germany BASF, dosage,.
It is the 1.5wt% of finishing coating materials total weight that thickener, which selects the RH-420 of rising sun electrification, dosage,.
It is the 0.3wt% of finishing coating materials total weight that preservative, which selects Shu Mei companies of Germany K40, dosage,.
It is the 2.5wt% of finishing coating materials total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 1.0wt% of finishing coating materials total weight that coalescents, which select alcohol ester 12, dosage,.
Preparation method:
Step 1) function slurry produces:
48.05 parts of deionized water is added in coating material production kettle, starts blender, 500 revs/min of governing speed, successively It is homogeneously added into dispersant pleased:0.5w parts, wetting agent WT:0.15 part, preservative K40:0.3 part, antifreeze propylene glycol: 2.5 parts, coalescents alcohol ester 12:1.0 parts, it is stirring evenly and then adding into 6.0 parts of functional material B, it, will using frequency vibration polishing Fineness controls within 15 μm, and required mesh number function slurry is made.
Step 2) finishing coating materials produce:
40.0 parts of pure-acrylic emulsion is added in function slurry obtained above, thickening is added in 600 revs/min of governing speed Agent RH-420:It 1.5 parts, stirs evenly, that is, the finishing coating materials with environmental protection and energy saving effect is made.
Lacquer middle coating intermediate(By weight)
21.25 parts of styrene-acrylic emulsion, 2.6 parts of water, self-control function smalt(10#-200#)64.5 parts, functional material A 8.25 Part, 3.4 parts of auxiliary agent A.
Auxiliary agent A includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polyacrylic acid sodium salt, as Japan Nuo Puke 5040, dosage be lacquer middle coating intermediate total weight 0.7wt%;
It is the 0.2wt% of lacquer middle coating intermediate total weight that wetting agent, which selects the WT of Germany BASF, dosage,.
It is the 0.6wt% of lacquer middle coating intermediate total weight that thickener, which selects the HS30000YP of Clariant, dosage,.
It is the 0.25wt% of lacquer middle coating intermediate total weight that preservative, which selects Shu Mei companies of Germany A28S, dosage,.
It is lacquer middle coating intermediate total weight that antifoaming agent, which selects the B556 of Japanese rising sun electrification Co., Ltd., dosage, 0.4wt%。
It is the 0.5wt% of lacquer middle coating intermediate total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 0.75wt% of lacquer middle coating intermediate total weight that coalescents, which select alcohol ester 12, dosage,.
Make the sand grains that function smalt is 10#-200# by oneself.
Functional material A is that the raw material mixing matched by following parts by weight is constituted:Zinc oxide:Barium sulfate:Talcum powder=1:9: 35。
Preparation method:
Step 1) base-material produces:
2.6 parts of deionized water is added in coating material production kettle, starts blender, governing speed is to 500 revs/min, successively Dispersant 5040 is added:0.7 part, wetting agent WT:0.2 part, thickener HS30000YP:0.6w parts,
Preservative A28S:0.25 part, antifoaming agent B556:0.4 part, antifreeze ethylene glycol:0.5 part, coalescents alcohol ester 12:0.75 part, 8.25 parts of functional material A, after feeding intake, rate of dispersion is improved to 1200 revs/min, is disperseed 40 minutes, To 15 μm of fineness, 21.25 parts of the styrene-acrylic emulsion weighed in parts by weight is added, continues stirring to get to required base-material.
Step 2) lacquer middle coating intermediate produces:
Mixing speed is adjusted to 600 revs/min, self-control function smalt is slowly added in the base-material of above-mentioned preparation(10#- 200#)64.5 parts, rotating speed is improved to 800 revs/min, stirs evenly, pays attention to control time within 15 minutes.
Subbing (by weight):
34 parts of styrene-acrylic emulsion 420V, 26.3 parts of water, 10 parts of titanium dioxide, 100 mesh~25 parts of 200 mesh silica flour, 4.7 parts of auxiliary agent C.
Auxiliary agent C includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polyacrylic acid sodium salt, such as the 5040 of Japan Nuo Puke, and dosage is the 0.3wt% of subbing total weight.
It is the 0.1wt% of subbing total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
Thickener selects the combination of the HS30000YP of Clariant and the TT-935 of Dow Chemical, and dosage is respectively bottom The 0.3wt% and 0.4wt% of coating total weight.
It is the 0.20wt% of subbing total weight that preservative, which selects Shu Mei companies of Germany A28S, dosage,.
It is the 0.4wt% of subbing total weight that antifoaming agent, which selects the B556 of Japanese rising sun electrification Co., Ltd., dosage,.
It is the 1.0wt% of subbing total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 2.0wt% of subbing total weight that coalescents, which select alcohol ester 12, dosage,.
The preparation method of the subbing includes the following steps:
26.3 parts of deionized water is added in coating material production kettle, starts blender, is homogeneously added into dispersant successively 5040:0.3 part, wetting agent CF-11:0.1 part, 0.3 part of thickener HS30000YP, preservative A28S:0.20 part, antifoaming agent B556:0.4 part, antifreeze ethylene glycol:1.0 parts, coalescents alcohol ester 12:2.0 parts, 1000 revs/min of high speed dispersions 15min is slow added into 10 parts of titanium dioxide and 100 mesh~25 parts of 200 mesh silica flour, and controls mixing speed when feeding intake 500~600 revs/min, and 1200 revs/min of high speed dispersion speed after feeding intake is controlled, high speed dispersion 45min adds Enter the styrene-acrylic emulsion of 34 parts by weight, add TT-935:It 0.4 part, reconciles, examine, packaging.
Embodiment 2
Finishing coating materials(By weight)
45 parts of silicone acrylic emulsion, 46.55 parts of water, functional material B:3 parts, auxiliary agent B:5.55 part.Wherein:
Functional material B is the mixture of hollow glass microbead and Opacifying polymers, weight ratio 1.5:1.
Auxiliary agent B includes dispersant, wetting agent, thickener, preservative, antifoaming agent, antifreeze and coalescents.
Dispersant is ammonium polyacrylate salt, and such as the 2500D of Dow Chemical, dosage is finishing coating materials total weight 0.3wt%。
It is finishing coating materials total weight that wetting agent, which selects US Air gas chemistry painting industry wetting agent DCO1, dosage, 0.10wt%。
It is the 1.15wt% of finishing coating materials total weight that thickener, which selects the TT-935 of Dow Chemical, dosage,.
It is the 0.25wt% of finishing coating materials total weight that preservative, which selects Shu Mei companies of Germany A28S, dosage,.
The Byk024 of Bi Ke companies, dosage are the 0.15wt% of finishing coating materials total weight.
It is the 2.0wt% of finishing coating materials total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 1.6wt% of finishing coating materials total weight that coalescents, which select alcohol ester 12, dosage,.
Preparation method:
Step 1) function slurry produces:
46.55 parts of deionized water is added in coating material production kettle, starts blender, 550 revs/min of governing speed, successively It is homogeneously added into dispersant 2500D:0.3 part, wetting agent DCO1:0.10 part, preservative A28S:0.25, antifoaming agent Byk024:0.15 part, antifreeze ethylene glycol:2.0 parts, coalescents alcohol ester 12:1.6 parts, it is stirring evenly and then adding into function material Expect 3.0 parts of B, using frequency vibration polishing, by fineness control within 15 μm, required mesh number function slurry is made.
Step 2) finishing coating materials produce:
45.0 parts of silicone acrylic emulsion lotion is added in function slurry obtained above, 600 revs/min of governing speed is added Thickener TT-935:It 1.15 parts, stirs evenly, that is, the finishing coating materials with environmental protection and energy saving effect is made.
True stone shape middle coating intermediate(By weight)
25 parts of pure-acrylic emulsion, 1.9 parts of water, self-control function smalt(10#-200#)60.0 parts, 10.0 parts of functional material A, help 3.1 parts of agent A.
Auxiliary agent A includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polypropylene acid sodium-salt, and such as the pleased of Dow Chemical, dosage is lacquer middle coating intermediate total weight 0.8wt%.
It is lacquer middle coating intermediate total weight that wetting agent, which selects US Air gas chemistry painting industry wetting agent DCO1, dosage, 0.2wt%。
It is the 0.3wt% of lacquer middle coating intermediate total weight that thickener, which selects the TT-935 of Dow Chemical, dosage,.
It is the 0.30wt% of lacquer middle coating intermediate total weight that preservative, which selects Shu Mei companies of Germany K40, dosage,.
It is the 0.5wt% of coating total weight that antifoaming agent, which selects the SN8034 of Henkel KGaA, dosage,.
Coalescents select the combination of propandiol butyl ether, alcohol ester 12 or both, and dosage is respectively lacquer middle coating intermediate The 0.6wt% and 0.4wt% of total weight.
Make function smalt by oneself:The smalt of 10#-200#.
Functional material A is made of the raw material matched including following parts by weight:Zinc oxide:Barium sulfate:Talcum powder=1: 12:23.
Preparation method:
Step 1) base-material produces:
1.9 parts of deionized water is added in coating material production kettle, starts blender, governing speed is to 600 revs/min, successively It is homogeneously added into dispersant pleased:0.8 part, wetting agent DCO1:0.2 part, preservative K40:0.30 part, antifoaming agent SN8034: 0.5 part, coalescents propandiol butyl ether, alcohol ester 12 are respectively 0.6 part and 0.4 part, and 10.0 parts of functional material A, feed intake end Afterwards, fast rate of dispersion is improved to 1500 revs/min, disperses 30 minutes, until after 15 μm of fineness, speed is down to 550 revs/min, Add 25 parts of the pure-acrylic emulsion weighed in parts by weight, thickener TT-935:0.3 part, continue to stir evenly to get to required Base-material.
Step 2) lacquer middle coating intermediate produces:
Mixing speed is adjusted to 500 revs/min, self-control function smalt is slowly added in the base-material of above-mentioned preparation(10#- 200#)60.0 parts, rotating speed is improved to 1000 revs/min, stirs evenly, pays attention to control time within 15 minutes.
Subbing (by weight):
28 parts of styrene-acrylic emulsion 420V, 27.1 parts of water, 5 parts of titanium dioxide, 100 mesh~35 parts of 200 mesh silica flour, 4.9 parts of auxiliary agent C.
Auxiliary agent C includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
The dispersant is polyacrylic acid sodium salt, as Japan Nuo Puke 5040, dosage is subbing total weight 0.5wt%。
It is the 0.2wt% of subbing total weight that wetting agent, which selects the WT of Germany BASF, dosage,.
It is respectively that bottom applies that thickener, which selects the combination of the sub- 250HBR across dragon and the RH-420 of Japanese rising sun electrification, dosage, Expect 0.2wt%, 0.8wt% of total weight.
It is the 0.1wt% of subbing total weight that preservative, which selects the R640 of Dow Chemical, dosage,.
It is the 0.1wt% of subbing total weight that antifoaming agent, which selects the NXZ of Henkel KGaA company, dosage,.
It is the 1.5wt% of subbing total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 1.5wt% of subbing total weight that coalescents, which select alcohol ester 12, dosage,.
The preparation method of the subbing includes the following steps:
27.1 parts of deionized water is added in coating material production kettle, starts blender, is homogeneously added into dispersant successively 5040:0.5 part, wetting agent WT:0.2 part, thickener 250HBR:0.2 part, preservative R640:0.1 part, antifoaming agent NXZ:0.1 Part, antifreeze propylene glycol:1.5 parts, coalescents alcohol ester 12:1.5 parts, 1350 revs/min of high speed dispersion 10min, then slowly 5 parts of titanium dioxide and 100 mesh~35 parts of 200 mesh silica flour is added, and controls 500~600 revs/min of mixing speed when feeding intake Clock, and 1200 revs/min of high speed dispersion speed after feeding intake is controlled, high speed dispersion 45min adds 28 parts of breast Liquid, thickener RH-420:It 0.8 part, reconciles, examine, packaging.
Embodiment 3
Finishing coating materials(By weight)
55 parts of pure-acrylic emulsion, 30 parts of water, functional material B:9 parts, auxiliary agent B:6.0 part.
Functional material B is the mixture of hollow glass microbead and Opacifying polymers, weight ratio 1:1.
Auxiliary agent B includes dispersant, wetting agent, thickener, preservative, antifoaming agent, antifreeze and coalescents.
Dispersant is ammonium polyacrylate salt, and such as the 2500D of Dow Chemical, dosage is finishing coating materials total weight 0.7wt%。
It is the 0.15wt% of finishing coating materials total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
It is the 0.45wt% of finishing coating materials total weight that thickener, which selects the RH-420 of rising sun electrification, dosage,.
It is the 0.15wt% of finishing coating materials total weight that preservative, which selects Shu Mei companies of Germany K40, dosage,.
It is the 0.35wt% of finishing coating materials total weight that antifoaming agent, which selects the A10 of Henkel KGaA, dosage,.
It is the 1.0wt% of finishing coating materials total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 3.2wt% of finishing coating materials total weight that coalescents, which select alcohol ester 12, dosage,.
Preparation method:
Step 1) function slurry produces:
30 parts of deionized water is added in coating material production kettle, starts blender, 600 revs/min of governing speed, successively uniformly Dispersant 2500D is added in ground:0.7 part, wetting agent CF-11:0.15 part, preservative K40:0.15 part, antifoaming agent A10: 0.35 part, antifreeze ethylene glycol:1.0 parts, coalescents alcohol ester 12:3.2 parts, it is stirring evenly and then adding into functional material B 9.0 Part, using frequency vibration polishing, by fineness control within 15 μm, required mesh number function slurry is made.
Step 2) finishing coating materials produce:
55.0 parts of pure-acrylic emulsion is added in function slurry obtained above, 500 revs/min of governing speed adds increasing Thick dose of RH-420:It 0.45 part, stirs evenly, that is, the finishing coating materials with environmental protection and energy saving effect is made.
Lacquer middle coating intermediate(By weight)
13.75 parts of silicone acrylic emulsion, 0.5 part of water, self-control function smalt(10#-200#)78.0 parts, functional material A 4.75 Part, 3.0 parts of auxiliary agent A.
Auxiliary agent A includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is ammonium polyacrylate salt, and such as the 2500D of Dow Chemical, dosage is lacquer middle coating intermediate gross weight The 0.4wt% of amount.
It is the 0.1wt% of lacquer middle coating intermediate total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
Thickener selects the mixing of the RH-420 of the sub- 250HBR and rising sun electrification across dragon, and dosage is respectively lacquer middle level The 0.7wt% and 0.3wt% of coating total weight.
The mixing of the LX150 of preservative selection Dow Chemical and the R640 of Dow Chemical, dosage are respectively The 0.10wt% and 0.05wt% of lacquer middle coating intermediate total weight.
It is lacquer middle coating intermediate total weight that antifoaming agent, which selects the B556 of Japanese rising sun electrification Co., Ltd., dosage, 0.25wt%。
It is the 0.8wt% of lacquer middle coating intermediate total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 0.3wt% of lacquer middle coating intermediate total weight that coalescents, which select alcohol ester 12, dosage,.
Make the smalt that function smalt is 10#-200# by oneself.
Functional material A is that the raw material mixing matched by following parts by weight is constituted:Zinc oxide:Barium sulfate:Talcum powder=1: 15:25.
Preparation method:
Step 1) base-material produces:
0.5 part of deionized water is added in coating material production kettle, starts blender, governing speed is to 500 revs/min, successively It is homogeneously added into dispersant 2500D:0.4 part, wetting agent CF-11:0.1 part, thickener 250HBR:0.7 part, preservative LX150 and R640 difference:0.10 part and 0.05 part, antifoaming agent B556:0.25 part, antifreeze propylene glycol:0.8 part, coalescents Alcohol ester 12:0.3 part, 4.75 parts of functional material A, after feeding intake, fast rate of dispersion is improved to 1200 revs/min, disperses 25 Minute, until after 15 μm of fineness, speed is down to 800 revs/min, adds the synthetic resin emulsion weighed in parts by weight 13.75 part, RH-420:0.3 part, continue to stir evenly to get to required base-material.
Step 2) lacquer middle coating intermediate produces:
Mixing speed is adjusted to 500 revs/min, self-control function smalt is slowly added in the base-material of above-mentioned preparation(10#- 200#)60.0 parts, rotating speed is improved to 800 revs/min, stirs evenly, pays attention to control time within 12 minutes, you can.
Subbing (by weight):
31 parts of styrene-acrylic emulsion 420V, 26.7 parts of water, 7.5 parts of titanium dioxide, 100 mesh~30 parts of 200 mesh silica flour, 4.8 parts of auxiliary agent C.
Auxiliary agent C includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polyacrylic acid sodium salt, such as Japan Nuo Puke 5040, dosage for subbing total weight 0.4wt%.
It is the 0.15wt% of subbing total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
Thickener selects the combination of the TT-935 of the sub- 250HBR and Dow Chemical across dragon, and dosage is respectively bottom 0.25wt%, 0.6wt% of coating total weight.
It is the 0.15wt% of subbing total weight that preservative, which selects the K40 of Shu Mei companies of Germany, dosage,.
It is the 0.25wt% of subbing total weight that antifoaming agent, which selects the A10 of Henkel KGaA company, dosage,.
It is the 1.25wt% of subbing total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 1.75wt% of subbing total weight that coalescents, which select alcohol ester 12, dosage,.
The preparation method of the subbing includes the following steps:
26.7 parts of deionized water is added in coating material production kettle, starts blender, is homogeneously added into dispersant successively 5040:0.4 part, wetting agent CF-11:0.15 part, thickener 250HBR:0.25 part, preservative K40:0.15 part, antifoaming agent A10: 0.25 part, antifreeze ethylene glycol:1.25 part,
Coalescents alcohol ester 12:1.75 parts, 1300 revs/min of high speed dispersion 12min are slow added into titanium dioxide 7.5 Part and 100 mesh~30 parts of 200 mesh silica flour, and 500~600 revs/min of mixing speed when feeding intake is controlled, and control is thrown 1350 revs/min, high speed dispersion 35min of high speed dispersion speed after material, adds 31 parts of lotion, TT-935:0.6 Part, it reconciles, examine, packaging.
Embodiment 4
Finishing coating materials(By weight)
50 parts of fluorine carbon emulsion, 35.5 parts of water, functional material B:9 parts, auxiliary agent B:5.5 part.
Functional material B is the mixture of hollow glass microbead and Opacifying polymers, weight ratio 2.0:1.
Auxiliary agent B includes dispersant, wetting agent, thickener, preservative, antifoaming agent, antifreeze and coalescents.
Dispersant is ammonium polyacrylate salt, the SN5027 of Japanese Nuo Puke, and dosage is finishing coating materials total weight 0.6wt%。
It is the 0.15wt% of finishing coating materials total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
It is the 0.40wt% of finishing coating materials total weight that thickener, which selects the TT-935 dosages of Dow Chemical,.
It is respectively that finishing coat applies that preservative, which selects the R640 of the LX150 and Dow Chemical of Dow Chemical, dosage, Expect the 0.10wt% of total weight.
It is the 0.15wt% of finishing coating materials total weight that antifoaming agent, which selects the SN8034 of Henkel KGaA, dosage,.
It is the 1.5wt% of finishing coating materials total weight that antifreeze, which selects propylene glycol, dosage,.
Coalescents select the combination of both propandiol butyl ether, alcohol ester 12, and dosage is respectively finishing coating materials total weight 1.5wt% and 1.0wt%.
Preparation method:
Step 1) function slurry produces:
32 parts of deionized water is added in coating material production kettle, starts blender, 580 revs/min of governing speed, successively uniformly Dispersant SN5027 is added in ground:0.6 part, wetting agent CF-11:0.15 part, preservative LX150 and R640, dosage is respectively 0.10 part, antifoaming agent SN8034:0.15 part, antifreeze propylene glycol:1.5 parts, coalescents propandiol butyl ether, 12 dosage of alcohol ester Respectively 1.5 parts and 1.0 parts, it is stirring evenly and then adding into 12.0 parts of functional material B, using frequency vibration polishing, fineness control is existed Within 15 μm, required mesh number function slurry is made.
Step 2) finishing coating materials produce:
50.0 parts of finishing coat lotion, thickener TT-935 are added in function slurry obtained above:It 0.40 part, adjusts 580 revs/min of speed, stirs evenly, that is, the finishing coating materials with environmental protection and energy saving effect are made.
Lacquer middle coating intermediate(By weight)
17.5 parts of silicone acrylic emulsion, 3.85 parts of water, self-control function smalt(10#-200#)69.0 parts, 6.5 parts of functional material A, 3.15 parts of auxiliary agent A,
Auxiliary agent A includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is the 5027 of ammonium polyacrylate salt Japan Nuo Puke, and dosage is lacquer middle coating intermediate total weight 0.6wt%。
It is the 0.15wt% of lacquer middle coating intermediate total weight that wetting agent, which selects the CF-11 dosages of Germany BASF,.
Thickener selects the mixing of the TT-935 of the sub- 250HBR and Dow Chemical across dragon, and dosage is respectively lacquer The 0.6wt% and 0.2wt% of middle coating intermediate total weight.
Preservative selects the mixing of the LX150 of Dow Chemical and the R640 of Dow Chemical, dosage respectively true The 0.10wt% of mineral varnish middle coating intermediate total weight.
It is the 0.30wt% of lacquer middle coating intermediate total weight that antifoaming agent, which selects the NXZ of Henkel KGaA, dosage,.
It is the 0.6wt% of lacquer middle coating intermediate total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 0.5wt% of lacquer middle coating intermediate total weight that coalescents, which select alcohol ester 12, dosage,.
Make the smalt that function smalt is 10#-200# by oneself.
The functional material A is that the raw material mixing matched by following parts by weight is constituted:Zinc oxide:Barium sulfate:Talcum Powder=1:12:30.
Preparation method:
Step 1) base-material produces:
3.85 parts of deionized water is added in coating material production kettle, starts blender, governing speed is to 520 revs/min, successively It is homogeneously added into dispersant 5027:0.6 part, wetting agent CF-11:0.15 part, thickener 250HBR:0.6 part, preservative LX150 and R640 dosages are respectively 0.10 part, antifoaming agent NXZ:0.30 part, antifreeze propylene glycol:0.6 part, coalescents alcohol ester 12:0.5 part, 6.5 parts of functional material A, after feeding intake, fast rate of dispersion is improved to 1350 revs/min, is disperseed 20 minutes, To 15 μm of fineness, speed is down to 800 revs/min, adds 17.5 parts of the silicone acrylic emulsion lotion weighed in parts by weight, TT-935:0.2 part, continue stirring to get to required base-material.
Step 2) lacquer middle coating intermediate produces:
Mixing speed is adjusted to 580 revs/min, self-control function smalt is slowly added in the base-material of above-mentioned preparation(10#- 200#)69.0 parts, rotating speed is improved to 950 revs/min, stirs evenly, pays attention to control time within 11 minutes, you can.
Subbing (by weight):
32.5 parts of styrene-acrylic emulsion TB-15,27.675 parts of water, 7.5 parts of titanium dioxide, 100 mesh~27.5 parts of 200 mesh silica flour, 4.825 parts of auxiliary agent C.
Auxiliary agent C includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polyacrylic acid sodium salt, and such as the pleased of Dow Chemical, dosage is subbing total weight 0.35wt%。
It is the 0.125wt% of subbing total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
It is respectively that bottom applies that thickener, which selects the combination of the sub- 250HBR across dragon and the RH-420 of Japanese rising sun electrification, dosage, Expect 0.275wt%, 0.5wt% of total weight.
Preservative selects the combination of the LXE and R640 of Dow Chemical, and dosage is respectively subbing total weight 0.1wt%、0.075wt%。
It is the 0.3wt% of subbing total weight that antifoaming agent, which selects the B556 of Japanese rising sun electrification, dosage,.
It is the 1.2wt% of subbing total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 1.9wt% of subbing total weight that coalescents, which select alcohol ester 12, dosage,.
The preparation method of the subbing includes the following steps:
27.675 parts of deionized water is added in coating material production kettle, starts blender, it is fast to be homogeneously added into dispersant successively Meaning:0.35, wetting agent CF-11:0.125 part, thickener 250HBR:0.275 part, preservative LXE and R640 dosage is respectively 0.1 Part, 0.075 part, antifoaming agent B556:0.3 part, 1.2 parts of antifreeze propylene glycol, coalescents alcohol ester 12:1.9 parts, 1000 turns/ Minute high speed dispersion 15min, is slow added into 7.5 parts of titanium dioxide and 100 mesh~27.5 parts of 200 mesh silica flour, and control throwing 500~600 revs/min of mixing speed when material, and 1200 revs/min of high speed dispersion speed after feeding intake is controlled, it is high Speed dispersion 40min, adds 32.5 parts of lotion, RH-420:It 0.5 part, reconciles, examine, packaging.
Embodiment 5
Finishing coating materials(By weight)
60 parts of silicone acrylic emulsion, 18.8 parts of water, functional material B:15 parts, auxiliary agent B:6.2 part.
Functional material B is the mixture of hollow glass microbead and Opacifying polymers, weight ratio 3:1.
Auxiliary agent B includes dispersant, wetting agent, thickener, preservative, antifoaming agent, antifreeze and coalescents.
Dispersant is the SN5040 of polyacrylic acid sodium salt such as Japan Nuo Puke, and dosage is finishing coating materials total weight 0.8wt%。
It is finishing coating materials total weight that wetting agent, which selects US Air gas chemistry painting industry wetting agent 1340, dosage, 0.20wt%。
It is the 0.10wt% of finishing coating materials total weight that thickener, which selects the HS30000YP of Clariant, dosage,.
It is the 0.10wt% of finishing coating materials total weight that preservative, which selects the R640 of Dow Chemical, dosage,.
It is the 0.50wt% of finishing coating materials total weight that antifoaming agent, which selects the A10 of Henkel KGaA, dosage,.
It is the 0.5wt% of finishing coating materials total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 4.0wt% of finishing coating materials total weight that coalescents, which select alcohol ester 12, dosage,.
Preparation method:
Step 1) function slurry produces:
18.8 parts of deionized water is added in coating material production kettle, starts blender, 540 revs/min of governing speed, successively It is homogeneously added into dispersant SN5040:0.8 part, wetting agent 1340:0.20 part, thickener HS30000YP:0.10 part, anti-corrosion Agent R640:0.10 part, antifoaming agent A10:0.50 part, antifreeze ethylene glycol:0.5 part, coalescents alcohol ester 12:It 4.0 parts, stirs Uniform rear 15.0 parts of addition functional material B is mixed, using frequency vibration polishing, by fineness control within 15 μm, required mesh number is made Function slurry.
Step 2) finishing coating materials produce:
60.0 parts of silicone acrylic emulsion is added in function slurry obtained above, 580 revs/min of governing speed stirs evenly, The finishing coating materials with environmental protection and energy saving effect are made.
Lacquer middle coating intermediate(By weight)
8.0 parts of pure-acrylic emulsion, 2 parts of elastic emulsion, 11.0 parts of water, self-control function smalt(10#-200#)73.5 parts, function 3.0 parts of materials A, 2.5 parts of auxiliary agent A.
Auxiliary agent A includes wetting agent, preservative, antifreeze, coalescents and thickener.
It is the 0.10wt% of lacquer middle coating intermediate total weight that wetting agent, which selects the CF-11 of Germany BASF, dosage,.
Thickener selects the mixing of two kinds of the RH-420 of the sub- 250HBR and rising sun electrification across dragon, and dosage is respectively lacquer The 0.8wt% of middle coating intermediate total weight and 0.4% wt%.
It is the 0.10wt% of lacquer middle coating intermediate total weight that preservative, which selects the R640 of Dow Chemical, dosage,.
It is the 1.0wt% of lacquer middle coating intermediate total weight that antifreeze, which selects propylene glycol, dosage,.
It is the 0.1wt% of lacquer middle coating intermediate total weight that coalescents, which select alcohol ester 12, dosage,.
Make the smalt that function smalt is 10#-200# by oneself.
Functional material A is that the raw material mixing matched by following parts by weight is constituted:Zinc oxide:Barium sulfate:Talcum powder=1: 15:30.
Preparation method:
Step 1) base-material produces:
11.0 parts of deionized water is added in coating material production kettle, starts blender, governing speed is to 500 revs/min, successively It is homogeneously added into wetting agent CF-11:0.10 part, thickener 250HBR:0.8 part, preservative R640:0.10 part, antifreeze third Glycol:1.0 parts, coalescents alcohol ester 12:0.1 part,
3.0 parts of functional material A after feeding intake, improves fast rate of dispersion to 1200 revs/min, disperses 25 minutes, until After 15 μm of fineness, speed is down to 650 revs/min, adds 8.0 parts of pure-acrylic emulsion, the elastic emulsion 2 weighed in parts by weight Part, RH-420:0.4 part, continue stirring to get to required base-material.
Step 2) lacquer middle coating intermediate produces:
Mixing speed is adjusted to 750 revs/min, self-control function smalt is slowly added in the base-material of above-mentioned preparation(10#- 200#)73.5 parts, rotating speed is improved to 1000 revs/min, stirs evenly, pays attention to control time within 35 minutes, you can.
Subbing (by weight):
29.5 parts of styrene-acrylic emulsion TB-15,28.125 parts of water, 5 parts of titanium dioxide, 100 mesh~32.5 parts of 200 mesh silica flour help 4.875 parts of agent C.
Auxiliary agent C includes dispersant, wetting agent, antifoaming agent, preservative, antifreeze, coalescents and thickener.
Dispersant is polyacrylic acid sodium salt, and such as the pleased of Dow Chemical, dosage is subbing total weight 0.45wt%。
It is the 0.175wt% of subbing total weight that wetting agent, which selects the WT of Germany BASF, dosage,.
Thickener selects the combination of the HS30000YP of Clariant and the RH-420 of Japanese rising sun electrification, and dosage is respectively bottom 0.225wt%, 0.7wt% of coating total weight.
It is the 0.125wt% of subbing total weight that preservative, which selects the A28S of Germany Shu Mei, dosage,.
It is the 0.2wt% of subbing total weight that antifoaming agent, which selects the SN8034 of Henkel KGaA company, dosage,.
It is the 1.4wt% of subbing total weight that antifreeze, which selects ethylene glycol, dosage,.
It is the 1.6wt% of subbing total weight that coalescents, which select alcohol ester 12, dosage,.
The preparation method of the subbing includes the following steps:
28.1 parts of deionized water is added in coating material production kettle, starts blender, it is fast to be homogeneously added into dispersant successively Meaning:0.45 part, wetting agent WT:0.175 part, thickener HS30000YP:0.225 part, preservative A28S:0.125 part, antifoaming agent SN8034:0.2 part, antifreeze ethylene glycol:1.4 parts, coalescents alcohol ester 12:1.6 parts, 1200 revs/min of high speed dispersions 12min is slow added into 5 parts of titanium dioxide and 100 mesh~32.5 parts of 200 mesh silica flour, and controls mixing speed when feeding intake 500~600 revs/min, and control 1000~1350 revs/min of high speed dispersion speed after feeding intake, high speed dispersion 35 ~45min adds 29.5 parts styrene-acrylic emulsion TB-15, RH-420:It 0.7 part, reconciles, examine, packaging.
The present invention is suitable for villa, advanced commercial and residential building, Administration Building, shop etc. and both requires lithotome decoration Effect and the place decoration for requiring energy-saving effect.
The performance of the present invention is referring to table 1.
Table 1
As seen from Table 1, properties of the present invention are satisfied by requirements of the national standard, and environmental-protecting performance is superior, can be used for various The higher occasion of environmental requirement, wherein, embodiment 4 is preference.
The present invention has bright compared with conventional stone-imitation type composite dope, conventional thermal barrier reflective coating and common exterior coating Aobvious energy-conserving action and decorative effect true to nature integrate decoration and energy saving, and main performance comparison is shown in Table 2.
The main property of 2 present invention of table and conventional stone-imitation type composite dope, conventional thermal barrier reflective coating, common exterior coating It can comparison
2 the performance test results of table show:The present invention had both had the lithotome decorative effect true to nature of conventional true stone-type coating With lasting decoration performance, and have energy-conserving action more superior than conventional thermal barrier reflective coating, have very strong creativeness;This Invention can be used for villa, advanced commercial and residential building, Administration Building, shop etc. and both require lithotome decorative effect, again The place with energy-saving effect is asked to decorate.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent defines.

Claims (18)

1. a kind of energy-saving ring fidelity stone-type composite dope, is made of finishing coating materials, lacquer middle coating intermediate and subbing, It is characterized in that:
The subbing is made of following raw materials in part by weight:28~34 parts of synthetic resin emulsion, 26.3~28.1 parts of water, titanium white 4.7~4.9 parts of 5~10 parts of powder, 25~35 parts of special type filler and auxiliary agent C;
The lacquer middle coating intermediate is made of following raw materials in part by weight:10.0~25.0 parts of synthetic resin emulsion, deionization 2.5~3.4 parts of 0.5~11.0 part of water, 3.0~10.0 parts of functional material A, 60.0~78 parts of function smalt and auxiliary agent A;
The function smalt is the smalt of 10#~200#, and the smalt is by inorganic bond material, one or more kinds of cold face Material uniformly mixing according to a certain percentage, using spray pyrolysis technologies, and by calculating enthalpy produced in chemical reaction Δ H's and free energy Δ G Thermodynamics analysis methods, size uniform to prepare, cladding is complete, film thickness is consistent, have excellent sunlight reflection function and The smalt of superior hiding powder function;
The finishing coating materials are made of following raw materials in part by weight:18.8~48.05 parts of deionized water, synthetic resin emulsion 5.5~6.2 parts of 40.0~60.0 parts, 3.0~15.0 parts of functional material B and auxiliary agent B;
Special type filler is the mesh silica flour of 100 mesh~200;Functional material A is made of zinc oxide, barium sulfate and talcum powder, function material Material B is made of hollow ceramic microballon and Opacifying polymers, and the function smalt, functional material A and functional material B are nanometer Grade.
2. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the lacquer middle coating intermediate It is one kind or arbitrary two kinds of mixing in styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion, fluorine carbon emulsion with synthetic resin emulsion.
3. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the finishing coating materials close It is pure-acrylic emulsion, silicone acrylic emulsion or fluorine carbon emulsion at resin emulsion.
4. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the subbing is set with synthesis Fat liquor is pure-acrylic emulsion or silicone acrylic emulsion.
5. the energy-saving ring fidelity stone-type composite dope as described in Claims 2 or 3 or 4, which is characterized in that the phenylpropyl alcohol breast Liquid, silicone acrylic emulsion are respectively the acrylic emulsion being grafted containing styrene monomer, silicon oxygen bond in molecule.
6. the energy-saving ring fidelity stone-type composite dope as described in Claims 2 or 3 or 4, which is characterized in that the pure-acrylic emulsion For the acrylic emulsion of 100% acrylic monomers synthesis.
7. energy-saving ring fidelity stone-type composite dope as claimed in claim 2, which is characterized in that the fluorine carbon emulsion is in molecule Acrylic emulsion containing carbon-fluorine bond grafting.
8. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the auxiliary agent A by pressing below The raw material of parts by weight proportioning is constituted:0~0.8 part of dispersant, 0.1~0.3 part of wetting agent, 0~0.5 part of antifoaming agent, preservative 0.3~1.2 part of 0.1~0.3 part, 0~1.0 part of antifreeze, 0.1~1.0 part of coalescents and thickener.
9. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the auxiliary agent B by pressing below The raw material of parts by weight proportioning is constituted:0.3~0.8 part of dispersant, 0.1~0.2 part of wetting agent, 0~0.5 part of antifoaming agent, anti-corrosion 0.1~0.3 part of agent, 0.5~2.5 part of antifreeze, 1.0~4.0 parts of coalescents, 0.1~1.5 part of thickener.
10. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the auxiliary agent C by pressing below The raw material of parts by weight proportioning is constituted:0.3~0.5 part of dispersant, 0.2~0.4 part of antifoaming agent, is prevented 0.1~0.2 part of wetting agent 0.1~0.2 part of rotten agent, 1.0~1.5 parts of antifreeze, 1.5~2.0 parts of coalescents, 0.7~1.0 part of thickener.
11. the energy-saving ring fidelity stone-type composite dope as described in claim 8 or 9 or 10, which is characterized in that the dispersant For Sodium Polyacrylate dipersant or ammonium polyacrylate dipersant.
12. the energy-saving ring fidelity stone-type composite dope as described in claim 8 or 9 or 10, which is characterized in that the antifreeze Select ethylene glycol or propylene glycol.
13. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the functional material A be by The raw material of following parts by weight proportioning is constituted:Zinc oxide:Barium sulfate:Talcum powder=1:9~15:25~35.
14. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the functional material A be by The raw material of following parts by weight proportioning is constituted:Zinc oxide:Barium sulfate:Talcum powder=1:12:30.
15. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the functional material B be by The raw material of following parts by weight proportioning is constituted:Hollow ceramic microballon:Opacifying polymers=1~3:1.
16. energy-saving ring fidelity stone-type composite dope as described in claim 1, which is characterized in that the functional material B be by The raw material of following parts by weight proportioning is constituted:Hollow ceramic microballon:Opacifying polymers=2:1.
17. the energy-saving ring fidelity stone-type composite dope as described in claim 15 or 16, which is characterized in that described is opaque poly- Close the Snowtex25 or Snowtex30 of Unihub-E or Ying Zhou foreign firms of South Korea that object is Dow Chemical.
18. the construction method of the energy-saving ring fidelity stone-type composite dope described in a kind of any one of claim 1 to 17 claim, It is characterised in that it includes following steps:
1) basal plane is handled:Levelling and consolidation process, drying are carried out to basal plane, obtain firm flat surfaces;
2) subbing is stirred evenly, the water for being optionally added into 0~5% adjusts viscosity to 75~80KU, is applied over Basal plane, dry 4~6h;
3) 10~15 minutes are stood after stirring the lacquer middle coating intermediate, routinely technique is constructed, dry 24~ 48h;
4) with the finishing coating materials, routinely technique carries out overlay treatment.
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