CN104119735A - Colorful coating - Google Patents

Colorful coating Download PDF

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Publication number
CN104119735A
CN104119735A CN201410355729.0A CN201410355729A CN104119735A CN 104119735 A CN104119735 A CN 104119735A CN 201410355729 A CN201410355729 A CN 201410355729A CN 104119735 A CN104119735 A CN 104119735A
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China
Prior art keywords
coating
colour
agent
adopts
emulsion
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CN201410355729.0A
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Chinese (zh)
Inventor
黄新良
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DANYANG HISENSE PAINT CHEMICAL PLANT
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DANYANG HISENSE PAINT CHEMICAL PLANT
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Priority to CN201410355729.0A priority Critical patent/CN104119735A/en
Publication of CN104119735A publication Critical patent/CN104119735A/en
Pending legal-status Critical Current

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Abstract

The invention provides a colorful coating. The colorful coating comprises the following components in percentage by mass: 50-55% of film forming matter, 2-6% of water-based color paste, 10-16% of accessory ingredients and 35-40% of deionized water. According to the film forming matter, synthetic copolymer emulsion is used as a film forming matter of the coating. The accessory ingredients comprise the following components in parts by weight: 0.2-0.4 part of dispersing agent, 2-5 parts of film forming additive, 4-6 parts of antifreezing agent, 0.1-0.2 part of antiseptic and antimildew agent, 2-3 parts of thickening agent, 0.1-0.3 part of defoaming agent, 0.2-0.6 part of fragrance enhancer and 0.2-0.6 part of thixotropic agent. The colorful coating is water-based coating; the coating has the paint characteristic and is free of toxicity, non-combustible and slight in fragrance, so that coating is good in safety during storing, transporting and using, free of pollution to the environment during construction and free of fire danger; the dried coating is tough, durable, wearable and anti-scratch; and meanwhile, the coating has resistance to washing with ethyl alcohol, detergent and water.

Description

Colour-changeable coating
Technical field
The present invention relates to a kind of colour-changeable coating.
Background technology
Coating is the surface that is coated in the object being coated with, and can form the material of the continuous film of firm attachment.Coating is widely used in the corrosion resistant coating of chemical industry equipment, storage tank, pipeline, container, the coating of coating food contact cap surface, the functional coating of household electrical appliances, electronic component and industrial equipments.But existing coating, poor solvent resistance while existing high temperature, adhesive property are poor, coating appearance poor aesthetics, are not used in the problems such as decorative coating mainly for the protection of coating.
Summary of the invention
The object of this invention is to provide a kind of colour-changeable coating; along with the variation of light and viewing angle, the color that film also can present variation; tough and tensile durable, wear-resisting, the resistance to delineation of dried film; and the scrubbing of ethanol-tolerant, washing composition and water; poor solvent resistance while solving the high temperature existing in prior art, adhesive property are poor, coating appearance poor aesthetics, are not used in the problems such as decorative coating mainly for the protection of coating.
Technical solution of the present invention is:
A kind of colour-changeable coating, the mass percent that comprises component and component is: filmogen 50--55, aqueous color paste 2-6, auxiliary agent 10-16, deionized water 35 ~ 40, filmogen adopts the film forming matter of synthetic copolymer emulsion as coating, and auxiliary agent is specially dispersion agent 0.2 ~ 0.4, film coalescence aid 2 ~ 5, frostproofer 4 ~ 6, Antisepticize and mildew preventive 0.1 ~ 0.2, thickening material 2 ~ 3, defoamer 0.1-0.3, sweetener 0.2 ~ 0.6, thixotropic agent 0.2 ~ 0.6.
Further, synthetic copolymer emulsion comprises vinylbenzene, Isooctyl acrylate monomer; Dispersion agent adopts negatively charged ion and nonionogenic tenside; Film coalescence aid adopts middle and high boiling point ester class, ethers; Frostproofer adopts glycols frostproofer; Thickening material adopts polyacrylate emulsion type thickening material; Defoamer adopts tributylphosphate, organosilicon; Thixotropic agent adopts silicon-dioxide, organobentonite, water system Viscotrol C wax, metallic soap or tensio-active agent.
Further, the production process of aqueous color paste is: by pigment, thixotropic agent, auxiliary agent, deionized water mix and blend, grind, add emulsion, auxiliary agent mix and blend, then add toning, auxiliary agent to carry out viscosity adjustment, obtain colour-changeable coating.
Further, the production process of colour-changeable coating is as follows:
By pigment, thixotropic agent, auxiliary agent, deionized water mix and blend, grind, add emulsion, auxiliary agent mix and blend, then add toning, auxiliary agent to carry out viscosity adjustment, obtain colour-changeable coating.
Further, adopt emulsion modifiedly, be cross-linked with emulsion with the water-base resin of macromolecule and auxiliary agent, make water-based emulsion particle in coating, form tridimensional network.
Further, while applying colour-changeable coating, the special primary coat of primary coat colour-changeable coating, the special primary coat of colour-changeable coating adopts the water diluent of synthetic resin emulsion, sealing basic unit; Middle painting adopts roller coat, spraying or brushes synthetic resin emulsion Xu Ke; After middle painting is dry, carries out face and be coated with colour-changeable coating.
The invention has the beneficial effects as follows:
This kind of colour-changeable coating is water-borne coatings, but film has paint characteristic, and nontoxicly do not fire, slightly fragrance, thereby storage, transport, the security of use is good, free from environmental pollution when construction, without fire hazard; Point primary coat, middle painting, face are coated with three coatings, and it is various that face is coated with construction means and methods, spray, roll, scrape, smear, seal, bullet all can; For showing specific artistic environment, color can on-the-spotly be allocated also chromatography arbitrarily, match with the middle painting of different color again, can present graceful decorative effect and the texture such as gorgeous changeable cloud, marble, soft silk fabric, along with the variation of light and viewing angle, the color that film also can present variation.
This kind of colour-changeable coating is long storage period, and use range is extensive, and under airtight suitable storage requirement, can reach l-2 storage period.Applicable basic unit is concrete, mortar face, plasterboard, plank, glass, metal etc., not only can do metope, ceiling finish, also can be used for the decoration of furniture, woodenware and some artworks.Tough and tensile durable, wear-resisting, the resistance to delineation of dried film, and the scrubbing of ethanol-tolerant, washing composition and water.Coating is concentrated to be sold, and adds suitable quantity of water dilution before use, can reduce trucking costs, increases construction area.
Embodiment
Describe the preferred embodiments of the present invention below in detail.
Embodiment
Colour-changeable coating, the mass percent that comprises component and component is: filmogen 50--55, aqueous color paste 2-6, auxiliary agent 10-16, deionized water 35 ~ 40, filmogen adopts the film forming matter of synthetic copolymer emulsion as coating, and auxiliary agent is specially dispersion agent 0.2 ~ 0.4, film coalescence aid 2 ~ 5, frostproofer 4 ~ 6, Antisepticize and mildew preventive 0.1 ~ 0.2, thickening material 2 ~ 3, defoamer 0.1-0.3, sweetener 0.2 ~ 0.6, thixotropic agent 0.2 ~ 0.6.
Filmogen to be to synthesize the film forming matter of copolymer emulsion as coating, and the factor such as polymerization degree to emulsion, molecular weight, viscosity, guarantor's light tint retention, thixotropy, after tackiness, gloss is selected.In test, synthesize multiple copolymer emulsion, finally determined the polymerized emulsion taking vinylbenzene, Isooctyl acrylate monomer etc. as principal monomer.Continuous pre-emulsification technology and special feed way on polymerization technique, are selected, to ensure high viscosity, gloss and the stability thereof of emulsion.
The tinting pigment of pigment cloud paint is mainly the natural mica through special processing, is aided with the pigment of various transparent colors.
In auxiliary agent, dispersion agent adopts some negatively charged ion and nonionogenic tenside, in order to disperse and moistening color stuffing solid particles surface, promotes that solids suspend in liquid, makes it to be easy to mixing, is uniformly dispersed, stabilising system, prevents that color stuffing from uniting and assembling.
Film coalescence aid adopts some middle and high boiling point ester class and ethers, in order to reduce emulsion film forming temperature, slows down water evaporates speed in film, increases film levelling property and sticking power.
Frostproofer adopts glycols frostproofer, to improve coating anti-freezing property.
Antisepticize and mildew preventive adopts some high-efficiency low-toxicity Antisepticize and mildew preventives, to prevent mouldy, the corrupt fouling of coating and coating, viscosity.
Thickening material adopts polyacrylate emulsion type thickening material, to adjust and to control coating denseness.
Defoamer adopts some high effective antifoaming agents, with eliminate color stuffing disperse in and with emulsion mix and blend in the middle of the bubble that produces.(7) sweetener: adopt the lasting essence of some lastings, to ensure coating fragrance.
Thixotropic agent adopts solid thixotropy, can make coating have excellent package stability, and coating is not stratified; There is again excellent application property, the easy levelling of coating, sagging not.
Taking yellow cloud paint as example, formula is expressed as follows with weight percent (%):
Benzene emulsion 50 ~ 55; Yellow ultramarine 2 ~ 6; Dispersion agent 0.2 ~ 0.4; Propylene glycol 4 ~ 6; Furtherance film 2 ~ 5; Thixotropic agent 0.2 ~ 0.6; PT sanitas 0.1 ~ 0.2; Defoamer tbp is appropriate; Yellow slurry 0.2 ~ 0.3; Thickening material 2 ~ 3; Deionized water 35 ~ 40.
In aqueous color paste production process, require aqueous color paste lovely luster, viscosity is suitable, and fineness is below 20um, and its production process is as follows:
By pigment, auxiliary agent, deionized water mix and blend, grind, then carry out viscosity adjustment after adding auxiliary agent, obtain aqueous color paste.
Colour-changeable coating requires part starting material fineness after grinding to reach below SOum, then with emulsion and various auxiliary agent mix and blend, suitably froth breaking, make it to become low-viscosity dope, under agitation add people's auxiliary agent and adjust viscosity, to reach required dope viscosity, its production process is as follows:
By pigment, thixotropic agent, auxiliary agent, deionized water mix and blend, grind, add emulsion, auxiliary agent mix and blend, then add toning, auxiliary agent to carry out viscosity adjustment, obtain colour-changeable coating.
The constructional method of colour-changeable coating comprises following several step.
The inspection of basic unit and processing, first will check that being coated with basic unit has or not the class materials such as earth, dust, remover, greasy dirt, and this class material can be removed with wire brush, scraper, organic solvent or soapless soap, then basic unit cleaned clean with broom, rag.If the substrate surface accumulation of salt in the surface soil, available light-coloured vinegar and clear water mixed solution are cleaned to pH value and are less than 9. 5.Secondly the water ratio and the basicity that check substrate surface, require substrate surface water ratio lower than 10%, and surperficial pH value is below 9.5, and available mortar moisture is taken into account surperficial PH_ meter and measured.Finally, require the defects such as substrate surface is smooth, bright and clean, no concave-convex.This is the key that ensures cloud paint decorative effect, if substrate surface injustice or cracklin, available putty levelling, large crack must be repaired by synthetic resins sand-cement slurry, uses after to be dried emery wheel, sand papering smooth again, then carries out coating application..
Primary coat construction, colour-changeable coating special bottom is painted with the water diluent of synthetic resin emulsion, can seal basic unit, prevents the accumulation of salt in the surface soil, increases coating adhesion.Generally with roller coat for well, also can brush, but require approximately even unanimously, prevent holiday.
Middle painting construction, in be painted with synthetic resin emulsion Xu Ke, this coating generally has higher screening box power.Levelling property and-the good performance of scrubbing, consistent in order to ensure substrate surface color even, create a kind of good background color environment constructional method for brushing surface coating and generally adopt roller coat, spraying or brushing.No matter adopt what method, all will guarantee brushing uniformity, without holiday, no sag, without brush mark, be generally coated with two times.
Face is coated with construction, after middle painting is dry, carries out face and is coated with construction.As previously mentioned, it is a lot of that cloud face is coated with constructional method, in different constructional methods and different color, is coated with and matches, and can present different decorative effects and texture.
Roll pad construction method, rolling pad is to be formed by three or four layers of special leather juxtaposition, the middle part of leather is tightened, be bundled into handle with adhesive plaster, make the blade of suitable size according to required decorative pattern size, when large-area construction, must two people coordinate, coating is first diluted to required viscosity by one people, according to the dry wet degree of temperature and the air 10%-40% that can add water, then evenly coat about 1-2 square meter with brush or roller, another people will roll and pad gently contact surface and be coated with and execute and transfer to out natural figure.Continue to repeat above-mentioned two steps construction, until all complete.Note junction, must in the time that coating is not dry, join, in order to avoid surface drying and form vestige affects decorative effect.
Scraper plate construction method, when large-area construction, also needs two people to coordinate as rolled as described in pad method.1-2 square meter evenly coated by coating by one, and another people criticizes spread coated paint with special scraper plate, makes it to be difform decorative pattern.Can not be completely vertical with basic unit, should be inclined to Small angle, fast.Also to note seam and receive head, also can chromatography, roll pad method.When construction, scraper plate falls hand, receipts hand operational procedure with rolling pad method.
Roller application method, the method is first with roller, coating to be evenly coated on metope, then uses the coating of another kind of color on the knurling roller tool roller of concrete floral designs.Can go out various decalcomanias by roller coat, its decorative effect can match in excellence or beauty with stamp wall paper.Use differential roller tool, can reach different decorative effects.
Spraying application method, this method is close with spray multicolor finish.First coating is diluted to applicable viscosity, then adopts special spray tip 2. ~ 3.5mm, air pressure 1 ~ 2 normal atmosphere, when spray macroparticle, pressure is low, when spray small-particle, pressure is high, nozzle distance metope 60 ~ 80cm) first horizontal direction is evenly sprayed two times, then vertical direction is evenly sprayed one time.As needing multicolour, the face that can take advantage of the another kind of color of wet shot in the time having sprayed first pass is coated with as second time.
Bullet is coated with construction method, and this method is used bullet to be coated with device versicolor coating is launched to metope, to form the colored point-like coating that stereoscopic sensation is strong.The coating forming, because various color dots are in picturesque disorder, sets off mutually, can reach the decorative effect of granitic plaster.
Seal construction method, this method is that special pattern or leather are stamped as affixing one's seal, but uniform sequential, can not repeat, in order to avoid affect decorative effect.Pay special attention to the cooperation of middle Base coating, color coordination is proper, can obtain excellent effect.
Compound construction method, in order to improve decorative effect, strengthens coating texture, ensures coating construction quality, can apply several instruments, multicolour, mutual chromatography simultaneously, then match from different middle Base coatings, thereby present pattern changeable and decorative effect.This compound construction method can be according to workmen's experience, and independently creative usually can obtain beyond thought effect.
Construction consumption and material cost analysis, several constructional methods are as follows with reference to consumption: roll pad method: 6 ~ 7m/kg; Scraper plate method: 8 ~ 10m/ kg; Spraying method: 10 ~ 12m/kg; Rolling method: 8 ~ 10m/ kg; Seal method: 8 ~ 10m/ kg.
Colour-changeable coating adopts flash type pigment.Flash type pigment has flash of light aluminium powder, nacreous mica pigment, sericite pearly pigment, superfine silicon dioxide effect pigment etc.Flash of light aluminium powder is strip metallic aluminium, light reflects and makes penta sparkle effect on the minute surface on aluminium flake surface, this aluminium powder is divided into regular shape " silver dollar type " and erose " corn flakes type " 2 classes, the former surface smoothing, flash effect is good, and coarse irregular the latter can produce a lot of scattered lights, outward appearance visual effect light is softer.
But flash of light aluminium powder still can not be directly used in water-borne coatings, because fierce chemical reaction can occur for superfine aluminium power and water-based base-material direct effect, produces a large amount of hydrogen and very large heat.After aluminium powder and water effect, the sparkle effect of aluminium powder disappears immediately, and color also will change, and the aluminium powder that therefore glistens need use after treatment.Available transparent coated with resin, or adopt phosphoric acid salt, chromating, flash of light aluminium powder is carried out to sealing treatment, eliminate its chemically reactive.After processing, can in colour-changeable coating, use, but common aluminium powder can not directly be applied.
Nacreous mica pigment or sericite pearly pigment by the reasonable flaky mica powder of the transparency at the much higher transparent metal oxide of its surface deposition one deck refractive index ratio mica as TiOz or FezO: form, in the time there is multiple reflections, refraction action in light on the different transparent layer interface of specific refractory power, form two bundle directional lights of anti-and refraction, there is separately interference of light phenomenon, can produce pearlescent brilliance.Be deposited on the metal oxide kind difference on sheet mica surface, nacreous pigments is just different, as being silvery white with TiOz, and Fe20: be redness, CrzO: be green.In the time that the oxide thickness that deposits on sheet mica is different, the color of the reflection interference light of generation also can be different, and in the time that viewer's angle is different, the color of interference light and light intensity also can change, and this phenomenon is referred to as to call goniochromatic effect.Nacreous mica pigment can be spelled mutually use with other spangles, pigment dyestuff, mineral dye, carries out effect complementation on the one hand, can reduce costs on the other hand.
The particle diameter of superfine titanic oxide powder only has 0.01 ~ 0.05mm, is 1/10 ~ 1/30 of traditional titanium dioxide pigment particle dia, and its particle diameter dimension approaches visible light wavelength, and therefore the diffraction phenomena of light just occurs radiation of visible light on these particles.As use is spelled in it and flash of light aluminium powder, nacreous mica powder etc., can in illumination area, show a kind of flavous opalescence, there is blue-opalescent in sidelight district, the black fine and soft religion of effect of the sudden strain of a muscle look at visual angle, the saturation ratio of color, decoration is good.Catch up with thin titanium dioxide generally in quite expecting, to account for below l/3.
Colour-changeable coating requires to have a thixotropy larger than other coating, the thixotropy of coating derive from system inner exist as hydrogen bond, Robert Van de Walle power grade rank key, can make the loose reticulated structure of System forming.In the time that system is subject to extraneous shear action, reticulated structure is destroyed, and system viscosity decreases, and removes when external force, and system reticulated structure recovers gradually, and viscosity rises again gradually, returns to original state.This to change with external force the structural changes causing be reversible, can repeatedly repeat. this thixotropy is brought many convenience to the construction of coating, can avoid coating sagging, increase the sparkle effect of rete.
Improve thixotropic method of colour-changeable coating:
Adopt emulsion modified.Crosslinked with the water-base resin of suitable macromolecule and auxiliary agent and emulsion, make water-based emulsion particle in coating, form tridimensional network, thereby strengthen the thixotropy of emulsion itself, intensity and the decorative effect of the weathering resistance of raising emulsion, glossiness, rete.
In coating, add thixotropic agent, as silicon-dioxide, organobentonite, water system Viscotrol C wax, metallic soap or tensio-active agent etc.Add this class thixotropic agent often to affect the refractive index of cloud paint, therefore in colour-changeable coating, can only consider few use.In colour-changeable coating, adopt 2 kinds of methods used time, thixotropy index should be controlled at 5 ~ 7, and the thixotropy index of colour-changeable coating is not more high better, because various indexs condition each other in colour-changeable coating, the too high meeting of thixotropy index makes levelling property variation, easily causes brush mark, constructional difficulties; Meanwhile, coating froth breaking difficulty, the bubble being included in coating can form fine age spot after film layer is dry, makes coating roughen, has destroyed the soft pearl effect of rete, has lost skin feel soft and moist, unreal cunning.
Colour-changeable coating is easy to occur flooding phenomenon.Spangles can from coating, appear in one's mind in pail pack solution surface with bucket all around, form a flash ring.This phenomenon is the problem in production technique, should first carry out pre-invasion to pigment, the auxiliary agents such as dispersion agent are first dissolved in deionized water, make the uniform aqueous solution, again spangles etc. is scattered in this solution, after high speed uniform stirring, again it and base-material is evenly mixed.As spangles directly drops into emulsion will depolymerization, may form tiny pigment small-particle and be suspended in coating surface.
Colour-changeable coating, because the common coating of its viscosity ratio is high, is easy to again entrained air in process of production through repeatedly stirring and grinding.For this reason, can add people's 0.1% one 0. 3% defoamers, as tributylphosphate, organosilicon etc., it is clean that exhaust is wanted, in order to avoid affect the surface smoothness of coating rete.
Colour-changeable coating quality product is coated quality, construction quality and is respectively accounted for 50%.And construction quality is in close relations with service tool, selection tool, tools will have abundant imagination, and instrument can not store up again slurry and gas storage simultaneously, so just can make rete reach good dreamlike visual effect.
Diameter 0. 1 ~ 0. 5mm colored plastic silk adding in colour-changeable coating, can use the materials such as polyethylene, polyester, nylon 66 to make.Wherein taking 66 of nylon as best, painted bright-coloured, high with the cohesive strength such as emulsion, resin, but before being added to coating, should carry out pre-invasion processing and eliminate Electrostatic Treatment, in order to avoid occur that cohesive strength is low, color silk is easily peeled off, or color silk is tied the group of being polymerized to, be difficult for disperseing, skewness, or precipitate bottomed etc.
The multiple colour flash sheet that adds in colour-changeable coating base-material, flash of light silk by 0. 015mm or 0.023mm polyester film through vacuum sputtering aluminize, aluminium film forms gold, silver color, the colour such as red, blue, green, purple, yellow through painted processing again, roll into the wide filament of lmm through rolling silk, be cut into again segment or the little square piece of lmm × lmm of 5 ~ lOmm, or be cut into little hexagonal disks O, pentagram sheet ☆ with blanking method.The flash effect quality of diamante is relevant with poly-vinegar film surface smooth finish, and smooth finish is higher, and vacuum aluminum-coated rear aluminium film is brighter, and the catoptrical ability of little square piece is also stronger.These diamantes add also must be made pre-wetted before base-material and eliminate Electrostatic Treatment, in order to avoid occur maldistribution, poor adhesive force, easily the disadvantage such as peel off.

Claims (6)

1. a colour-changeable coating, it is characterized in that, the mass percent that comprises component and component is: filmogen 50--55, aqueous color paste 2-6, auxiliary agent 10-16, deionized water 35 ~ 40, filmogen adopts the film forming matter of synthetic copolymer emulsion as coating, and auxiliary agent is specially dispersion agent 0.2 ~ 0.4, film coalescence aid 2 ~ 5, frostproofer 4 ~ 6, Antisepticize and mildew preventive 0.1 ~ 0.2, thickening material 2 ~ 3, defoamer 0.1-0.3, sweetener 0.2 ~ 0.6, thixotropic agent 0.2 ~ 0.6.
2. colour-changeable coating as claimed in claim 1, is characterized in that: synthetic copolymer emulsion comprises vinylbenzene, Isooctyl acrylate monomer; Dispersion agent adopts negatively charged ion and nonionogenic tenside; Film coalescence aid adopts middle and high boiling point ester class, ethers; Frostproofer adopts glycols frostproofer; Thickening material adopts polyacrylate emulsion type thickening material; Defoamer adopts tributylphosphate, organosilicon; Thixotropic agent adopts silicon-dioxide, organobentonite, water system Viscotrol C wax, metallic soap or tensio-active agent.
3. colour-changeable coating as claimed in claim 2, is characterized in that, the production process of aqueous color paste is: by pigment, thixotropic agent, auxiliary agent, deionized water mix and blend, grind, add emulsion, auxiliary agent mix and blend, then add toning, auxiliary agent to carry out viscosity adjustment, obtain colour-changeable coating.
4. colour-changeable coating as claimed in claim 3, is characterized in that, the production process of colour-changeable coating is as follows:
By pigment, thixotropic agent, auxiliary agent, deionized water mix and blend, grind, add emulsion, auxiliary agent mix and blend, then add toning, auxiliary agent to carry out viscosity adjustment, obtain colour-changeable coating.
5. the colour-changeable coating as described in claim 1-4 any one, is characterized in that, adopts emulsion modifiedly, is cross-linked with emulsion with the water-base resin of macromolecule and auxiliary agent, makes water-based emulsion particle in coating, form tridimensional network.
6. colour-changeable coating as claimed in claim 5, is characterized in that, while applying colour-changeable coating, and the special primary coat of primary coat colour-changeable coating, the special primary coat of colour-changeable coating adopts the water diluent of synthetic resin emulsion, sealing basic unit; Middle painting adopts roller coat, spraying or brushes synthetic resin emulsion Xu Ke; After middle painting is dry, carries out face and be coated with colour-changeable coating.
CN201410355729.0A 2014-07-25 2014-07-25 Colorful coating Pending CN104119735A (en)

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CN104446256A (en) * 2014-12-05 2015-03-25 刘娟 Building crystalline bloom prevention mortar and building crystalline bloom treatment method
CN105331231A (en) * 2015-11-06 2016-02-17 南通市乐佳涂料有限公司 Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof
CN106634606A (en) * 2015-10-30 2017-05-10 丹阳市海信涂料化工厂 Elastic fireproof colorful paint
CN106700847A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Preparation method of colorful coating
CN106700848A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Film forming component used for colorful coating and preparation method thereof
CN106700849A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Multicolor paint
CN107141901A (en) * 2017-05-24 2017-09-08 钱小平 A kind of colour-changeable coating
CN107163636A (en) * 2017-05-24 2017-09-15 钱小平 A kind of weathering resistance coating
CN107304314A (en) * 2016-08-23 2017-10-31 如皋长江科技产业有限公司 A kind of colour-changeable coating

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104446256A (en) * 2014-12-05 2015-03-25 刘娟 Building crystalline bloom prevention mortar and building crystalline bloom treatment method
CN106634606A (en) * 2015-10-30 2017-05-10 丹阳市海信涂料化工厂 Elastic fireproof colorful paint
CN105331231A (en) * 2015-11-06 2016-02-17 南通市乐佳涂料有限公司 Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof
CN105331231B (en) * 2015-11-06 2018-09-11 南通市乐佳涂料有限公司 A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method
CN107304314A (en) * 2016-08-23 2017-10-31 如皋长江科技产业有限公司 A kind of colour-changeable coating
CN106700847A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Preparation method of colorful coating
CN106700848A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Film forming component used for colorful coating and preparation method thereof
CN106700849A (en) * 2016-12-29 2017-05-24 芜湖乐普汽车科技有限公司 Multicolor paint
CN107141901A (en) * 2017-05-24 2017-09-08 钱小平 A kind of colour-changeable coating
CN107163636A (en) * 2017-05-24 2017-09-15 钱小平 A kind of weathering resistance coating

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Application publication date: 20141029

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