CN104151907A - Reflectively thermal-insulation color putty paste - Google Patents

Reflectively thermal-insulation color putty paste Download PDF

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Publication number
CN104151907A
CN104151907A CN201410430946.1A CN201410430946A CN104151907A CN 104151907 A CN104151907 A CN 104151907A CN 201410430946 A CN201410430946 A CN 201410430946A CN 104151907 A CN104151907 A CN 104151907A
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CN
China
Prior art keywords
parts
thermal
emulsion
insulation
putty paste
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Pending
Application number
CN201410430946.1A
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Chinese (zh)
Inventor
王植飞
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SHANGHAI LVTEDAN THERMAL INSULATION ENGINEERING Co Ltd
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SHANGHAI LVTEDAN THERMAL INSULATION ENGINEERING Co Ltd
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Priority to CN201410430946.1A priority Critical patent/CN104151907A/en
Publication of CN104151907A publication Critical patent/CN104151907A/en
Pending legal-status Critical Current

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    • Y02P20/121

Abstract

The invention provides a reflectively thermal-insulation color putty paste which consists of following components, by weight, 1-20 parts of pure water, 1-20 parts of a sunlight and near-infrared reflectively thermal-insulation functional material, 1-15 parts of a cold pigment, 10-50 parts of a synthetic resin emulsion, 5-20 parts of an additive and 50-80 parts of a filling material. The invention also provides a preparation method of the reflectively thermal-insulation color putty paste. The pure water, the water-soluble synthetic resin, the additive, the filling material, the reflectively thermal-insulation functional material and the cold pigment are mixed uniformly in a dispersion container to prepare the putty paste. With addition of the functional material, which has a strong reflectively thermal-insulation effect on sunlight and near infrared ray, to the putty paste, the putty paste has a reflective effect on the sunlight and the near infrared ray of which a wavelength is 780-2500. Meanwhile, a sunlight reflecting ratio, a near infrared ray reflecting ratio and a hemisphere emitting rate of the putty paste can all reach a specification in a relative standard. The putty paste can effectively reduce the temperature of a whole thermal-insulation system, even a wall body, can improve a thermal-insulation and energy-saving effect and reduce a thermal bridge effect.

Description

A kind of reflective insulation color lacquer putty cream
Technology neck city:
The invention belongs to chemical field, especially a kind of reflective insulation color lacquer putty cream.
Background technology:
Before two thousand years, China has been used tung oil, lime, jute to make the wood seam that putty paste is criticized diveder ship, and plate seam during furniture paint, the side seam of door and window etc.After Iron And Steel Industry prosperity, steel equipment rises in a large number, equipment surface need be filled up defect, also adopt putty paste to criticize embedding, the creme of using when the water-proof putty cream of present architectural use, batch wall putty and rubber terrace are suppressed, the sizing material that rolling plastic film is used are all the derivative of putty paste in fact, just starting material and using method are different, so the purposes of putty paste is more and more extensive.Putty paste is by using function to have: 1. furniture is with criticizing spachtling cream; 2. the caulking compounds that cracking resistance for building is squeegeeed; 3. the molecular sieve putty paste that automobile and steel equipment are used; 4. hot glue that the work in-process in plastic, rubber Industrial processes are used as production string rubber etc.Material type classification by putty paste has time: 1. lipid while making to paint (as criticize embedding furniture putty paste); 2. solvent borne synthetic resins (as epoxy putty cream); 3. rubber-like (as silicone rubber seal cream); 4. water-soluble synthetic resin class (batch wall use various putty pastes); When 5. sheet rubber compacting is produced, use rubber and plastic creme etc.
Along with social progress; the raising of the mankind to the degree of protection of environment; not only the kind of putty paste grows with each passing day; and increasing product is to water-soluble innoxious development; and the quality of putty paste and function have also had new raising; country very payes attention to building energy conservation in recent years, requires building energy conservation more than 50%, and task is very heavy.The glass curtain wall adopting in building external structure, ceramic tile veneer wall, the cladding wall of slabstone, aluminium-plastic panel decorative wall, heat insulation decoration integrated plate wall etc. all need a large amount of colored filleting putty pastes.Traditional color lacquer putty cream does not have the reflective insulation function of solar heat, in summer, can import a large amount of solar heat absorbing into body of wall, after being raise, body of wall temperature becomes heat bridge, and then import into indoor, thereby to indoor air conditioning electricity build-up of pressure, impel a large amount of wastes of electric power energy, must improve and functionalization upgrading.
Summary of the invention:
The object of the present invention is to provide a kind of reflective insulation color lacquer putty cream, described this reflective insulation color lacquer putty cream will solve the reflective insulation function that color lacquer putty cream of the prior art does not have solar heat, the technical problem that make the body of wall effect of heat insulation of buildings poor, heat bridge effect is large, energy dissipation is many.
A kind of reflective insulation color lacquer putty of the present invention cream, is grouped into by the one-tenth of following weight part:
Further, by the near infrared ray that is 750-2500nm light wave to sunlight and wavelength, one or more in the powder body material of reflection function and the hollow glass bead of the above fineness of 200 order and the hollow haydite of the above fineness of 200 orders are formed described infrared external reflection heat-insulation functional material, and it is TM550 type, TM800 type infrared reflecting paint and the Shanghai generation exhibition chemical industry product TK501W type dust health powder that Britain Huntsman Corporation produces that the described near infrared ray that is 750-2500nm light wave to sunlight and wavelength has the powder body material of reflection function.
Further, one or more in the of all kinds cold pigment that described cold pigment is produced or sold by Britain Huntsman Corporation, Shanghai Shi Zhan chemical company, upper sea God's promise company are formed.
Further, described cold pigment series is one or more the combination in redness, yellow, blue look, green, brown, white and their induced color.
Further, described synthetic resin emulsion is one or more the combination in water-soluble silicon acrylate elastic emulsion, pure acrylate elastic emulsion, phenylpropyl alcohol elastic emulsion, fluorine carbon emulsion, polyaminoester emulsion, acrylate and vinyl acetate emulsion, aqueous epoxy emulsion EVA emulsion and their soluble derivative.
Further, two or more the combination of described auxiliary agent in ether of cellulose, wilkinite, dispersion agent, wetting agent, sanitas, sterilant, Lauryl Alcohol ester, propylene glycol, defoamer, PH conditioning agent, lignocellulose, thickening material.
Further, described filler be water-ground limestone (coarse whiting),, two or more the combination in light calcium carbonate (fine particle calcium carbonate), silica powder, wollastonite powder, talcum powder, marble dust, diatomite, blaue fixe.
Further, described ether of cellulose is one or more the combination in Natvosol, carboxymethyl propyl cellulose, carboxymethyl cellulose.
The present invention also provides a kind of preparation method of reflective insulation color lacquer putty cream, and water-soluble synthetic resin emulsion, auxiliary agent, filler, infrared external reflection heat-insulation functional material, cold pigment are mixed in dispersion cup.
Further, adopt thickening material or with pure water, carry out the denseness of accommodation reflex insulating color putty paste.
Further, adopt thickening material or pure water to carry out the denseness of accommodation reflex insulating color putty paste.
Concrete, the invention provides a kind of reflective insulation color lacquer putty cream, by the combination of following weight part, formed: as follows
Further, described filler is commercially available conventional products, fineness 325 orders or more than.
Further, the first-selected hollow haydite for LG-DOW production of described hollow haydite.Described hollow glass bead is Shanghai 3M company product.
Further, described synthetic resins is first-selected be BASF 7016G, LG-DOW 2468, Shanghai sunrise 4369, one or more in the RS9389 of the 998AD of Shanghai Bao Lijia and KD96, Shanghai Ahmedabad richness etc. and fluorine carbon emulsion, polyaminoester emulsion, acrylate and vinyl acetate emulsion, aqueous epoxy emulsion, EVA emulsion and their various derivatives are formed.
Further, described Mierocrystalline cellulose first-selection is auspicious safe carboxymethyl propyl cellulose, the carboxymethyl cellulose (CMC) of producing of Natvosol or Shandong of Clariant and sub-2.5-10 ten thousand viscosity of producing across dragon.
Further, described Lauryl Alcohol ester first-selection is the neat large Lauryl Alcohol ester producing of Yi Siman and China.
Further, described dispersion agent is sea this special chemical of name FX600.
Further, described wetting agent is Shanghai Hai Chuan SN-996.
Further, described sanitas is 5251.
Further, described sterilant is the LXE of ROHM AND HAAS (Tao Shi).
Further, described defoamer is Shenzhen Hai Chuan product.
Further, the AMP-95 that described PH conditioning agent is Shanghai grid.
Further, described thickening material is 530 of Shanghai grid company.
Infrared external reflection heat-insulation functional material of the present invention: one or more in the hollow haydite that infrared external reflection heat-insulating powder is wherein opened up the TK501W dust health powder of Chemical Manufacture and the hollow glass micropearl of the above fineness of 200 order and the above fineness of 200 order by Britain's Hensel infrared reflecting paint TM550, TM800 producing advanced in years and Shanghai generation are formed.
According to GB/T235-2014 architectural reflective heat-insulation paint (People's Republic of China's building industry industry) standard, stipulate: the reflectivity of the thickness of coating rete sunlight more than 150 μ m and when its color is low lightness should reach 0.25-0.65, to infrared reflection ratio, should reach 0.4, when its color is high brightness, to ultrared reflectivity, should reach more than 0.8.After reflective insulation putty paste of the present invention applies, can avoid being coated with position and produce sudden-heat phenomenon, thereby delay the work-ing life of lagging material, reach the lasting booster action to the heat-insulation and heat-preservation of existing insulating wall material.
In putty paste of the present invention, added sunlight and near infrared ray have been produced to reflective insulation material, comprise infrared reflecting paint and the commercially available cold pigment of colour, (as Britain's Hensel steps, Shanghai generation exhibition chemical industry, upper sea God's promise, Shanghai Ke Naiou development or the cold pigment sold), forms these functional materials and synthetic resin emulsion, auxiliary agent, filler, cold pigment mixing manufacture.Play the effect to the reflection of infra-red heat auxiliary heat-insulation and heat-preservation, can effectively reduce the even temperature of body of wall of whole heat insulation system, improve heat preservation energy-saving effect, alleviate heat bridge effect.Simultaneously product of the present invention also can be produced various flexible thin slices by rolling press, makes Sunshade film, waterproof membrane, thermal insulation plaster mould material and uses, and the colorful sliver also can be used as in the multicolor finish of natural-like stone is used.Can save a large amount of electric power energies, Social benefit and economic benefit is very considerable.Reflective insulation putty paste of the present invention can, at glass curtain wall, ceramic tile veneer wall, stone material dry suspending wall, heat insulation decoration integrated plate wall, even directly be used at concrete surface.
Embodiment:
Embodiment 1
Take 2 parts of pure water, 5 parts of synthetic resins flexible silicon acrylic emulsions, 35 parts of synthetic resins pure-acrylic emulsions, 0.1 part of the Natvosol of 30000 viscosity, 1 part of dispersion agent, 2 parts of wetting agents, 0.1 part of defoamer, 0.1 part of sanitas, 0.1 part, sterilant, 2 parts of Lauryl Alcohol esters, 0.5 part of propylene glycol, 1 part of wilkinite, after stirring, take again and drop into 8 parts of TM550 infrared reflecting paints, the cold pigment of white (rutile-type R-706 titanium dioxide) 5 parts, 50 parts of water-ground limestones, 1 part, diatomite, 0.1 part of lignocellulose, 4 parts of talcum powder, after continuing to mix with 400-1000 rotating speed, dropping into kneader mediates evenly again, with AMP-95, regulate PH=7-9, when putty paste water content is too high, it is suitable that application thickening material is thickened to denseness, be white putty paste, can pack warehouse-in stand-by.
Embodiment 2
Take 3 parts of pure water, 0.2 part of the carboxymethyl propyl cellulose of 100000 viscosity, infrared reflecting paint TM8008 part, 2 parts, cold pigment rouge and powder, after fully mixing, take again 20 parts of synthetic resins fluorine carbon emulsions, 20 parts of elastomeric propylene yogurt liquid, 1 part of dispersion agent, 0.5 part of wetting agent, 0.2 part of sanitas, 1 part of Lauryl Alcohol ester, 1 part of propylene glycol, 10 parts of fine particle calcium carbonates, 60 parts of coarse whitings, 2 parts of lignocelluloses, mix and adjust and drop into screw extrusion press after PH=7-10 and mix and extrude, this product denseness adds water and adjusts rare when too thick, when denseness is too rare, with thickening material thickening, regulate, repeat to mix and extrude once, be red putty paste, packing warehouse-in is standby.
Embodiment 3
Take 20 parts of polyurethane elastic emulsions, 20 parts of elastic styrene acrylic emulsions, 5 parts of pure water, 0.3 part of the Natvosol of 30000 viscosity, 1 part of dispersion agent, 0.6 part of wetting agent, 0.2 part, sterilant, 1.5 parts of Lauryl Alcohol esters, 0.5 part of propylene glycol, 0.5 part of lignocellulose, after feeding intake respectively, low speed is dispersed to evenly, adjust after PH=7-10, take successively again and drop into 5 parts of wollastonite powder, 1 part, diatomite, infrared reflecting paint TM5507 part, 1 part of cold pigment bloom, 60 parts of dicalcium powders, 1 part of lignocellulose, the speed turning with 400-1000 drops into kneader and mediates evenly after mixing, adjust PH=7-10, pasty consistence should be and is suitable for construction for highest standard, be yellow putty paste.
Embodiment 4
Take 15 parts of pure acrylic acid synthetic resin emulsions, 30 parts of silicon acrylate elastic emulsions, 8 parts of pure water, 0.1 part of the Natvosol of 50000 viscosity, 0.5 part of dispersion agent, 0.2 part of sanitas, 0.1 part, sterilant, 0.5 part of wetting agent, 2 parts of Lauryl Alcohol esters, after low speed (400-1000 turns) dispersing and mixing, drop into successively 1 part, barium sulfate, 2 parts of cold Pigment greens, infrared reflecting paint TM55010 part, 65 parts of dicalcium powders, 6 parts of the hollow glass micropearls of 325 order fineness, 6 parts of the hollow glass micropearls of 325 order fineness, 3 parts of lignocelluloses, middling speed mixes the banburying of rear input Banbury mixer to completely even, and the integrity of attention protection hollow glass micropearl, after qualified by mortar consistency determining apparatus check denseness, be green putty paste, packing warehouse-in is standby.
Embodiment 5
Take 10 parts of EVA emulsions, 35 parts of pure acrylate elastic emulsions, 7 parts of pure water, 0.12 part of the carboxymethyl of 50000 viscosity (CMC) Mierocrystalline cellulose, 0.5 part of dispersion agent, 0.1 part of sanitas, 0.5 part of Lauryl Alcohol ester, regulate after PH=7-10, take again 0.5 part of cold Pigment black, dust health powder TK501W15 part, 5 parts of cold Pigment whites (R-902 titanium dioxide), 60 parts of dicalcium powders, 5 parts of the hollow haydites of 300 order fineness, 0.5 part of lignocellulose, after turning the mixing of middling speed mixing machine with 400-1000, input kneader is kneaded into homogeneous paste, after adjusting PH and denseness, be the reflective insulation putty paste of grey, after quality inspection, packing warehouse-in is standby.

Claims (10)

1. a reflective insulation color lacquer putty cream, is characterized in that being grouped into by the one-tenth of following weight part:
Infrared external reflection heat-insulation functional material 4-50 part;
Cold pigment 1-15 part;
Pure water 1-20 part;
Synthetic resin emulsion 10-50 part;
Auxiliary agent 5-20 part;
Filler 50-80 part.
2. a kind of reflective insulation color lacquer putty cream as claimed in claim 1, it is characterized in that: by the near infrared ray that is 750-2500nm light wave to sunlight and wavelength, one or more in the powder body material of reflection function and the hollow glass bead of the above fineness of 200 order and the hollow haydite of the above fineness of 200 orders are formed described infrared external reflection heat-insulation functional material, it is the TM550 type that Britain Huntsman Corporation produces that the described near infrared ray that is 750-2500nm light wave to sunlight and wavelength has the powder body material of reflection function, TM800 type infrared reflecting paint and Shanghai generation exhibition chemical industry product TK501W type dust health powder.
3. a kind of reflective insulation color lacquer putty cream as claimed in claim 1, is characterized in that: one or more in the of all kinds cold pigment that described cold pigment is produced or sold by Britain Huntsman Corporation, Shanghai Shi Zhan chemical company, upper sea God's promise company are formed.
4. a kind of reflective insulation color lacquer putty cream as claimed in claim 3, is characterized in that: described cold pigment series is one or more the combination in redness, yellow, blue look, green, brown, white and their induced color.
5. a kind of reflective insulation color lacquer putty cream as claimed in claim 1, is characterized in that: described synthetic resin emulsion is one or more the combination in water-soluble silicon acrylate elastic emulsion, pure acrylate elastic emulsion, phenylpropyl alcohol elastic emulsion, fluorine carbon emulsion, polyaminoester emulsion, acrylate and vinyl acetate emulsion, aqueous epoxy emulsion EVA emulsion and their soluble derivative.
6. a kind of reflective insulation color lacquer putty cream as claimed in claim 1, is characterized in that: two or more the combination of described auxiliary agent in ether of cellulose, wilkinite, dispersion agent, wetting agent, sanitas, sterilant, Lauryl Alcohol ester, propylene glycol, defoamer, PH conditioning agent, lignocellulose, thickening material.
7. a kind of reflective insulation color lacquer putty cream as claimed in claim 1, is characterized in that: described filler is two or more the combination in water-ground limestone, light calcium carbonate, silica powder, wollastonite powder, talcum powder, marble dust, diatomite, blaue fixe.
8. a kind of reflective insulation color lacquer putty cream as claimed in claim 7, is characterized in that: described ether of cellulose is one or more the combination in Natvosol, carboxymethyl propyl cellulose, carboxymethyl cellulose.
9. a kind of preparation method of reflective insulation color lacquer putty cream described in claim 1, is characterized in that: water-soluble synthetic resin emulsion, auxiliary agent, filler, infrared external reflection heat-insulation functional material, cold pigment are mixed in dispersion cup.
10. a kind of preparation method of reflective insulation color lacquer putty cream as claimed in claim 9, is characterized in that: adopt thickening material or with pure water, carry out the denseness of accommodation reflex insulating color putty paste.
CN201410430946.1A 2014-08-28 2014-08-28 Reflectively thermal-insulation color putty paste Pending CN104151907A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962125A (en) * 2015-06-17 2015-10-07 安徽省七博士化工新材料有限公司 Zirconia-doped rare earth modified interior wall putty powder and preparing method thereof
CN105199467A (en) * 2015-10-23 2015-12-30 广西兴安县桂兴矿粉厂 Environment-friendly putty powder
CN105820691A (en) * 2016-05-13 2016-08-03 上海绿特丹保温工程有限公司 Thin antistatic reflective heat-insulation wall coating
CN105924631A (en) * 2016-06-03 2016-09-07 滁州市龙飞化工有限公司 Alkyd resin for industrial varnish baking and adhesion promoter thereof
CN105936666A (en) * 2016-06-03 2016-09-14 滁州市龙飞化工有限公司 Alkyd resin for PU wood lacquer and adhesion promoter thereof
CN105949446A (en) * 2016-06-03 2016-09-21 滁州市龙飞化工有限公司 Alkyd resin for air-drying paint and adhesion promoter of alkyd resin
CN106147413A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 The sprayable water-repellent paint of a kind of reflection and heat insulation
CN106189547A (en) * 2016-07-29 2016-12-07 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106243845A (en) * 2016-07-29 2016-12-21 浙江春明防水建材有限公司 A kind of transparent rapid hardening environment-friendly type building water-repellent paint
CN107090201A (en) * 2017-06-07 2017-08-25 湖北工业大学 A kind of preparation method of putty paste
CN108276873A (en) * 2018-02-05 2018-07-13 合肥峰腾节能科技有限公司 A kind of low thermal conductivity environmental protection coating material and preparation method thereof
US10570308B2 (en) 2016-07-08 2020-02-25 Akzo Nobel Coatings International B.V. Heat insulating coating composition, method for applying such coating composition and kit of parts comprising such coating composition
CN111040623A (en) * 2019-12-26 2020-04-21 常州佳尔科仿真器材有限公司 Special functional heat-insulation and temperature-reduction coating and preparation method thereof
CN111269630A (en) * 2020-04-23 2020-06-12 南宁居得适涂料有限公司 Preparation method of stone-like paint for heat insulation of inner and outer walls
CN112063218A (en) * 2020-10-27 2020-12-11 安徽天锦云节能防水科技有限公司 Sound-insulation and heat-preservation putty for buildings and preparation method thereof
CN116814109A (en) * 2023-06-27 2023-09-29 西安德润九州新材料有限公司 High-crack-resistance leveling putty and preparation method thereof

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962125A (en) * 2015-06-17 2015-10-07 安徽省七博士化工新材料有限公司 Zirconia-doped rare earth modified interior wall putty powder and preparing method thereof
CN105199467A (en) * 2015-10-23 2015-12-30 广西兴安县桂兴矿粉厂 Environment-friendly putty powder
CN105820691A (en) * 2016-05-13 2016-08-03 上海绿特丹保温工程有限公司 Thin antistatic reflective heat-insulation wall coating
CN105924631A (en) * 2016-06-03 2016-09-07 滁州市龙飞化工有限公司 Alkyd resin for industrial varnish baking and adhesion promoter thereof
CN105936666A (en) * 2016-06-03 2016-09-14 滁州市龙飞化工有限公司 Alkyd resin for PU wood lacquer and adhesion promoter thereof
CN105949446A (en) * 2016-06-03 2016-09-21 滁州市龙飞化工有限公司 Alkyd resin for air-drying paint and adhesion promoter of alkyd resin
US10570308B2 (en) 2016-07-08 2020-02-25 Akzo Nobel Coatings International B.V. Heat insulating coating composition, method for applying such coating composition and kit of parts comprising such coating composition
CN106243845A (en) * 2016-07-29 2016-12-21 浙江春明防水建材有限公司 A kind of transparent rapid hardening environment-friendly type building water-repellent paint
CN106189547A (en) * 2016-07-29 2016-12-07 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106189547B (en) * 2016-07-29 2018-09-25 浙江春明防水建材有限公司 A kind of environmental protection rapid hardening building water-proof paint
CN106147413B (en) * 2016-07-29 2018-10-09 浙江春明防水建材有限公司 A kind of water-repellent paint that reflection and heat insulation is sprayable
CN106147413A (en) * 2016-07-29 2016-11-23 浙江春明防水建材有限公司 The sprayable water-repellent paint of a kind of reflection and heat insulation
CN107090201A (en) * 2017-06-07 2017-08-25 湖北工业大学 A kind of preparation method of putty paste
CN107090201B (en) * 2017-06-07 2019-08-09 湖北工业大学 A kind of preparation method of putty paste
CN108276873A (en) * 2018-02-05 2018-07-13 合肥峰腾节能科技有限公司 A kind of low thermal conductivity environmental protection coating material and preparation method thereof
CN111040623A (en) * 2019-12-26 2020-04-21 常州佳尔科仿真器材有限公司 Special functional heat-insulation and temperature-reduction coating and preparation method thereof
CN111269630A (en) * 2020-04-23 2020-06-12 南宁居得适涂料有限公司 Preparation method of stone-like paint for heat insulation of inner and outer walls
CN112063218A (en) * 2020-10-27 2020-12-11 安徽天锦云节能防水科技有限公司 Sound-insulation and heat-preservation putty for buildings and preparation method thereof
CN116814109A (en) * 2023-06-27 2023-09-29 西安德润九州新材料有限公司 High-crack-resistance leveling putty and preparation method thereof

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Application publication date: 20141119