CN102535790A - High-emulation elastic outer wall decoration panel and manufacturing method thereof - Google Patents

High-emulation elastic outer wall decoration panel and manufacturing method thereof Download PDF

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Publication number
CN102535790A
CN102535790A CN2012100546134A CN201210054613A CN102535790A CN 102535790 A CN102535790 A CN 102535790A CN 2012100546134 A CN2012100546134 A CN 2012100546134A CN 201210054613 A CN201210054613 A CN 201210054613A CN 102535790 A CN102535790 A CN 102535790A
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Prior art keywords
flexible
carcass
elastic outer
layer
facing plate
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CN2012100546134A
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夏良强
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Yantai Tonghua Waterproof & Thermal Insulation Engineering Co Ltd
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Yantai Tonghua Waterproof & Thermal Insulation Engineering Co Ltd
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Priority to CN2012100546134A priority Critical patent/CN102535790A/en
Publication of CN102535790A publication Critical patent/CN102535790A/en
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Abstract

The invention discloses a high-emulation outer wall decoration panel. The high-emulation outer wall decoration panel is characterized in that a flexible transparent protection layer is used as a surface layer; a drawing pattern layer is used as a middle layer; a flexible carcass layer is used as a bottom layer; according to the flexible carcass layer, one surface of non-woven fabric is compounded with a polymer mortar layer to be used as a bonding surface of the flexible carcass layer; the other surface of the non-woven fabric is compounded with true tone slurry to be used as a drawing surface of the flexible carcass layer; drawing patterns are subjected to transfer printing on the drawing surface by printing or using a transfer printing film to form a drawing pattern layer; and the flexible transparent protection layer is coated on the drawing pattern layer. The high-emulation outer wall decoration panel disclosed by the invention is obtained by using a series of work procedures such as production of the flexible carcass bonding surface, preparation of true stone slurry, production of the flexible carcass drawing surface, drawing and printing, production of flexible transparent protection layer and production of finished products; and the obtained products can be quickly constructed in a large area, is vivid in decoration effect and has low possibility of being polluted by a bonding agent.

Description

A kind of high emulation elastic outer wall facing plate and preparation method thereof
 
Technical field
The present invention relates to a kind of exterior wall finish plate, particularly relate to a kind of high emulation elastic outer wall facing plate and preparation method thereof.
Background technology
At present; The stone material that decoration of exterior wall both domestic and external is commonly used, ceramic veneer etc.; General heavy, hard, frangible, the high energy consumption of matter is applied in that Chang Yin is pasted not strongly on the body of wall, comes off and be prone to cause; Cause public harm because of it has radioactive pollution, its matter is heavy, can cause the accident such as hurt sb.'s feelings of pounding after hard the coming off.Along with the continuous appearance of imitative ceramic novel flexible face brick, disclosing some flexible decorative facing bricks in recent years, is 200610171046.5 a kind of flexible decorative panel (brick) as disclosing a kind of application number in the prior art; It is made up of cement sheet layer, prime coat, decorative layer and cover enamelled coating, and the cement sheet material scribbles one deck acrylic primer as bottom on the cement sheet material; Spray one deck ornament materials then; Be coated with one deck finish again, after the oven dry, cut into decorative panel (brick) and get final product.200910230638.3 a kind of flexible decorative facing brick and production technology thereof a kind of application number are also disclosed in the prior art are; It is that it is to adopt sheet material as basic unit's carcass 1; The color sand sizing material of polymer on it is as the body 2 of brick; Clear dope through blade coating, baking, spraying, cutting action, is produced flexible decorative facing brick as brick face topping 3.Its production technology is subsequent use for making the sheet material carcass in advance; With natural colour sand clean, screening, oven dry, then by weight the natural colour sand and 35%~45% polymer emulsion that take by weighing 55%~65%, put into the color sand sizing material preparation of polymer still, stir, it is subsequent use to produce polymer coloured silk sand sizing material; The sheet material carcass is incorporated on the set platform of flexible decorative facing brick production line, adds the color sand sizing material of polymer on it, carry out blade coating, pressing, annular knurl, piecemeal after, get into streamline and dewater, dry; Spraying clear dope brick face topping; By size cutting, packing.Though these tapestry bricks have improved the defective that decoration of exterior wall stone material, ceramic veneer exist; But because of its size less than normal, time-consuming when pasting, and very easily receive the pollution of cementing agent; Its color, pattern are more single; Decorative effect relatively poor (especially stone imitation pattern is not true to nature) therefore, receives bigger restriction in practical application.
Summary of the invention
The object of the invention is exactly to the defective that exists in the above-mentioned prior art; A kind of high emulation elastic outer wall facing plate is provided; This facing plate not only can be realized the large tracts of land rapid construction; And its decorative effect is true to nature, is not subject to the pollution of cementing agent, and the present invention simultaneously also wants to provide the preparation method of this high emulation elastic outer wall facing plate.
For realizing that the technical scheme that above-mentioned purpose of the present invention adopts is: a kind of high emulation elastic outer wall facing plate; It is characterized in that adopting the flexible and transparent topping as surface layer; The middle level is the layer that paints, and bottom then is flexible body piles, and described flexible body piles contain reinforcement material; Its bottom surface is that the flexible carcass that polymer mortar is processed is pasted face; The flexible carcass drawing face that end face is then processed for true stone slurry will paint through printing or transfer film is needed on and constitutes the layer that paints on the drawing face, and the flexible and transparent topping then is coated on the layer that paints.
Described reinforcement material can adopt at least a of nonwoven or grid cloth.
A kind of method of making above-mentioned high emulation elastic outer wall facing plate is characterized in that following these steps to carry out:
1, making polymer cement sheet material carcass is that flexible carcass is pasted face: polymer mortar is pressed on the slurry platform of polymer cement sheet material carcass production line; Reinforcement material is incorporated on the slurry platform; Through coating, pressing, oven dry, winding process, it is subsequent use to produce polymer cement sheet material carcass on streamline;
2, the true stone slurry of preparation: natural colour sand is cleaned, screens, dries, take by weighing natural colour sand 55%~65%, polymer emulsion 35%~45% according to percentage by weight then, put into the preparation still, stir, it is subsequent use to produce true stone slurry;
3, make flexible carcass drawing face: the polymer cement sheet material carcass of making is incorporated on the set platform of high emulation elastic outer wall facing plate tinuous production; Adding true stone slurry applies; Under 40 ℃-80 ℃ environment, flattening dehydration under 50 ℃-90 ℃ environment, oven dry, polishing on the streamline;
4, drawing is printed: on flexible carcass drawing face, print or pattern transferring, make and paint;
5, make the flexible and transparent topping: on the aspect of painting, the coating flexible clear dope dehydrates under 70 ℃-90 ℃ condition in the streamline drying tunnel, makes high emulation elastic outer wall facing plate;
6, make finished product: the high emulation elastic outer wall facing plate that will make by standard size cuts, rolling, check, packing get final product.
Prepared polymer cement sheet material carcass can be a composition polymer mortar at reinforcement material, also can be at two faces of reinforcement material composition polymer mortar all, is preferably a composition polymer mortar at reinforcement material.
When composition polymer mortar at reinforcement material, apply true stone slurry at the another side that does not have the composition polymer mortar of reinforcement material, make flexible carcass drawing face.
Described polymer emulsion is preferably processed by following materials of weight proportions: emulsion polymerization 25%~35%, thickener 0.5%~1%, coalescents 2%~6%, deionized water 28%~36%, solid flame retardant 25%~33%.
Described polymer mortar is to process after being mixed by the weight ratio of 1:1.5~2 by bonding adhesive and inorganic powder.
Described bonding adhesive is processed by following materials of weight proportions: emulsion polymerization 75-85 %, fire retardant 5-10%, coalescents 1-6%, deionized water 5-10%, thickener 0-1.5%.
Described inorganic powder is processed by following materials of weight proportions: quartz sand 20-30%, powdered whiting 20-30%, solid flame retardant 5-15%, cement 25-35%.
Cement preferably adopts at least a in PO425 cement or the white portland cement.
Described pattern transferring is to adopt the pattern of transfer film through the transfer interpreter transfer printing.Transfer film can comprise any transfer films applicatory such as heat transfer film, light transfer film or water transfer printing film, and transfer interpreter can comprise any suitable transfer interpreters such as heat transfer machine, light transfer interpreter, water transfer interpreter.
The printing that paints is to obtain photo through camera or computer earlier; Then the photo pattern is input to omnipotent printing of inkjet printer to the drawing face of flexible body piles; Perhaps the photo pattern is printed to earlier on transfer film such as heat transfer film, light transfer film or the water transfer printing film, be transferred on the drawing face of flexible body piles through corresponding transfer interpreter again.
High emulation elastic outer wall facing plate according to method of the present invention is made not only has pliability, weatherability preferably, and has high simulated decorative effect; Its make efficiency is high, need not high temperature sintering, energy-conserving and environment-protective; It is simple and easy quick to construct, and as the same rapid construction of wallpapering work, the high resiliency that product had can guarantee that body of wall or thermal insulation dehiscence line stop at this; Its long service life has than vast market prospect.
Description of drawings
Fig. 1 is the structural representation of an embodiment of the present invention.
Fig. 2 is the structural representation of the another kind of embodiment of the present invention.
The specific embodiment
For specifying the present invention, below in conjunction with the example of accompanying drawing and practical implementation the present invention is done further detailed description, yet said embodiment should not explain with the mode of restriction.
Embodiment 1:
Can find out among the embodiment that provides by Fig. 1; The present invention contains flexible and transparent topping (being surface layer) 1, layer (being the middle level) 2, flexible body piles (bottom) 3 paint; Flexible body piles 3 are to paste face 5 at a composition polymer mortar of reinforcement material 4 as flexible carcass; The compound true stone slurry of another side is as drawing face 6, will paint through printing or transfer film is needed on and processes the layer 2 that paints on the drawing face 6, and 1 of flexible and transparent topping is coated on the layer 2 that paints.
The concrete production method of above-mentioned high emulation elastic outer wall facing plate is following:
1, making polymer cement sheet material carcass is that flexible carcass is pasted face: earlier reinforcement material is incorporated on the slurry platform of polymer cement sheet material carcass production line; Again polymer mortar is pressed on the slurry platform of polymer cement sheet material carcass production line; Polymer mortar and reinforcement material converge and evenly cover on it on the slurry platform; Through pressing, oven dry, winding process, the polymer cement sheet material carcass of producing 0.6 mm~0.8 mm is subsequent use on streamline.This polymer cement sheet material carcass is that the one side at reinforcement material is compounded with polymer mortar.
Polymer mortar is to adopt bonding adhesive and inorganic powder in stir back and making of the ratio of 1:1.5~2.
Above-mentioned bonding adhesive is processed by following materials of weight proportions: emulsion polymerization 75-85 %, fire retardant 5-10%, coalescents 1-6%, deionized water 5-10%, thickener 0-1.5%.In this ratio, take by weighing raw material and put into agitator, stirring gets final product.
Example: can press column weight amount ratio and take by weighing raw material:
1., emulsion polymerization 75 %, fire retardant 10%, coalescents 6%, deionized water 8%, thickener 1%.
2., emulsion polymerization 85 %, fire retardant 5%, coalescents 5%, deionized water 5%.
3., emulsion polymerization 79.5 %, fire retardant 8%, coalescents 1%, deionized water 10%, thickener 1.5%.
Inorganic powder is processed by following materials of weight proportions: quartz sand 20-30%, powdered whiting 20-30%, solid flame retardant 5-15%, PO425 cement (or white portland cement) 25-35%.In this ratio, take by weighing raw material and put into agitator, stirring gets final product.
Example: can press column weight amount ratio and take by weighing raw material:
1., quartz sand 20%, powdered whiting 30%, solid flame retardant 15%, PO425 cement (or white portland cement) 35%.
2., quartz sand 30%, powdered whiting 30%, solid flame retardant 15%, PO425 cement (or white portland cement) 25%.
3., quartz sand 30%, powdered whiting 30%, solid flame retardant 5%, PO425 cement (or white portland cement) 35%.
4., quartz sand 28%, powdered whiting 28%, solid flame retardant 13%, PO425 cement (or white portland cement) 31%.
5., quartz sand 30%, powdered whiting 20%, solid flame retardant 15%, PO425 cement (or white portland cement) 35%.
2, the true stone slurry of preparation: natural colour sand (preferably choosing white) is cleaned, screens, dries; Take by weighing natural colour sand 55%~65%, polymer emulsion 35%~45% according to percentage by weight then; Put into the preparation still, stir, it is subsequent use to produce true stone slurry.
Polymer emulsion is processed by following materials of weight proportions: emulsion polymerization 25%~35%, thickener 0.5%~1%, coalescents 2%~6%, deionized water 28%~36%, solid flame retardant 25%~33%.In this ratio, take by weighing raw material and put into agitator, stirring gets final product.
Example: can press column weight amount ratio and take by weighing raw material:
1., emulsion polymerization 25%, thickener 1%, coalescents 6%, deionized water 36%, solid flame retardant 32%.
2., emulsion polymerization 35%, thickener 0.8%, coalescents 3.2%, deionized water 28%, solid flame retardant 33%.
3., emulsion polymerization 35%, thickener 0.5%, coalescents 5%, deionized water 34.5%, solid flame retardant 25%.
4., emulsion polymerization 32%, thickener 0.8%, coalescents 2%, deionized water 35%, solid flame retardant 30.2%.
3, make the drawing face of flexible carcass: will produce good polymer cement sheet material carcass and be incorporated on the set platform of high emulation elastic outer wall facing plate tinuous production; The one side that does not have the composition polymer mortar at reinforcement material; Adding true stone slurry applies; Under 40 ℃-80 ℃ environment, flattening on the streamline, under 50 ℃-90 ℃ environment, dewatering, dry, polish, making the flexible carcass drawing face of 0.8mm-1mm.
4, drawing is printed: on flexible carcass drawing face; Adopt omnipotent ink-jet printer directly to print or adopt transfer film, make that obtaining (marble, granite, Art Stone, jade, agate or personage's landscape painting etc.) true to nature on the drawing face of flexible carcass paints through the transfer interpreter transfer printing.
More particularly; The printing that paints is to obtain photo through camera, computer earlier; Then the photo pattern is input to omnipotent printing of inkjet printer to the drawing face of flexible body piles; Perhaps earlier the photo pattern is printed on transfer film such as heat transfer film, light transfer film or the water transfer printing film, be transferred on the drawing face of flexible body piles through corresponding transfer interpreter.
Transfer interpreter can be selected any suitable transfer interpreters such as heat transfer machine, light transfer interpreter or water transfer interpreter for use.
5, make the flexible and transparent topping: after printing on the drawing face of flexible carcass paints, adopt the technology coating flexible clear dope of spraying or roller coat, in 70 ℃-90 ℃ drying tunnel, dehydrate, make high emulation elastic outer wall facing plate.
The technology of spraying or roller coat is common process of the prior art, just no longer repeats here.
Flexible and transparent coating can adopt the water-based Silicone acrylic emulsion that has excellent weather resistance, benzene emulsion, pure-acrylic emulsion, flexible fluorine carbon varnish, polyurethane lacquer, polyureas varnish in the mixture of any or several kinds.
6, make finished product: the high emulation elastic outer wall facing plate that will make, by standard size cut, rolling, check, packing get final product.
Embodiment 2:
Can find out among the embodiment that provides by Fig. 2; The present invention contains flexible and transparent topping (being surface layer) 1, layer (being the middle level) 2, flexible body piles (bottom) 3 paint; In flexible body piles 3; At all compound one layer of polymeric mortar of two faces of reinforcement material 4, one side is wherein pasted face 5 as flexible carcass, and on the upper surface of the polymer mortar layer 7 of another side the true stone slurry of compound again one deck as drawing face 6; To paint through printing or transfer film is needed on and processes the layer 2 that paints on the drawing face 6,1 of flexible and transparent topping is coated on the layer 2 that paints.
Reinforcement material can adopt at least a of nonwoven or grid cloth.
The concrete production method of above-mentioned high emulation elastic outer wall facing plate is following:
1, making polymer cement sheet material carcass is that flexible carcass is pasted face: earlier polymer mortar is joined on the slurry platform of polymer cement sheet material carcass production line; Then reinforcement material is incorporated on the slurry platform of polymer cement sheet material carcass production line; Reinforcement material is positioned at polymer mortar; Also promptly all contain polymer mortar at two faces of reinforcement material, through pressing, oven dry, winding process, the polymer cement sheet material carcass of producing 0.6 mm~0.8 mm is subsequent use on streamline.This polymer cement sheet material carcass is that two faces at reinforcement material all are compounded with polymer mortar, and one side wherein can be used as flexible carcass and pastes face.
2, the true stone slurry of preparation, method is with embodiment 1.
3, make the drawing face of flexible carcass: will produce good polymer cement sheet material carcass and be incorporated on the set platform of high emulation elastic outer wall facing plate tinuous production; Adding true stone slurry applies; Under 40 ℃-80 ℃ environment, flattening on the streamline; Under 50 ℃-90 ℃ environment, dewater, dry, polish, make the drawing face of the flexible carcass of 0.8mm-1mm.
4, drawing is printed: method is with embodiment 1.
5, make the flexible and transparent topping: method is with embodiment 1.
6, make finished product: method is with embodiment 1.
Said omnipotent ink-jet printer, heat transfer machine, light transfer interpreter, water transfer interpreter and heat transfer film, light transfer film, water transfer printing film are all commercially available homemade or imported product.
Described natural colour sand, nonwoven, fluorine carbon varnish, polyurethane lacquer, polyureas varnish are the commercially available prod.
Described emulsion polymerization can adopt at least a in the following raw materials according of directly buying on the market: pure-acrylic emulsion, benzene emulsion, Silicone acrylic emulsion;
Described thickener can adopt at least a in the following raw materials according of directly buying on the market: TE936, TT935, UH420, GD8201, GD8202, D-105.
Described coalescents can adopt at least a in the following raw materials according of directly buying on the market: CZ-12, TEXANOL.
Described solid flame retardant can adopt at least a in the following raw materials according of directly buying on the market: FRN, PX-200, PBT, MZY.
Above-described polymer cement sheet material carcass production line, high emulation elastic outer wall facing plate tinuous production and each production line are all the common apparatus in the industry; The method of using these equipment to produce is also known as the one of ordinary skilled in the art, no longer repeats here.

Claims (9)

1. one kind high emulation elastic outer wall facing plate; It is characterized in that adopting flexible and transparent topping (1) as surface layer; The middle level is the layer (2) that paints, and bottom then is flexible body piles (3), and described flexible body piles (3) contain reinforcement material (4); Its bottom surface is that the flexible carcass that polymer mortar is processed is pasted face (5); The flexible carcass drawing face (6) that end face is then processed for true stone slurry will paint through printing or transfer film is needed on drawing face (6) and goes up and constitute the layer (2) that paints, and flexible and transparent topping (1) then is coated on the layer (2) that paints.
2. according to the described a kind of high emulation elastic outer wall facing plate of claim 1, it is characterized in that described reinforcement material (4) is at least a of nonwoven or grid cloth.
3. method of making the described high emulation elastic outer wall facing plate of claim 1 is characterized in that following these steps to carry out:
1., making polymer cement sheet material carcass is that flexible carcass is pasted face: polymer mortar is pressed on the slurry platform of polymer cement sheet material carcass production line; Reinforcement material is incorporated on the slurry platform; Through coating, pressing, oven dry, winding process, it is subsequent use to produce polymer cement sheet material carcass on streamline;
2., the true stone slurry of preparation: natural colour sand is cleaned, screens, dries, take by weighing natural colour sand 55%~65%, polymer emulsion 35%~45% according to percentage by weight then, put into the preparation still, stir, it is subsequent use to produce true stone slurry;
3., make flexible carcass drawing face: the polymer cement sheet material carcass of making is incorporated on the set platform of high emulation elastic outer wall facing plate tinuous production; Add true stone slurry and apply, on streamline, get final product through flattening, dewater, dry, polishing;
4., drawing prints: on flexible carcass drawing face, print or pattern transferring, make and paint;
5., make the flexible and transparent topping: on the aspect of painting, the coating flexible clear dope dehydrates in drying tunnel, makes high emulation elastic outer wall facing plate;
6., make finished product: the high emulation elastic outer wall facing plate that will make by standard size cuts, rolling, check, packing get final product.
4. according to the method for the high emulation elastic outer wall of the described making of claim 3 facing plate, it is characterized in that described pattern transferring, is to adopt the pattern of transfer film through the transfer interpreter transfer printing.
5. according to the method for claim 3 or the high emulation elastic outer wall of 4 described making facing plate; It is characterized in that the described printing that paints is to obtain photo through camera or computer earlier; Then the photo pattern is input to printing of inkjet printer to flexible carcass drawing face; Perhaps the photo pattern is printed to earlier on the transfer film, be transferred on the flexible carcass drawing face through corresponding transfer interpreter again.
6. according to the method for the high emulation elastic outer wall of the described making of claim 3 facing plate, it is characterized in that prepared polymer cement sheet material carcass is a composition polymer mortar at reinforcement material.
7. according to the method for the high emulation elastic outer wall of the described making of claim 6 facing plate, it is characterized in that applying true stone slurry in the one side that does not have the composition polymer mortar of reinforcement material.
8. according to the method for the high emulation elastic outer wall of the described making of claim 3 facing plate, when it is characterized in that making flexible carcass drawing face, in 40-80 ℃ environment under, flattening on the streamline, under 50-90 ℃ environment, dewater, dry.
9. according to the method for the high emulation elastic outer wall of the described making of claim 3 facing plate, it is characterized in that described polymer mortar is to process after being mixed by the weight ratio of 1:1.5~2 by bonding adhesive and inorganic powder; Described bonding adhesive is processed by following materials of weight proportions: emulsion polymerization 75-85 %, fire retardant 5-10%, coalescents 1-6%, deionized water 5-10%, thickener 0-1.5%; Described inorganic powder is processed by following materials of weight proportions: quartz sand 20-30%, powdered whiting 20-30%, solid flame retardant 5-15%, cement 25-35%; Described polymer emulsion is processed by following materials of weight proportions: emulsion polymerization 25%~35%, thickener 0.5%~1%, coalescents 2%~6%, deionized water 28%~36%, solid flame retardant 25%~33%.
CN2012100546134A 2012-03-05 2012-03-05 High-emulation elastic outer wall decoration panel and manufacturing method thereof Pending CN102535790A (en)

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
CN103821306A (en) * 2014-01-13 2014-05-28 东营瑞源特种建筑材料有限公司 Antipollution high-simulation wall flexible stone facing material and production method thereof
CN103821305A (en) * 2014-01-13 2014-05-28 东营瑞源特种建筑材料有限公司 Antipollution wall flexible stone decorating material and production method thereof
CN103993721A (en) * 2014-04-30 2014-08-20 洛阳德邦建筑科技有限公司 Method for manufacturing sand wall paint surface layer decorative board
CN103993720A (en) * 2014-04-30 2014-08-20 洛阳德邦建筑科技有限公司 Preparation method of natural stone paint surface layer decorative plate
CN104860587A (en) * 2015-05-08 2015-08-26 南通聚仁新材料科技有限公司 Double-layer structure flexible finishing material and preparation method thereof
CN105019624A (en) * 2015-07-31 2015-11-04 长沙怡景建材科技有限公司 Building decoration paster and manufacturing method thereof
CN107253266A (en) * 2017-07-05 2017-10-17 深圳市威锴众润建材科技有限公司 A kind of method of concrete surface pattern-making
CN109080371A (en) * 2018-10-18 2018-12-25 福州市马尾第二实验幼儿园 A kind of drawing board
CN110111665A (en) * 2019-05-10 2019-08-09 谢争光 A kind of sample color rendition method

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CN101713244A (en) * 2009-11-19 2010-05-26 夏良强 Flexible decorative facing brick and production process thereof
CN201679178U (en) * 2010-02-01 2010-12-22 罗华东 Multilayer compound decorative board
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CN101713244A (en) * 2009-11-19 2010-05-26 夏良强 Flexible decorative facing brick and production process thereof
CN201679178U (en) * 2010-02-01 2010-12-22 罗华东 Multilayer compound decorative board
CN202493002U (en) * 2012-03-05 2012-10-17 烟台同化防水保温工程有限公司 High-simulation elastic wood veneer of outer wall

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103821306A (en) * 2014-01-13 2014-05-28 东营瑞源特种建筑材料有限公司 Antipollution high-simulation wall flexible stone facing material and production method thereof
CN103821305A (en) * 2014-01-13 2014-05-28 东营瑞源特种建筑材料有限公司 Antipollution wall flexible stone decorating material and production method thereof
CN103993721A (en) * 2014-04-30 2014-08-20 洛阳德邦建筑科技有限公司 Method for manufacturing sand wall paint surface layer decorative board
CN103993720A (en) * 2014-04-30 2014-08-20 洛阳德邦建筑科技有限公司 Preparation method of natural stone paint surface layer decorative plate
CN104860587A (en) * 2015-05-08 2015-08-26 南通聚仁新材料科技有限公司 Double-layer structure flexible finishing material and preparation method thereof
CN104860587B (en) * 2015-05-08 2017-04-05 南通聚仁新材料科技有限公司 A kind of double-decker flexibility finishing material and preparation method thereof
CN105019624A (en) * 2015-07-31 2015-11-04 长沙怡景建材科技有限公司 Building decoration paster and manufacturing method thereof
CN107253266A (en) * 2017-07-05 2017-10-17 深圳市威锴众润建材科技有限公司 A kind of method of concrete surface pattern-making
CN107253266B (en) * 2017-07-05 2019-05-10 深圳市威锴众润建材科技有限公司 A kind of method of concrete surface pattern-making
CN109080371A (en) * 2018-10-18 2018-12-25 福州市马尾第二实验幼儿园 A kind of drawing board
CN109080371B (en) * 2018-10-18 2024-04-02 福州市马尾第二实验幼儿园 Drawing board
CN110111665A (en) * 2019-05-10 2019-08-09 谢争光 A kind of sample color rendition method

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Application publication date: 20120704