CN105062284A - Water-based water-in-water imitation granite paint and preparation method thereof - Google Patents
Water-based water-in-water imitation granite paint and preparation method thereof Download PDFInfo
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- CN105062284A CN105062284A CN201510511949.2A CN201510511949A CN105062284A CN 105062284 A CN105062284 A CN 105062284A CN 201510511949 A CN201510511949 A CN 201510511949A CN 105062284 A CN105062284 A CN 105062284A
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- water
- defoamer
- protecting glue
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- sterilant
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Abstract
The invention discloses water-based water-in-water imitation granite paint and a preparation method thereof. The paint is prepared from the following raw materials in percentage by weight: 9-10% of water, 0.8-1.2% of an antifreeze, 0.4-0.6% of a film-forming additive, 0.3-0.5% of a defoamer, 0.15-0.25% of a biocide, 25-27% of emulsion, 0.7-0.9% of a thickener, 60% of color grains, wherein the color grains are prepared from water, a protective colloid solution, a stabilizer, a base paint and color paste; the base paint is prepared from water, a thickener, a dispersant, an antifreeze, a film-forming additive, a defoamer, a biocide, titanium dioxide, kaolin, emulsion and a protective colloid solution; the protective colloid solution is prepared from water and protection glue. The water-based water-in-water imitation granite paint provided by the invention solves the problems that the conventional water-based imitation granite paint is uneven in quality and poor in waterproofness, anti-ultraviolet property and flexibility, the color grains are unstable and cracky, the color grain boundary is not clear, and the color grains are not environment-friendly.
Description
Technical field
the present invention relates to building coating technical field, particularly a kind of water-based water-water artificial granite paint and preparation method thereof.
Background technology
building coating has decoration functions, defencive function and livability and improves function.Decoration functions is the function of beautifying the appearance value improving it by buildings.Defencive function refers to architecture protection thing not by the impact of environment and the function of destruction.
in order to pursue wear-resisting, magnificent effect attractive in appearance, people usually decorate outdoor facing with grouan, but grouan cost costly, and reserves are fewer and feweri, and thus the application of grouan material is limited to.In this context, people develop various artificial granite coating, to reach the effect of lithotome.
recent years, the manufacturing enterprise of studies in China aqueousance artificial granite coating is more, but most of aqueousance artificial granite coating quality ginseng is secondary uneven on the market, some water-repellancies, uvioresistant, snappiness are poor, some look grains are unstable easily broken, some look grain obscure boundaries, or containing a large amount of VOC in coating, do not reach the standard of HG/T4343--2012 " aqueous colorful building coating " and GB24408--2009 " in exterior coating for building limits of harmful substances ", drastically influence popularization and the use of aqueousance artificial granite coating.
Summary of the invention
the object of this invention is to provide a kind of water-based water-water artificial granite paint and preparation method thereof, solve aqueousance artificial granite coating quality ginseng secondary uneven, water-repellancy, uvioresistant, snappiness are poor, and look grain is unstable easily broken, look grain obscure boundary, the problem such as not environmentally.
object of the present invention is achieved through the following technical solutions:
a kind of water-based water-water artificial granite paint and preparation method thereof, be prepared from by following weight percent by raw material, water 9-10%, frostproofer 0.8-1.2%, film coalescence aid 0.4-0.6%, defoamer 0.3-0.5%, sterilant 0.15-0.25%, emulsion 25-27%, thickening material 0.7-0.9%, look grain 60%; Described look grain is prepared from by water 5-7%, protecting glue solution 17-19%, stablizer 0.40-0.60%, base paint 34-36%, mill base 37.4-43.6%; Described base paint is prepared from by water 46-49%, thickening material 1-2%, dispersion agent 0.40-0.60%, frostproofer 0.8-1.2%, film coalescence aid 0.40-0.60%, defoamer 0.30-0.50%, sterilant 0.15-0.25%, titanium dioxide 0.8-1.2%, kaolin 3-6%, emulsion 33-37%, protecting glue solution 5-7%; Described protecting glue solution is prepared from by water 92-95%, protecting glue 5-8%.
described a kind of water-based water-water artificial granite paint and preparation method thereof, optimum weight per-cent pressed by raw material, water 9.8%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, emulsion 26%, thickening material 0.8%, look grain 60%.
described look grain Raw presses optimum weight per-cent, water 6%, protecting glue solution 18%, stablizer 0.50%, base paint 35%, mill base 40.5%.
described base paint Raw presses optimum weight per-cent, water 47.8%, thickening material 1.5%, dispersion agent 0.5%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, titanium dioxide 1%, kaolin 5%, emulsion 35%, protecting glue solution 6%.
described protecting glue solution Raw presses optimum weight per-cent, water 93%, protecting glue 7%.
described water is deionized water; Described thickening material is HBR250 thickening material; Described dispersion agent is ammonium salt dispersant A 40; Described frostproofer is propylene glycol frostproofer; Described film coalescence aid is Texanol film coalescence aid; Described defoamer is A10 defoamer; Described sterilant is RS sterilant; Described titanium dioxide is R706 titanium dioxide; Described emulsion new special siloxane-acrylate copolymer emulsion.
the preparation method of described water-based water-water artificial granite paint, the concrete steps of its preparation method are:
step 1, prepare protecting glue solution:
by weight percentage, take water, protecting glue, drop in whipping device, vulgar stirring 30 minutes, protecting glue dissolves without particle, obtained protecting glue solution;
step 2, prepare base paint:
(1) water, thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant, titanium dioxide, kaolin, emulsion, protecting glue solution by weight percentage, is taken;
(2) water is dropped into whipping device, add thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant under low rate mixing, low rate mixing 5 minutes, dissolves completely;
(3) improve mixing speed to high-speed stirring, add titanium dioxide, kaolin, high-speed stirring 25 minutes;
(4) reduce mixing speed to moderate-speed mixer, slowly add emulsion, protecting glue solution, moderate-speed mixer 5 minutes, makes it mix completely, obtained base paint;
step 3, prepare look grain:
(1) base paint and mill base is chosen as requested;
(2) by weight percentage, take water, protecting glue solution, stablizer, base paint, mill base, then adopt granulator granulation, obtained look grain;
step 4, prepare finished product coating:
(1) by weight percentage, required water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain is taken, for subsequent use;
(2) open whipping device, under low rate mixing, add water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain, low rate mixing 5 minutes, obtained finished product coating.
beneficial effect of the present invention:
a kind of water-based water-water artificial granite paint prepared by the present invention, obtained water-water artificial granite paint possesses following characteristics:
(1) weathering resistance, alkali resistance, snappiness, self-cleaning, anti-ultraviolet property are splendid, not fugitive color;
(2) coatingsurface is concavo-convex submissive, and color interpenetrates, and in spraying process, look grain bursts forth naturally, creates the aesthetic feeling especially as natural granite;
(3) environmental protection and energy saving: meet the environmental requirement of country to building coating completely, complete Water-borne modification, VOC content is extremely low.In the decoration of exterior wall, multicolor finish lighter in weight, the body of wall that it can not give year of a specified duration brings load-bearing, the valuable stone material that substitutable resources is increasingly rare, and external wall outer insulation material can also be coordinated to carry out the artificial grantie decoration of specialty.
Embodiment
below in conjunction with specific embodiment, concrete technical scheme of the present invention is described in further detail.
in an embodiment, described water is deionized water.
described thickening material is HBR250 thickening material.
described dispersion agent is ammonium salt dispersant A 40.
described frostproofer is propylene glycol frostproofer.
described film coalescence aid is Texanol film coalescence aid.
described defoamer is A10 defoamer.
described sterilant is RS sterilant.
described titanium dioxide is R706 titanium dioxide.
described emulsion new special siloxane-acrylate copolymer emulsion.
embodiment 1
a kind of water-based water-water artificial granite paint and preparation method thereof, be prepared from by following weight percent by raw material, water 9-10%, frostproofer 0.8-1.2%, film coalescence aid 0.4-0.6%, defoamer 0.3-0.5%, sterilant 0.15-0.25%, emulsion 25-27%, thickening material 0.7-0.9%, look grain 60%; Described look grain is prepared from by water 5-7%, protecting glue solution 17-19%, stablizer 0.40-0.60%, base paint 34-36%, mill base 37.4-43.6%; Described base paint is prepared from by water 46-49%, thickening material 1-2%, dispersion agent 0.40-0.60%, frostproofer 0.8-1.2%, film coalescence aid 0.40-0.60%, defoamer 0.30-0.50%, sterilant 0.15-0.25%, titanium dioxide 0.8-1.2%, kaolin 3-6%, emulsion 33-37%, protecting glue solution 5-7%; Described protecting glue solution is prepared from by water 92-95%, protecting glue 5-8%.
the concrete steps of its preparation method are:
step 1, prepare protecting glue solution:
by weight percentage, take water, protecting glue, drop in whipping device, vulgar stirring 30 minutes, protecting glue dissolves without particle, obtained protecting glue solution;
step 2, prepare base paint:
(1) water, thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant, titanium dioxide, kaolin, emulsion, protecting glue solution by weight percentage, is taken;
(2) water is dropped into whipping device, add thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant under low rate mixing, low rate mixing 5 minutes, dissolves completely;
(3) improve mixing speed to high-speed stirring, add titanium dioxide, kaolin, high-speed stirring 25 minutes;
(4) reduce mixing speed to moderate-speed mixer, slowly add emulsion, protecting glue solution, moderate-speed mixer 5 minutes, makes it mix completely, obtained base paint;
step 3, prepare look grain:
(1) base paint and mill base is chosen as requested;
(2) by weight percentage, take water, protecting glue solution, stablizer, base paint, mill base, then adopt granulator granulation, obtained look grain;
step 4, prepare finished product coating:
(1) by weight percentage, required water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain is taken, for subsequent use;
(2) open whipping device, under low rate mixing, add water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain, low rate mixing 5 minutes, obtained finished product coating.
embodiment 2
a kind of water-based water-water artificial granite paint and preparation method thereof, optimum weight per-cent pressed by raw material, water 9.8%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, emulsion 26%, thickening material 0.8%, look grain 60%.
embodiment 3
in the present invention, described look grain Raw presses optimum weight per-cent, water 6%, protecting glue solution 18%, stablizer 0.50%, base paint 35%, mill base 40.5%.
embodiment 4
in the present invention; described base paint Raw presses optimum weight per-cent, water 47.8%, thickening material 1.5%, dispersion agent 0.5%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, titanium dioxide 1%, kaolin 5%, emulsion 35%, protecting glue solution 6%.
embodiment 5
in the present invention, described protecting glue solution Raw presses optimum weight per-cent, water 93%, protecting glue 7%.
embodiment 6
the basic mechanical design feature of product prepared by the present invention is as following table 1.
the basic mechanical design feature of a table 1 water-based water-water artificial granite paint
| Project | Index |
| Condition in container | Without lump, in uniform state after stirring |
| Cryostatic stabilization (5 circulations) | Never degenerate |
| Appearance of film | Appearance of film is normal, color, decorative pattern no significant difference compared with bragging about |
| Time of drying (surface drying)/h≤ | 4 |
| Thermal storage stability | Pass through |
| Alkali resistance (48) h | Without exception |
| Water tolerance (96) h | Without exception |
| Abrasion resistance/time >= | 2000 |
| Acid rain resistance (48) h | Without exception |
| Moisture-proof cold cycling (5 times) | Without exception |
| Contamination resistance/level≤ | 2 |
| Resistance to artificial weathering | 1000h is non-foaming, do not peel off, flawless, without efflorescence, without obvious variable color loss of gloss |
water-based water-water artificial granite paint condition in container is without a lump as can be seen from the above table, in uniform state after stirring; Never degenerate after cryostatic stabilization 5 circulations; Appearance of film is normal, color, decorative pattern no significant difference compared with bragging about; Time of drying≤4h; Thermal storage stability is good; Alkali resistance 48h is without exception; Water tolerance 96h is without exception; Abrasion resistance>=2000 time; Acid rain resistance 48h is without exception; Cold and hot 5 circulations of moisture-proof are without exception; Contamination resistance≤2 grade; The 1000h of resistance to artificial weathering is non-foaming, do not peel off, flawless, without efflorescence, without obvious variable color loss of gloss.
The above is only the preferred embodiment of the present invention, those of ordinary skill in the art is to be understood that, modify to technical scheme of the present invention or replace on an equal basis, and not departing from purport and the scope of technical solution of the present invention, it all should be considered as in the middle of right of the present invention.
Claims (7)
1. water-based water-water artificial granite paint and preparation method thereof, it is characterized in that: be prepared from by following weight percent by raw material, water 9-10%, frostproofer 0.8-1.2%, film coalescence aid 0.4-0.6%, defoamer 0.3-0.5%, sterilant 0.15-0.25%, emulsion 25-27%, thickening material 0.7-0.9%, look grain 60%; Described look grain is prepared from by water 5-7%, protecting glue solution 17-19%, stablizer 0.40-0.60%, base paint 34-36%, mill base 37.4-43.6%; Described base paint is prepared from by water 46-49%, thickening material 1-2%, dispersion agent 0.40-0.60%, frostproofer 0.8-1.2%, film coalescence aid 0.40-0.60%, defoamer 0.30-0.50%, sterilant 0.15-0.25%, titanium dioxide 0.8-1.2%, kaolin 3-6%, emulsion 33-37%, protecting glue solution 5-7%; Described protecting glue solution is prepared from by water 92-95%, protecting glue 5-8%.
2. a kind of water-based water-water artificial granite paint according to claim 1 and preparation method thereof, it is characterized in that: raw material by optimum weight per-cent, water 9.8%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, emulsion 26%, thickening material 0.8%, look grain 60%.
3. a kind of water-based water-water artificial granite paint according to claim 1 and preparation method thereof; it is characterized in that: described look grain Raw by optimum weight per-cent, water 6%, protecting glue solution 18%, stablizer 0.50%, base paint 35%, mill base 40.5%.
4. a kind of water-based water-water artificial granite paint according to claim 1 and preparation method thereof; it is characterized in that: described base paint Raw by optimum weight per-cent, water 47.8%, thickening material 1.5%, dispersion agent 0.5%, frostproofer 1%, film coalescence aid 0.5%, defoamer 0.4%, sterilant 0.2%, titanium dioxide 1%, kaolin 5%, emulsion 35%, protecting glue solution 6%.
5. a kind of water-based water-water artificial granite paint according to claim 1 and preparation method thereof, is characterized in that: described protecting glue solution Raw by optimum weight per-cent, water 93%, protecting glue 7%.
6. a kind of water-based water-water artificial granite paint according to claim 1 and preparation method thereof, is characterized in that: described water is deionized water; Described thickening material is HBR250 thickening material; Described dispersion agent is ammonium salt dispersant A 40; Described frostproofer is propylene glycol frostproofer; Described film coalescence aid is Texanol film coalescence aid; Described defoamer is A10 defoamer; Described sterilant is RS sterilant; Described titanium dioxide is R706 titanium dioxide; Described emulsion new special siloxane-acrylate copolymer emulsion.
7. the preparation method of water-based water-water artificial granite paint according to claim 1-7 any one, is characterized in that: the concrete steps of its preparation method are:
Step 1, prepare protecting glue solution:
By weight percentage, take water, protecting glue, drop in whipping device, vulgar stirring 30 minutes, protecting glue dissolves without particle, obtained protecting glue solution;
Step 2, prepare base paint:
(1) water, thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant, titanium dioxide, kaolin, emulsion, protecting glue solution by weight percentage, is taken;
(2) water is dropped into whipping device, add thickening material, dispersion agent, frostproofer, film coalescence aid, defoamer, sterilant under low rate mixing, low rate mixing 5 minutes, dissolves completely;
(3) improve mixing speed to high-speed stirring, add titanium dioxide, kaolin, high-speed stirring 25 minutes;
(4) reduce mixing speed to moderate-speed mixer, slowly add emulsion, protecting glue solution, moderate-speed mixer 5 minutes, makes it mix completely, obtained base paint;
Step 3, prepare look grain:
(1) base paint and mill base is chosen as requested;
(2) by weight percentage, take water, protecting glue solution, stablizer, base paint, mill base, then adopt granulator granulation, obtained look grain;
Step 4, prepare finished product coating:
(1) by weight percentage, required water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain is taken, for subsequent use;
(2) open whipping device, under low rate mixing, add water, frostproofer, film coalescence aid, defoamer, sterilant, emulsion, thickening material, look grain, low rate mixing 5 minutes, obtained finished product coating.
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| CN201510511949.2A CN105062284A (en) | 2015-08-20 | 2015-08-20 | Water-based water-in-water imitation granite paint and preparation method thereof |
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| CN201510511949.2A CN105062284A (en) | 2015-08-20 | 2015-08-20 | Water-based water-in-water imitation granite paint and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419535A (en) * | 2015-12-16 | 2016-03-23 | 亚士漆(上海)有限公司 | Multicolor water-in-water primer-topcoat coating and preparation method thereof |
| CN106883697A (en) * | 2017-02-27 | 2017-06-23 | 河北晨阳工贸集团有限公司 | A kind of dumb light water-in-water multicolor coating |
| CN107418443A (en) * | 2017-07-26 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | A kind of water-based high imitative coating and preparation method thereof |
| CN107474730A (en) * | 2017-09-26 | 2017-12-15 | 阜南县腾祥工艺品有限公司 | A kind of true mineral varnish of artificial granite |
| CN108395740A (en) * | 2018-03-25 | 2018-08-14 | 安徽东泰建筑装饰材料有限公司 | The production method of liquid-state granite coating |
| CN110437693A (en) * | 2019-07-30 | 2019-11-12 | 河北晨阳工贸集团有限公司 | A kind of anti-formaldehyde liquid artificial granite paint of ordor removing and preparation method thereof |
| CN110668734A (en) * | 2018-07-03 | 2020-01-10 | 河南裕彩科技研发有限公司 | Sand-in-sand colorful interior and exterior wall building coating and preparation method thereof |
| CN112646408A (en) * | 2020-08-12 | 2021-04-13 | 安徽雅特兰新材料科技有限公司 | Preparation method of water-in-water colorful stone-like paint |
| CN113502127A (en) * | 2021-08-04 | 2021-10-15 | 重庆凯茜蔓科技有限公司 | Flat-coating granite artistic coating and preparation method thereof |
| CN113527965A (en) * | 2021-07-05 | 2021-10-22 | 濮阳展辰新材料有限公司 | Water-in-water temperature-sensitive color-changing coating and preparation method thereof |
| CN115260885A (en) * | 2022-03-21 | 2022-11-01 | 墙酷新材料(厦门)股份有限公司 | Granite-highly-imitated multicolor paint and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419535A (en) * | 2015-12-16 | 2016-03-23 | 亚士漆(上海)有限公司 | Multicolor water-in-water primer-topcoat coating and preparation method thereof |
| CN106883697A (en) * | 2017-02-27 | 2017-06-23 | 河北晨阳工贸集团有限公司 | A kind of dumb light water-in-water multicolor coating |
| CN107418443A (en) * | 2017-07-26 | 2017-12-01 | 芜湖市三山龙城新材料有限公司 | A kind of water-based high imitative coating and preparation method thereof |
| CN107474730A (en) * | 2017-09-26 | 2017-12-15 | 阜南县腾祥工艺品有限公司 | A kind of true mineral varnish of artificial granite |
| CN108395740A (en) * | 2018-03-25 | 2018-08-14 | 安徽东泰建筑装饰材料有限公司 | The production method of liquid-state granite coating |
| CN110668734A (en) * | 2018-07-03 | 2020-01-10 | 河南裕彩科技研发有限公司 | Sand-in-sand colorful interior and exterior wall building coating and preparation method thereof |
| CN110437693A (en) * | 2019-07-30 | 2019-11-12 | 河北晨阳工贸集团有限公司 | A kind of anti-formaldehyde liquid artificial granite paint of ordor removing and preparation method thereof |
| CN112646408A (en) * | 2020-08-12 | 2021-04-13 | 安徽雅特兰新材料科技有限公司 | Preparation method of water-in-water colorful stone-like paint |
| CN113527965A (en) * | 2021-07-05 | 2021-10-22 | 濮阳展辰新材料有限公司 | Water-in-water temperature-sensitive color-changing coating and preparation method thereof |
| CN113502127A (en) * | 2021-08-04 | 2021-10-15 | 重庆凯茜蔓科技有限公司 | Flat-coating granite artistic coating and preparation method thereof |
| CN115260885A (en) * | 2022-03-21 | 2022-11-01 | 墙酷新材料(厦门)股份有限公司 | Granite-highly-imitated multicolor paint and preparation method thereof |
| CN115260885B (en) * | 2022-03-21 | 2023-08-25 | 墙酷新材料(厦门)股份有限公司 | High-imitation granite multicolor paint and preparation method thereof |
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