CN102660181A - Water-in-water imitation granite multicolor coating and preparation method thereof - Google Patents
Water-in-water imitation granite multicolor coating and preparation method thereof Download PDFInfo
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Abstract
The invention discloses water-in-water imitation granite multicolor coating and a preparation method thereof, belonging to the technical field of building decoration material. The coating comprises the following components: 20-30% of elastic silicone acrylic emulsion, 0.2-1.6% of film forming aid, 1..0-1.5% of propylene glycol, 0.2-3% of 4500 (organically modified bentonite), 6-15% of water, 50-60% of colored particles and a proper amount of thickener; and the raw materials are uniformly mixed to obtain the water-in-water imitation granite multicolor coating. The coating is completely water-based, has extremely low VOC (volatile organic compounds) content, and is real environment-friendly building coating; the colors can be mixed at will, the size of the colored particles can be controlled at will, the colors penetrate into each other, and the coating can imitate natural granite in color and has high imitation property and excellent decoration effect; and the same texture effect same as that of the raw granite can be obtained by the construction technology of one-time spraying and the like, the construction technology is simple and quick, and the problems of unavailable field operation and low imitation property of multiple spraying for painting multiple colors to the conventional raw granite are solved.
Description
Technical field
The present invention is specifically related to a kind of preparation method of water bag water artificial granite multicolor finish, belongs to decorating building art work technical field.
Background technology
Natural granite is good because of its weather resistance; Have excellent decoration and protection effect; In high-grade decoration of exterior wall engineering, use wider. but lithotome is as a kind of hard brittle material; Its material homogeneity is relatively poor, and the flexural strength discreteness is big, in generation, exploitation, the course of processing, can produce some slight and don't detectable internal injuries unavoidably.Though stone material is not born the load of three-dimensional arrangement in curtain wall, must bear the influence of loads such as deadweight, wind, earthquake, deformation of wall and temperature and effect.Even the stone material that therefore uses meets the regulation of national product standard, but still after the several years, has potential safety hazard unavoidably, and involves great expense, certain radiativity is arranged again, consider that from the environmental protection and energy saving aspect its application is downtrending gradually.
Some is approaching on decorative effect though as the true mineral varnish of the artificial granite of one of substitute; Product performance also have performance preferably; But, on color is selected, can not follow one's bent, and product itself still exists, and splitting resistance is poor, contamination resistance not enough because its main raw material is a natural colour sand; Shortcomings such as emulation property difference can only be lacked the application of the alternative grouan of part.
Its principle of aqueous colorful trade sales coating oil-in-water-type multicolor finish different from the past, through adopting the colloid of innovation, the use gel particles replaces oily particle, has significantly reduced organic solvent content in the coating.But water-thinned color coating for internal and external wall at present on the market, its pattern, decorative pattern are tiny, broken unrest mostly, and the coating poor storage stability of processing, difficulty of construction is big, can not satisfy the demand of association area.The researchist complies with the market requirement, has invented water bag water artificial granite multicolor finish.
Summary of the invention
The preparation method who the purpose of this invention is to provide a kind of artificial granite multicolor finish of the full water-based system without organic solvent, multicolour; It has reached the stage that it is difficult to distinguish the true from the false to the simulated effect of grouan; And clear abundant, the environmental protection of floral designs, steady quality; It is higher to have remedied the grouan cost, and difficulty of construction is big, shortcomings such as colorful true mineral varnish floating.
The present invention is able to solve through following technical proposals
A kind of water bag of the present invention water artificial granite multicolor finish is characterized in that it comprises following feed composition and weight percent thereof:
Elasticity organosilicon-modified acrylic emulsion 20%-30%
Film coalescence aid 1 lauryl alcohol ester 0.2%-1.6%
Film coalescence aid 2 terepthaloyl moietie or Ucar 35 1%-1.5%
4500 organic bentonite 0.2%-3%
Deionized water 6%-15%
Self-control colour particles 50%-60%
Thickening material PEMULEN TR2 0.1%-0.3%
The preparation method of a kind of water bag of the present invention water artificial granite multicolor finish is characterized in that having following process and step:
A. make the preparation of colour particles by oneself
(1) preparation of the protection sol solution of about 8% concentration: raw material and weight proportion are: 40 parts in water, and GTS 3.3-3.7 part is added to the water GTS under stirring at low speed, stirs 30min and becomes transparent colloidal liquid, and subsequent use, GTS is a kind of organobentonite;
(2) preparation of white basis lacquer: the raw material and the weight proportion of white basis lacquer are: water 40%-50%, Mierocrystalline cellulose 0.3%-0.8%, PH regulator 0.1%-0.2%, dispersion agent 0.4%-0.6%; Wetting agent 0.1%-0.2%, skimmer 0.2%-0.5%, fungus-proof pesticide 0.05%-0.1%; White titanium pigment 1%-2%, kaolin 10%-15% adds in a mixing bowl by above-mentioned weight part; High speed dispersion to fineness is 20-30 μ m, adds flexible silicon acrylic emulsion 25%-30% again behind the reduction rotating speed, protection glue 6%-12%; Film coalescence aid 0.5%-1%, wetting agent 0.3%-0.5% stirs;
(3) toning: by design requirements, the white basis lacquer use mill base that step (2) is made is deployed into required color respectively, mixes into basic colored paint of all kinds in proportion with different monochromes, mixture colors or polychrome;
(4) colored paint granulation: the protection glue that colored paint that above-mentioned steps is made and step (1) make carries out granulation with the 1:1 weight ratio, processes the different colour particles of color;
(5) colored paint is filtered through 5 orders-30 purpose filter cloth, the size of the concrete required particle of the several certificates of order is confirmed, guarantees to make the particle that reaches the target size size.
B. becoming lacquer craftwork is the preparation of multicolor finish
Get flexible silicon acrylic emulsion 20%-30%, film coalescence aid 0.2%-1.6%, Ucar 35 1%-1.5%; 4500 (organic bentonite) 0.2%-3%, water 6%-15% mixes the back and adds the above-mentioned colour particles 50%-60% that makes; And the thickening material of 0.1%-0.3%; Transfer viscosity to 80-85KU, stir, promptly get water bag water multicolor finish.
Raw materials used characteristics and mechanism among the present invention:
Described emulsion is the elasticity organosilicon-modified acrylic emulsion, and higher ionic dissociation energy makes coating have excellent anti-uv-ray and persistent weathering resistance between reticulated structure that silicon third is filmed and the siliconoxygen bond; Organosilicon has excellent hydrophobic nature, makes between the water-repellancy of filming and the ventilation property to reach balance preferably; In addition, adopt elastic emulsion to prevent wall crazing.
Described film coalescence aid 1 is an alcohol ester 12, avoids the use of harmful film coalescence aid such as gylcol ether.The contriver goes out this formulation for coating material to filler to the especial manufacture that influences of granulation, so the color stuffing composition is reasonable, and the full-aqueous multicolour paint of preparation has environmental protection, steady quality, the controlled advantage of colour particles granulation process.
Described film coalescence aid 2 is terepthaloyl moietie or Ucar 35.
Described 4500 is a kind of through organically-modified wilkinite, and very intensive thixotropy and thickening power can be provided in water.
Described water is deionized water, to prevent the preparation of metals ion contained in the water and impurity effect particle.
Described particle is to carry out the colour particles that granulation makes by colored paint and protection sol solution with the weight ratio of 1:1.
Described thickening material 530 essence are PEMULEN TR2s, are a kind of hydrophobically-modified alkali swelling type thickening materials, and the particularly suitable water-based system can not produce the wire drawing phenomenon in the thixotropy of raising coating and the spraying process.
It is to adopt GTS organic bentonite as protection glue that the present invention makes the used protection glue of colour particles by oneself; Utilize the synusia shape structure of smectite in the wilkinite and can in water or organic solvent, swelling be dispersed into colloid clay characteristic; Insert through ion exchange technique that organic insulating covering agent processes; Have good thickening, thixotropy; Suspension stability, high-temperature stability, oilness, film-forming properties, water tolerance and chemicalstability can guarantee that particle becomes dispersion state and can not assemble to precipitate.
In the preparation that white basis coats with lacquer among the present invention:
Described Mierocrystalline cellulose is two kinds: HBR-250 Natvosol and G-200, two kinds of thickening materials of experiment proof mix use, more can effectively improve the water-retentivity and the thixotropy of base paint.
Described PH regulator is AMP-95, and it is moisture 5% commodity of compound 2-amino-2-methyl-1-propanol.
Described dispersion agent 120v is the acid/acrylic amide type dispersion agent, the dispersion of the rubber-emulsion paint that the white titanium pigment content of suitable high gloss is high.
Described wetting agent 396 and 399 is a kind of non-ionic wetting agents in 396 of slurrying stage use, can improve the dispersion efficiency of color stuffing as dispersing auxiliary; 399 mainly is the lacquering stage that is used for the later stage, is the special modified anion tensio-active agent of 50% activeconstituents, has good wettability and saturated colour system stability at water-based paint system.
Described skimmer 195 is special efficacy skimmers of non-ionic type 100% activeconstituents, and the tackiness agent by latex or emulsion are made has superior froth breaking and deaeration effect to the polyacrylic emulsion.
Described fungus-proof pesticide FE-66 is that isothiazolinone derivatives does not contain formaldehyde, does not contain the universal in-can preservation agent of heavy metal.
Described white titanium pigment is a rutile type, and this type of white titanium pigment lattice is fine and close, stable, has the ultraviolet ability of strong absorption, is difficult for efflorescence, and weathering resistance is good.
Described kaolin is calcined kaolin, and fillers such as the talcum powder that generally uses in the replacement rubber-emulsion paint, coarse whiting make the colour particles of preparation have translucent, possess certain mechanical strength and stability simultaneously and have good suspension property and dry hiding power.
Coating of the present invention has the following advantages:
(1) coating does not add the banned substance of HJ/T201-2005 " environmental labelling product technical requirements water-borne coatings " standard code, product safety, environmental protection in the preparation process;
(2) color can be modulated arbitrarily, and the big I of colour particles is arbitrarily controlled; Just can obtain the grain effect the same through construction technology such as spraying once with former stone, the construction technology simple and fast, what overcome that the true mineral varnish multicolour of conventional grouan repeatedly sprays can not construction operation property and low emulation property;
(3) adopt perfluor silicone resin system, make coating have extremely strong chemicalstability, thereby have excellent anti-uv-ray and persistent weathering resistance.Adopt ceramic mineral dye simultaneously, guarantee its persistent tint retention, reach work-ing life more than 20 years;
(4) deadweight of water bag water multicolor finish is far smaller than true stone material, is fit to very much be sprayed on the external thermal insulation wall surface, has better security and cost performance;
(5) preparation method is simple, is easy to scale operation.
Embodiment
After specific embodiment of the present invention being described at present.
Embodiment 1
(1) preparation of the protection sol solution of about 8% concentration: raw material and weight proportion are: water 400g, and GTS 34g is added to the water GTS under stirring at low speed, stirs 30min and becomes transparent colloidal liquid, and is subsequent use;
(2) preparation of white basis lacquer: the raw material and the weight proportion of white basis lacquer are: water 420g, Mierocrystalline cellulose HBR-250,5g; G200 5g, PH regulator 1.5g, dispersion agent 120V 6g, wetting agent 396 1g, skimmer 195 3g; Fungus-proof pesticide FE-66 1.50g, white titanium pigment 20g, kaolin 100g adds in a mixing bowl by above-mentioned weight part; High speed dispersion to fineness is 20-30 μ m, adds flexible silicon acrylic emulsion 280g again behind the reduction rotating speed, protection glue 120g, film coalescence aid 6g; Ucar 35 10g, wetting agent 5g, thickening material 530 5g, water 11g (mixing the back uses) stirs;
(3) toning: by design requirements, the white basis lacquer use mill base that step (2) is made is deployed into required color respectively, mixes into basic colored paint of all kinds in proportion with different monochromes, mixture colors or polychrome;
(4) colored paint granulation: the protection glue that colored paint that step (3) is made and step (1) make carries out granulation with the 1:1 weight ratio, processes the different colour particles of color.
(5) becoming lacquer craftwork is the preparation of multicolor finish: get flexible silicon acrylic emulsion 20g, film coalescence aid 0.5g, Ucar 35 1g; 4500 10g, water 10g mixes the back and adds the particle 55g that (4) make; Thickening material 3.4g; FE-66 0.1g mixes, and promptly gets water bag water artificial granite multicolor finish.
Embodiment 2
(1) preparation of the protection sol solution of about 8% concentration: raw material and weight proportion are: water 400g, and GTS 35g is added to the water GTS under stirring at low speed, stirs 30min and becomes transparent colloidal liquid, and is subsequent use;
(2) preparation of white basis lacquer: the raw material and the weight proportion of white basis lacquer are: water 440g, Mierocrystalline cellulose HBR-250,4.5g; G200 5.5g, PH regulator 1.0g, dispersion agent 120V 5g, wetting agent 396 1.5g; Skimmer 195 4g, fungus-proof pesticide FE-66 1.00g, white titanium pigment 10g, kaolin 120g; Add in a mixing bowl by above-mentioned weight part, high speed dispersion to fineness is 20-30 μ m, adds flexible silicon acrylic emulsion 250g again behind the reduction rotating speed, protection glue 110g; Film coalescence aid 10g, Ucar 35 8g, wetting agent 4.5g, thickening material 530 8g water 17g (mixing the back uses) stir;
(3) toning: by design requirements, the white basis lacquer use mill base that step (2) is made is deployed into required color respectively, mixes into basic colored paint of all kinds in proportion with different monochromes, mixture colors or polychrome;
(4) colored paint granulation: the protection glue that colored paint that step (3) is made and step (1) make carries out granulation with the 1:1 weight ratio, processes the different colour particles of color.
(5) becoming lacquer craftwork is the preparation of multicolor finish: get flexible silicon acrylic emulsion 22g, film coalescence aid 0.8g, Ucar 35 1.2g; 4500 11.3g, water 7.55g mixes the back and adds the particle 52g that (4) make; Thickening material 5g; FE-66 0.15g mixes, and promptly gets water bag water artificial granite multicolor finish.
Embodiment 3
(1) preparation of the protection sol solution of about 8% concentration: raw material and weight proportion are: water 400g, and GTS 36g is added to the water GTS under stirring at low speed, stirs 30min and becomes transparent colloidal liquid, and is subsequent use;
(2) preparation of white basis lacquer: the raw material and the weight proportion of white basis lacquer are: water 460g, Mierocrystalline cellulose HBR-250 6g; G200 4g, PH regulator 2g, dispersion agent 120V 5.5g, wetting agent 396 1.5g; Skimmer 195 5g, fungus-proof pesticide FE-66 1.0g, white titanium pigment 15g, kaolin 110g; Add in a mixing bowl by above-mentioned weight part, high speed dispersion to fineness is 20-30 μ m, adds flexible silicon acrylic emulsion 260g again behind the reduction rotating speed, protection glue 100g; Film coalescence aid 6g, Ucar 35 8g, wetting agent 3.5g, thickening material 530 5.5g water 7g (mixing the back uses) stir;
(3) toning: by design requirements, the white basis lacquer use mill base that step (2) is made is deployed into required color respectively, mixes into basic colored paint of all kinds in proportion with different monochromes, mixture colors or polychrome;
(4) colored paint granulation: the protection glue that colored paint that step (3) is made and step (1) make carries out granulation with the 1:1 weight ratio, processes the different colour particles of color.
(5) becoming lacquer craftwork is the preparation of multicolor finish: get flexible silicon acrylic emulsion 30g, film coalescence aid 1.5g, Ucar 35 1g; 4500 10g, water 5g mixes the back and adds the particle 50g that (4) make; Thickening material 2.4g; FE-66 0.1g mixes, and promptly gets water bag water artificial granite multicolor finish.
The water bag water artificial granite multicolor finish of above-mentioned preparation according to standard GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion ", carries out technology for detection to it, and the result sees table 1
The reagent source of using in this instance is following:
Dispersion agent: 120V, Giovanni Miami additive company;
Wetting agent: 396, Giovanni Miami additive company;
Wetting agent: 399, Giovanni Miami additive company;
Skimmer: 195, Giovanni Miami additive company;
Sanitas: FE-66, Giovanni Miami additive company;
Thickening material: 530, Giovanni Miami additive company;
The elasticity organosilicon-modified acrylic emulsion, LG-DOW;
HBR250, Shanghai grid trade Co., Ltd;
G200, Shanghai grid trade Co., Ltd;
Aqueous color paste, the Clariant chemical industry;
PH regulator: AMP-95, LG-DOW;
Protection glue: GTS, Giovanni Miami additive company;
4500 (modified alta-muds), Giovanni Miami additive company;
Film coalescence aid 1 (lauryl alcohol ester), Eastman Chemical Company;
White titanium pigment, commercially available;
Kaolin, commercially available (4000 order).
Claims (2)
1.. a water bag water artificial granite multicolor finish is characterized in that it comprises following feed composition and weight proportion thereof:
Elasticity organosilicon-modified acrylic emulsion 20%-30%;
Film coalescence aid 1 lauryl alcohol ester 0.2%-1.6%;
Film coalescence aid 2 terepthaloyl moietie or Ucar 35 1%-1.5%;
4500 organic bentonite 0.2%-3%;
Deionized water 6%-15%;
Self-control colour particles 50%-60%;
Thickening material PEMULEN TR2 0.1%-0.3%.
2.. the preparation method of a water bag water artificial granite multicolor finish is characterized in that having following process and step:
A. make the preparation of colour particles by oneself
(1) preparation of the protection sol solution of about 8% concentration: raw material and weight proportion are: 40 parts in water, and GTS 3.3-3.7 part is added to the water GTS under stirring at low speed, stirs 30min and becomes transparent colloidal liquid, and subsequent use, GTS is a kind of organobentonite;
(2) preparation of white basis lacquer: the raw material and the weight proportion of white basis lacquer are: water 40%-50%, Mierocrystalline cellulose 0.3%-0.8%, PH regulator 0.1%-0.2%, dispersion agent 0.4%-0.6%; Wetting agent 0.1%-0.2%, skimmer 0.2%-0.5%, fungus-proof pesticide 0.05%-0.1%; White titanium pigment 1%-2%, kaolin 10%-15% adds in a mixing bowl by above-mentioned weight part; High speed dispersion to fineness is 20-30 μ m, adds flexible silicon acrylic emulsion 25%-30% again behind the reduction rotating speed, protection glue 6%-12%; Film coalescence aid 0.5%-1%, wetting agent 0.3%-0.5% stirs;
(3) toning: by design requirements, the white basis lacquer use mill base that step (2) is made is deployed into required color respectively, mixes into basic colored paint of all kinds in proportion with different monochromes, mixture colors or polychrome;
(4) colored paint granulation: the protection glue that colored paint that above-mentioned steps is made and step (1) make carries out granulation with the 1:1 weight ratio, processes the different colour particles of color;
(5) the colored paint particle is filtered through 5 orders-30 purpose filter cloth, the size of the concrete required particle of the several certificates of order is confirmed, guarantees to make the particle that reaches the target size size;
B. becoming lacquer craftwork is the preparation of multicolor finish
Get flexible silicon acrylic emulsion 20%-30%, film coalescence aid 0.2%-1.6%, Ucar 35 1%-1.5%; 4500 (organic bentonite) 0.2%-3%, water 6%-15% mixes the back and adds the above-mentioned colour particles 50%-60% that makes; And the thickening material of 0.1%-0.3%; Transfer viscosity to 80-85KU, stir, promptly get water bag water multicolor finish.
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Application publication date: 20120912 |