CN103627272A - Liquid rock particles of artificial granite sand textured coating - Google Patents
Liquid rock particles of artificial granite sand textured coating Download PDFInfo
- Publication number
- CN103627272A CN103627272A CN201310546412.0A CN201310546412A CN103627272A CN 103627272 A CN103627272 A CN 103627272A CN 201310546412 A CN201310546412 A CN 201310546412A CN 103627272 A CN103627272 A CN 103627272A
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- agent
- artificial granite
- liquid
- liquid rock
- coating
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- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 33
- 239000011435 rock Substances 0.000 title claims abstract description 24
- 239000010438 granite Substances 0.000 title claims abstract description 22
- 239000004576 sand Substances 0.000 title claims abstract description 18
- 239000011248 coating agent Substances 0.000 title abstract description 16
- 238000000576 coating method Methods 0.000 title abstract description 16
- 239000002245 particle Substances 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 9
- 229920002678 cellulose Polymers 0.000 claims abstract description 9
- 230000008961 swelling Effects 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 239000003973 paint Substances 0.000 claims description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 235000013618 yogurt Nutrition 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- 238000004581 coalescence Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- -1 phenylethene modified vinylformic acid Chemical class 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000009288 screen filtration Methods 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 230000008676 import Effects 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002585 base Substances 0.000 abstract description 4
- 239000004575 stone Substances 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000007798 antifreeze agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 238000005034 decoration Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000004088 simulation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004566 building material Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses liquid rock particles of an artificial granite sand textured coating. The artificial granite coating is excellent in texture performance, crack resistance, weather fastness and dirt resistance, and also has excellent simulation on natural stone. The liquid rock particles of the artificial granite sand textured coating are prepared from an elastic acrylic emulsion, titanium dioxide, natural painted sand, inorganic powder, inorganic gel, a setting agent, an antifreeze agent, a defoaming agent, a bactericide, a dispersant, an alkali swelling and thickening agent, a cellulose thickening agent, a wetting agent, a coalescing agent and water. The liquid rock particles are capable of causing the decoration effect of the artificial granite coating to be vivider and also causing the artificial granite coating to have excellent weather fastness, acid-base resistance and hardness and natural color and gloss just as the natural stone; the liquid rock particles are used in the artificial granite sand textured coating to achieve the imitation stone effect of single-gun multiple colors.
Description
Technical field
What the present invention related to is a kind of liquid rock grain of artificial granite sandy paint, belongs to building material field.
Background technology
Artificial granite coating has good texture performance, cracking resistance, weathering resistance and anti-pollution, and has the emulation that pair lithotome is good.But, the imitative hardcore that traditional artificial granite coating is used is the color sheet of high molecular polymer latex, the petrochemical materials that its need of production consumption is a large amount of, production unit also will expend a large amount of electric energy, and complex manufacturing, experience tens procedures such as dispersion, grinding, filtration, roller coating, airing, the demoulding, freezing, broken, sub-sieve, packing, produce in process of production waste water, solid waste and dust pollution.Therefore, provide a kind of liquid rock grain of artificial granite sandy paint, promote the decorative effect of artificial granite coating, improve weathering resistance, the resistance to acids and bases of coating, hardness and naturally color and gloss are necessary.
Summary of the invention
The liquid rock grain that the object of this invention is to provide a kind of artificial granite sandy paint, makes the decorative effect of artificial granite coating more true to nature and have weathering resistance, a resistance to acids and bases that lithotome is good, hardness and naturally color and gloss.Overcome tradition and prepare that artificial granite sandy paint is existing need to consume a large amount of petrochemical materialss, production unit also will expend the deficiency of a large amount of electric energy.
Foregoing invention object, is achieved through the following technical solutions: a kind of liquid rock grain of artificial granite sandy paint, is prepared from by the component of following percent by weight: elastomeric propylene yogurt liquid 10%-50%; Titanium dioxide 10%-15%; Natural colour sand 5%-8%; Inorganic powder 3%-5%; Inorganic gel 2%-5%; Setting agent 3%-5%; Antifreezing agent 1%-2%; Defoamer 0.3%-0.8%; Sterilant 0.1%-0.15%; Dispersion agent 0.1%-0.4%; Alkali swelling thickening material 1%-1.5%, cellulose thickener 0.1%-0.2%; Wetting agent 0.1%-0.15%; Film coalescence aid 0.5%-1%; Surplus is water;
The preparation method of the liquid rock grain of artificial granite sandy paint is:
Water is dropped into a mixing bowl, under 300-500 rev/min of speed, add cellulose thickener, stir and add dispersion agent after 10 minutes, defoamer, wetting agent, titanium dioxide, under 800-1200 rev/min of speed, disperse 30 minutes, sand milling, be less than 50 microns to fineness, then under 300-500 rev/min of speed, add elastomeric propylene yogurt liquid, antifreezing agent, film coalescence aid, alkali swelling thickening material, sterilant, stir 30 minutes to even, proceed to kneader, under agitation slowly, add natural colour sand in batches, inorganic powder, inorganic gel, setting agent, to even, with the screen filtration requiring, obtain described liquid rock grain again.
Described elastomeric propylene yogurt liquid is a kind of or arbitrary combination of two kinds in pure acrylic acid synthetic emulsion, phenylethene modified vinylformic acid synthetic emulsion;
Described frostproofer is a kind of of ethylene glycol, propylene glycol or both arbitrary combination;
Described titanium dioxide is a kind of of import rutile-type, domestic rutile-type or both arbitrary combination;
Described defoamer, sterilant, dispersion agent, alkali swelling thickening material, cellulose thickener are the reagent that aqueous architectural coating is conventional, all have merchandise sales;
The grain diameter of described natural colour sand is between 100 microns-1000 microns;
The grain diameter preferable range of described inorganic powder is 1 micron-2000 microns;
Described inorganic gel is one or more the arbitrary combination in silicate, calcium carbonate, magnesium oxide.
Take the present invention of above-mentioned measure, take high molecular synthetic resin emulsion as base-material, adopting the color sand of pure natural and inorganic powder is filler, use inorganic gel as linking agent, through operations such as dispersion, grinding, granulation, sub-sieve, sizings, process liquid rock grain, there is superpower water-fast, weathering resistance, anti-cracking, can combine closely with all kinds of water-based mineral varnish.Liquid rock grain can make the decorative effect of artificial granite coating more true to nature and have weathering resistance, a resistance to acids and bases that lithotome is good, and hardness and naturally color and gloss, used in artificial granite sandy paint, can reach the colorful imitative stone effect of single rifle.Liquid rock grain prepared by the present invention is special innovative technology manufacture, it is the softness that differs in size of 1-12mm and there is elastic irregular sheet molectron, the color of every kind of liquid rock grain all consists of natural inorganic element, will never change colour, resistance to fire-retardant, color or shape are all to form according to grain color, configuration of surface manufacture in natural grouan, can make the decorative effect nondiscoloration of coating and not affect coating property.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described in detail, but the invention is not restricted to these embodiment.
Embodiment 1
A liquid rock grain, by weight, composition of raw materials one:
| Component | Formula (wt%) |
| Elastomeric propylene yogurt liquid 2788 | 45 |
| Titanium dioxide 706 | 12 |
| Ethylene glycol | 1.2 |
| Defoamer SPA-202 | 0.35 |
| Sterilant 709 | 0.12 |
| Wetting agent SF-1 | 0.12 |
| Film coalescence aid (lauryl alcohol fat) | 0.8 |
| Cellulose thickener HBR 250 | 0.15 |
| Dispersion agent 5040 | 0.2 |
| Alkali swelling thickening material ASE-60 | 1.2 |
| Natural colour sand (200 microns of median sizes) | 3.5 |
| Inorganic powder (0.2 millimeter of median size) | 6 |
| Inorganic gel | 3 |
| Setting agent | 3.5 |
| Water | 22.86 |
Embodiment 2
A liquid rock grain, by weight, composition of raw materials two:
| Component | Formula (wt%) |
| Elastomeric propylene yogurt liquid 2788 | 48 |
| Titanium dioxide 706 | 10 |
| Ethylene glycol | 1.5 |
| Defoamer SPA-202 | 0.3 |
| Sterilant 709 | 0.11 |
| Wetting agent SF-1 | 0.12 |
| Film coalescence aid (lauryl alcohol fat) | 0.9 |
| Cellulose thickener HBR 250 | 0.12 |
| Dispersion agent 5040 | 0.18 |
| Alkali swelling thickening material ASE-60 | 1.1 |
| Natural colour sand (200 microns of median sizes) | 3.4 |
| Inorganic powder (0.2 millimeter of median size) | 7 |
| Inorganic gel | 2 |
| Setting agent | 4 |
| Water | 21.26 |
The preparation technology of above-mentioned coating formula is as follows:
Water is dropped into a mixing bowl, under 300-500 rev/min of speed, add cellulose thickener, stir and add dispersion agent after 10 minutes, defoamer, wetting agent, titanium dioxide, under 800-1200 rev/min of speed, disperse 30 minutes, sand milling, be less than 50 microns to fineness, then under 300-500 rev/min of speed, add elastomeric propylene yogurt liquid, antifreezing agent, film coalescence aid, alkali swelling thickening material, sterilant, stir 30 minutes to even, proceed to kneader, under agitation slowly, add natural colour sand in batches, inorganic powder, inorganic gel, setting agent, to even, with the screen filtration requiring, obtain described liquid rock grain again.
The key technical indexes that liquid rock grain prepared by the present invention reaches is as follows:
Container internal state: easily stir;
Outward appearance: particle is independently suspended in disperse phase;
Surface drying: 2h;
Do solid work: 7h;
Above-described embodiment is only explanation technical conceive of the present invention and feature, and its object is to allow person skilled in the art can understand content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences that spirit is done according to the present invention change or modify, within all should being encompassed in protection scope of the present invention.
Claims (1)
1. a liquid rock grain for artificial granite sandy paint, is characterized in that described liquid rock grain is prepared from by the component of following percent by weight: elastomeric propylene yogurt liquid 10%-50%; Titanium dioxide 10%-15%; Natural colour sand 5%-8%; Inorganic powder 3%-5%; Inorganic gel 2%-5%; Setting agent 3%-5%; Antifreezing agent 1%-2%; Defoamer 0.3%-0.8%; Sterilant 0.1%-0.15%; Dispersion agent 0.1%-0.4%; Alkali swelling thickening material 1%-1.5%, cellulose thickener 0.1%-0.2%; Wetting agent 0.1%-0.15%; Film coalescence aid 0.5%-1%; Surplus is water;
The preparation method of the liquid rock grain of artificial granite sandy paint is:
Water is dropped into a mixing bowl, under 300-500 rev/min of speed, add cellulose thickener, stir and add dispersion agent after 10 minutes, defoamer, wetting agent, titanium dioxide, under 800-1200 rev/min of speed, disperse 30 minutes, sand milling, be less than 50 microns to fineness, then under 300-500 rev/min of speed, add elastomeric propylene yogurt liquid, antifreezing agent, film coalescence aid, alkali swelling thickening material, sterilant, stir 30 minutes to even, proceed to kneader, under agitation slowly, add natural colour sand in batches, inorganic powder, inorganic gel, setting agent, to even, with the screen filtration requiring, obtain described liquid rock grain again,
Described elastomeric propylene yogurt liquid is a kind of or arbitrary combination of two kinds in pure acrylic acid synthetic emulsion, phenylethene modified vinylformic acid synthetic emulsion;
Described frostproofer is a kind of of ethylene glycol, propylene glycol or both arbitrary combination;
Described titanium dioxide is a kind of of import rutile-type, domestic rutile-type or both arbitrary combination;
The grain diameter of described natural colour sand is between 100 microns-1000 microns;
The grain diameter preferable range of described inorganic powder is 1 micron-2000 microns;
Described inorganic gel is one or more the arbitrary combination in silicate, calcium carbonate, magnesium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310546412.0A CN103627272B (en) | 2013-11-07 | 2013-11-07 | Liquid rock particles of artificial granite sand textured coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310546412.0A CN103627272B (en) | 2013-11-07 | 2013-11-07 | Liquid rock particles of artificial granite sand textured coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103627272A true CN103627272A (en) | 2014-03-12 |
| CN103627272B CN103627272B (en) | 2015-07-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310546412.0A Active CN103627272B (en) | 2013-11-07 | 2013-11-07 | Liquid rock particles of artificial granite sand textured coating |
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| Country | Link |
|---|---|
| CN (1) | CN103627272B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104004453A (en) * | 2014-05-28 | 2014-08-27 | 福州真师傅涂料有限公司 | Elastic granite paint and preparation method thereof |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104312351A (en) * | 2014-11-17 | 2015-01-28 | 广西启利新材料科技股份有限公司 | Sand-in-water colorful imitation stone paint |
| CN105130367A (en) * | 2015-07-13 | 2015-12-09 | 汇彩涂料（上海）股份有限公司 | Sand-wall stone-like building coating |
| CN105176267A (en) * | 2015-10-19 | 2015-12-23 | 佛山市高明阳光逸采涂料有限公司 | Waterborne wood-grained color developing agent and preparation method thereof |
| CN105295606A (en) * | 2015-11-25 | 2016-02-03 | 亚士漆(上海)有限公司 | Lacquer for construction in low temperature and high humidity condition and preparation method thereof |
| CN105366989A (en) * | 2015-11-25 | 2016-03-02 | 卓达新材料科技集团有限公司 | Anti-cracking relief coating aggregate and preparation method and application thereof |
| CN105505221A (en) * | 2015-12-26 | 2016-04-20 | 铃鹿复合建材（上海）有限公司 | Ultra-thin rock slice and preparation method thereof |
| CN107177261A (en) * | 2017-06-23 | 2017-09-19 | 张聪聪 | High-performance sand textured coating and preparation method thereof |
| CN107353747A (en) * | 2017-06-22 | 2017-11-17 | 河北晨阳工贸集团有限公司 | A kind of imitation wood line texture sand textured coating and preparation method thereof |
| CN110607096A (en) * | 2019-10-10 | 2019-12-24 | 福建桓兴材料科技有限公司 | Granite-like pure benzene elastic coating formula and manufacturing process |
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| CN102660181A (en) * | 2012-05-08 | 2012-09-12 | 上海大学 | Water-in-water imitation granite multicolor coating and preparation method thereof |
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2013
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| CN1492009A (en) * | 2002-10-23 | 2004-04-28 | 北方工业大学 | Environment protection type sand wall shaped building paint and its preparing method |
| CN1903960A (en) * | 2006-08-16 | 2007-01-31 | 巢启 | Thin layer multi coloured sand wall shaped paint |
| CN101492577A (en) * | 2008-01-23 | 2009-07-29 | 吴钢 | Process for producing watersoluble stone design imitating color slice and use scheme |
| CN102660181A (en) * | 2012-05-08 | 2012-09-12 | 上海大学 | Water-in-water imitation granite multicolor coating and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104004453A (en) * | 2014-05-28 | 2014-08-27 | 福州真师傅涂料有限公司 | Elastic granite paint and preparation method thereof |
| CN104194457B (en) * | 2014-08-29 | 2017-06-20 | 亚士创能科技(上海)股份有限公司 | Sand wall-like multicolor finish and preparation method thereof |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104312351A (en) * | 2014-11-17 | 2015-01-28 | 广西启利新材料科技股份有限公司 | Sand-in-water colorful imitation stone paint |
| CN105130367A (en) * | 2015-07-13 | 2015-12-09 | 汇彩涂料（上海）股份有限公司 | Sand-wall stone-like building coating |
| CN105130367B (en) * | 2015-07-13 | 2017-10-10 | 汇彩涂料（上海）股份有限公司 | A kind of sand wall-like builds stone-like coating |
| CN105176267A (en) * | 2015-10-19 | 2015-12-23 | 佛山市高明阳光逸采涂料有限公司 | Waterborne wood-grained color developing agent and preparation method thereof |
| CN105366989A (en) * | 2015-11-25 | 2016-03-02 | 卓达新材料科技集团有限公司 | Anti-cracking relief coating aggregate and preparation method and application thereof |
| CN105295606A (en) * | 2015-11-25 | 2016-02-03 | 亚士漆(上海)有限公司 | Lacquer for construction in low temperature and high humidity condition and preparation method thereof |
| CN105505221A (en) * | 2015-12-26 | 2016-04-20 | 铃鹿复合建材（上海）有限公司 | Ultra-thin rock slice and preparation method thereof |
| CN107353747A (en) * | 2017-06-22 | 2017-11-17 | 河北晨阳工贸集团有限公司 | A kind of imitation wood line texture sand textured coating and preparation method thereof |
| CN107177261A (en) * | 2017-06-23 | 2017-09-19 | 张聪聪 | High-performance sand textured coating and preparation method thereof |
| CN107177261B (en) * | 2017-06-23 | 2019-07-26 | 河北晨阳工贸集团有限公司 | High-performance sand textured coating and preparation method thereof |
| CN110607096A (en) * | 2019-10-10 | 2019-12-24 | 福建桓兴材料科技有限公司 | Granite-like pure benzene elastic coating formula and manufacturing process |
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| Publication number | Publication date |
|---|---|
| CN103627272B (en) | 2015-07-15 |
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