CN103756486A - Waterborne colorful building coating and preparation method - Google Patents

Waterborne colorful building coating and preparation method Download PDF

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Publication number
CN103756486A
CN103756486A CN201410029110.0A CN201410029110A CN103756486A CN 103756486 A CN103756486 A CN 103756486A CN 201410029110 A CN201410029110 A CN 201410029110A CN 103756486 A CN103756486 A CN 103756486A
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parts
deionized water
varnish
colorful
sol solution
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CN201410029110.0A
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CN103756486B (en
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陈明凤
胡启良
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重庆美斯丽涂料有限公司
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Abstract

The invention discloses a waterborne colorful building coating and a preparation method. The waterborne colorful building coating comprises the following components in parts by mass: 3-8 parts of varnish and 100 parts of colorful granules. The preparation method comprises the following steps in sequence: (1) preparing 10% protective colloid solution; (2) preparing a white base paint; (3) modulating colors; (4) preparing a dispersion medium; (5) preparing varnish; (6) preparing colorful granules; finally preparing the waterborne colorful building coating. The waterborne colorful building coating has the advantages that the prepared coating can not bond, agglomerate, float or sink; the colorful granules are free from cross color and have clear boundaries; the coating system has stable viscosity and is free from post-thickening; the colorful granules have high strength, are flexible and are adjustable in sizes and shapes; various colorful granules in different colors can be matched and mixed according to random proportion; the effects and textures of granite and marble can be simulated to the life by spraying the coating once, thus meeting the stone-like decoration requirements of colorful patterns of exterior walls of buildings.

Description

A kind of aqueous colorful building coating and preparation method
Technical field
The present invention relates to building coating technical field, relate in particular to a kind of aqueous colorful building coating and preparation method.
Background technology
In recent years, External Thermal Insulation Technology for External has become the mainstream technology of China's building energy conservation, due to external thermal insulation bearing capacity a little less than, therefore there is light weight, environmental protection, safety, easily the exterior coating of the advantages such as renovation has become the main way of current exterior wall finish.But generic latex paint color is single, cannot realize the decoration requirement of the imitative stone material of external wall.The true mineral varnish preparation process of color sandstone sheet complexity, true mineral varnish consumption is large, and every square meter cost is high, and sliver and color sand splash down in a large number and causes waste during spraying application.Oil-in-water-type multicolor finish is containing noxious solvent, and environmental pollution is large, unfavorable environmental protection.Easy agglomerating, the color grain floating of bonding or sink when water type multicolor paint for water drum is stored on the market at present, affect the homogeneity of coating, and color grain intensity is low, can not bear vibration, collision, impact and spray gun pressure, causes easy colour contamination, obscurity boundary between color grain.After coating system, thickening is serious, cannot spray.
Summary of the invention
For prior art above shortcomings, object of the present invention is just to provide a kind of aqueous colorful building coating and preparation method, to overcome the shortcoming and defect of currently available products, meets decorating outer wall of building requirement; Agglomerating, the floating of can not boning or sink, not colour contamination, sharpness of border between color grain; Coating system stable viscosity, without male offspring thickening phenomenon; Color grain intensity is high, pliable and tough, and size shape is adjustable, and the color grain of multiple different colours can mix in arbitrary proportion collocation.
To achieve these goals, the technical solution used in the present invention is such: a kind of aqueous colorful building coating, is characterized in that: its composition and ratio of quality and the number of copies are: 3-8 part varnish, 100 parts of color grains; Wherein:
The composition of described varnish and ratio of quality and the number of copies are: 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener;
Composition and the ratio of quality and the number of copies of described color grain are: 100 parts of dispersion medium, 100 parts of colored base paints;
The composition of described dispersion medium and ratio of quality and the number of copies are: 45-49 part deionized water, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99,8-10 part lithium magnesium silicate, 45-55 part 10% concentration protection sol solution;
Described colored base paint, composition and ratio of quality and the number of copies are: 100 parts of white basis paints, 0.1-1 part mill base;
The composition of described white basis paint and ratio of quality and the number of copies are: 60-65 part deionized water, 0.5-1 part are done the ammonium polyacrylate salt of dispersion agent, alkylphenol polyoxyethylene that 0.5-1 part is made wetting agent, mineral oil, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part that 1-2 part is made defoamer and do the silicone oil of defoamer, 5-8 part 10% concentration protection sol solution;
Composition and the ratio of quality and the number of copies of described 10% concentration protection sol solution are: 89.5-89 part deionized water, 0.5-1 part trisodium phosphate, 10 parts of lithium magnesium silicates.
A preparation method for above-mentioned aqueous colorful building coating, comprises the steps:
The preparation of (1) 10% protection sol solution: first 89.5-89 part deionized water is added in a mixing bowl, add 0.5-1 part trisodium phosphate to being dissolved in the water completely under 500r/min stirring at low speed; Add again 10 parts of lithium magnesium silicate 1500r/min high-speed stirring to exceed 45min, then keep 500r/min stirring at low speed, standby;
(2) preparation of white basis paint: raw material and weight part proportioning are: 60-65 part deionized water, 0.5-1 part is made the ammonium polyacrylate salt of dispersion agent, 0.5-1 part is made the alkylphenol polyoxyethylene of wetting agent, 1-2 part is made the mineral oil of defoamer, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part is made the silicone oil of defoamer, and the 10% concentration protection sol solution that 5-8 part is made by step (1), is placed on the raw material of above-mentioned weight part proportioning in a mixing bowl, first adds deionized water, then under 500 revs/min of rotating speeds, adds successively dispersion agent, wetting agent, mineral oil antifoam agent, Natvosol, pH adjusting agent, sterilant, film coalescence aid, propylene glycol, then carries rotating speed to 1200-1500 rev/min and adds titanium dioxide, kaolin stirs 30 minutes, then rotating speed is down to 500-600 rev/min and adds elasticity pure-acrylic emulsion and silicon oil foam killer to stir, and finally adds the 10% concentration protection sol solution being made by step (1), continues to stir more than 30 minutes, standby,
(3) toning: by design requirements, the white basis paint making by 100 parts of steps (2) mixes with 0.1-1 part mill base, stirs, the colored base paint of furnishing;
(4) preparation of dispersion medium: raw material and weight part proportioning are 45-49 part deionized waters, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99, 8-10 part lithium magnesium silicate, the 10% concentration protection sol solution that 45-55 part is made by step (1), by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings by trisodium phosphate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 is added to the water, be stirred to completely and dissolve, the 10% concentration protection sol solution that finally adds lithium magnesium silicate and made by step (1) is greater than 45 minutes 1500 revs/min of stirrings, standby,
(5) preparation of varnish: raw material and weight part proportioning are 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener, by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings, add successively pH adjusting agent, sterilant, film coalescence aid, benzene emulsion, defoamer, alkali swells polypropylene hydrochlorate thickening material, polyurethane thickener to stir, standby;
(6) preparation of color grain: raw material and weight part proportioning are 100 parts of dispersion medium that made by step (4), 100 parts of monochromes that made by step (3), mixture colors or polychrome base paints, opening stirrer adds monochrome, mixture colors or polychrome base paint in dispersion medium, 40 revs/min of rotating speeds so that monochrome, mixture colors or polychrome base paint do not sink to being as the criterion, monochrome, mixture colors or polychrome base paint add rear rotating speed and carry to 90~130 revs/min, observe while stirring color grain particle diameter, until reach design requirements;
(7) last: raw material and weight part proportioning are the varnish that 3-8 part is made by step (5), 100 parts of color grains that made by step (6), opening stirrer adds coloured silk and in varnish, stirs and obtain this coating, rotating speed is controlled at and just makes color grain and varnish can stir evenly and not destroy color grain to be as the criterion, if lacquering viscosity does not reach construction requirement, can add in right amount the adjustment of alkali swells polypropylene hydrochlorate thickening material, viscosity is adjusted complete stopping immediately and is stirred.
Compared with prior art, the invention has the advantages that:
1, preparation technology is simple, and the general general production unit of emulsion paint can be suitable for.
2, can not bond agglomerating, floating or sink, not colour contamination, sharpness of border between color grain; Coating system stable viscosity, without male offspring thickening phenomenon; Color grain intensity is high, pliable and tough, and size shape is adjustable, and the color grain of multiple different colours can mix in arbitrary proportion collocation.
3, once spraying gets final product imitation granite true to nature and marmorean effect and texture, and the imitative stone that meets the colorful floral designs of external wall is decorated requirement.
 
Embodiment
Embodiment: a kind of aqueous colorful building coating, its composition and ratio of quality and the number of copies are: 3-8 part varnish, 100 parts of color grains.Wherein:
The composition of described varnish and ratio of quality and the number of copies are: 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener.
Composition and the ratio of quality and the number of copies of described color grain are: 100 parts of dispersion medium, 100 parts of colored base paints.
The composition of described dispersion medium and ratio of quality and the number of copies are: 45-49 part deionized water, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99,8-10 part lithium magnesium silicate, 45-55 part 10% concentration protection sol solution.
Described colored base paint, composition and ratio of quality and the number of copies are: 100 parts of white basis paints, 0.1-1 part mill base.
The composition of described white basis paint and ratio of quality and the number of copies are: 60-65 part deionized water, 0.5-1 part are done the ammonium polyacrylate salt of dispersion agent, alkylphenol polyoxyethylene that 0.5-1 part is made wetting agent, mineral oil, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part that 1-2 part is made defoamer and do the silicone oil of defoamer, 5-8 part 10% concentration protection sol solution.
Composition and the ratio of quality and the number of copies of described 10% concentration protection sol solution are: 89.5-89 part deionized water, 0.5-1 part trisodium phosphate, 10 parts of lithium magnesium silicates.
A kind of above-mentioned aqueous colorful building coating and preparation method, comprise the steps:
The preparation of (1) 10% concentration protection sol solution: first 89.5-89 part deionized water is added in a mixing bowl, add 0.5-1 part trisodium phosphate to being dissolved in the water completely under 500r/min stirring at low speed; Slowly add again 10 parts of lithium magnesium silicate 1500r/min high-speed stirring to exceed 45min, then keep 500r/min stirring at low speed standby.
(2) preparation of white basis paint: raw material and weight part proportioning are 60-65 part deionized waters, 0.5-1 part is made the ammonium polyacrylate salt of dispersion agent, 0.5-1 part is made the alkylphenol polyoxyethylene of wetting agent, 1-2 part is made the mineral oil of defoamer, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part is made the silicone oil of defoamer, and the 10% concentration protection sol solution that 5-8 part is made by step (1) first adds deionized water in a mixing bowl by above-mentioned weight part, under 500 revs/min of rotating speeds, add successively dispersion agent, wetting agent, mineral oil antifoam agent, Natvosol, pH adjusting agent, sterilant, film coalescence aid, propylene glycol, carries rotating speed to 1200-1500 rev/min and adds titanium dioxide, kaolin stirs 30 minutes, rotating speed is down to 500-600 rev/min adds elasticity pure-acrylic emulsion and silicon oil foam killer to stir, finally add after the 10% concentration protection sol solution being made by step (1), rotating speed is brought up to stirring and is as the criterion, be stirred to visual inspection coating moist and form thixotroping body till, the general used time is more than 30 minutes, standby.
(3) toning: by design requirements, the white basis paint making by 100 parts of steps (2) mixes with 0.1-1 part mill base (red, yellow, blue or its combination), stir, the colored base paint of furnishing, uses different monochromes, mixture colors or polychrome to distinguish according to the above ratio furnishing base paint of all kinds.
(4) preparation of dispersion medium: raw material and weight part proportioning are 45-49 part deionized waters, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99, 8-10 part lithium magnesium silicate, the 10% concentration protection sol solution that 45-55 part is made by step (1), by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings by trisodium phosphate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 is added to the water, be stirred to completely and dissolve, the 10% concentration protection sol solution that finally adds lithium magnesium silicate and made by step (1) 1500 revs/min of stirrings be greater than 45 minutes standby.
(5) preparation of varnish: raw material and weight part proportioning are 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener, by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings, add successively pH adjusting agent, sterilant, film coalescence aid, benzene emulsion, defoamer, alkali swells polypropylene hydrochlorate thickening material, polyurethane thickener to stir standby.
(6) preparation of color grain: raw material and weight part proportioning are 100 parts of dispersion medium that made by step (4), 100 parts of monochromes that made by step (3), mixture colors or polychrome base paints, opening stirrer adds monochrome, mixture colors or polychrome base paint in dispersion medium, 40 revs/min of rotating speeds so that monochrome, mixture colors or polychrome base paint do not sink to being as the criterion, monochrome, mixture colors or polychrome base paint add rear rotating speed and carry to 90~130 revs/min, observe while stirring color grain particle diameter, until reach design requirements.
(7) preparation of water-soluble colorful coating: raw material and weight part proportioning are the varnish that 3-8 part is made by step (5), 100 parts of color grains that made by step (6), opening stirrer adds coloured silk and in varnish, stirs and obtain this coating, rotating speed is controlled at and just makes color grain and varnish can stir evenly and not destroy color grain to be as the criterion, if lacquering viscosity does not reach construction requirement, can add in right amount the adjustment of alkali swells polypropylene hydrochlorate thickening material, viscosity is adjusted complete stopping immediately and is stirred.
Embodiment is as follows:
Table 1 is 10% concentration protection sol solution Preparation Example, raw material and weight proportion umber list 1:
(table 1)
Table 2 is white basis paint Preparation Examples, raw material and weight proportion umber list 2:
(table 2)
Raw material 1 2 3 4
Deionized water 60 62 63 65
Ammonium polyacrylate salt 0.5 0.6 0.8 1.0
Alkylphenol polyoxyethylene 1 0.8 0.6 0.5
Mineral oil 1 1 2 2
Natvosol 12 11 13 10
PH adjusting agent 2 1 1 2
Titanium dioxide 20 15 10 10
Kaolin 10 15 20 30
Sterilant 1 2 3 1
Film coalescence aid 5 10 8 6
Propylene glycol 10 5 8 6
Elastomeric propylene yogurt liquid 20 30 25 25
Silicone oil 2 1 3 2
10% concentration protection sol solution 5 6 7 8
Table 3 is colored base paint Preparation Examples, raw material and weight proportion umber list 3:
(table 3)
Table 4 is dispersion medium Preparation Examples, raw material and weight proportion umber list 4:
(table 4)
Table 5 is varnish Preparation Examples, raw material and weight proportion umber list 5:
(table 5)
Table 6 is water-soluble colorful coating Preparation Examples, raw material and weight proportion umber list 6:
(table 6)
Finally it should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention but not restriction technologies scheme, those of ordinary skill in the art is to be understood that, those are modified or are equal to replacement technical scheme of the present invention, and do not depart from aim and the scope of the technical program, all should be encompassed in the middle of claim scope of the present invention.

Claims (2)

1. an aqueous colorful building coating, is characterized in that: its composition and ratio of quality and the number of copies are: 3-8 part varnish, 100 parts of color grains; Wherein:
The composition of described varnish and ratio of quality and the number of copies are: 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener;
Composition and the ratio of quality and the number of copies of described color grain are: 100 parts of dispersion medium, 100 parts of colored base paints;
The composition of described dispersion medium and ratio of quality and the number of copies are: 45-49 part deionized water, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99,8-10 part lithium magnesium silicate, 45-55 part 10% concentration protection sol solution;
Described colored base paint, composition and ratio of quality and the number of copies are: 100 parts of white basis paints, 0.1-1 part mill base;
The composition of described white basis paint and ratio of quality and the number of copies are: 60-65 part deionized water, 0.5-1 part are done the ammonium polyacrylate salt of dispersion agent, alkylphenol polyoxyethylene that 0.5-1 part is made wetting agent, mineral oil, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part that 1-2 part is made defoamer and do the silicone oil of defoamer, 5-8 part 10% concentration protection sol solution;
Composition and the ratio of quality and the number of copies of described 10% concentration protection sol solution are: 89.5-89 part deionized water, 0.5-1 part trisodium phosphate, 10 parts of lithium magnesium silicates.
2. the preparation method of a kind of aqueous colorful building coating according to claim 1, is characterized in that: comprise the steps:
The preparation of (1) 10% protection sol solution: first 89.5-89 part deionized water is added in a mixing bowl, add 0.5-1 part trisodium phosphate to being dissolved in the water completely under 500r/min stirring at low speed; Add again 10 parts of lithium magnesium silicate 1500r/min high-speed stirring to exceed 45min, then keep 500r/min stirring at low speed, standby;
(2) preparation of white basis paint: raw material and weight part proportioning are: 60-65 part deionized water, 0.5-1 part is made the ammonium polyacrylate salt of dispersion agent, 0.5-1 part is made the alkylphenol polyoxyethylene of wetting agent, 1-2 part is made the mineral oil of defoamer, 10-13 part Natvosol, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 5-10 part propylene glycol, 10-20 part titanium dioxide, 10-30 part kaolin, 20-30 part elastomeric propylene yogurt liquid, 1-3 part is made the silicone oil of defoamer, and the 10% concentration protection sol solution that 5-8 part is made by step (1), is placed on the raw material of above-mentioned weight part proportioning in a mixing bowl, first adds deionized water, then under 500 revs/min of rotating speeds, adds successively dispersion agent, wetting agent, mineral oil antifoam agent, Natvosol, pH adjusting agent, sterilant, film coalescence aid, propylene glycol, then carries rotating speed to 1200-1500 rev/min and adds titanium dioxide, kaolin stirs 30 minutes, then rotating speed is down to 500-600 rev/min and adds elastomeric propylene yogurt liquid and silicon oil foam killer to stir, and finally adds the 10% concentration protection sol solution being made by step (1), continues to stir more than 30 minutes, standby,
(3) toning: by design requirements, the white basis paint making by 100 parts of steps (2) mixes with 0.1-1 part mill base, stirs, the colored base paint of furnishing;
(4) preparation of dispersion medium: raw material and weight part proportioning are 45-49 part deionized waters, 0.5-1 part trisodium phosphate, 0.5-1 part tripoly phosphate sodium STPP, 0.5-1 part Sodium hexametaphosphate 99, 8-10 part lithium magnesium silicate, the 10% concentration protection sol solution that 45-55 part is made by step (1), by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings by trisodium phosphate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 is added to the water, be stirred to completely and dissolve, the 10% concentration protection sol solution that finally adds lithium magnesium silicate and made by step (1) is greater than 45 minutes 1500 revs/min of stirrings, standby,
(5) preparation of varnish: raw material and weight part proportioning are 50-60 part deionized water, 1-2 part pH adjusting agent, 1-2 part sterilant, 5-10 part film coalescence aid, 25-35 part benzene emulsion, 1-3 part defoamer, 10-18 part alkali swells polypropylene hydrochlorate thickening material, 10-15 part polyurethane thickener, by above-mentioned weight part, in a mixing bowl, first add deionized water, under 500 revs/min of stirrings, add successively pH adjusting agent, sterilant, film coalescence aid, benzene emulsion, defoamer, alkali swells polypropylene hydrochlorate thickening material, polyurethane thickener to stir, standby;
(6) preparation of color grain: raw material and weight part proportioning are 100 parts of dispersion medium that made by step (4), 100 parts of monochromes that made by step (3), mixture colors or polychrome base paints, opening stirrer adds monochrome, mixture colors or polychrome base paint in dispersion medium, 40 revs/min of rotating speeds so that monochrome, mixture colors or polychrome base paint do not sink to being as the criterion, monochrome, mixture colors or polychrome base paint add rear rotating speed and carry to 90~130 revs/min, observe while stirring color grain particle diameter, until reach design requirements;
(7) last: raw material and weight part proportioning are the varnish that 3-8 part is made by step (5), 100 parts of color grains that made by step (6), opening stirrer adds coloured silk and in varnish, stirs and obtain this coating, rotating speed is controlled at and just makes color grain and varnish can stir evenly and not destroy color grain to be as the criterion, if lacquering viscosity does not reach construction requirement, can add in right amount the adjustment of alkali swells polypropylene hydrochlorate thickening material, viscosity is adjusted complete stopping immediately and is stirred.
CN201410029110.0A 2014-01-22 2014-01-22 A kind of aqueous colorful building coating and preparation method CN103756486B (en)

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CN104263118A (en) * 2014-10-20 2015-01-07 济南玛博伦环保涂料有限公司 Water-in-water faux marble paint and preparation method thereof
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CN105038456A (en) * 2015-07-29 2015-11-11 福建欧品建筑材料科技有限公司 Imitative amphibole granite colorful coating and preparation method thereof
CN106280959A (en) * 2016-09-07 2017-01-04 广西大学 Water-in-water type sound insulation multi-color and preparation method thereof
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CN107284068A (en) * 2017-06-30 2017-10-24 孙铁宁 Water-base ink indoors and outdoor inkjet printing design for advertisement method
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CN110791161A (en) * 2019-11-22 2020-02-14 雅士利涂料(苏州)有限公司 Sand-in-water granite-imitated coating and preparation method thereof

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CN104250482A (en) * 2014-09-27 2014-12-31 安徽铁创新材料科技有限公司 Method for preparing multicolor paint for imitating litchi surface granite
CN104263118A (en) * 2014-10-20 2015-01-07 济南玛博伦环保涂料有限公司 Water-in-water faux marble paint and preparation method thereof
CN104387981A (en) * 2014-11-28 2015-03-04 龙岩市宝丽涂料有限公司 Preparation method of artificial marble coating and application of artificial marble coating in construction
CN104387981B (en) * 2014-11-28 2016-08-17 龙岩市宝丽涂料有限公司 The preparation method of a kind of imitation marble paint and the application in construction thereof
CN104725923A (en) * 2015-03-26 2015-06-24 湖州科达化工燃料有限公司 Novel thickening agent for emulsion architecture coating and preparation method thereof
CN105038456A (en) * 2015-07-29 2015-11-11 福建欧品建筑材料科技有限公司 Imitative amphibole granite colorful coating and preparation method thereof
CN105017906A (en) * 2015-08-14 2015-11-04 刘善江 Water-in-water multi-color water paint and preparation method thereof
CN106336154A (en) * 2016-08-18 2017-01-18 天津市荣新涂料股份有限公司 Environmentally-friendly sand-in-water colorful paint and preparation method thereof
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CN110791161A (en) * 2019-11-22 2020-02-14 雅士利涂料(苏州)有限公司 Sand-in-water granite-imitated coating and preparation method thereof

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