Summary of the invention
For the prior art above shortcomings; the invention provides the imitative bleeding aqueous colorful base paint of a kind of suspension type; the density of this base paint is substantially the same with the density of protection glue; no matter the finished product of making coats with lacquer the viscosity height; its particle all can be good at being suspended in the protection sol solution; can not precipitate conglomeration, color grain can sagging yet after the spraying.
Further, the invention provides the preparation method of the anti-bleeding aqueous colorful base paint of a kind of suspension type.
The technical solution used in the present invention is as follows:
A kind of suspension type is prevented bleeding aqueous colorful base paint, is made by the material of following weight percent:
Deionized water: 25%~50%; Natvosol: 0.3%~1.4%, PH conditioning agent: 0.1%~1.5%, dispersing auxiliary: 0.2%~0.55%; wetting aid: 0.1%~0.3%; the froth breaking auxiliary agent: 0.1%~0.5%, titanium dioxide: 1.0%~5.0%, filler: 10~40%; self-crosslinking elastic emulsion: 15%~35%; biocide mildewcide: 0.2%~0.6%, hollow glass bead: 0.5%~7.0%, protective colloid solution: 5.0%~20%.
Further, described Natvosol is Natrosol Plus.
Further, described wetting aid is the anionic wetting aid.
Further, described dispersing auxiliary is the negatively charged ion dispersing auxiliary.
Further, described filler comprises one or more the mixing in water-ground limestone, calcined kaolin, talcum powder, process white, the mica powder.
Further, described hollow glass bead is the hollow glass bead of hydrophobically modified type.
Further, described protective colloid solution is lithium magnesium silicate modified alta-mud solution, and this strength of solution is 3%~14%.
Further, made by the material of following weight percent: deionized water: 32.4%, Natrosol Plus: 0.6%, PH conditioning agent: 0.2%, negatively charged ion dispersing auxiliary: 0.4%, negatively charged ion wetting aid: 0.1%, froth breaking auxiliary agent: 0.3%, titanium dioxide: 1.5%, water-ground limestone: 15%, calcined kaolin: 15%, self-crosslinking elastic emulsion: 22.1%, biocide mildewcide: 0.4%, hollow glass bead: 2.0%, concentration is 6% protective colloid solution: 10%.
The preparation method of the anti-bleeding aqueous colorful base paint of a kind of suspension type; above-mentioned component; to be ground to fineness≤50 μ m after raw material deionized water, Natvosol, PH conditioning agent, dispersing auxiliary, wetting aid, froth breaking auxiliary agent, titanium dioxide and the filler mixing and stirring first, add again raw material self-crosslinking elastic emulsion, biocide mildewcide, hollow glass bead and protective colloid solution stirring and mix.
Compared to existing technology, the present invention has following beneficial effect:
1, the present invention has added hollow glass bead in prescription; the hollow structure that it is special; reduced the density of base paint system, made it basically identical with the protective colloid solution density, like this; after the colorful granulation and after the multi-color lacquer storage; its color grain all can be suspended in the colorful system uniformly, after the spraying, because himself density is low; on body of wall, colorful particle can sagging yet.Simultaneously, because suspension type and the bleeding resistance of colorful particle, the finished product multi-color lacquer coating storge quality of being made by the colorful base paint of this kind is greatly improved.
2, the present invention selects anionic wetting agent and negatively charged ion dispersing auxiliary, and its ionic charge is consistent with protective colloid solution, helps it to repel each other with electric charge, stops after the colorful particle granulation particle and protective colloid solution miscible, prevents colorful particle bleeding.
3, the present invention selects Natrosol Plus as thickening material, reduce the water-soluble of aqueous colorful base paint, its molecular chain launches rear special " card room " structure energy active block pigment molecule, filler molecule, water molecules, emulsion molecule, make it collaborative with the electric charge effect of repelling each other after granulation, improved the impervious look ability of colorful base paint.
Embodiment
The embodiment of the invention is filled a prescription such as following table (weight percent):
Material name |
Embodiment 1 |
Embodiment 2 |
Embodiment 2 |
Embodiment 3 |
Embodiment 4 |
Natvosol |
0.6 |
0.4 |
0.8 |
1.2 |
1.4 |
The PH conditioning agent |
0.2 |
0.2 |
0.2 |
0.15 |
0.15 |
Dispersing auxiliary |
0.4 |
0.4 |
0.4 |
0.4 |
0.3 |
Wetting aid |
0.1 |
0.1 |
0.3 |
0.1 |
0.1 |
The froth breaking auxiliary agent |
0.3 |
0.3 |
0.3 |
0.3 |
0.3 |
Titanium dioxide |
1.5 |
2.5 |
1.0 |
2.0 |
5 |
Filler |
30(wherein, water-ground limestone: 15%, calcined kaolin: 15%) |
35 (wherein, water-ground limestone: 10%, talcum powder: 8%, process white: 5%, mica powder 12%) |
18(wherein, calcined kaolin 10%, mica powder 8%) |
12(wherein, calcined kaolin 8%, process white 4%) |
10(all is talcum powder) |
The self-crosslinking elastic emulsion |
22.1 |
18 |
30 |
35 |
30 |
Biocide mildewcide |
0.4 |
0.4 |
0.4 |
0.4 |
0.4 |
Hollow glass bead |
2.0 |
2.8 |
1.5 |
0.8 |
0.5 |
Protective colloid solution |
The 10(strength of solution is 6%) |
The 12(strength of solution is 3%) |
The 8(strength of solution is 14%) |
The 6(strength of solution is 10%) |
The 6(strength of solution is 10%) |
Deionized water |
32.4 |
27.9 |
39.1 |
41.65 |
45.85 |
Specifeca tion speeification
|
Density 1.03g/cm
3 |
Density 1.03g/cm
3 |
Density 1.02g/cm
3 |
Density 1.04g/cm
3 |
Density 1.02g/cm
3 |
Result of use
|
Be suspended in protective colloid solution |
Be suspended in protective colloid solution |
Be suspended in protective colloid solution |
Be suspended in protective colloid solution |
Be suspended in protective colloid solution |
Make the storage characteristics of multicolor finish
|
12 months without precipitation, without conglomeration, without bleeding |
12 months without precipitation, without conglomeration, without bleeding |
12 months without precipitation, without conglomeration, without bleeding |
12 months without precipitation, without conglomeration, without bleeding |
12 months without precipitation, without conglomeration, nonbleeding |
Make the spraying flow of multicolor finish
|
Single spraying 0.4kg/m
2Sagging not
|
Single spraying 0.4kg/m
2Sagging not
|
Single spraying 0.4kg/m
2Sagging not
|
Single spraying 0.4kg/m
2Sagging not
|
Single spraying 0.4kg/m
2Sagging not
|
In the said components, Natvosol is Natrosol Plus, adopts the Asia to stride imperial HBR250, and its main effects is to provide stable space " card room " mechanism to colorful base paint, prevents miscible, the bleeding of colorful particle.The PH conditioning agent is DOW Chemical AMP-95.Dispersing auxiliary is extra large river 5034 anionic dispersing agents, and wetting aid is these NUOSPERSE FA 620 anion surfactants of hamming; 5034 dispersion agents and FA620 wetting agent be because its negatively charged ion attribute, with protective colloid solution with like charges, produce electrostatic repulsion, prevent colorful base paint bleeding.The froth breaking auxiliary agent is extra large river SN-154 defoamer, and titanium dioxide is the chemistry R902 of Du Pont
+The self-crosslinking elastic emulsion is ROHM AND HAAS 2468; biocide mildewcide is Ke Laien HF-1 sterilant; hollow glass bead is the hollow glass bead of the VS5500 of 3M company hydrophobically modified; this product is white powder; have extremely low tap density, its obvious effect is to reduce the density of colorful base paint, makes it can suspend in the multicolor finish system.Protective colloid solution is the Lockwood RD Magnesium Silicate q-agent reason 3%-14% aqueous solution, protects colorful particle color independent, colour mixture not, nonbleeding.
By the ratio of each component in above-described embodiment be listed as with deionized water, Natvosol, PH conditioning agent, dispersing auxiliary, wetting aid, froth breaking auxiliary agent, titanium dioxide, filler by described order add stir be ground to fineness≤50 μ m after; add again self-crosslinking elastic emulsion, biocide mildewcide, hollow glass bead; the aqueous colorful base paint that mixing is made behind the protective colloid solution, its density is all at 1.03g/cm
3, the colorful base paint of this kind is made colorful finished product coating (weight percent) by following scheme:
Protective colloid solution: 30%, colorful base paint: 30%, pure-acrylic emulsion: 36%, film coalescence aid: 4%; Wherein, the protective colloid strength of solution is 8%.
The colorful finished product coating that uses the colorful base paint granulation of this kind to make, its storge quality of 12 months is much larger than 2-3 month storge quality of common water-soluble colorful coating, and single does not stay the quantity for spray of extension much larger than the 0.2kg/m of common water-soluble colorful coating
2, the suspension of particle has solved the particle precipitation problem in the production process.
Need to prove at last, above embodiment is only in order to illustrate technical scheme of the present invention but not the restriction technologies scheme, although the applicant has been described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, those are made amendment to technical scheme of the present invention or are equal to replacement, and do not break away from aim and the scope of the technical program, all should be encompassed in the middle of the claim scope of the present invention.