CN106634340A - Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide - Google Patents
Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide Download PDFInfo
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- CN106634340A CN106634340A CN201611122123.8A CN201611122123A CN106634340A CN 106634340 A CN106634340 A CN 106634340A CN 201611122123 A CN201611122123 A CN 201611122123A CN 106634340 A CN106634340 A CN 106634340A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The invention discloses water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide. Through a series of processes, zinc ions and lanthanum ions are added into the silicon dioxide preparation to obtain the lanthanum-zinc antibacterial silicon dioxide; the dispersibility is better; the granularity is uniform; the lanthanum-zinc antibacterial silicon dioxide can be well dispersed in the paint; a good bacteriostasis effect is achieved; meanwhile, the toughness and the abrasion-resistant performance of a coating film are not lowered. The prepared paint has the advantages that the multicolor rock slices are firm and flexible; the crushing cannot easily occur; the multicolor rock slices are enabled not to be damaged in the storage and transportation processes; the quality of the multicolor rock slice paint is improved; the construction is convenient; inclined spraying and direct spraying can be realized; in addition, the paint film has a long-acting bacteriostasis function; the paint is suitable for being used for indoor decoration.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of aqueous colorful sliver of addition lanthanum zinc antibacterial silica
Coating.
Background technology
Aqueous compound sliver artificial granite paint is also sliver paint, granite mineral varnish, belong to novel pure Water-borne modification without appointing
The sand textured building coating of what solvent-borne type material, is rich in the style of granite, the intension of granite, the noble quality of granite, Hua Gang
The grade of rock, is the upgrading kind of traditional natural real stone paint.It is right with extensive application of the new coating in construction market
The research that the formula of sliver is combined in building coating is increasingly paid close attention to by numerous research workers.The imitative flower of aqueous compound sliver
Hilllock rock coating is formulated with high-quality synthetic resin emulsion, coating colored compound sliver, filler, auxiliary agent etc., with tradition conjunction
Resin emulsion sand textured coating is compared, and it is excellent that its application property, Low Temperature Thermal deposit stability, water-fast and alkali resistance, coating temperature-change resistance
Good, During Initial Stage Construction does not split, impact resistance, stain resistant, and weather-proof, adhesion strength is high, and coating exactly likes natural granite, can be used in building
The decoration of wall and exterior wall, also can be cladding with the natural granite for substituting matter weight as the finish coat of External Thermal Insulation System,
Mitigate building to bear a heavy burden, reduce the protection opened Bian, be conducive to ecological environment of granite ore deposit.
Colorful compound sliver is synthesized by high molecular polymer, therefore with superpower water-fast, weatherability, can be with all kinds of aqueous stones
Paint is combined closely.The resistance to tensile strength of compound sliver and pick up determine the quality of compound sliver, so as to determine water paint
Quality.《The improvement of composite rock slice prescription in outer wall building coating》By being modified to formula in one text, add wetting agent, divide
Powder, defoamer, thickener, coalescents, fungusproof anti-corrosion agent, pH value conditioning agents, coordinate acrylate and vinyl acetate emulsion to answer with styrene-acrylic emulsion
Match somebody with somebody, make the compound sliver having excellent weather resistance.Although can be lifted compound with acrylate and vinyl acetate emulsion of styrene-acrylic emulsion makes compound sliver
Weatherability, but the lifting of the tensile strength, pick up for compound sliver is modified limited, needs further to match somebody with somebody compound sliver
Emulsion in side is further modified, to meet the demand of the compound sliver of high-quality, while carrying out to water paint a series of
Functional form is modified, to meet demand of the interior wall with colorful sliver paint development.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of water of addition lanthanum zinc antibacterial silica
The colorful sliver coating of property.
The present invention is achieved by the following technical solutions：
A kind of aqueous colorful sliver coating of addition lanthanum zinc antibacterial silica, is made up of the raw material of following weight portion：Water
Property base polyurethane prepolymer for use as 5.5-6.5, Lauryl Alcohol ester 1-1.1, Sodium Polyacrylate 0.45-0.5, trioctyl lemon acid 0.5-
0.55th, ultra-fine natural color stuffing 60-65, appropriate deionized water, styrene 4-4.5, n-butyl acrylate 6-6.4, potassium peroxydisulfate
0.6-0.65, pure-acrylic emulsion 80-85, defoamer NXZ1-1.2, propane diols 2.5-3, butyl glycol ether 4-5, cobalt naphthenate 1-
1.3rd, pregelatinized starch 4-4.5, titanium dioxide 9-10, sodium acid carbonate 2-3, waterglass 13-14, lanthanum nitrate 1-1.2, zinc sulfate 2-
3；
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous
Or it is several.
A kind of aqueous colorful sliver coating of addition lanthanum zinc antibacterial silica, is made up of step in detail below：
（1）Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature
Again the deionized water of amount, with stirring and emulsifying 40-50 minute under 800-1000 rev/min of speed, is subsequently adding potassium peroxydisulfate, heats
To 80-85 DEG C, insulation reaction 90-120 minute, discharge after cooling, obtain modifying cinepazid emulsion；Modifying cinepazid emulsion is added and is divided
In scattered machine, stirred with 1500-1800 rev/min of speed, Lauryl Alcohol ester, Sodium Polyacrylate, citric acid three are added while stirring
The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10
The film that thickness is 18-19 microns is made after minute, is dried under the conditions of temperature is for 155-160 DEG C, after product cooling, broken
It is broken, then sieved with the mesh screen of 7-9 millimeter mesh, obtain the colorful compound sliver that is modified；
（2）Sodium acid carbonate is dissolved in after the 2-3 times of deionized water measured and is heated to 50-60 DEG C, mixed with waterglass, be heated to 90-
95 DEG C, adjust pH with after 300-400 rev/min of speed stirring reaction 20-30 minute and lanthanum nitrate, sulphur are sequentially added as 5-6, then
Sour zinc, with suction filtration while hot after 200-300 rev/min of speed stirring reaction 20-30 minute, and is washed with deionized, by filter cake
It is put in baking oven and the filter cake of drying is ground with 110-120 DEG C of drying, cross 300 mesh sieves, obtains lanthanum zinc antibacterial silica；
（3）The deionized water that pregelatinized starch addition total amount 22-24 times is measured, is heated to 60-70 DEG C, with 500-600 rev/min
Speed is cooled to room temperature after stirring 15-20 minutes, add pure-acrylic emulsion, propane diols, butyl glycol ether, continues with 800-1000
Rev/min speed stirring 10-15 minutes after add step（2）Product and remaining residual components, stir 20-30 minutes；
（4）To step in the state of 750-1000 rev/min of stirring（3）Step is slowly added in the product for obtaining（1）Obtain
Be modified colorful compound sliver, obtains final product after being sufficiently stirred for 10-15 minutes.
It is an advantage of the invention that：The present invention is added in the preparation of styrene-acrylic emulsion first with Waterborne Polyurethane Prepolymer,
Without any emulsifying agent, using Waterborne Polyurethane Prepolymer as emulsifying agent, the elongation at break of emulsion, water-fast is improved
Property, enhance the tensile strength of compound sliver and reduce pick up, simultaneously because addition trioctyl lemon acid and 12 carbon
Cooperating for alcohol ester, improves the shaping shape of compound sliver, not broken；The present invention will meet sliver and mutually tie with pure-acrylic emulsion
Close, the interior wall coating artificial granite effect prepared is good, high from heavy and light, bin stability, complete aqueous safety non-toxic, while reducing
The exploitation of granite, is conducive to ecological protection.
The present invention is added to zinc ion, lanthanum ion in the preparation of silica by a series of technique, obtains lanthanum zinc
Antibacterial silica, preferably, homogeneous grain diameter can be good at being dispersed in coating dispersiveness, with good fungistatic effect, together
Shi Buhui reduces toughness, the wearability of film；The colorful sliver of coating made by the present invention is solid flexible, not broken, it is ensured that
Storage transportation does not result in damages, improves the quality of colorful sliver coating, easy construction, can tiltedly spray, direct-injection, and paint
Film has long-acting bacteria resistance function, and suitable interior decoration is used.
Specific embodiment
A kind of aqueous colorful sliver coating of addition lanthanum zinc antibacterial silica, by following weight portion（Kilogram）Raw material system
Prepare into：Waterborne Polyurethane Prepolymer 5.5, Lauryl Alcohol ester 1, Sodium Polyacrylate 0.45, trioctyl lemon acid 0.5, ultra-fine day
Right color stuffing 60, appropriate deionized water, styrene 4, n-butyl acrylate 6, potassium peroxydisulfate 0.6, pure-acrylic emulsion 80, defoamer
NXZ1, propane diols 2.5, butyl glycol ether 4, cobalt naphthenate 1, pregelatinized starch 4, titanium dioxide 9, sodium acid carbonate 2, waterglass
13rd, lanthanum nitrate 1, zinc sulfate 2；
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous
Or it is several.
A kind of aqueous colorful sliver coating of addition lanthanum zinc antibacterial silica, is made up of step in detail below：
（1）Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature
The deionized water of times amount, with stirring and emulsifying under 800 revs/min of speed 40 minutes, is subsequently adding potassium peroxydisulfate, is heated to 80 DEG C,
Insulation reaction 90 minutes, discharges after cooling, obtains modifying cinepazid emulsion；Modifying cinepazid emulsion is added in dispersion machine, with 1500
Rev/min speed stirring, while stirring add Lauryl Alcohol ester, Sodium Polyacrylate, trioctyl lemon acid and total amount equivalent
Deionized water, continues to add ultra-fine natural color stuffing after stirring 10 minutes, and it is 18 microns to continue to make thickness after stirring 8 minutes
Film, dries under the conditions of temperature is for 155 DEG C, after product cooling, is crushed, and then with the mesh screen screening of 7 millimeters of mesh, obtains
To modified colorful compound sliver；
（2）Sodium acid carbonate is dissolved in after the deionized water of 2 times of amounts and is heated to 50 DEG C, mixed with waterglass, be heated to 90 DEG C, with
300 revs/min of speed stirring reaction adjusts pH after 20 minutes be 5, lanthanum nitrate, zinc sulfate is then sequentially added, with 200 revs/min
Speed stirring reaction suction filtration while hot after 20 minutes, and be washed with deionized, filter cake is put in baking oven with 110 DEG C of dryings,
The filter cake of drying is ground, 300 mesh sieves are crossed, lanthanum zinc antibacterial silica is obtained；
（3）Pregelatinized starch is added into the deionized water of 22 times of amounts of total amount, 60 DEG C are heated to, with 500 revs/min of speed 15 are stirred
Room temperature is cooled to after minute, pure-acrylic emulsion, propane diols, butyl glycol ether is added, continues to stir 10 points with 800 revs/min of speed
Step is added after clock（2）Product and remaining residual components, stir 20 minutes；
（4）To step in the state of 750 revs/min of stirrings（3）Step is slowly added in the product for obtaining（1）What is obtained is modified more
The compound sliver of coloured silk, obtains final product after being sufficiently stirred for 10 minutes.
It is uniform after coating stirring obtained in the embodiment of the present invention that without shadow is fast, application property is good, easily spraying, levelability is good,
Low tempertaure storage without caking, heat-storage without lump, go mouldy, condense and constituent change, surface drying time is less than 4 hours；Film is resistance to
Water, alkaline-resisting 48 hours nothings rise and rouse, ftracture, coming off；Adhesion strength is more than 0.5MPa, meets national standard.
Claims (2)
1. it is a kind of addition lanthanum zinc antibacterial silica aqueous colorful sliver coating, it is characterised in that by the original of following weight portion
Material preparation is made：Waterborne Polyurethane Prepolymer 5.5-6.5, Lauryl Alcohol ester 1-1.1, Sodium Polyacrylate 0.45-0.5, citric acid
Three monooctyl ester 0.5-0.55, ultra-fine natural color stuffing 60-65, appropriate deionized water, styrene 4-4.5, n-butyl acrylate 6-
6.4th, potassium peroxydisulfate 0.6-0.65, pure-acrylic emulsion 80-85, defoamer NXZ1-1.2, propane diols 2.5-3, butyl glycol ether 4-5,
Cobalt naphthenate 1-1.3, pregelatinized starch 4-4.5, titanium dioxide 9-10, sodium acid carbonate 2-3, waterglass 13-14, lanthanum nitrate 1-
1.2nd, zinc sulfate 2-3；
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous
Or it is several.
2. according to claim 1 it is a kind of addition lanthanum zinc antibacterial silica aqueous colorful sliver coating, it is characterised in that
It is made up of step in detail below：
（1）Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature
Again the deionized water of amount, with stirring and emulsifying 40-50 minute under 800-1000 rev/min of speed, is subsequently adding potassium peroxydisulfate, heats
To 80-85 DEG C, insulation reaction 90-120 minute, discharge after cooling, obtain modifying cinepazid emulsion；Modifying cinepazid emulsion is added and is divided
In scattered machine, stirred with 1500-1800 rev/min of speed, Lauryl Alcohol ester, Sodium Polyacrylate, citric acid three are added while stirring
The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10
The film that thickness is 18-19 microns is made after minute, is dried under the conditions of temperature is for 155-160 DEG C, after product cooling, broken
It is broken, then sieved with the mesh screen of 7-9 millimeter mesh, obtain the colorful compound sliver that is modified；
（2）Sodium acid carbonate is dissolved in after the 2-3 times of deionized water measured and is heated to 50-60 DEG C, mixed with waterglass, be heated to 90-
95 DEG C, adjust pH with after 300-400 rev/min of speed stirring reaction 20-30 minute and lanthanum nitrate, sulphur are sequentially added as 5-6, then
Sour zinc, with suction filtration while hot after 200-300 rev/min of speed stirring reaction 20-30 minute, and is washed with deionized, by filter cake
It is put in baking oven and the filter cake of drying is ground with 110-120 DEG C of drying, cross 300 mesh sieves, obtains lanthanum zinc antibacterial silica；
（3）The deionized water that pregelatinized starch addition total amount 22-24 times is measured, is heated to 60-70 DEG C, with 500-600 rev/min
Speed is cooled to room temperature after stirring 15-20 minutes, add pure-acrylic emulsion, propane diols, butyl glycol ether, continues with 800-1000
Rev/min speed stirring 10-15 minutes after add step（2）Product and remaining residual components, stir 20-30 minutes；
（4）To step in the state of 750-1000 rev/min of stirring（3）Step is slowly added in the product for obtaining（1）Obtain
Be modified colorful compound sliver, obtains final product after being sufficiently stirred for 10-15 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122123.8A CN106634340A (en) | 2016-12-08 | 2016-12-08 | Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122123.8A CN106634340A (en) | 2016-12-08 | 2016-12-08 | Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide |
Publications (1)
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| CN106634340A true CN106634340A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611122123.8A Pending CN106634340A (en) | 2016-12-08 | 2016-12-08 | Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107244884A (en) * | 2017-06-22 | 2017-10-13 | 安徽省德邦瓷业有限公司 | A kind of preparation method for releasing glaze domestic ceramics certainly of antibacterial silica addition |
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|---|---|---|---|---|
| CN101456965A (en) * | 2008-12-30 | 2009-06-17 | 江阴国联化工有限公司 | Method for preparing dry-type water-soluble colorful rock slices |
| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN105017871A (en) * | 2015-07-13 | 2015-11-04 | 华南理工大学 | Ultraviolet-proof exterior wall coating and preparation method therefor |
| CN105219195A (en) * | 2015-09-30 | 2016-01-06 | 三棵树涂料股份有限公司 | A kind of aqueous colorful compound sliver paint and preparation method thereof |
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2016
- 2016-12-08 CN CN201611122123.8A patent/CN106634340A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN101456965A (en) * | 2008-12-30 | 2009-06-17 | 江阴国联化工有限公司 | Method for preparing dry-type water-soluble colorful rock slices |
| CN105017871A (en) * | 2015-07-13 | 2015-11-04 | 华南理工大学 | Ultraviolet-proof exterior wall coating and preparation method therefor |
| CN105219195A (en) * | 2015-09-30 | 2016-01-06 | 三棵树涂料股份有限公司 | A kind of aqueous colorful compound sliver paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 唐晓宁: "亚微细含镧锌系抗菌白炭黑的制备及性能研究", 《硅酸盐通报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107244884A (en) * | 2017-06-22 | 2017-10-13 | 安徽省德邦瓷业有限公司 | A kind of preparation method for releasing glaze domestic ceramics certainly of antibacterial silica addition |
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Application publication date: 20170510 |