CN106590272A - Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall - Google Patents

Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall Download PDF

Info

Publication number
CN106590272A
CN106590272A CN201611123670.8A CN201611123670A CN106590272A CN 106590272 A CN106590272 A CN 106590272A CN 201611123670 A CN201611123670 A CN 201611123670A CN 106590272 A CN106590272 A CN 106590272A
Authority
CN
China
Prior art keywords
stirring
added
deionized water
modified
colorful
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611123670.8A
Other languages
Chinese (zh)
Inventor
孟广科
李强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Fuyang Fujian Building Materials Co Ltd
Original Assignee
Anhui Fuyang Fujian Building Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Fuyang Fujian Building Materials Co Ltd filed Critical Anhui Fuyang Fujian Building Materials Co Ltd
Priority to CN201611123670.8A priority Critical patent/CN106590272A/en
Publication of CN106590272A publication Critical patent/CN106590272A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for an interior wall. Carboxyl and an amido bond are intruded into a polyethyleneimine molecular chain by a chemical grafting method to prepare modified polyethyleneimine, nano-silver is prepared by reducing the modified polyethyleneimine, and the stability of a nano-silver aqueous solution can be improved, so that the antibacterial effect of the coating is improved; and the colorful rock slice coating provided by the invention is applied to decoration of the interior wall, has excellent construction property, excellent leveling property, high painting film adhering capacity, high weather resistance and a lifelike granite imitating effect, reduces the bearing load of the wall body, has excellent antibacterial property, and is healthy, safe and environmentally-friendly.

Description

The enhanced colorful sliver of interior wall of one kind addition modified polyethyleneimine nano silver antibacterial Coating
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of addition modified polyethyleneimine nano silver antibacterial is enhanced Interior wall is with colorful sliver coating.
Background technology
The compound sliver artificial granite paint of aqueouss is also sliver paint, granite mineral varnish, belong to novel pure Water-borne modification without times The sand textured building coating of what solvent-borne type material, is rich in the style of granite, the intension of granite, the noble quality of granite, Hua Gang The grade of rock, is the upgrading kind of traditional natural real stone paint.It is right with extensive application of the new coating in construction market The research that the formula of sliver is combined in building coating is increasingly paid close attention to by numerous research workers.The imitative flower of the compound sliver of aqueouss Hilllock rock coating is formulated with high-quality synthetic resin emulsion, coating colored compound sliver, filler, auxiliary agent etc., with tradition conjunction Resin emulsion sand textured coating is compared, and it is excellent that its application property, Low Temperature Thermal deposit stability, water-fast and alkali resistance, coating temperature-change resistance Good, During Initial Stage Construction does not split, impact resistance, stain resistant, and weather-proof, adhesion strength is high, and coating exactly likes natural granite, can be used in building The decoration of wall and exterior wall, also can be cladding with the natural granite for substituting matter weight as the finish coat of External Thermal Insulation System, Mitigate building to bear a heavy burden, reduce the protection opened Bian, be conducive to ecological environment of granite ore deposit.
Colorful compound sliver is synthesized by high molecular polymer, therefore with superpower water-fast, weatherability, can be with all kinds of aqueouss stones Paint is combined closely.The resistance to tensile strength of compound sliver and pick up determine the quality of compound sliver, so as to determine water paint Quality.《The improvement of composite rock slice prescription in outer wall building coating》By being modified to formula in one text, add wetting agent, divide Powder, defoamer, thickening agent, coalescents, fungusproof anti-corrosion agent, pH value regulators, coordinate acrylate and vinyl acetate emulsion to answer with styrene-acrylic emulsion Match somebody with somebody, make the compound sliver having excellent weather resistance.Although can be lifted compound with acrylate and vinyl acetate emulsion of styrene-acrylic emulsion makes compound sliver Weatherability, but the lifting of the tensile strength, pick up for compound sliver is modified limited, needs further to match somebody with somebody compound sliver Emulsion in side is further modified, to meet the demand of the compound sliver of high-quality, while carrying out to water paint a series of Functional type is modified, to meet demand of the interior wall with colorful sliver paint development.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided one kind addition modified polyethyleneimine nanometer silver Antibacterial enhanced interior wall is with colorful sliver coating.
The present invention is achieved by the following technical solutions:
One kind adds the enhanced interior wall of modified polyethyleneimine nano silver antibacterial with colorful sliver coating, by the original of following weight portion Material preparation is made:Appropriate deionized water, Waterborne Polyurethane Prepolymer 5-6, styrene 4-4.5, n-butyl acrylate 6-6.4, ten Two carbon alcohol ester 1-1.2, sodium polyacrylate 0.45-0.5, trioctyl lemon acid 0.5-0.55, ultra-fine natural color stuffing 60-65, mistake Potassium sulfate 0.6-0.65, pure-acrylic emulsion 80-85, butyl glycol ether 4-5, Propylene Glycol 2.5-3, defoamer NXZ1-1.2, six inclined phosphorus Sour sodium 0.8-1, quartz sand 13-15, xanthan gum 4-5, polyethyleneimine 7-8, the hydroxide of methacrylic acid 3-3.5,1mol/L Appropriate sodium solution, silver nitrate 2-2.4;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
Described one kind adds the enhanced interior wall of modified polyethyleneimine nano silver antibacterial with colorful sliver coating, by following tool Body step is made:
(1)Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under room temperature Again the deionized water of amount, with stirring and emulsifying 40-50 minute under 800-1000 rev/min of speed, is subsequently adding potassium peroxydisulfate, heats To 80-85 DEG C, insulation reaction 90-120 minute, discharge after cooling, obtain modifying cinepazid emulsion;Modifying cinepazid emulsion is added and is divided In scattered machine, stirred with 1500-1800 rev/min of speed, Lauryl Alcohol ester, sodium polyacrylate, citric acid three are added while stirring The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10 The thin film that thickness is 18-19 microns is made after minute, is dried under the conditions of temperature is for 155-160 DEG C, after product cooling, broken It is broken, then sieved with the mesh screen of 7-9 millimeter mesh, obtain the colorful compound sliver that is modified;
(2)Polyethyleneimine is dissolved in the 10-12 times of deionized water measured, metering system is added dropwise under stirring under room temperature Acid, continues stirring reaction 3-4 hour after being added dropwise to complete, it is 10 that reaction adjusts pH after terminating with the sodium hydroxide solution of 1mol/L, Then it is put into be evaporated under reduced pressure in Rotary Evaporators after carrying out dialysis in deionized water 2-2.5 days and removes moisture, obtains modified poly- Aziridine;Modified polyethyleneimine is dissolved in the 8-10 times of deionized water measured to be formed to be added after solution and is dissolved in 3-5 times and is measured The silver nitrate of ionized water, is put on electric furnace after stirring and is heated to boiling, and after solution yellowing modified poly ethylene is obtained Imine nanometer silver aqueous solution;
(3)The deionized water that xanthan gum addition total amount 22-24 times is measured, is heated to 50-60 DEG C, with 500-600 rev/min of speed Room temperature is cooled to after stirring 15-20 minutes, pure-acrylic emulsion, Propylene Glycol, butyl glycol ether is added, is continued with 800-1000 rev/min Speed stirring 10-15 minutes after add step(2)Product and remaining residual components, stir 20-30 minutes;
(4)To step in the state of 750-1000 rev/min of stirring(3)Step is slowly added in the product for obtaining(1)Obtain Be modified colorful compound sliver, obtains final product after being sufficiently stirred for 10-15 minutes.
It is an advantage of the invention that:The present invention is added in the preparation of styrene-acrylic emulsion first with Waterborne Polyurethane Prepolymer, Without any emulsifying agent, using Waterborne Polyurethane Prepolymer as emulsifying agent, the elongation at break of emulsion, water-fast is improved Property, enhance the tensile strength of compound sliver and reduce pick up, simultaneously because addition trioctyl lemon acid and 12 carbon Cooperating for alcohol ester, improves the molding shape of compound sliver, not broken;The present invention will meet sliver and mutually tie with pure-acrylic emulsion Close, the interior wall coating artificial granite effect prepared is good, high from heavy and light, bin stability, full aqueouss safety non-toxic, while reducing The exploitation of granite, is conducive to ecological protection.
The present invention introduces carboxyl and amido link using chemical graft method in polyethyleneimine strand, prepares modified poly- Aziridine, then prepare nanometer silver with its reduction, it is possible to increase the stability of nano-silver water solution, so as to improve the anti-of coating Bacterium effect;Colorful sliver coating made by the present invention, for the decoration of interior wall, workability is excellent, and levelability is good, paint film attachment Power is good, good weatherability, possesses artificial granite effect true to nature, alleviates body of wall heavy burden, is provided simultaneously with excellent anti-microbial property, is good for Health safety and environmental protection.
Specific embodiment
One kind adds the enhanced interior wall of modified polyethyleneimine nano silver antibacterial with colorful sliver coating, by following weight portion (Kilogram)Raw material make:Appropriate deionized water, Waterborne Polyurethane Prepolymer 5, styrene 4, n-butyl acrylate 6, ten It is two carbon alcohol esters 1, sodium polyacrylate 0.45, trioctyl lemon acid 0.5, ultra-fine natural color stuffing 60, potassium peroxydisulfate 0.6, pure third newborn Liquid 80, butyl glycol ether 4, Propylene Glycol 2.5, defoamer NXZ1, sodium hexameta phosphate 0.8, quartz sand 13, xanthan gum 4, polyethyleneimine Amine 7, methacrylic acid 3,1mol/L sodium hydroxide solution is appropriate, silver nitrate 2;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
Described one kind adds the enhanced interior wall of modified polyethyleneimine nano silver antibacterial with colorful sliver coating, by following tool Body step is made:
(1)Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under room temperature The deionized water of times amount, with stirring and emulsifying under 800 revs/min of speed 40 minutes, is subsequently adding potassium peroxydisulfate, is heated to 80 DEG C, Insulation reaction 90 minutes, discharges after cooling, obtains modifying cinepazid emulsion;Modifying cinepazid emulsion is added in dispersion machine, with 1500 Rev/min speed stirring, while stirring add Lauryl Alcohol ester, sodium polyacrylate, trioctyl lemon acid and total amount equivalent Deionized water, continues to add ultra-fine natural color stuffing after stirring 10 minutes, and it is 18 microns to continue to make thickness after stirring 8 minutes Thin film, dries under the conditions of temperature is for 155 DEG C, after product cooling, is crushed, and then with the mesh screen screening of 7 millimeters of mesh, obtains To modified colorful compound sliver;
(2)Polyethyleneimine is dissolved in the deionized water of 10 times of amounts, methacrylic acid is added dropwise under stirring under room temperature, Continue stirring reaction 3 hours after being added dropwise to complete, it is 10, Ran Hou that reaction adjusts pH after terminating with the sodium hydroxide solution of 1mol/L It is put into be evaporated under reduced pressure in Rotary Evaporators after dialysis being carried out in deionized water 2 days and removes moisture, obtains modified polyethyleneimine;Will Modified polyethyleneimine is dissolved in the deionized water of 8 times of amounts being formed and the silver nitrate for being dissolved in 3 times of amount deionized waters is added after solution, stirs It is put on electric furnace after mixing uniformly and is heated to boiling, modified polyethyleneimine nano-silver water solution is obtained after solution yellowing;
(3)Xanthan gum is added into the deionized water of 22 times of amounts of total amount, 50 DEG C are heated to, is stirred 15 minutes with 500 revs/min of speed After be cooled to room temperature, pure-acrylic emulsion, Propylene Glycol, butyl glycol ether are added, after continuing to be stirred 10 minutes with 800 revs/min of speed Add step(2)Product and remaining residual components, stir 20 minutes;
(4)To step in the state of 750 revs/min of stirrings(3)Step is slowly added in the product for obtaining(1)What is obtained is modified more The compound sliver of coloured silk, obtains final product after being sufficiently stirred for 10 minutes.
It is uniform after coating stirring obtained in the embodiment of the present invention that without shadow is fast, application property is good, easily spraying, levelability is good, Low tempertaure storage without caking, heat-storage without lump, go mouldy, condense and constituent change, surface drying time is less than 4 hours;Film is resistance to Water, alkaline-resisting 48 hours nothings rise and rouse, ftracture, coming off;Adhesion strength is more than 0.5MPa, meets national standard.

Claims (2)

1. it is a kind of to add the modified polyethyleneimine nano silver antibacterial colorful sliver coating of enhanced interior wall, it is characterised in that by The raw material of following weight portion is made:Appropriate deionized water, Waterborne Polyurethane Prepolymer 5-6, styrene 4-4.5, acrylic acid It is N-butyl 6-6.4, Lauryl Alcohol ester 1-1.2, sodium polyacrylate 0.45-0.5, trioctyl lemon acid 0.5-0.55, ultra-fine natural Color stuffing 60-65, potassium peroxydisulfate 0.6-0.65, pure-acrylic emulsion 80-85, butyl glycol ether 4-5, Propylene Glycol 2.5-3, defoamer NXZ1-1.2, sodium hexameta phosphate 0.8-1, quartz sand 13-15, xanthan gum 4-5, polyethyleneimine 7-8, methacrylic acid 3-3.5, The sodium hydroxide solution of 1mol/L is appropriate, silver nitrate 2-2.4;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
2. according to claim 1 a kind of enhanced interior wall of addition modified polyethyleneimine nano silver antibacterial is applied with colorful sliver Material, it is characterised in that be made up of step in detail below:
(1)Waterborne Polyurethane Prepolymer is put in reactor, styrene, n-butyl acrylate and total amount 4 are added under room temperature Again the deionized water of amount, with stirring and emulsifying 40-50 minute under 800-1000 rev/min of speed, is subsequently adding potassium peroxydisulfate, heats To 80-85 DEG C, insulation reaction 90-120 minute, discharge after cooling, obtain modifying cinepazid emulsion;Modifying cinepazid emulsion is added and is divided In scattered machine, stirred with 1500-1800 rev/min of speed, Lauryl Alcohol ester, sodium polyacrylate, citric acid three are added while stirring The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10 The thin film that thickness is 18-19 microns is made after minute, is dried under the conditions of temperature is for 155-160 DEG C, after product cooling, broken It is broken, then sieved with the mesh screen of 7-9 millimeter mesh, obtain the colorful compound sliver that is modified;
(2)Polyethyleneimine is dissolved in the 10-12 times of deionized water measured, metering system is added dropwise under stirring under room temperature Acid, continues stirring reaction 3-4 hour after being added dropwise to complete, it is 10 that reaction adjusts pH after terminating with the sodium hydroxide solution of 1mol/L, Then it is put into be evaporated under reduced pressure in Rotary Evaporators after carrying out dialysis in deionized water 2-2.5 days and removes moisture, obtains modified poly- Aziridine;Modified polyethyleneimine is dissolved in the 8-10 times of deionized water measured to be formed to be added after solution and is dissolved in 3-5 times and is measured The silver nitrate of ionized water, is put on electric furnace after stirring and is heated to boiling, and after solution yellowing modified poly ethylene is obtained Imine nanometer silver aqueous solution;
(3)The deionized water that xanthan gum addition total amount 22-24 times is measured, is heated to 50-60 DEG C, with 500-600 rev/min of speed Room temperature is cooled to after stirring 15-20 minutes, pure-acrylic emulsion, Propylene Glycol, butyl glycol ether is added, is continued with 800-1000 rev/min Speed stirring 10-15 minutes after add step(2)Product and remaining residual components, stir 20-30 minutes;
(4)To step in the state of 750-1000 rev/min of stirring(3)Step is slowly added in the product for obtaining(1)Obtain Be modified colorful compound sliver, obtains final product after being sufficiently stirred for 10-15 minutes.
CN201611123670.8A 2016-12-08 2016-12-08 Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall Pending CN106590272A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611123670.8A CN106590272A (en) 2016-12-08 2016-12-08 Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611123670.8A CN106590272A (en) 2016-12-08 2016-12-08 Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall

Publications (1)

Publication Number Publication Date
CN106590272A true CN106590272A (en) 2017-04-26

Family

ID=58598672

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611123670.8A Pending CN106590272A (en) 2016-12-08 2016-12-08 Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall

Country Status (1)

Country Link
CN (1) CN106590272A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456965A (en) * 2008-12-30 2009-06-17 江阴国联化工有限公司 Method for preparing dry-type water-soluble colorful rock slices
CN104342002A (en) * 2014-10-14 2015-02-11 凤阳徽亨商贸有限公司 Anti-corrosion coating capable of emitting aromatic odor for glass door and preparation method of anti-corrosion coating
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105925095A (en) * 2016-05-03 2016-09-07 梁冬 Wear-resistant fireproof modified coating for building interior wall

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456965A (en) * 2008-12-30 2009-06-17 江阴国联化工有限公司 Method for preparing dry-type water-soluble colorful rock slices
CN104342002A (en) * 2014-10-14 2015-02-11 凤阳徽亨商贸有限公司 Anti-corrosion coating capable of emitting aromatic odor for glass door and preparation method of anti-corrosion coating
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105925095A (en) * 2016-05-03 2016-09-07 梁冬 Wear-resistant fireproof modified coating for building interior wall

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈家力等: "改性聚乙烯亚胺/纳米银的制备及其在棉织物中的应用", 《纺织学报》 *

Similar Documents

Publication Publication Date Title
CN103013298B (en) A kind of powder coating containing modified Nano carbon and preparation method thereof
CN103059696B (en) A kind of powder coating containing modified meerschaum powder and preparation method thereof
CN103013296B (en) A kind of containing attapulgite modified powder coating and preparation method thereof
CN102627902B (en) Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof
CN103045044B (en) Powder coating of a kind of energy-conserving and environment-protective and preparation method thereof
CN103013279B (en) A kind of powdery paints that contains modification trees ashes and preparation method thereof
CN103937388B (en) Nano combined gel coat of weather resistant and preparation method thereof
CN103319991A (en) Nanometer powder coating and preparation method thereof
CN108084841A (en) A kind of acidproof alkaline simulating golden colour powdery paints and preparation method thereof
CN109294347A (en) A kind of Gao Baose water paint and production method
CN105315799A (en) Formula and preparation method of interior wall latex paint
CN102351464A (en) Nanometer calcium carbonate paint and production process
CN104877504A (en) Graphene added anticorrosion latex paint for outer wall and preparation method thereof
CN100480339C (en) Modified barite and preparation method thereof
CN104650721A (en) Waterproof paint with high corrosion resistance and adhesive property and preparation method of waterproof paint
CN106590272A (en) Modified polyethyleneimine nano-silver added and antibacterial property enhanced colorful rock slice coating for interior wall
CN106634342A (en) Multicolor rock slice paint added with platinum-loaded activated kaolin and achieving indoor air purification effect
CN106675281A (en) Colorful rock slice coating with graphite grafted polyaniline and with electromagnetic shielding effect
CN103614018A (en) Development of elastic antiacid energy-saving environment-friendly texture coating
CN106634340A (en) Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide
CN101864235B (en) Method for preparing exterior wall coating
CN104312387B (en) Starlight pattern powder coating and preparation method thereof
CN106854410A (en) A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping
CN106675282A (en) Adsorption and purification enhanced colored rock sheet inner wall coating with porous starch with synergic honeycomb-shaped manganese dioxide
CN104292900A (en) Toughened ceramic-like waterproof coating for automobile

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170426