CN106366742A - Water-based multicolor stone like coating and preparation method thereof - Google Patents
Water-based multicolor stone like coating and preparation method thereof Download PDFInfo
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- CN106366742A CN106366742A CN201610759240.9A CN201610759240A CN106366742A CN 106366742 A CN106366742 A CN 106366742A CN 201610759240 A CN201610759240 A CN 201610759240A CN 106366742 A CN106366742 A CN 106366742A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a water-based multicolor stone like coating. The coating is prepared from 7% parts of pre-binding buffer, color master batch, and silicone acrylic emulsion. The color master batch is prepared from deionized water, preservative, dry film antiseptic, methyl hydroxyethyl cellulose, diethanol amine, dispersant, surfactant, titanium dioxide, elastic silicone acrylic emulsion, coalescing agent, antifoaming agent, 10% lithium magnesium silicate solution, and color paste; the preparation of the water-based multicolor stone like coating is a process of mixing 7% parts of pre-binding buffer, color master batch, and silicone acrylic emulsion then filtering the mixture. The present invention provides water-based multicolor stone like coating and preparation method thereof. The stability of the stone like coating is high; the hardness, the anti-cracking and anti-graffiti abilities of the coating are good. The durability of the product, especially the water resistance, water white resistance, weather resistance, and acid and alkali resistance are better than the qualities of other products of the same type. The product achieves the effect of being almost naturally stone like.
Description
Technical field
The invention belongs to technical field of coatings is and in particular to a kind of aqueous colorful stone-like coating and preparation method thereof.
Background technology
Colorful stone-like coating is mainly used in imitation stone material, so also known as liquid stone, colorful stone-like coating is art coatings
The very big class coating of middle manufacture difficulty, its effect is vivid, either texture, or color is all close to lithotome,
Simply slightly it is short of in hardness.
Conventionally, as being natural stone to be imitated by manual method, by raw material and production technology shadow in itself
Ring, to the fidelity of granite, marble etc. not, along with production technology is complex and difficulty is larger so that at present
Colorful stone-like coating on market is poor in anti-scribble performance, and less stable, resistance to water, water-whitening resistance are inadequate simultaneously
Ideal, is easy to fall off under adverse weather condition.
Content of the invention
Not enough for prior art, the invention provides a kind of aqueous colorful stone-like coating and preparation method thereof, this imitative stone
Paint stability is high, hardness is good, cracking resistance, anti-scribble are good, the durability of product especially resistance to water, water-whitening resistance, weather-proof
Property, resistance to acids and bases are all better than other products similar, have reached the effect closer to lithotome；This preparation method process is simple,
Easy to operate, controllability is strong.
For realizing goal of the invention, the present invention employs the following technical solutions:
A kind of aqueous colorful stone-like coating, including 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, its weight portion is:
7% pre- sol solutionses 10-30 part；
Colored masterbatch 30-50 part；
Silicone acrylic emulsion 30-50 part；
Described colour masterbatch includes following components, by weight:
Deionized water 50-55 part；
Preservative 0.1-0.3 part；
Dry film antifungus agent 0.2-0.4 part；
Methyl ethyl hydroxyethyl cellulose 0.4-0.8 part；
Diethanolamine 0.1-0.3 part；
Dispersant 0.3-0.7 part；
Surfactant 0.05-0.2 part；
Titanium dioxide 1-5 part；
Elastic silicone acrylic emulsion 20-40 part；
Coalescents 0.5-1.5 part；
Defoamer 0.2-0.3 part；
10% lithium magnesium silicate solution 5-15 part；
Mill base 1-3 part.
It is preferably, the weight portion of described 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion is:
7% 20 parts of pre- sol solutionses；
40 parts of colored masterbatch；
40 parts of silicone acrylic emulsion；
The weight portion of described colour masterbatch is:
52.4 parts of deionized water；
0.2 part of preservative；
0.3 part of dry film antifungus agent；
0.6 part of methyl ethyl hydroxyethyl cellulose；
0.2 part of diethanolamine；
0.5 part of dispersant；
0.1 part of surfactant；
2.5 parts of titanium dioxide；
30 parts of elastic silicone acrylic emulsion；
1 part of coalescents；
0.2 part of defoamer；
10% 10 parts of lithium magnesium silicate solution；
2 parts of mill base.
It is preferably, described preservative is one or more of zincum salts, silver salt class, copper salt kind.
Be preferably, described dispersant is commercially available Quadrafos, any one or two kinds in polyacrylate any
Mixture.
It is preferably, described coalescents select TMPD isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether
Or its mixture.
Be preferably, described defoamer is commercial mineral oils defoamer, in organic silicon defoamer any one or two
Any mixture planted.
The preparation method of the aqueous colorful stone-like coating of the present invention, comprises the steps:
Step one, after putting into deionized water, opens dispersion machine and adjusts rotating speed 200-300rpm/min, by suitable in dispersion paint mixing kettle
Sequence is gradually added preservative, dry film antifungus agent, methyl ethyl hydroxyethyl cellulose, diethanolamine, dispersant, surfactant
Afterwards, step up rotating speed to 1000-1200rpm/min, disperse 5 minutes, dispersion uniformly adds titanium white after translucent paste
Powder, continues dispersion 20 minutes at a high speed, reduces rotating speed to 800 rpm/min after fineness≤40um, sequentially adds flexible silicon third breast
Liquid, coalescents, defoamer, 10% lithium magnesium silicate solution, adding mill base, to be tuned into required color stand-by；
Step 2, adds mix homogeneously after colored masterbatch in 7% pre- sol solutionses, then becomes various with the strainer filtering of regulation particle diameter
The color grains of specification, place 30 minutes, add silicone acrylic emulsion to get product after cladding.
The invention has the beneficial effects as follows: the invention provides a kind of aqueous colorful stone-like coating and preparation method thereof, this is imitated
Stone paint stability is high, hardness is good, cracking resistance, anti-scribble are good, the durability of product especially resistance to water, water-whitening resistance, resistance to
Hou Xing, resistance to acids and bases are all better than other products similar, have reached the effect closer to lithotome；This preparation method technique letter
Single, easy to operate, controllability is strong.
Specific embodiment
Below by specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of aqueous colorful stone-like coating, including 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, its weight portion is:
7% pre- sol solutionses 10-30 part；
Colored masterbatch 30-50 part；
Silicone acrylic emulsion 30-50 part；
Described colour masterbatch includes following components, by weight:
Deionized water 50-55 part；
Preservative 0.1-0.3 part；
Dry film antifungus agent 0.2-0.4 part；
Methyl ethyl hydroxyethyl cellulose 0.4-0.8 part；
Diethanolamine 0.1-0.3 part；
Dispersant 0.3-0.7 part；
Surfactant 0.05-0.2 part；
Titanium dioxide 1-5 part；
Elastic silicone acrylic emulsion 20-40 part；
Coalescents 0.5-1.5 part；
Defoamer 0.2-0.3 part；
10% lithium magnesium silicate solution 5-15 part；
Mill base 1-3 part.
Additionally, described preservative is one or more of zincum salts, silver salt class, copper salt kind, described dispersant is commercially available
Any mixture of any one or two kinds in Quadrafos, polyacrylate, described coalescents select trimethyl penta
Glycol isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether or its mixture, described defoamer is commercial mineral oils froth breaking
Any mixture of any one or two kinds in agent, organic silicon defoamer.
Additionally, described dispersant is Tao Shi 731a dispersant, described surfactant is Tao Shi bd405 surfactant,
Described titanium dioxide is Du Pont's r902+ titanium dioxide.
The preparation method of the aqueous colorful stone-like coating of the present invention, comprises the steps:
Step one, after putting into deionized water, opens dispersion machine and adjusts rotating speed 200-300rpm/min, by suitable in dispersion paint mixing kettle
Sequence is gradually added preservative, dry film antifungus agent, methyl ethyl hydroxyethyl cellulose, diethanolamine, dispersant, surfactant
Afterwards, step up rotating speed to 1000-1200rpm/min, disperse 5 minutes, dispersion uniformly adds titanium white after translucent paste
Powder, continues dispersion 20 minutes at a high speed, reduces rotating speed to 800 rpm/min after fineness≤40um, sequentially adds flexible silicon third breast
Liquid, coalescents, defoamer, 10% lithium magnesium silicate solution, adding mill base, to be tuned into required color stand-by；
Step 2, adds mix homogeneously after colored masterbatch in 7% pre- sol solutionses, then becomes various with the strainer filtering of regulation particle diameter
The color grains of specification, place 30 minutes, add silicone acrylic emulsion to get product after cladding.
Embodiment 2
The preparation method of aqueous colorful stone-like coating is same as Example 1, and difference is:
A kind of aqueous colorful stone-like coating, including 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, its weight portion is:
7% 20 parts of pre- sol solutionses；
40 parts of colored masterbatch；
40 parts of silicone acrylic emulsion；
The weight portion of described colour masterbatch is:
52.4 parts of deionized water；
0.2 part of preservative；
0.3 part of dry film antifungus agent；
0.6 part of methyl ethyl hydroxyethyl cellulose；
0.2 part of diethanolamine；
0.5 part of dispersant；
0.1 part of surfactant；
2.5 parts of titanium dioxide；
30 parts of elastic silicone acrylic emulsion；
1 part of coalescents；
0.2 part of defoamer；
10% 10 parts of lithium magnesium silicate solution；
2 parts of mill base.
Additionally, described preservative is one or more of zincum salts, silver salt class, copper salt kind, described dispersant is commercially available
Any mixture of any one or two kinds in Quadrafos, polyacrylate, described coalescents select trimethyl penta
Glycol isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether or its mixture, described defoamer is commercial mineral oils froth breaking
Any mixture of any one or two kinds in agent, organic silicon defoamer.
Additionally, described dispersant is Tao Shi 731a dispersant, described surfactant is Tao Shi bd405 surfactant,
Described titanium dioxide is Du Pont's r902+ titanium dioxide.
Embodiment 3
The preparation method of aqueous colorful stone-like coating is same as Example 1, and difference is:
A kind of aqueous colorful stone-like coating, including 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, its weight portion is:
7% 10 parts of pre- sol solutionses；
50 parts of colored masterbatch；
40 parts of silicone acrylic emulsion；
Described colour masterbatch includes following components, by weight:
55 parts of deionized water；
0.1 part of preservative；
0.2 part of dry film antifungus agent；
0.4 part of methyl ethyl hydroxyethyl cellulose；
0.1 part of diethanolamine；
0.3 part of dispersant；
0.1 part of surfactant；
1 part of titanium dioxide；
26.1 parts of elastic silicone acrylic emulsion；
0.5 part of coalescents；
0.2 part of defoamer；
10% 15 parts of lithium magnesium silicate solution；
1 part of mill base.
Additionally, described preservative is one or more of zincum salts, silver salt class, copper salt kind, described dispersant is commercially available
Any mixture of any one or two kinds in Quadrafos, polyacrylate, described coalescents select trimethyl penta
Glycol isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether or its mixture, described defoamer is commercial mineral oils froth breaking
Any mixture of any one or two kinds in agent, organic silicon defoamer.
Additionally, described dispersant is Tao Shi 731a dispersant, described surfactant is Tao Shi bd405 surfactant,
Described titanium dioxide is Du Pont's r902+ titanium dioxide.
Embodiment 4
The preparation method of aqueous colorful stone-like coating is same as Example 1, and difference is:
A kind of aqueous colorful stone-like coating, including 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, its weight portion is:
7% 30 parts of pre- sol solutionses；
40 parts of colored masterbatch；
30 parts of silicone acrylic emulsion；
Described colour masterbatch includes following components, by weight:
50 parts of deionized water；
0.3 part of preservative；
0.4 part of dry film antifungus agent；
0.8 part of methyl ethyl hydroxyethyl cellulose；
0.3 part of diethanolamine；
0.7 part of dispersant；
0.2 part of surfactant；
5 parts of titanium dioxide；
32.5 parts of elastic silicone acrylic emulsion；
1.5 parts of coalescents；
0.3 part of defoamer；
10% 5 parts of lithium magnesium silicate solution；
3 parts of mill base.
Additionally, described preservative is one or more of zincum salts, silver salt class, copper salt kind, described dispersant is commercially available
Any mixture of any one or two kinds in Quadrafos, polyacrylate, described coalescents select trimethyl penta
Glycol isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether or its mixture, described defoamer is commercial mineral oils froth breaking
Any mixture of any one or two kinds in agent, organic silicon defoamer.
Additionally, described dispersant is Tao Shi 731a dispersant, described surfactant is Tao Shi bd405 surfactant,
Described titanium dioxide is Du Pont's r902+ titanium dioxide.
The foregoing is only the specific embodiment of the present invention, but the architectural feature of the present invention is not limited thereto, the present invention
Can be used on similar product, in the field of the invention, the change made or modification are all for any those skilled in the art
Cover among the scope of the claims of the present invention.
Claims (7)
1. a kind of aqueous colorful stone-like coating it is characterised in that: include 7% pre- sol solutionses, colored masterbatch and silicone acrylic emulsion, it is heavy
Amount part is:
7% pre- sol solutionses 10-30 part；
Colored masterbatch 30-50 part；
Silicone acrylic emulsion 30-50 part；
Described colour masterbatch includes following components, by weight:
Deionized water 50-55 part；
Preservative 0.1-0.3 part；
Dry film antifungus agent 0.2-0.4 part；
Methyl ethyl hydroxyethyl cellulose 0.4-0.8 part；
Diethanolamine 0.1-0.3 part；
Dispersant 0.3-0.7 part；
Surfactant 0.05-0.2 part；
Titanium dioxide 1-5 part；
Elastic silicone acrylic emulsion 20-40 part；
Coalescents 0.5-1.5 part；
Defoamer 0.2-0.3 part；
10% lithium magnesium silicate solution 5-15 part；
Mill base 1-3 part.
2. aqueous colorful stone-like coating as claimed in claim 1 it is characterised in that: described 7% pre- sol solutionses, colored masterbatch and
The weight portion of silicone acrylic emulsion is:
7% 20 parts of pre- sol solutionses；
40 parts of colored masterbatch；
40 parts of silicone acrylic emulsion；
The weight portion of described colour masterbatch is:
52.4 parts of deionized water；
0.2 part of preservative；
0.3 part of dry film antifungus agent；
0.6 part of methyl ethyl hydroxyethyl cellulose；
0.2 part of diethanolamine；
0.5 part of dispersant；
0.1 part of surfactant；
2.5 parts of titanium dioxide；
30 parts of elastic silicone acrylic emulsion；
1 part of coalescents；
0.2 part of defoamer；
10% 10 parts of lithium magnesium silicate solution；
2 parts of mill base.
3. aqueous colorful stone-like coating as claimed in claim 1 or 2 it is characterised in that: described preservative be zincum salts, silver salt
One or more of class, copper salt kind.
4. aqueous colorful stone-like coating as claimed in claim 1 or 2 it is characterised in that: described dispersant be commercially available polyphosphoric acid
Any mixture of any one or two kinds in salt, polyacrylate.
5. aqueous colorful stone-like coating as claimed in claim 1 or 2 it is characterised in that: described coalescents select trimethyl
Pentanediol isobutyrate, propylene glycol, one kind of dipropylene glycol methyl ether or its mixture.
6. aqueous colorful stone-like coating as claimed in claim 1 or 2 it is characterised in that: described defoamer be commercial mineral oil
Any mixture of any one or two kinds in class defoamer, organic silicon defoamer.
7. the method for aqueous colorful stone-like coating described in preparation claim 1-6 any one is it is characterised in that include as follows
Step:
Step one, after putting into deionized water, opens dispersion machine and adjusts rotating speed 200-300rpm/min, by suitable in dispersion paint mixing kettle
Sequence is gradually added preservative, dry film antifungus agent, methyl ethyl hydroxyethyl cellulose, diethanolamine, dispersant, surfactant
Afterwards, step up rotating speed to 1000-1200 rpm/min, disperse 5 minutes, dispersion uniformly adds titanium white after translucent paste
Powder, continues dispersion 20 minutes at a high speed, reduces rotating speed to 800rpm/min after fineness≤40um, sequentially adds flexible silicon third breast
Liquid, coalescents, defoamer, 10% lithium magnesium silicate solution, adding mill base, to be tuned into required color stand-by；
Step 2, adds mix homogeneously after colored masterbatch in 7% pre- sol solutionses, then becomes various with the strainer filtering of regulation particle diameter
The color grains of specification, place 30 minutes, add silicone acrylic emulsion to get product after cladding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610759240.9A CN106366742A (en) | 2016-08-30 | 2016-08-30 | Water-based multicolor stone like coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610759240.9A CN106366742A (en) | 2016-08-30 | 2016-08-30 | Water-based multicolor stone like coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366742A true CN106366742A (en) | 2017-02-01 |
Family
ID=57901294
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| CN201610759240.9A Pending CN106366742A (en) | 2016-08-30 | 2016-08-30 | Water-based multicolor stone like coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109750807A (en) * | 2018-11-29 | 2019-05-14 | 宁波华宝石节能科技股份有限公司 | Sandstone metope and its construction method |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008073273A2 (en) * | 2006-12-08 | 2008-06-19 | E. I. Du Pont De Nemours And Company | Water-based coating composition |
| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN102311691A (en) * | 2011-07-27 | 2012-01-11 | 吴锦章 | Novel colorful wall paint |
| CN105038470A (en) * | 2015-07-31 | 2015-11-11 | 纽沃得复合建材（上海）有限公司 | Multicolored paint and preparation method thereof |
-
2016
- 2016-08-30 CN CN201610759240.9A patent/CN106366742A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008073273A2 (en) * | 2006-12-08 | 2008-06-19 | E. I. Du Pont De Nemours And Company | Water-based coating composition |
| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN102311691A (en) * | 2011-07-27 | 2012-01-11 | 吴锦章 | Novel colorful wall paint |
| CN105038470A (en) * | 2015-07-31 | 2015-11-11 | 纽沃得复合建材（上海）有限公司 | Multicolored paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109750807A (en) * | 2018-11-29 | 2019-05-14 | 宁波华宝石节能科技股份有限公司 | Sandstone metope and its construction method |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
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Application publication date: 20170201 |