CN107189690A - A kind of anticracking environment-friendly type paint and preparation method thereof - Google Patents
A kind of anticracking environment-friendly type paint and preparation method thereof Download PDFInfo
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- CN107189690A CN107189690A CN201710543785.0A CN201710543785A CN107189690A CN 107189690 A CN107189690 A CN 107189690A CN 201710543785 A CN201710543785 A CN 201710543785A CN 107189690 A CN107189690 A CN 107189690A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/007—Fragrance additive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses anticracking environment-friendly type paint, including following parts by weight of component：18 22 parts of bean plant short oil class alkyd resin, 30 36 parts of Hydroxylated acrylic resin, 12 16 parts of epoxy resin freezing plastic, 35 46 parts of rosin, 59 parts of sodium carboxymethylcellulose, 3 12 parts of sodium silicoaluminate, 0.1 0.7 parts of essential oil, 12 22 parts of iron chloride, 14 parts of pigment, 0.1 0.3 parts of dibutyl tin laurate, 58 parts of stabilizer.The paint has good crack resistence performance, as the growth of use time is not in the phenomenon that comes off of cracking, and nontoxic, and poisonous volatilization gas will not be given out in use, does not have any influence to the body of people, has a safety feature.In addition present invention also offers a kind of method for preparing above-mentioned anticracking environment-friendly type paint, this method is simple to operate, and fidelity factor is high.
Description
Technical field
The present invention relates to paint technology field, and in particular to a kind of anticracking environment-friendly type paint and preparation method thereof.
Background technology
The origin of paint there is no final conclusion, and B.C. 6000, China was baking mixed with inorganic compound and organic pigment
Paint is improved；B.C. 1500, in French and Hispanic cavern, paint had been used for painting and decorated；It is Egyptian
People manufacture blueness and red pigment with dyestuff such as indigo and madder, but this paint is still far from perfect；18th century, due to flax
The exploitation of benevolence oil and zinc oxide, develop paint industry rapidly；20th century, painting technology has significant development, occurs in that
Adhesion strength bigger, glossiness is higher, fire-retardant, anticorrosive most with vegetable oil with the high a variety of colors of heat endurance paint early stage
For primary raw material, therefore it is called " paint ".
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses is mixed
Compound coating.Paint as thickness oil colour, it is not dry in the case of it is inflammable, it is water insoluble, be slightly soluble in fat, dissolve in alcohol, aldehyde,
Ether, benzene, alkane, are soluble in gasoline, kerosene, diesel oil.Paint species is many currently on the market, but mainly contains toluene, also there is a small amount of
Benzene, influences very big to human body.
Environment protection oil paint refers to the performance indications of painting, safety index on the premise of respective product standard is met.Symbol
Close the painting for the technical requirements that National Environmental famous special product is proposed.Be applied to body surface can be formed with protection, decoration or
A class I liquid I or the general name of solid material for the solid coated film of property.Paint is indispensable during Household fit-up and decoration
One of material, in recent years, with the continuous improvement of people's lives, and environmentally friendly cry grows to even greater heights, and people are to decoration
The requirement more and more higher of paint.Because it is family expenses it should be further noted that environmental protection and security, paint species now on the market are various, but
It is the increase with people to the functional requirement of paint, existing paint can not meet this needs of people, and paint is
Through being no longer only only to require excellent protective value, decoration functions, there is higher requirement to its security, in addition existing market
On the paint that uses will lose viscosity with the growth of use time, cause oil paint cracking to come off；In simultaneously general paint
There is poisonous volatilization gas in face, and people suck these poisonous volatilization gas for a long time, it will the serious body for having had influence on people
Body health.
The content of the invention
In view of the defect of above-mentioned prior art, the invention solves the problems that technical problem is to provide a kind of anticracking environment-friendly type paint,
It is required that the component of the paint is free of harmful raw material of substance, it is environmentally friendly, and its adhesive force is good, it is not easy to crack to come off, use the longevity
Life length；The present invention also provides a kind of method for preparing above-mentioned anticracking environment-friendly type paint in addition, and this method is simple to operate, fidelity factor
It is high.
In view of the above-mentioned technical problem to be solved, the present invention provides following technical solution：A kind of anticracking environment-friendly type
Paint, including following parts by weight of component：18-22 parts of bean plant short oil class alkyd resin, 30-36 parts of Hydroxylated acrylic resin,
12-16 parts of epoxy resin freezing plastic, 35-46 parts of rosin, 5-9 parts of sodium carboxymethylcellulose, 3-12 parts of sodium silicoaluminate, essential oil 0.1-
0.7 part, 12-22 parts of iron chloride, 1-4 parts of pigment, 0.1-0.3 parts of dibutyl tin laurate, 5-8 parts of stabilizer.
It is preferred that, the paint includes following parts by weight of component：20 parts of bean plant short oil class alkyd resin, hydroxy
33 parts of acid resin, 14 parts of epoxy resin freezing plastic, 40 parts of rosin, 7 parts of sodium carboxymethylcellulose, 10 parts of sodium silicoaluminate, essential oil 0.4
Part, 19 parts of iron chloride, 3 parts of pigment, 0.2 part of dibutyl tin laurate, 6 parts of stabilizer.
It is preferred that, the pigment type is organic pigment.
It is preferred that, the essential oil is osmanthus essential oil, refined jasmine oil, honeysuckle essential oil, tea tree ethereal oil, Peppermint essential oil, santal
One or more combination in essential oil, Chinese ilex essential oil, lemon or clove oil.
It is preferred that, the stabilizer is any one in organotin, lead salt and zinc soap.
Present invention also offers a kind of method for preparing above-mentioned environment protection oil paint, comprise the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 30-60 DEG C, until being completely dissolved；
（2）Pigment, dibutyl tin laurate and stabilizer are placed on into another vessel in heating to be stirred to 50-80 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 10-30 minutes.
It is preferred that, step（1）In heating-up temperature be 50 DEG C.
It is preferred that, step（2）In heating-up temperature be 80 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows：
（1）In the present invention by add Hydroxylated acrylic resin, bean plant short oil class alkyd resin, epoxy resin freezing plastic,
Pigment ensures that the environment protection oil paint prepared has good crack resistence performance, is not in out with the growth of use time
Split the phenomenon come off；
（2）The harmful substances such as formaldehyde and trimethylbenzene are not contained in the raw material of the present invention, it is to avoid in conventional paint drying process
Air pollution, using safety, to the basic non-hazardous of operating personnel, realizes clean manufacturing；From nontoxic natural pigment and auxiliary agent
The environment protection oil paint of development, indices have reached real requirement, because it is nontoxic, not only reduce environmental pollution, improve
Coating efficiency, reduces construction link, has saved operating expenses；
（3）Essential oil component is with the addition of in the environment protection oil paint of the present invention, it, which has, releives and bracing effect, for some diseases
Disease, also releives and mitigates the function of symptom, and can also play purification air, sterilization, the effect sterilized, while can be pre-
Prevent some communicable diseases；
（4）The method for preparing the environment protection oil paint of the present invention, operating procedure is simple, and fidelity factor is high, is conducive to industrialization promotion.
Embodiment
With reference to specific embodiment, technical scheme is expanded on further.These embodiments are merely to illustrate this
The optimal case of invention rather than limit the scope of the invention.
Embodiment 1
A kind of anticracking environment-friendly type paint, including following parts by weight of component：18 parts of bean plant short oil class alkyd resin, hydroxy
30 parts of acid resin, 12 parts of epoxy resin freezing plastic, 35 parts of rosin, 5 parts of sodium carboxymethylcellulose, 3 parts of sodium silicoaluminate, essential oil 0.1
Part, 12 parts of iron chloride, 1 part of organic pigment, 0.1 part of dibutyl tin laurate, 5 parts of organotin.
Wherein essential oil is the composition of osmanthus essential oil, refined jasmine oil and honeysuckle essential oil.
A kind of method for preparing above-mentioned anticracking environment-friendly type paint is present embodiments provided, is comprised the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 30 DEG C, until being completely dissolved；
（2）Organic pigment, dibutyl tin laurate and organotin are placed on into another vessel in heating to be stirred to 50 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 10 minutes.
Embodiment 2
A kind of anticracking environment-friendly type paint, including following parts by weight of component：22 parts of bean plant short oil class alkyd resin, hydroxy
36 parts of acid resin, 16 parts of epoxy resin freezing plastic, 46 parts of rosin, 9 parts of sodium carboxymethylcellulose, 12 parts of sodium silicoaluminate, essential oil 0.7
Part, 22 parts of iron chloride, 4 parts of organic pigment, 0.3 part of dibutyl tin laurate, 8 parts of lead salt.
Wherein essential oil is the composition of refined jasmine oil, honeysuckle essential oil and tea tree ethereal oil.
A kind of method for preparing above-mentioned anticracking environment-friendly type paint is present embodiments provided, is comprised the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 60 DEG C, until being completely dissolved；
（2）Organic pigment, dibutyl tin laurate and lead salt are placed on into another vessel in heating to be stirred to 80 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 30 minutes.
Embodiment 3
A kind of anticracking environment-friendly type paint, including following parts by weight of component：19 parts of bean plant short oil class alkyd resin, hydroxy
31 parts of acid resin, 13 parts of epoxy resin freezing plastic, 36 parts of rosin, 6 parts of sodium carboxymethylcellulose, 4 parts of sodium silicoaluminate, essential oil 0.2
Part, 13 parts of iron chloride, 2 parts of organic pigment, 0.2 part of dibutyl tin laurate, 6 parts of zinc soap.
Wherein, essential oil is the composition of honeysuckle essential oil, tea tree ethereal oil and Peppermint essential oil.
A kind of method for preparing above-mentioned anticracking environment-friendly type paint is present embodiments provided, is comprised the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 35 DEG C, until being completely dissolved；
（2）Organic pigment, dibutyl tin laurate and zinc soap are placed on into another vessel in heating to be stirred to 55 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 15 minutes.
Embodiment 4
A kind of anticracking environment-friendly type paint, including following parts by weight of component：20 parts of bean plant short oil class alkyd resin, hydroxy
33 parts of acid resin, 14 parts of epoxy resin freezing plastic, 40 parts of rosin, 7 parts of sodium carboxymethylcellulose, 10 parts of sodium silicoaluminate, essential oil 0.4
Part, 19 parts of iron chloride, 3 parts of organic pigment, 0.2 part of dibutyl tin laurate, 6 parts of organotin.
Wherein, the essential oil is the composition of tea tree ethereal oil, Peppermint essential oil and sandalwood essential oil.
A kind of method for preparing above-mentioned anticracking environment-friendly type paint is present embodiments provided, is comprised the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 50 DEG C, until being completely dissolved；
（2）Organic pigment, dibutyl tin laurate and organotin are placed on into another vessel in heating to be stirred to 80 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 15 minutes.
Above-described embodiment is solidified by adding Hydroxylated acrylic resin, bean plant short oil class alkyd resin, epoxy resin
Glue, pigment ensure that the environment protection oil paint prepared has good crack resistence performance, are not in the growth of use time
Ftractureed the phenomenon come off, and nontoxic, and poisonous volatilization gas will not be given out in use, the body of people is not appointed
What influences, and has a safety feature.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to previous embodiment
Described technical scheme is modified, or carries out equivalent substitution to which part technical characteristic.All spirit in the present invention
Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of anticracking environment-friendly type paint, it is characterised in that including following parts by weight of component：Bean plant short oil class alkyd resin
18-22 parts, 30-36 parts of Hydroxylated acrylic resin, 12-16 parts of epoxy resin freezing plastic, 35-46 parts of rosin, carboxymethyl cellulose
5-9 parts of sodium, 3-12 parts of sodium silicoaluminate, 0.1-0.7 parts of essential oil, 12-22 parts of iron chloride, 1-4 parts of pigment, dibutyl tin laurate
0.1-0.3 parts, 5-8 parts of stabilizer.
2. anticracking environment-friendly type paint according to claim 1, it is characterised in that the paint includes following parts by weight group
Point：20 parts of bean plant short oil class alkyd resin, 33 parts of Hydroxylated acrylic resin, 14 parts of epoxy resin freezing plastic, 40 parts of rosin,
7 parts of sodium carboxymethylcellulose, 10 parts of sodium silicoaluminate, 0.4 part of essential oil, 19 parts of iron chloride, 3 parts of pigment, dibutyl tin laurate
0.2 part, 6 parts of stabilizer.
3. anticracking environment-friendly type paint according to claim 1, it is characterised in that the pigment type is organic pigment.
4. anticracking environment-friendly type paint according to claim 1, it is characterised in that the essential oil is osmanthus essential oil, jasmine essence
One kind in oil, honeysuckle essential oil, tea tree ethereal oil, Peppermint essential oil, sandalwood essential oil, Chinese ilex essential oil, lemon or clove oil
Or several combinations.
5. anticracking environment-friendly type according to claim 1 paint, it is characterised in that the stabilizer be organotin, lead salt and
Any one in zinc soap.
6. a kind of method for preparing the environment protection oil paint as described in claim any one of 1-5, it is characterised in that comprise the following steps：
（1）By bean plant short oil class alkyd resin, Hydroxylated acrylic resin, epoxy resin freezing plastic, rosin, carboxymethyl cellulose
Plain sodium, sodium silicoaluminate, essential oil and iron chloride are placed on a container for stirring, are heated to 30-60 DEG C, until being completely dissolved；
（2）Pigment, dibutyl tin laurate and stabilizer are placed on into another vessel in heating to be stirred to 50-80 DEG C；
（3）By step（1）And step（2）Two kinds of obtained solution are stirred at room temperature uniformly, then add in grinder and carry out
Grinding 10-30 minutes.
7. the preparation method of environment protection oil paint according to claim 6, it is characterised in that：Step（1）In heating-up temperature be
50℃。
8. the preparation method of environment protection oil paint according to claim 6, it is characterised in that step（2）In heating-up temperature be
80℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710543785.0A CN107189690A (en) | 2017-07-05 | 2017-07-05 | A kind of anticracking environment-friendly type paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710543785.0A CN107189690A (en) | 2017-07-05 | 2017-07-05 | A kind of anticracking environment-friendly type paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189690A true CN107189690A (en) | 2017-09-22 |
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ID=59880346
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710543785.0A Withdrawn CN107189690A (en) | 2017-07-05 | 2017-07-05 | A kind of anticracking environment-friendly type paint and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893577A (en) * | 2015-06-18 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Cracking preventing paint |
| CN105462492A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Environment-friendly paint and preparation method thereof |
| CN106318092A (en) * | 2016-08-22 | 2017-01-11 | 安徽宇瑞环保建设有限公司 | Anti-cracking environment-friendly paint |
| CN106543889A (en) * | 2016-10-19 | 2017-03-29 | 南京爱斯利尔环保设备工程有限公司 | A kind of environment protection oil paint |
-
2017
- 2017-07-05 CN CN201710543785.0A patent/CN107189690A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893577A (en) * | 2015-06-18 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Cracking preventing paint |
| CN105462492A (en) * | 2015-12-31 | 2016-04-06 | 文登蓝岛建筑工程有限公司 | Environment-friendly paint and preparation method thereof |
| CN106318092A (en) * | 2016-08-22 | 2017-01-11 | 安徽宇瑞环保建设有限公司 | Anti-cracking environment-friendly paint |
| CN106543889A (en) * | 2016-10-19 | 2017-03-29 | 南京爱斯利尔环保设备工程有限公司 | A kind of environment protection oil paint |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170922 |
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