CN102690536B - A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof - Google Patents
A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof Download PDFInfo
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- CN102690536B CN102690536B CN201110068236.5A CN201110068236A CN102690536B CN 102690536 B CN102690536 B CN 102690536B CN 201110068236 A CN201110068236 A CN 201110068236A CN 102690536 B CN102690536 B CN 102690536B
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- curtain walls
- aluminum curtain
- building aluminum
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 28
- 239000000919 ceramic Substances 0.000 title claims abstract description 19
- 239000003973 paint Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000006185 dispersion Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 238000005524 ceramic coating Methods 0.000 claims abstract description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 229910000077 silane Inorganic materials 0.000 claims abstract description 9
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 6
- 230000005070 ripening Effects 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000440 bentonite Substances 0.000 claims description 7
- 229940092782 bentonite Drugs 0.000 claims description 7
- 229910000278 bentonite Inorganic materials 0.000 claims description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 3
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 3
- LYQSURKAATZNON-UHFFFAOYSA-N 1-chlorooctane silane Chemical compound [SiH4].C(CCCCCCC)Cl LYQSURKAATZNON-UHFFFAOYSA-N 0.000 claims description 2
- 229910000906 Bronze Inorganic materials 0.000 claims description 2
- 239000005046 Chlorosilane Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 239000010974 bronze Substances 0.000 claims description 2
- WMVAGLJQQGYKCW-UHFFFAOYSA-N chloro(hexadecyl)silane Chemical compound CCCCCCCCCCCCCCCC[SiH2]Cl WMVAGLJQQGYKCW-UHFFFAOYSA-N 0.000 claims description 2
- YGZSVWMBUCGDCV-UHFFFAOYSA-N chloro(methyl)silane Chemical group C[SiH2]Cl YGZSVWMBUCGDCV-UHFFFAOYSA-N 0.000 claims description 2
- GTPDFCLBTFKHNH-UHFFFAOYSA-N chloro(phenyl)silicon Chemical compound Cl[Si]C1=CC=CC=C1 GTPDFCLBTFKHNH-UHFFFAOYSA-N 0.000 claims description 2
- UZBDLHYCYNXFRF-UHFFFAOYSA-N chloro(prop-1-enyl)silane Chemical class C(=CC)[SiH2]Cl UZBDLHYCYNXFRF-UHFFFAOYSA-N 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229920002313 fluoropolymer Polymers 0.000 claims description 2
- 239000004811 fluoropolymer Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- MECMQNITHCOSAF-UHFFFAOYSA-N manganese titanium Chemical compound [Ti].[Mn] MECMQNITHCOSAF-UHFFFAOYSA-N 0.000 claims description 2
- JPQBRSQJGWOTGC-UHFFFAOYSA-N methyl(silyloxysilyloxy)silane Chemical class C[SiH2]O[SiH2]O[SiH3] JPQBRSQJGWOTGC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- -1 octyl group chlorosilanes Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 229940080314 sodium bentonite Drugs 0.000 claims description 2
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 2
- RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 claims description 2
- OOXSLJBUMMHDKW-UHFFFAOYSA-N trichloro(3-chloropropyl)silane Chemical compound ClCCC[Si](Cl)(Cl)Cl OOXSLJBUMMHDKW-UHFFFAOYSA-N 0.000 claims description 2
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 claims description 2
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 claims description 2
- 239000005050 vinyl trichlorosilane Substances 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 claims 1
- 239000005052 trichlorosilane Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 abstract description 4
- 230000002401 inhibitory effect Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000011435 rock Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000009514 concussion Effects 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- DOEHJNBEOVLHGL-UHFFFAOYSA-N trichloro(propyl)silane Chemical compound CCC[Si](Cl)(Cl)Cl DOEHJNBEOVLHGL-UHFFFAOYSA-N 0.000 description 1
- QLNOVKKVHFRGMA-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical group [CH2]CC[Si](OC)(OC)OC QLNOVKKVHFRGMA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof, belongs to ceramic coating technical field.It includes the compositions such as Alumina gel, Ludox, pigment, filler, anti-settling agent, silane monomer, auxiliary agent, catalyst.This preparation method includes that (1) weighs the Alumina gel of respective component, Ludox, pigment, filler and anti-settling agent, carries out high speed dispersion, be then ground it, as component A after carrying out initial stage mixing；(2) weigh the silane monomer of respective component and do not glue auxiliary agent, as B component；(3) catalyst of respective component is weighed as component C；(4) carry out above-mentioned component A, B component and component C being sufficiently mixed and roll the ceramic coating described in ripening generation.This ceramic coating is coated on building aluminum curtain walls, reacted after formed for inorganic molecule structure, there is natural noninflammability energy, for the fire safety important in inhibiting of building.
Description
Technical field
The invention belongs to ceramic coating technical field, relate to a kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation thereof
Method.
Background technology
Along with economic fast development, building curtain wall decoration materials constantly occur to develop and innovation, and aluminum matter curtain wall is due to weight
The feature such as gently, appearance is magnificent has become the preferred object of decorating outer wall of building.Along with the progress of baking vanish technology, aluminum curtain walls is more
New replacement speed is the most quickly.The first generation uses transparent stickup to be coated with the aluminium that surface processes, owing to dull coloring is dim and is weak to purple
The defects such as outside line, are quickly substituted by fluorocarbon coating.Fluorocarbon coating is referred to as second filial generation aluminum decorative material, and it compensate for first
For the deficiency of product, add colorful multiformity, and the endurance of 20 years can be kept, so by rapid popularization and application.So
And, along with the concept of low-carbon environment-friendly is increasingly taken seriously by the whole world, petroleum resources the most in short supply, all the more in the urgent need to more excellent
Elegant environment-friendly products of new generation replace.The environment-friendly type building aluminum curtain walls of present invention exploitation fire prevention non-combustible ceramic coating, he
Inorganic structure from encounter ultraviolet, automobile exhaust thing, atmospheric pollution, acid rain will aging, pollute organic coating different, pottery
Coating can play its distinctive coating performance, not only possesses various color and beautiful outward appearance, also has the resistant of brilliance
Metachromia and endurance, allow and build the image remaining brand-new.In addition the more important thing is, the ceramic coating of the present invention has fire prevention
The performance do not fired, makes building use safer.
Summary of the invention
It is an object of the invention to provide a kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof.
A kind of environmental-friendly ceramic paint for building aluminum curtain walls, it includes following component:
Component A:
B component:
Silane monomer 4-20%
Auxiliary agent 1-2%
C component:
Catalyst 1-10%
Wherein, aforesaid ratio is launched by proportion, and total amount is 100%.
Further, described a kind of environmental-friendly ceramic paint for building aluminum curtain walls, also there is following technical characteristic:
Described Alumina gel, for water-dispersion type alumina in Nano level, its granularity is 10-100nm, and alumina content is
20%-50%.
Described Ludox, for water-dispersion type nanoscale silicon, its granularity is 10-100nm, and silica content is 20-
50%.
Described pigment is titanium dioxide, or be that titanium dioxide and copper-chrome black, ferrimanganic be black, titanium manganese brown, siderochrome palm fibre, cobalt blue, titanium
One or more in nickel yellow, titanium green, titanium dioxide, wollastonite powder, iron oxide yellow, iron oxide red, aluminium powder and pearly-lustre bronze
Mixture.
Described filler, for one or more in nano-sized crystal powder silicon dioxide, potassium titanate crystal whisker, aluminium oxide
Mixture.
Described anti-settling agent, swollen for the sodium bentonite in inorganic bentonite, calcium-base bentonite, lithium bentonite, hydrogen-based
One or more mixture of profit soil.
Described silane monomer be methylchlorosilane, phenyl chlorosilane, methylvinyl-chlorosilanes, ethyl trichlorosilane,
Propyltrichlorosilan, vinyl trichlorosilane, n-octyl chloride silane, cetyl chlorosilane, ten trifluoro tetrahydrochysene octyl group chlorosilanes,
One or more mixture in γ-chloropropyl trichloro-silane and fluoropolymer emulsion.
Described auxiliary agent is silicon fluoride, containing hydrogen silicone oil, tetramethyl-ring tetrasiloxane or 7 methyl trisiloxanes.
Described catalyst is acid or acid salt.
The preparation method of a kind of environmental-friendly ceramic paint for building aluminum curtain walls, the method comprises the steps:
Step 1, according to aforementioned proportion, weighs the Alumina gel of respective component, Ludox, pigment, filler and anti-settling agent, carries out
Carry out high speed dispersion after initial stage mixing, then it is ground until its fineness reaches below 15 μm, as A group
Point；
Step 2, according to aforementioned proportion, weighs the silane monomer of respective component and does not glues auxiliary agent, as B component；
Step 3, according to aforementioned proportion, weighs the catalyst of respective component as component C；
Step 4, carries out being sufficiently mixed and rolling ripening 16-24h by above-mentioned component A, B component and component C, generates described
Ceramic coating.
Further, the preparation method of described a kind of environmental-friendly ceramic paint for building aluminum curtain walls, also there is following technology
Feature:
High speed dispersion described in step 1, uses high speed dispersor band zigzag dispersion impeller to realize.
Described high speed dispersion, is to use high speed dispersor band zigzag dispersion impeller with rotating speed 900-1000r/min, dispersion
Time is that 2-3h realizes.
In the grinding described in step 1, being to use basket type sand mill, milling time 6-8h realizes.
Implement the present invention, have the advantages that
This environmental-friendly ceramic paint for building aluminum curtain walls of the present invention, molten with nanoscale alumina sol, nano silicone
Glue is film forming matter, and the chemical bond after film forming, based on " Si=0 " and " Al=0 ", is entirely inorganic molecule structure, due to its grain
Degree, between nanoscale, in follow-up application and forming process, it is possible to use the viscosity of this colloid self and adhesive force, replaces
Traditional organic solvent and bonding agent filler etc., have natural safety non-toxic, is that a kind of environment-friendly type thermostable is coated with
Material.During prepared by this ceramic coating, can be according to the actual application of coating, by changing kind and the ratio of silane monomer
Example and do not glue auxiliary agent make the hydrophobic property for adjusting coating, it is achieved certain anti-pollution function easy to clean.This ceramic coating
Main selection natural crystal inorganic bentonite replaces traditional organic reagent as anti-settling agent, decreases the environment in formulation for coating material
Pollution factor, and this type of Ore is at high temperature without harmful gas release, safe and reliable, there is positive environment protecting.It addition,
This ceramic coating is coated on building aluminum curtain walls, reacted after formed for inorganic molecule structure, there is natural noninflammability energy, right
Fire safety important in inhibiting in building.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail:
Specific embodiment 1:
Component A:
B component:
C component
Concrete preparation method comprises the steps:
Step 1, adds all material of component A formula and the bead of the Φ=1.5mm of equal-volume part in vial,
Then concussion is ground 2 hours, obtains Mischung, now the pH=7.5 of Mischung in vial, fineness≤15um.
Step 2, according to aforementioned proportion, weighs the Degussa MTMS in B component and Degussa silicon fluoride.
Step 3, according to aforementioned proportion, weighs the glacial acetic acid of respective component in C component.
Step 4, rocks in the existing Mischung that will prepare in the glacial acetic acid addition step 1 of C component and uniformly obtains mixture f.
Step 5, adds in mixture f by B component, quickly rocks and makes material therein start reaction, reaches equal with system
It is terminal mutually.
Step 6, under 25 DEG C of environment, rolls ripening 8 hours, the ceramic coating described in generation.
Further, high speed dispersion described in step 1, is to use high speed dispersor band zigzag dispersion impeller with rotating speed
900-1000r/min, jitter time are that 2-3h realizes.
Further, in the grinding described in step 1, being to use basket type sand mill, milling time 6-8h realizes.
Specific embodiment 2:
Self-control inorganic sol
Component A:
B component:
C component
Concrete preparation method comprises the steps:
Step 1, adds all material of component A formula and the bead of the Φ=1.5mm of equal-volume part in vial,
Then concussion is ground 2 hours, obtains mixture g, the now pH=7.5 of mixture g in vial, fineness≤15um.
Step 2, according to aforementioned proportion, weighs 1 in B component, 3,5-tri-[3-(trimethoxysilyl) propyl group]-1,
3,5-triazine-2,4,6 (1H, 3H, 5H)-triketone and tetramethyl-ring tetrasiloxanes.
Step 3, according to aforementioned proportion, weighs the p-methyl benzenesulfonic acid of respective component in C component and is dissolved in the mixed of isopropyl alcohol and water
Close liquid.
Step 4, now uniformly obtains mixture h by rocking in C component addition B component.
Step 5, adds component A in the mixture h that step 4 obtains, and quickly rocks and make the material in component A and B group
Material in Fen starts reaction, reaches homogeneous as terminal with system.
Step 6, under 25 DEG C of environment, rolls ripening 4 hours, the ceramic coating described in generation.
Further, high speed dispersion described in step 1, is to use high speed dispersor band zigzag dispersion impeller with rotating speed
900-1000r/min, jitter time are that 2-3h realizes.
Further, in the grinding described in step 1, being to use basket type sand mill, milling time 6-8h realizes.
Formulation composition is been described by by the experimental section of the technical program with the most frequently used white, and other colors can be passed through
Color pigment is selected to be realized.Particularly select as the production of the company such as Heubach, Shepherd with metal-oxide as core
Color pigment, can be that the properties of infrared reflection of film increases substantially, reach so-called " cold film ".
Being above the description of this invention and non-limiting, other embodiment based on inventive concept, all in the present invention
Protection domain among.
Claims (9)
1. an environmental-friendly ceramic paint for building aluminum curtain walls, it is characterised in that it includes following component:
Component A:
B component:
Silane monomer 4 20%
Auxiliary agent 1-2%
C component:
Catalyst 1-10%
Wherein, aforesaid ratio is launched by proportion, and total amount is 100%；
Described silane monomer is methylchlorosilane, phenyl chlorosilane, methylvinyl-chlorosilanes, ethyl trichlorosilane, propyl group
Trichlorosilane, vinyl trichlorosilane, n-octyl chloride silane, cetyl chlorosilane, ten trifluoro tetrahydrochysene octyl group chlorosilanes, γ mono-
One or more mixture in chloropropyl trichloro-silane and fluoropolymer emulsion；
Described Alumina gel, for water-dispersion type alumina in Nano level, its granularity is 10-100nm, and alumina content is 20%-
50%；Described Ludox, for water-dispersion type nanoscale silicon, its granularity is 10-100nm, and silica content is 20-
50%；Described catalyst is acid or acid salt.
2. according to a kind of environmental-friendly ceramic paint for building aluminum curtain walls described in claim l, it is characterised in that described pigment
For titanium dioxide, or be that titanium dioxide and copper-chrome black, ferrimanganic be black, titanium manganese brown, siderochrome palm fibre, cobalt blue, titanium yellow, titanium green, wollastonite powder, oxygen
Change one or more the mixture in iron oxide yellow, iron oxide red, aluminium powder and pearly-lustre bronze.
3. according to a kind of environmental-friendly ceramic paint for building aluminum curtain walls described in claim l, it is characterised in that described fills out
Material, for one or more the mixture in nano-sized crystal powder silicon dioxide, potassium titanate crystal whisker, aluminium oxide.
4. according to a kind of environmental-friendly ceramic paint for building aluminum curtain walls described in claim l, it is characterised in that described is anti-settling
Agent, for the sodium bentonite in inorganic bentonite, calcium-base bentonite, lithium bentonite, the bentonitic one of hydrogen-based or one with
On mixture.
5. according to a kind of environmental-friendly ceramic paint for building aluminum curtain walls described in claim l, it is characterised in that described auxiliary agent
For silicon fluoride, containing hydrogen silicone oil, tetramethyl-ring tetrasiloxane or 7 methyl trisiloxanes.
6. the preparation method of an environmental-friendly ceramic paint for building aluminum curtain walls, it is characterised in that the method comprises the steps:
Step l, according to the ratio described in claim l, weighs the Alumina gel of respective component, Ludox, pigment, filler and anti-settling
Agent, carries out high speed dispersion, is then ground it until its fineness reaches below 15 μm, is made after carrying out initial stage mixing
For component A；
Step 2, according to the ratio described in claim l, weighs silane monomer and the auxiliary agent of respective component, as B component；
Step 3, according to the ratio described in claim l, weighs the catalyst of respective component as component C；
Step 4, carries out above-mentioned component A, B component and component C being sufficiently mixed and roll ripening 16 24h, described in generation
Ceramic coating.
The preparation method of a kind of environmental-friendly ceramic paint for building aluminum curtain walls the most according to claim 6, it is characterised in that
High speed dispersion described in step l, uses high speed dispersor band zigzag dispersion impeller to realize.
8., according to the preparation method of a kind of environmental-friendly ceramic paint for building aluminum curtain walls described in claim 6 or 7, its feature exists
In, described high speed dispersion, is to use high speed dispersor band zigzag dispersion impeller with rotating speed 900 1 1000r/min, jitter time
Realize for 2-3h.
The preparation method of a kind of environmental-friendly ceramic paint for building aluminum curtain walls the most according to claim 6, it is characterised in that
In the grinding described in step l, being to use basket type sand mill, milling time 6-8h realizes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110068236.5A CN102690536B (en) | 2011-03-21 | 2011-03-21 | A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110068236.5A CN102690536B (en) | 2011-03-21 | 2011-03-21 | A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102690536A CN102690536A (en) | 2012-09-26 |
| CN102690536B true CN102690536B (en) | 2016-09-14 |
Family
ID=46856282
Family Applications (1)
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| TW200631899A (en) * | 2005-03-09 | 2006-09-16 | Tokai Ryokaku Tetsudo Kk | Titanium oxide-coating agent, and forming method for titanium oxide-coating film |
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| US8354480B2 (en) * | 2007-04-26 | 2013-01-15 | Dow Corning Corporation | Aqueous silicone emulsion for imparting water repellency |
| CN101781479B (en) * | 2009-12-04 | 2011-10-26 | 上海宜瓷龙新材料科技有限公司 | Environment-friendly nano ceramic film coating with self heat radiating function and preparation method thereof |
| CN101781482B (en) * | 2009-12-04 | 2011-12-28 | 上海瓷龙化工有限公司 | Photocatalytic self-cleaning nano ecology coating and preparation method thereof |
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