CN106519965A - 9H ceramic paint - Google Patents

9H ceramic paint Download PDF

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Publication number
CN106519965A
CN106519965A CN201610741669.5A CN201610741669A CN106519965A CN 106519965 A CN106519965 A CN 106519965A CN 201610741669 A CN201610741669 A CN 201610741669A CN 106519965 A CN106519965 A CN 106519965A
Authority
CN
China
Prior art keywords
ceramic paint
ceramic
silicon solution
paint
monosilane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610741669.5A
Other languages
Chinese (zh)
Inventor
周建兰
赵育安
钟树满
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boluo Huizhou Zhicheng Chemical Co Ltd
Original Assignee
Boluo Huizhou Zhicheng Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boluo Huizhou Zhicheng Chemical Co Ltd filed Critical Boluo Huizhou Zhicheng Chemical Co Ltd
Priority to CN201610741669.5A priority Critical patent/CN106519965A/en
Publication of CN106519965A publication Critical patent/CN106519965A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses 9H ceramic paint. The 9H ceramic paint is prepared from the following ingredients in percentage by mass: 40% of silicon solution, 40% of monosilane, 19.98% of titanium white, 0.01% of silicone oil and 0.01% of neutralizer. A method for preparing the 9H ceramic paint specifically comprises the following steps of proportionally weighing the raw materials, dispersing the silicon solution and the titanium white until the degree of fineness is 10 microns or less, then, adding the ingredients, i.e., the monosilane, the silicone oil and the neutralizer into the dispersion, and carrying out stirring for 6 hours. By adopting the technical scheme of the invention, the 9H ceramic paint has the following beneficial effects that the 9H ceramic paint disclosed by the invention can enable the hardness of a paint film to exceed 9H, is high in hardness and is scratch-resistant, fireproof, smokeless, environmentally friendly and pollution-free; and meanwhile, the 9H ceramic paint further has the characteristics of rich colors and delicate paint film hand feeling.

Description

A kind of 9H ceramic coatings
Technical field
A kind of the present invention relates to technical field of coatings, more particularly to high-rigidity ceramic coating being applied on ceramics.
Background technology
Ceramic coating hardness itself is high, but toughness is poor, in use, is easily collided, is impacted, being scraped etc. and cause Adhesive force is deteriorated, ftractures or come off;Chinese patent CN105566956A, discloses a kind of high abrasion-proof and high temperature resistant water boiling resistance aqueous Ceramic coating, its main technical schemes is:By tri- component of A, B, C according to mass ratio:666:333:1 mixes, wherein:A groups Point:Percentages based on ceramic coating gross mass:Ludox 26-30%, antimony solution 13-15%, inorganic high-temperature resistant face Material 5-13% and silica 8-12%;B component:Percentages based on ceramic coating gross mass:Silane 30-34%, Wetting agent 0.4-0.6%, levelling agent 0.4-0.6%;Component C:Percentages based on ceramic coating gross mass:Catalyst 0.1%, made by which, ceramic hardness can reach 8H, it is well known that, antimony is heavy metal, not only pollutes environment, and right Health of human body is harmful to, and is clearly prohibitted the use of in some fields.
In today of the track traffics such as high ferro, city underground great development, the design that the disaster prevention in its place is related will be Emphasis.Traditional solvent-borne coating is more with organic solvents such as toluene, dimethylbenzene, butyl acetates as diluent, and which manufactures and constructed Journey causes huge pollution because of a large amount of discharges of organic solvent to environment.Traditional solvent-borne coating products are using in similar subway Stand, the place of the enclosed environment such as station, once fire, produces a large amount of poisonous dense smokes, often increases and evacuates passenger, the disaster relief of putting out a fire Difficulty.It is in addition, mobility of people is big during track traffic circulation, also big to the colliding with of ornament materials, abrasive probability, The contaminated possibility in surface also increases.Existing ceramic water-soluble environmental protection coating material, the surface state in work progress to substrate Requirement is relatively low, need to do sandblasting, bead, and operation is simple.
The content of the invention
It is an object of the invention to provide a kind of high rigidity, scratch resistance, the ceramics painting for preventing fires smokeless and environment friendly and pollution-free Material.
Further object is that providing the preparation method of above-mentioned ceramic coating.
For solving above technical problem, the present invention provides a kind of 9H ceramic coatings, is made up of following component by mass fraction:
Silicon solution 40%
Monosilane 40%
Titanium dioxide 19.98%
Silicone oil:0.01%
Nertralizer 0.01%.
Preferably, the silicon solution is many alkoxy silane water-base resins and complex.
A kind of method for preparing 9H ceramic coatings, specifically includes following steps:Take above-mentioned raw materials in proportion, by silicon solution and Titanium dioxide fineness of dispersion to below 10um, then plus monosilane, silicone oil, nertralizer component, stir 6 hours.
Had the advantages that using technical scheme:The 9H ceramic coatings of the present invention can allow hardness of paint film 9H is crossed, high rigidity, scratch resistance, fire prevention are smokeless and environment friendly and pollution-free, meanwhile, also with various colors, paint film feel is fine and smooth.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below in conjunction with specific embodiment.
Embodiment 1
The present invention provides a kind of 9H ceramic coatings, is made up of following component by mass fraction:
Specifically, the silicon solution is many alkoxy silane water-base resins and complex.
Preparation method:Above-mentioned raw materials are taken in proportion, by silicon solution and titanium dioxide fineness of dispersion to below 10um, then plus first silicon Alkane, silicone oil, nertralizer component, stir 6 hours.
The 9H ceramic coatings of the present invention can allow hardness of paint film to cross 9H, and high rigidity, scratch resistance, fire prevention are smokeless, and environmental protection It is pollution-free, meanwhile, also with various colors, paint film feel is fine and smooth.
The testing result of embodiments of the invention 1 is as shown in the table:
As upper table can be seen that the ceramic coating using the present invention, hardness can reach 9H, and acidproof, water-fast, resistance to Heat, it is wear-resisting, and flat appearance is smooth.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (3)

1. a kind of 9H ceramic coatings, it is characterised in that be made up of following component by mass fraction:
Silicon solution 40%
Monosilane 40%
Titanium dioxide 19.98%
Silicone oil:0.01%
Nertralizer 0.01%.
2. a kind of 9H ceramic coatings according to claim 1, it is characterised in that:The silicon solution is many alkoxy silane water Property resin and complex.
3. a kind of method for preparing 9H ceramic coatings as claimed in claim 1, it is characterised in that comprise the following steps:By than Example take above-mentioned raw materials, by silicon solution and titanium dioxide fineness of dispersion to below 10um, then plus monosilane, silicone oil, nertralizer component, stir Mix 6 hours.
CN201610741669.5A 2016-08-27 2016-08-27 9H ceramic paint Pending CN106519965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610741669.5A CN106519965A (en) 2016-08-27 2016-08-27 9H ceramic paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610741669.5A CN106519965A (en) 2016-08-27 2016-08-27 9H ceramic paint

Publications (1)

Publication Number Publication Date
CN106519965A true CN106519965A (en) 2017-03-22

Family

ID=58343619

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610741669.5A Pending CN106519965A (en) 2016-08-27 2016-08-27 9H ceramic paint

Country Status (1)

Country Link
CN (1) CN106519965A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102690536A (en) * 2011-03-21 2012-09-26 上海宜瓷龙新材料科技有限公司 Environment-friendly ceramic paint for building aluminum curtain walls and preparation method thereof
CN103013193A (en) * 2012-12-13 2013-04-03 慧智科技(中国)有限公司 Titanium-containing ceramic paint and protective coating
CN103030358A (en) * 2012-12-13 2013-04-10 慧智科技(中国)有限公司 Ceramic paint and coating having stereoscopic effect
CN104087160A (en) * 2014-07-24 2014-10-08 无锡卡秀堡辉涂料有限公司 High-wear-resistant and crack-resistant ceramic paint and preparation method thereof
CN104761935A (en) * 2015-03-20 2015-07-08 英德市雅家涂料有限公司 Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102690536A (en) * 2011-03-21 2012-09-26 上海宜瓷龙新材料科技有限公司 Environment-friendly ceramic paint for building aluminum curtain walls and preparation method thereof
CN103013193A (en) * 2012-12-13 2013-04-03 慧智科技(中国)有限公司 Titanium-containing ceramic paint and protective coating
CN103030358A (en) * 2012-12-13 2013-04-10 慧智科技(中国)有限公司 Ceramic paint and coating having stereoscopic effect
CN104087160A (en) * 2014-07-24 2014-10-08 无锡卡秀堡辉涂料有限公司 High-wear-resistant and crack-resistant ceramic paint and preparation method thereof
CN104761935A (en) * 2015-03-20 2015-07-08 英德市雅家涂料有限公司 Antimicrobial non-viscous aqueous inorganic nano coating priming paint and preparation method thereof

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SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
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Application publication date: 20170322