CN106118456A - Anti-slip agent for ceramic tiles and preparation method and application thereof - Google Patents
Anti-slip agent for ceramic tiles and preparation method and application thereof Download PDFInfo
- Publication number
- CN106118456A CN106118456A CN201610442790.8A CN201610442790A CN106118456A CN 106118456 A CN106118456 A CN 106118456A CN 201610442790 A CN201610442790 A CN 201610442790A CN 106118456 A CN106118456 A CN 106118456A
- Authority
- CN
- China
- Prior art keywords
- component
- ceramic tile
- acid
- preparation
- antilubricant
- Prior art date
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- Granted
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- 239000000919 ceramic Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 239000012748 slip agent Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 claims abstract description 23
- 229920002545 silicone oil Polymers 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 8
- 150000007524 organic acids Chemical class 0.000 claims abstract description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000003921 oil Substances 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- -1 MTMS Chemical compound 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 238000005498 polishing Methods 0.000 claims description 8
- 239000011449 brick Substances 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001117 sulphuric acid Substances 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 3
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 claims description 3
- RNIHAPSVIGPAFF-UHFFFAOYSA-N Acrylamide-acrylic acid resin Chemical compound NC(=O)C=C.OC(=O)C=C RNIHAPSVIGPAFF-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 3
- 150000003376 silicon Chemical class 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 230000003373 anti-fouling effect Effects 0.000 abstract description 9
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses an anti-slip agent for ceramic tiles and a preparation method and application thereof, wherein the anti-slip agent for the ceramic tiles is composed of a component A and a component B, wherein the component A comprises the following components in percentage by weight: 5 to 50 percent of organic or inorganic acid, 0.1 to 1 percent of dispersion stabilizer and the balance of water, wherein the component B comprises the following components in percentage by weight: 0.5-50% of silicone oil, 0.5-10% of silane coupling agent, 0.1-1% of dispersion stabilizer, 0.1-1% of emulsifier and the balance of water. The anti-slip agent for the ceramic tiles is used for anti-slip treatment of the surfaces of the ceramic tiles, has good anti-slip and anti-fouling effects, and simplifies the anti-slip treatment process of the surfaces of the ceramic tiles.
Description
Technical field
The invention belongs to ceramic tile surface processing technology field, be specifically related to a kind of ceramic tile antilubricant and preparation method thereof and
Application.
Background technology
Along with the raising of people's living standard, huge numbers of families come into by ceramic tile, in the process that its range of application constantly expands
In, also occur in that some problem demanding prompt solutions, such as: water smoothness Tai Gaoyi skidding etc. is met on surface, so exploitation meets masses
The anti-skid brick product of demand becomes main flow.
Existing Antiskid ceramic tile is by being provided with fold striped or sags and crests at ceramic tile surface, with increase floor tile face with
Human body sole or the frictional force of sole, prevent skidding from falling down.Processing mode is required higher by this mode, adds ceramic tile processing
Difficulty.Occurred in that at present the employing super clean bright Ceramic Tiles of acid corrosion to prepare skid-proof ceramic tile, but obtained by the method
Anti-skid brick anti-fouling effect is poor, and the discharge of acid solution in the course of processing, causes the impact on environment relatively big, causes environment
Pollute.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of ceramic tile antilubricant, this antilubricant
For ceramic tile surface being carried out anti-skidding process, the most anti-skidding and anti-fouling effect, simplify ceramic tile surface anti-skidding process technique simultaneously.
Another object of the present invention is to provide the preparation method of a kind of ceramic tile antilubricant, obtained by this preparation method
A kind of ceramic tile antilubricant.
Third object of the present invention is to provide the ceramic tile antilubricant of the present invention Ceramic Tiles in super clean bright polishing
Application in surface anti-skid treatment.
For solving the problems referred to above, the technical solution adopted in the present invention is as follows:
A kind of ceramic tile antilubricant, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Organic or inorganic acid 5%-50%,
Dispersion stabilizer 0.1%-1%,
Water surplus；
B component includes following component by weight percentage:
Silicone oil 0.5%-50%,
Silane coupler 0.5%～10%,
Dispersion stabilizer 0.1%～1%,
Emulsifying agent 0.1-1%
Water surplus.
As further scheme, silane coupler of the present invention is selected from sodium methyl silicate, methyl trimethoxy epoxide silicon
One or more in alkane, MTES and methyl triacetoxysilane.
As further scheme, dispersion stabilizer of the present invention is amine ether type monomer or copolymerization, is selected from
Ethylene glycol, butyl glycol ether, diethylene glycol dimethyl ether, isomerous tridecanol polyoxyethylene ether, NPE,
Diethanolamine, triethanolamine, acrylic acid-acrylamide copolymer, polyoxyethylene ether one or more.
As further scheme, organic/inorganic acid of the present invention selected from chromic acid, boric acid, phosphoric acid, hydrochloric acid, sulphuric acid,
One or more in oxalic acid, acetic acid.
As further scheme, silicone oil of the present invention selected from methyl-silicone oil, methylhydroxy silicone oil, amido silicon oil,
One or more in linear silicone oils, modified silicon oil, silicon oil of low hydrogen content, high containing hydrogen silicone oil.
As further scheme, component A of the present invention is 1:(1-3 with the mass ratio of B component).
A kind of preparation method of ceramic tile antilubricant, this preparation method comprises the following steps:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
The ceramic tile antilubricant of the present invention application in the anti-skidding process of ceramic brick surface of super clean bright polishing, wherein
Component A is 1:(1-3 with the mass ratio of B component).
Compared to existing technology, the beneficial effects of the present invention is:
Ceramic tile antilubricant the most of the present invention is for carrying out anti-skidding process to ceramic tile surface, and have concurrently is anti-skidding and antifouling
Effect, simplifies ceramic tile surface anti-skidding process technique simultaneously；
Component A and B component in ceramic tile antilubricant the most of the present invention are independently packed, in use according to one
Fixed ratio mixing, can be used for the anti-skidding process of ceramic brick surface of super clean bright polishing.
Below in conjunction with detailed description of the invention, the present invention is described in further detail.
Detailed description of the invention
Ceramic tile antilubricant of the present invention, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Organic or inorganic acid 5%-50%,
Dispersion stabilizer 0.1%-1%,
Water surplus；
B component includes following component by weight percentage:
Silicone oil 0.5%-50%,
Silane coupler 0.5%～10%,
Dispersion stabilizer 0.1%～1%,
Emulsifying agent 0.1-1%
Water surplus.
As further scheme, silane coupler of the present invention is selected from sodium methyl silicate, methyl trimethoxy epoxide silicon
One or more in alkane, MTES and methyl triacetoxysilane.
As further scheme, dispersion stabilizer of the present invention is amine ether type monomer or copolymerization, is selected from
Ethylene glycol, butyl glycol ether, diethylene glycol dimethyl ether, isomerous tridecanol polyoxyethylene ether, NPE,
Diethanolamine, triethanolamine, acrylic acid-acrylamide copolymer, polyoxyethylene ether one or more.
As further scheme, organic/inorganic acid of the present invention selected from chromic acid, boric acid, phosphoric acid, hydrochloric acid, sulphuric acid,
One or more in oxalic acid, acetic acid.Consider cost and environmental friendliness, in the present invention, it is preferred to organic/inorganic acid be
Oxalic acid or acetic acid.
In the present invention, it is good that the silicone oil in B component has good chemical stability, insulating properties and hydrophobic performance, and has
There is less surface tension.As further scheme, silicone oil of the present invention selected from methyl-silicone oil, methylhydroxy silicone oil,
One or more in amido silicon oil, linear silicone oils, modified silicon oil, silicon oil of low hydrogen content, high containing hydrogen silicone oil.
As further scheme, component A of the present invention is 1:(1-3 with the mass ratio of B component).
A kind of preparation method of ceramic tile antilubricant, this preparation method comprises the following steps:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
The ceramic tile antilubricant of the present invention application in the anti-skidding process of ceramic brick surface of super clean bright polishing, wherein
Component A is 1:(1-3 with the mass ratio of B component).In the process of surface treatment of Ceramic Tiles, initially with component A to ceramic watch
Face carries out anti-skidding process, uses B component to process the most again, makes Ceramic Tiles have anti-fouling effect.
The following is specific embodiment of the present invention, in the following embodiments, the raw material, the reagent that are used all can be by purchasing
Buyer's formula obtains.Embodiment 1
A kind of ceramic tile antilubricant, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Oxalic acid 50%
Diethanolamine 1%
Water surplus；
B component includes following component by weight percentage:
Methyl-silicone oil 0.5%
MTMS 1% emulsifying agent 0.1%
Water surplus.
Its preparation method is as follows:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
Embodiment 2
A kind of ceramic tile antilubricant, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Acetic acid 49%
Butyl glycol ether 1%
Water surplus；
B component includes following component by weight percentage:
Methyl-silicone oil 45%
MTMS 5%
Polyoxyethylene ether 0.1%
Emulsifying agent 1%
Water surplus；
Its preparation method is as follows:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
Embodiment 3
A kind of ceramic tile antilubricant, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Sulphuric acid 5%
Triethanolamine 1%
Water surplus；
B component includes following component by weight percentage:
Amido silicon oil 25%
MTMS 5%
Triethanolamine 1%
Emulsifying agent 1%
Water surplus；
Its preparation method is as follows:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
Embodiment 4
A kind of ceramic tile antilubricant, is made up of component A and B component, wherein
Component A includes following component by weight percentage:
Phosphoric acid 25%
Triethanolamine 0.5%
Water surplus；
B component includes following component by weight percentage:
Amido silicon oil 50 parts
MTMS 10%
Triethanolamine 0.1%
Emulsifying agent 0.1%
Water surplus；
Its preparation method is as follows:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
Application Example 1
Use the ceramic tile antilubricant described in embodiment 1 that the Ceramic Tiles through super clean bright polishing is processed, first use A
Component carries out anti-skidding process to ceramic brick surface, then shows to carry out antifouling process to Ceramic Tiles by B component；Wherein component A and B
The mass ratio of component is 1:1.
Application Example 2
The ceramic tile antilubricant described in embodiment 1 is used to process, the Ceramic Tiles through super clean bright polishing first by A
Component and B component mixing, then show Ceramic Tiles to carry out antifouling process；Wherein component A is 1:2 with the mass ratio of B component.
Application Example 3
The ceramic tile antilubricant described in embodiment 1 is used to process, the Ceramic Tiles through super clean bright polishing first by A
Component and B component mixing, then show Ceramic Tiles to carry out antifouling process；Wherein component A is 1:3 with the mass ratio of B component.
Skidproof effect and the anti-fouling effect of the Ceramic Tiles after the process of Application Example 1-3 are shown in Table 1.
Table 1
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limit the scope of protection of the invention with this,
The change of any unsubstantiality that those skilled in the art is done on the basis of the present invention and replacement belong to institute of the present invention
Claimed scope.
Claims (8)
1. a ceramic tile antilubricant, it is characterised in that be made up of component A and B component, wherein
Component A includes the following component in terms of percetage by weight percent:
Organic or inorganic acid 5%-50%,
Dispersion stabilizer 0.1%-1%,
Water surplus；
B component includes following component by weight percentage:
Silicone oil 0.5%-50%,
Silane coupler 0.5%～10%,
Dispersion stabilizer 0.1%～1%,
Emulsifying agent 0.1-1%,
Water surplus.
Ceramic tile antilubricant the most according to claim 1, it is characterised in that described silane coupler is selected from methane-siliconic acid
One or more in sodium, MTMS, MTES and methyl triacetoxysilane.
3. the ceramic tile antilubricant stated according to claim 1, it is characterised in that described dispersion stabilizer selected from ethylene glycol,
Butyl glycol ether, diethylene glycol dimethyl ether, isomerous tridecanol polyoxyethylene ether, NPE, diethanolamine, three
Ethanolamine, acrylic acid-acrylamide copolymer, polyoxyethylene ether one or more.
4. according to the ceramic tile antilubricant described in any one of claim 1-3, it is characterised in that described organic/inorganic acid is selected from
One or more in chromic acid, boric acid, phosphoric acid, hydrochloric acid, sulphuric acid, oxalic acid, acetic acid.
5. according to the ceramic tile antilubricant described in any one of claim 1-3, it is characterised in that described silicone oil is selected from methyl silicon
One or two in oil, methylhydroxy silicone oil, amido silicon oil, linear silicone oils, modified silicon oil, silicon oil of low hydrogen content, high containing hydrogen silicone oil
More than Zhong.
6. according to the ceramic tile antilubricant described in any one of claim 1-3, it is characterised in that described component A and the matter of B component
Amount ratio is 1:(1-3).
7. the preparation method of a ceramic tile antilubricant as claimed in claim 1, it is characterised in that this preparation method include with
Lower step:
1) preparation of component A: each composition in component A is proportionally mixed, stirs, obtain component A；
2) each composition in B component is proportionally mixed by the preparation of B component, stirs, obtains B component；
3) component A obtained and B component are independently packed.
8. the answering in the anti-skidding process of ceramic brick surface of super clean bright polishing of the ceramic tile antilubricant as described in claim 1-3
With, it is characterised in that wherein component A is 1:(1-3 with the mass ratio of B component).
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| CN201610442790.8A CN106118456B (en) | 2016-06-17 | 2016-06-17 | Anti-slip agent for ceramic tiles and preparation method and application thereof |
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| CN201610442790.8A CN106118456B (en) | 2016-06-17 | 2016-06-17 | Anti-slip agent for ceramic tiles and preparation method and application thereof |
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| CN106118456B CN106118456B (en) | 2018-11-27 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201161A (en) * | 2017-06-28 | 2017-09-26 | 安徽爱弥儿环境科技有限公司 | A kind of anti-skid intensifier for smooth brick masonry surface and preparation method thereof |
| CN107325788A (en) * | 2017-06-13 | 2017-11-07 | 上海世卿防滑防护科技有限公司 | A kind of preparation method of floor tile antilubricant |
| CN107325790A (en) * | 2017-07-28 | 2017-11-07 | 河北畅步地面防滑工程技术有限公司 | A kind of anti-skidding agent prescription of floor tile and preparation method |
| CN107476528A (en) * | 2017-06-09 | 2017-12-15 | 信益陶瓷(中国)有限公司 | A kind of super clean bright on-slip brick and its manufacture method |
| CN107880848A (en) * | 2017-10-25 | 2018-04-06 | 刘彦麟 | A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method |
| CN109251058A (en) * | 2018-09-28 | 2019-01-22 | 佛山市善益科技有限公司 | A kind of ceramic tile antilubricant and preparation method thereof |
| CN109437972A (en) * | 2018-10-29 | 2019-03-08 | 李登科 | On-slip agent and preparation method thereof |
| CN109705811A (en) * | 2018-12-20 | 2019-05-03 | 上海地宝防滑防护科技有限公司 | A kind of safety and environmental protection resistant antilubricant and preparation method thereof |
| CN111944485A (en) * | 2020-09-14 | 2020-11-17 | 安徽双虹化工科技有限公司 | Ceramic tile surface anti-slip agent and preparation method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN113004868A (en) * | 2021-02-26 | 2021-06-22 | 郝士军 | Anti-slip agent and preparation method thereof |
| CN113636870A (en) * | 2021-07-13 | 2021-11-12 | 广东富强陶瓷有限公司 | Production process of antibacterial wear-resistant anti-skid glazed ceramic tile |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107476528A (en) * | 2017-06-09 | 2017-12-15 | 信益陶瓷(中国)有限公司 | A kind of super clean bright on-slip brick and its manufacture method |
| CN107325788A (en) * | 2017-06-13 | 2017-11-07 | 上海世卿防滑防护科技有限公司 | A kind of preparation method of floor tile antilubricant |
| CN107201161A (en) * | 2017-06-28 | 2017-09-26 | 安徽爱弥儿环境科技有限公司 | A kind of anti-skid intensifier for smooth brick masonry surface and preparation method thereof |
| CN107325790B (en) * | 2017-07-28 | 2019-05-10 | 河北畅步地面防滑工程技术有限公司 | A kind of preparation method of floor tile antilubricant |
| CN107325790A (en) * | 2017-07-28 | 2017-11-07 | 河北畅步地面防滑工程技术有限公司 | A kind of anti-skidding agent prescription of floor tile and preparation method |
| CN107880848A (en) * | 2017-10-25 | 2018-04-06 | 刘彦麟 | A kind of floor tile decontamination antilubricant and floor tile decontaminate anti-skidding method |
| CN109251058A (en) * | 2018-09-28 | 2019-01-22 | 佛山市善益科技有限公司 | A kind of ceramic tile antilubricant and preparation method thereof |
| CN109437972A (en) * | 2018-10-29 | 2019-03-08 | 李登科 | On-slip agent and preparation method thereof |
| CN109705811A (en) * | 2018-12-20 | 2019-05-03 | 上海地宝防滑防护科技有限公司 | A kind of safety and environmental protection resistant antilubricant and preparation method thereof |
| CN111944485A (en) * | 2020-09-14 | 2020-11-17 | 安徽双虹化工科技有限公司 | Ceramic tile surface anti-slip agent and preparation method thereof |
| CN112063299A (en) * | 2020-09-27 | 2020-12-11 | 广东粤固建材科技有限公司 | Ceramic tile antifouling agent and preparation method thereof |
| CN113004868A (en) * | 2021-02-26 | 2021-06-22 | 郝士军 | Anti-slip agent and preparation method thereof |
| CN113636870A (en) * | 2021-07-13 | 2021-11-12 | 广东富强陶瓷有限公司 | Production process of antibacterial wear-resistant anti-skid glazed ceramic tile |
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| CN106118456B (en) | 2018-11-27 |
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Address after: 526000 No.7 Fenggang Road, high tech Zone, Zhaoqing City, Guangdong Province Patentee after: GUANGDONG NADE NEW MATERIALS Co.,Ltd. Address before: 528000 Shishan muyuan, Nanhai District, Foshan City, Guangdong Province:Jin Zigang) 528000 Shishan muyuan, Nanhai District, Foshan City, Guangdong Province Patentee before: GUANGDONG NADE NEW MATERIALS Co.,Ltd. |