CN106497473A - A kind of environment protection type single-component vitrified brick gum and preparation method thereof - Google Patents
A kind of environment protection type single-component vitrified brick gum and preparation method thereof Download PDFInfo
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- CN106497473A CN106497473A CN201610921468.3A CN201610921468A CN106497473A CN 106497473 A CN106497473 A CN 106497473A CN 201610921468 A CN201610921468 A CN 201610921468A CN 106497473 A CN106497473 A CN 106497473A
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- type single
- environment protection
- component
- vitrified brick
- protection type
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a kind of environment protection type single-component vitrified brick gum and preparation method thereof, the percentage by weight of each component of the vitrified brick gum is：Emulsion 60%～80%, waterproofing agent 10%～20.5%, adhesive 7%～13%, dispersant 0.2%～0.7%, defoamer 0.2%～0.6%, preservative 0.3%～0.6%, modifying agent 1.5%～5%.A kind of environment protection type single-component vitrified brick gum proposed by the present invention, the bonding for fully achieving vitrified tile require, efficiently solve occur when vitrified tile bonds hollowing, the problems such as flake, come off, and it is simple to construct, have the advantages that environmental protection, with low cost.The emulsion that aqueous epoxy resin emulsion and carboxylic styrene butadiene latex by solid content more than 50% is mixed into is mixed with other components, realize that the solid content of gum reaches 50%～55%, limit so as to meet increasingly strict VOC, also so that gum shows high cohesive force.
Description
Technical field
The invention belongs to building material field, more particularly, to a kind of environment protection type single-component vitrified brick gum.
Background technology
High water absorbing capacity that at present, the internal and external ornament of home decoration, large-scale club, supermarket and building is adopted (5%～
10%) pottery brick, its low intensity, style are single, specification is little, thus have been not suitable for the market demand of high speed development；With
This simultaneously, vitrified tile has the advantages that low water suction, intensity high, specification and wide in variety because of which, has been widely used in building dress
Decorations market.
Vitrified tile is fired according to a certain percentage and is formed by quartz sand, mud, then through polishing bright but need not polish, its
Surface is smooth bright as glass-mirror.Which is better than general at aspects such as water absorption rate, straightness of sides, bending strength, resistance to acids and bases
Logical glazed tile, polished bricks and general marble.Vitrified tile is a kind of good ornament materials, for interior decoration, with very
Good decorative effect.But as the water absorption rate of vitrified tile itself is less than 5 ‰ so which is very tired when pasting to cement layer surface
Difficult.Vitrified brick gum can effectively improve the adhesion strength at the vitrified tile back side and cement layer surface, be maximally effective interface at present
Bond enhancing material.
At present, the vitrified brick gum on market is various in style, and a part of vitrified brick gum is by dry powder component and liquid group
Point two parts composition, during use, dry powder component and liquid component are mixed and stirred according to a certain percentage, for paving ceramic tile, vitrified tile,
The back side of the ornament materials such as floor tile, but the synthetic of this double-component will be mixed in strict accordance with the ratio of dry powder and liquid portion
With, there is certain requirement to preparation condition, and in-convenience in use；Some vitrified brick gum typically with natural rubber is
Raw material and cement class adhesive is adopted, the vitrified brick gum with natural rubber as raw material usually contains formaldehyde, high cost, toxicity
Height, in addition preparation condition also have corresponding requirement, not economical and practical enough, be a kind of using the vitrified brick gum of cement class adhesive
Response type polymer cement sill, have the advantages that with low cost, but bonding force decreases, and hollowing easily occurs existing
As causing swivel to come off, especially in vibration and stabilization transform, easily flaking and peel off.
Content of the invention
It is contemplated that at least solving one of technical problem present in prior art.For this purpose, the present invention proposes a kind of ring
Guarantor's type one pack system vitrified brick gum and preparation method thereof, the present invention is achieved by the following technical solutions：
On the one hand, the present invention provides a kind of environment protection type single-component vitrified brick gum, each component of the vitrified brick gum
Percentage by weight is：Emulsion 60%～80%, waterproofing agent 10%～20.5%, adhesive 7%～13%, dispersant 0.2%～
0.7%, defoamer 0.2%～0.6%, preservative 0.3%～0.6%, modifying agent 1.5%～5%.
Further, the emulsion is aqueous epoxy resin emulsion and the mixture of carboxylic styrene butadiene latex, the aqueous ring
Oxygen tree fat liquor is EP-44 aqueous epoxy resin emulsions, and the carboxylic styrene butadiene latex is that Shanghai Gaoqiao BASF dispersion is limited
The SD35Sap carboxylic styrene butadiene latexs of company.
Further, the waterproofing agent is the mixture of raw lacquer and tung oil.
Further, described adhesive is that cornstarch and the mixture of silicone acrylic emulsion, the mesh number of the cornstarch are
1900～2100 mesh, SD-528 silicone acrylic emulsion of the silicone acrylic emulsion for Nantong Shengda Chemical Co., Ltd..
Further, the defoamer be BYK1740 defoamers, the preservative be water paint preservative, described point
Powder is 9040 dispersants of Hydropalat.
Further, A-151 silane coupler of the modifying agent for U.S. combinating carbide company.
On the other hand, present invention also offers a kind of method for preparing environment protection type single-component vitrified brick gum, including as follows
Step：
A, the emulsion for putting into 60%～80% in agitating device；
B, successively in agitating device input 0.2%～0.7% dispersant, 0.1%～0.3% defoamer, 0.3%
～0.6% preservative, 10%～20.5% waterproofing agent, stir；
C, the adhesive of input 7%～13%, 0.1%～0.3% defoamer and 1.5%～5% modification in device
Agent, stirs, and obtains final product environment protection type single-component vitrified brick gum.
A kind of environment protection type single-component vitrified brick gum proposed by the present invention, fully achieves the bonding requirement of vitrified tile,
Vitrified tile is posted on different base materials, efficiently solve vitrified tile bond when occur hollowing, flake, come off
Problem, and it is simple to construct；Aqueous epoxy resin emulsion and carboxylic styrene butadiene latex by solid content more than 50% is mixed into
Emulsion mix with other components, realize that the solid content of gum reaches 50%～55%, so as to meet increasingly strict VOC limits
System, also so that gum shows high cohesive force, while also simplify construction procedure；Silicon third breast of the solid content more than 48%
The adhesive that liquid and cornstarch are mixed, the adhesive are mixed based on environment-friendly materials, further increase gum
Environmental protection characteristic, also enhance the viscosity of gum, improve the tensile strength of gum；By raw lacquer and tung oil both natural liquids
Prepared environment-friendly type waterproofing agent, improves the performance of the water-fast of gum, humidity；BYK1740 defoamers are can be with without VOC
Biodegradable defoamer.The preparation method of the environment protection type single-component gum that the present invention is provided, by the preparation technology to gum
In feeding sequence and ingredient proportion control so that in preparation process, the mixture in each stage is uniformly mixed and fully divides
Dissipate, so as to improve the stability of gum.
Specific embodiment
With reference to the invention that embodiment further illustrates the application, but embodiment is not construed as the limit to right of the present invention
Fixed.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " illustrative examples ",
The description of " example ", " specific example " or " some examples " etc. means specific features, the knot described with reference to the embodiment or example
Structure, material or feature are contained at least one embodiment or example of the present invention.In this manual, to above-mentioned term
Schematic representation is not necessarily referring to identical embodiment or example.And, the specific features of description, structure, material or spy
Point can be combined in any one or more embodiments or example in an appropriate manner.
Embodiment 1～5
Embodiment 1～5 provides a kind of environment protection type single-component vitrified brick gum, the weight of each component of the vitrified brick gum
Amount degree is as shown in table 1；
The method for preparing the gum comprises the steps：
A, the emulsion for putting into 60%～80% in agitating device；
B, successively in agitating device input 0.2%～0.7% dispersant, 0.1%～0.3% defoamer, 0.3%
～0.6% preservative, 10%～20.5% waterproofing agent, stir；
C, the adhesive of input 7%～13%, 0.1%～0.3% defoamer and 1.5%～5% modification in device
Agent, stirs, and obtains final product environment protection type single-component vitrified brick gum.
Table 1
Embodiment 6
Performance test is carried out to vitrified brick gum obtained in above-described embodiment 1～5, with reference to JC/T547-2005《Ceramic wall
Floor tile adhesive》Criterion performance test is carried out to vitrified brick gum, its result is as shown in table 2：
Knowable to embodiment 6, a kind of environment protection type single-component vitrified brick gum proposed by the present invention fully achieves vitreous
The bonding of brick requires, vitrified tile is posted on different base materials, efficiently solve the sky occurred when vitrified tile bonds
The problems such as rousing, flake, coming off, and it is simple to construct, have the advantages that environmental protection, with low cost.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that：Not
These embodiments can be carried out with multiple changes, modification, replacement and modification in the case of the principle and objective that depart from the present invention, this
The scope of invention is limited by claim and its equivalent.
Claims (7)
1. a kind of environment protection type single-component vitrified brick gum, it is characterised in that the weight percent of each component of the vitrified brick gum
Than for：Emulsion 60%～80%, waterproofing agent 10%～20.5%, adhesive 7%～13%, dispersant 0.2%～0.7% disappear
Infusion 0.2%～0.6%, preservative 0.3%～0.6%, modifying agent 1.5%～5%.
2. a kind of environment protection type single-component vitrified brick gum according to claim 1, it is characterised in that the emulsion is aqueous
Epoxy resin latex and the mixture of carboxylic styrene butadiene latex, the aqueous epoxy resin emulsion are EP-44 aqueous epoxy resins breast
Liquid, SD35Sap carboxylic styrene butadiene latex of the carboxylic styrene butadiene latex for Shanghai Gaoqiao BASF dispersion Co., Ltd.
3. a kind of environment protection type single-component vitrified brick gum according to claim 1, it is characterised in that the waterproofing agent is made a living
Paint and the mixture of tung oil.
4. a kind of environment protection type single-component vitrified brick gum according to claim 1, it is characterised in that described adhesive is jade
Rice starch and the mixture of silicone acrylic emulsion, the mesh number of the cornstarch is 1900～2100 mesh, and the silicone acrylic emulsion is Nantong
The SD-528 silicone acrylic emulsions of Sheng Da Chemical Co., Ltd.s.
5. a kind of environment protection type single-component vitrified brick gum according to claim 1, it is characterised in that the defoamer is
BYK1740 defoamers, the preservative are water paint preservative, and the dispersant is 9040 dispersants of Hydropalat.
6. a kind of environment protection type single-component vitrified brick gum according to claim 1, it is characterised in that the modifying agent is U.S.
The A-151 silane couplers of Union Carbide Corporation of state.
7. a kind of method for preparing the arbitrary described environment protection type single-component vitrified brick gum of claim 1 to 6, it is characterised in that
Comprise the steps：
A, the emulsion for putting into 60%～80% in agitating device；
B, successively in agitating device input 0.2%～0.7% dispersant, 0.1%～0.3% defoamer, 0.3%～
0.6% preservative, 10%～20.5% waterproofing agent, stir；
C, the adhesive, 0.1%～0.3% defoamer and 1.5%～5% modifying agent that put into 7%～13% in device, stir
Mix uniformly, obtain final product environment protection type single-component vitrified brick gum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921468.3A CN106497473B (en) | 2016-10-21 | 2016-10-21 | A kind of environment protection type single-component vitrified brick gum and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921468.3A CN106497473B (en) | 2016-10-21 | 2016-10-21 | A kind of environment protection type single-component vitrified brick gum and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106497473A true CN106497473A (en) | 2017-03-15 |
| CN106497473B CN106497473B (en) | 2019-06-04 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916554A (en) * | 2017-04-28 | 2017-07-04 | 湖北碱克新材料有限公司 | A kind of one pack system vitrified brick gum |
| CN107033821A (en) * | 2017-04-28 | 2017-08-11 | 湖北碱克新材料有限公司 | A kind of new vitrified brick gum |
| CN108676522A (en) * | 2018-06-11 | 2018-10-19 | 刘晓辰 | Novel vitrified brick gum |
| CN108977125A (en) * | 2018-08-13 | 2018-12-11 | 天津市科垣新型建材有限公司 | A kind of strength cross-linking type ceramic tile gum |
| CN108997954A (en) * | 2018-08-11 | 2018-12-14 | 安徽华祺汽车装饰有限公司 | A kind of adhesive for automobile internal decoration and preparation method thereof |
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| CN101701138A (en) * | 2009-11-19 | 2010-05-05 | 夏良强 | Cohesive glue for flexible decorative tile and manufacturing method thereof |
| CN101888983A (en) * | 2007-11-20 | 2010-11-17 | 阿格拉纳斯塔克有限公司 | Building material compositions |
| CN103396045A (en) * | 2013-07-24 | 2013-11-20 | 黄继军 | Environment-friendly ecological brick and production method thereof |
| CN105238307A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Soundproof adhesive with high adhesion stress |
| CN105969308A (en) * | 2016-06-27 | 2016-09-28 | 浙江共创建材科技有限公司 | Eco-friendlyceramic tilegum for vitrified tiles |
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Patent Citations (5)
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| CN101888983A (en) * | 2007-11-20 | 2010-11-17 | 阿格拉纳斯塔克有限公司 | Building material compositions |
| CN101701138A (en) * | 2009-11-19 | 2010-05-05 | 夏良强 | Cohesive glue for flexible decorative tile and manufacturing method thereof |
| CN103396045A (en) * | 2013-07-24 | 2013-11-20 | 黄继军 | Environment-friendly ecological brick and production method thereof |
| CN105238307A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Soundproof adhesive with high adhesion stress |
| CN105969308A (en) * | 2016-06-27 | 2016-09-28 | 浙江共创建材科技有限公司 | Eco-friendlyceramic tilegum for vitrified tiles |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916554A (en) * | 2017-04-28 | 2017-07-04 | 湖北碱克新材料有限公司 | A kind of one pack system vitrified brick gum |
| CN107033821A (en) * | 2017-04-28 | 2017-08-11 | 湖北碱克新材料有限公司 | A kind of new vitrified brick gum |
| CN108676522A (en) * | 2018-06-11 | 2018-10-19 | 刘晓辰 | Novel vitrified brick gum |
| CN108997954A (en) * | 2018-08-11 | 2018-12-14 | 安徽华祺汽车装饰有限公司 | A kind of adhesive for automobile internal decoration and preparation method thereof |
| CN108977125A (en) * | 2018-08-13 | 2018-12-11 | 天津市科垣新型建材有限公司 | A kind of strength cross-linking type ceramic tile gum |
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| Publication number | Publication date |
|---|---|
| CN106497473B (en) | 2019-06-04 |
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